JEE MAIN-2020

07-01-2020 SHIFT -2
CHEMISTRY SOLUTIONS
CONTACT FOR ONLINE CLASSES (CRASH COURSE) JEE & NEET
MAHESH
8247475215
 SECTION – 1 : (Maximum Marks : 80)
OBJECTIVE TYPE
This section contains 20 multiple choice questions. Each question has 4 choices (1), (2), (3) and (4) for its
answer, out of which Only One is correct.
1. Which of the following reactions are possible ?
Cl

(A) Anhy. AlCl3

+ 

Cl
Cl Cl
(B) + Cl2(excess) AlCl3
Dark
Cl Cl
Cl
CH=CH2
(C) Anhy. AlCl3
+ CH2=CH–Cl 

CH2–CH=CH2
(D) Anhy. AlCl3
+ CH2=CH–CH2–Cl 

(1) A, B, C (2) B, D (3) A, C, D (4) A, C

Ans. (2)
Sol. Vinyl halides and aryl halides do not give Friedel craft's reaction.

2. A and B are in the given reaction ?

NH2

Ac2O Br
2
A AcOH B

CH3
NHCOCH3 NHCOCH3 NHCOCH3 NH–COCH3
Br Br COCH3

(1) (2) Br (3) (4)

CH3 CH3 CH2Br CH2–Br
Ans. (1)
O O
Sol.
NH2 NH–C–CH3 NH–C–CH3
Br
Ac2O Br2
AcOH

CH3 CH3 CH3

3. The correct statement about gluconic acid is

(1) It is prepared by oxidation of glucose with HNO3
(2) It is obtained by partial oxidation of glucose
(3) It is dicarboxylic acid
(4) It forms hemiactal or acetal
Ans. (2)
CH2–CH–CH–CH–CH–COOH
Sol. Gluconic acid is obtained by partial oxidation of glucose by Tollen's
OH OH OH OH OH

reagent or Fehling solution or Br2,H2O.

Gluconic acid can not form hemiacetal or acetal
4. Stability order of following alkoxide ions is

NO2 NO2
O2N

O– O– O–
(A) (B) (C)

(1) C > B > A (2) A > C > B (3) B > A > C (4) C > A > B
Ans. (1)
Sol. When negative charge is delocalised with electron withdrawing group like (NO 2) then stability increases.
(A) Negative charge is delocalised with NO2 group
(B) Negative charge is delocalised with carbon of alkene
(C) Negative charge is localised

O
HBr Na
A B
5.  Ether
CH2–Br 
A and B are –

Br Br Br Br

(1) OH & (2) OH

&
CH2Br O CH2Br

OH OH OH OH

(3*) Br (4) Br
& &
CH2Br CH2Br
Ans. (3)
H +
O OH
O OH
Sol. HBr Br
Br Na, ether
(SN2)
CH2–Br CH2–Br Wurtz reaction
CH2–Br

6. For the complex [Ma2b2] if M is sp3 or dsp2 hybridised respectively then total number of optical isomers
are respectively :
(1) 1, 1 (2) 2, 1 (3) 0, 0 (4) 1, 2
Ans. (3)
Sol. Both will not show optical isomerism. due to plane of symmetry

7. Bond order and magnetic nature of CN– are respectively

(1) 3, diamagnetic (2) 3, paramagnetic
(3) 2.5, paramagnetic (4) 2.5, diamagnetic
Ans. (1)
Sol. CN– is a 14 electron system.

8. Which of the following is incorrect?

       
(1) m NaCl  m NaBr  m KCl  m KBr (2) m H2O  m HCl  m NaOH  m NaCl
       
(3) m Nal  m NaBr  m NaBr  m KBr (4) m NaCl  m KCl  m NaBr  m KBr
Ans. (3)
Sol. Refer Kohlraushs Law
 9. NaOH  Cl2  A + other products
Hot & conc.

Ca(OH)2  Cl2  B + other products

Cold & dil.

A & B are respectively

(1) NaClO3, Ca(OCl)2 (2) NaClO3, Ca(ClO3)2
(3) NaCl, Ca(ClO3)2 (4) NaClO, Ca(ClO3)2

Ans. (1)
Sol. 6NaOH + 3Cl2 5NaCl + NaClO3 + 3H2O
2Ca(OH)2 + Cl2 Ca(OCl)2 + CaCl2 + H2O
10. There are two beakers (I) having pure volatile solvent and (II) having volatile solvent and non-volatile
solute. If both beakers are placed together in a closed container then:
(1) Volume of solvent beaker will decrease and solution beaker will increase
(2) Volume of solvent beaker will increase and solution beaker will also increase
(3) Volume of solvent beaker will decrease and solution beaker will also decrease
(4) Volume of solvent beaker will increase and solution beaker will decrease
Ans. (1)
Sol. There will be lowering in vapour pressure in second beaker.
11. Metal with low melting point containing impurities of high melting point can be purified by
(1) Zone refining (2) Vapor phase refining
(3) Distillation (4) Liquation
Ans. (4)
Sol. Refer ncert ISOLATION OF ELEMENTS(Purification)

12. Which of the following statements are correct ?

(I) On decomposition of H2O2, O2 gas is released .
(II) 2-ethylanthraquinol is used in preparation of H2O2
(III) On heating KClO3, Pb(NO3)2, NaNO3, O2 gas is released.
(IV) In the preparation of sodium peroxoborate, H2O2 is treated with sodium metaborate.
(1) I, II, IV (2) II, III, IV (3) I, II, III, IV (4) I, II, III
Ans. (3)
Sol. I and II are from preparation of Hydrogen peroxide

13. Amongs the following which is redox reaction ?

(1) N2 + O2 
2000K
 (2) Formation of O3 from O2
(3) Reaction between NaOH and H2SO4 (4) Reaction between AgNO3 and NaCl
Ans. (1)
Sol. N2 + O2 2NO
3O2 2O3
2NaOH + H2SO4 Na2SO4 + 2H2O
AgNO3 + NaCl NaNO3 + AgCl

A
B
No. of
14. C
Molecules

Speed
Select the correct options :
(1) A = CMPS, B = CAverage, C = CRMS (2) A = CAverage, B = CMPS, C = CRMS
(3) A = CRMS, B = CAverage, C = CMPS, (4) A = CAverage, B = CMPS, C = CRMS
Ans. (1)
Sol. CRMS > CAvg > CMPS
15. Which one of the following amongs each pair will release maximum energy on gaining one electron
(A = F, Cl), (B = S, Se), (C = Li, Na)
(1) (A) = Cl, (B) = S, (C) = Li (2) (A) = S, (B) = Cl, (C) = Li
(3) (A) = Li, (B) = Cl, (C) = S (4) (A) = Cl, (B) = Li, (C) = S
Ans. (1)
Sol. refer electron gain enthalpies in respective groups

16. Which of the following statements are incorrect ?

(A) Co+3 with strong field ligand forms high magnetic moment complex.
(B) For Co+3 if pairing energy(P) > o then the complex formed will have t 2g
4
,eg2 configuration
(C) For [Co(en)3]3+ absorbed is less than absorbed for [CoF6]3–
(D) If o = 18000 cm–1 for Co+3 then with same ligands for it t = 16000 cm–1
(1) A, D (2) B, C (3) A, B (4) A, B, C, D
Ans. (1)
Sol. Refer Crystal field theory
17. 0.6 g of urea on strong heating with NaOH evolves NH3. Liberated NH3 will combine completely with
which of the following HCl solution ?
(1) 100 mL of 0.2 N HCl (2) 400 mL of 0.2 N HCl
(3) 100 mL of 0.1 N HCl (4) 200 mL of 0.2 N HCl
Ans. (1)
Sol. 2 × mole of Urea  mole of NH3 ........(1)
mole of NH3 = mole of HCl ........(2)
 mole of HCl = 0.02 mole

NUMERICAL TYPE
21. Number of sp hybrid carbon atoms in aspartame is –
2

Ans. 9
O O O
Sol.
HO–C–CH2–CH–C–NH–CH–C–OCH3
* * *
NH2 CH2
* *
*
* *
*
All starred carbon atoms of aspartame are sp2 hybrid. Aspartame is methyl ester of dipeptide formed
from aspartic acid and phenylalanine.

22. 3 gram of acetic acid is mixed in 250 mL of 0.1 M HCl. This mixture is now diluted to 500 mL. 20 mL of
1
this solution is now taken is another container mL of 5M NaOH is added to this. Find the pH of this
2
solution. Find the pH of this solution. (log 3 = 0.4771, pKa = 4.74)

Ans. 5.22
Sol. m mole of acidic acid in 20 mL = 2
m mole of HCl in 20 mL = 1
m mole of NaOH = 2.5
CH3COOH + NaOH (remaining)  CH3COONa + water
2 3/2 0 0
0.5 0 3/2 -
3/2
pH = PKa + log
2
= 4.74 + log 3
= 4.74 + 0.48 = 5.22
23. Flocculation value for As2S3 sol by HCl is 30 m mole L–1. Calcualte mass of H2SO4 required in gram for
250 mL sol.
Ans. 00.37
Sol. For 1L sol 30 m mol of HCl is required
 For 1L sol 15 m mol H2SO4 is required
For 250 mL of sol
15
 103 m mol H2SO4 0.3675 g
4

24. NaCl 

K 2Cr2O7 (s)
 (A) 
NaOH
 (B) 
dil.H2SO4
 (C)
Conc.H2SO4 H2O2

Determine total number of atoms in per unit formula of (A), (B) & (C)

Ans. 18.00
Sol. (A) = CrO2Cl2
(B) = Na2CrO4
(C) = CrO5
25. Calculate fH° (In kJ/mol) for C2H6(g), if cH° [C(graphite)] = –393.5 kJ/mol,
CHº [H2(g)] = –286 kJ/mol and
CHº [C6H6(g)] = –1560 kJ/mol

Ans. (–85.00)

Sol. C6H2(g) + 3.5O2(g)  2CO2(g) + 3H2O(l)

2 × (–393.5) + 3 × (–286) – (–1560) = –85 kJ/mol