NARAYANA IIT ACADEMY 12-01-20_Jr.

IIT-N-120_CTM-23_Qp
23. ‘n’ drops of water, each of radius 2 mm, fall through air at a terminal velocity of 8cms 1 . If
they coalesce to form a single drop, then the terminal velocity of the combined drop is
32cm s 1 . The value of ‘n’ is.
24. A rod of length 6 m has specific gravity 25/ 36 . One end of the rod is tied to a 5 m long rope,
which in turn is tied to the floor of a pool 10 m deep, as shown. Find the length (in m) of the
part of rod which is out of water.

25. A frog sits at one end of a long board of length L = 5m. The board rests on a frictionless
horizontal table. The frog wants to jump to the opposite end of the board. The minimum take-
off speed (in m/s) relative to ground ‘v’ that allows the frog to do the trick is n 5 . Find ‘n’.
(The board and the frog have equal masses).

CHEMISTRY Max Marks: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
26. Rank the following species in order of decreasing nucleophilicity in a polar protic solvent (most
 least nucleophilic)
O
||
CH 3 CH 2 CH 2O  CH 3 CH 2 CH 2 S  CH 3 CH 2 C  O 
1  2  3
A) 3 > 1 > 2 B) 2 > 3 > 1 C) 1 > 3 > 2 D) 2 > 1 > 3
27. Alkyl halides can be prepared by all the following methods except
ZnCl2
A) CH 3CH 2OH  HCl  g   
2 2 SO Cl .475 K
B) CH 3  CH  CH 2  

C) C2 H 5OH  NaCl 
CCl4 .Re flux
D) CH 3COOAg  Br2  

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
28.

Major product (A) is:

A) B)

C) H 2C  CH 2 D)

29. Select the correct product from the following

P1 and P2 are respectively

A) B)

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
C) D)

30. Yield of the reaction w.r.t to R-X here as shown below generally will follow the order
X 2 / hv
RCOOAg 
CCl4  R  X  CO2  AgX

A) 10  20  30 B) 30  20  10 C) 20  30  10 D) 30  10  20
31. Which of the following methods gives rise to 1-bromo-2-phenyl ethane ?
A) benzene + Oxirane + H  followed by reaction with HBr
B) benzene + Oxirane + H  followed by reaction with P / Br2
C) propene + HBr followed by reaction with benzene in the presence of AlCl3
D) styrene + H 3O  + followed by reaction with P / Br2
32. Which of the following alkyl halide is most reactive towards CH 3  OH ?

A) B) C) D)

33. Identify the principal organic product of the following reaction

A B C D

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
34.

Above reaction has maximum rate when

A) Y = -I B) Y = - Br C) Y = - Cl D) Y = - F
35.

A) C6 H 5OC2 H 5 B) C2 H 5OC2 H 5 C) C6 H 5OC6 H 5 D) C6 H 5 I

36.

The products of the above reaction are

A) B)

C) D)

37. Among the given halides, which one will give same product in both S N 1 and S N 2 reactions

A) III only B) I & II C) III & IV D) I, III & IV

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
38. Which of the following is a feasible reaction?
A)

B)

C)

D)

39. The reagent used to prepare alkyl fluorides from alkyl chlorides or alkyl bromides is,
A) BF3 B) HF C) SbF3 in HF D) F2
40. Arrange the following halides in decreasing order of reactivity in S N 1 reaction

A) II > III> IV > I B) IV > III > II > I C) III > IV > II > I D) I > II > III> IV

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
41.

A) B)

C) 1 : 1 mix of A and B D) 2 : 1 mix of A and B

42. CH 3CH 2 CH 2 OH  PBr3  A

CH 3CH 2CH 2 OH  Na  B , A  B  C
Product ‘C’ is
A)  CH 3CH 2CH 2 2 O B) CH 3  CH  CH 2
C) Both 1 & 2 D)  CH 3CH 2  2 O
43. Which of the following ether cannot be prepared by Williamson’s synthesis

A) B)

C) D) ALL

HI
44. P  Q  Anisole  RS
Correct statement among the following is
A) P and Q are C6 H 5ONa and C2 H 5Cl
B) R and S are C6 H 5 I and CH 3OH
C) R and S are C6 H 5OH and CH 3 I
D) P and Q are C6 H 5Cl and CH 3ONa

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NARAYANA IIT ACADEMY 12-01-20_Jr.IIT-N-120_CTM-23_Qp
45. When a mixture containing PCl3 and PCl5 is heated with ethyl alcohol total of 4 moles of ethyl
chloride is formed. Mole ratio of PCl3 and PCl5 in the mixture is
A) 3 : 1 B) 1 : 1 C) 1 : 3 D) 2 : 1
SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical values comprising of positive
or negative decimal numbers (place value ranging from Thousands Place to Hundredths Place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme: +4 for correct answer, 0 in all other cases.
46. The heat of vaporization of water and heat of fusion of ice are 540 cal/g and 80 cal/g. Then the
Svap
ratio of for water is (nearly)
S fus
47. Count the number of species which can act as Bronsted Lowry acid as well as base in
aqueous medium
H 2 PO4 , H 2 PO3 , H 2 PO2 , B  OH 3 , HS 


48. How many among the following aqueous solution can act as a buffer solution
i) 100 ml of 0.1M 3 CH COONa + 50 ml of 0.1M HCl
ii) 100 ml of 0.1M CH3COOH 50ml of 0.1 M NaOH
iii) 100 ml of 0.1 M Borax solution
iv) 100 ml of 1 M H 3 PO4  150 ml of 1M NaOH
v) 100 ml of 0.1 M NH 4Cl + 50 ml of 0.1 M NaOH
49. How many of the following ions have the same magnetic moments?
Fe2  , Mn2  , Cr 2  , Ni
50. How many of the following reactions are endothermic
i) CH 4  g   C  g   4 H  g  ii) C2 H 6  O2  CO2  g   H 2 O  l 
iii) Cl  g   e   Cl   g  iv) S   g   e  S 2   g 
v) Ne  g   e  Ne1  g  vi) N   g   e  N 2   g 

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