Professional Documents
Culture Documents
Solutions and Colligatives MHT CET Synopsis PDF
Solutions and Colligatives MHT CET Synopsis PDF
Solutions and Colligatives MHT CET Synopsis PDF
W1 (
p~ -
p~ --
PA ]
( 11) Elevation in boiling point:
L'. Tb = Kbm where, m = molality
Kb = Molal elevation in boiling point
W2
or L'.Tb = 1000 x Kb x - ~ - where , W 1 = Wt of solvent
W1 x M2
W2 = W of solute
M2 = Molar mass of solute
(12) Depression in freezing point:
Kr x l000 x W2
or
W1 x M2
(13) Van't Hoff equation:
1t = cRT or where, 1r = Osmotic pressure
n = no . of moles
(42)
So /11tio11s and Colligmfn, Pruperties 43
Concentration of Solutions
( 1) Percen tage bv m ass (W / W) = Mass of solu te x 100
' Mass of solution
No . of m oles of solute
(4) Molarity (M) = - - - - - - - - -
Volume of solution in dm 3
=; ) number of m oles of the solute
(..., Molality (mj = - - - - - - - - - --
m ass of solvent in kg
* Solubility of solute in solvent:
Solubili ty of solute is th e maximum amount of solute that dissolves compl etely in a given amount of solve nt at
a con s tan t temperature .
Solubility of Gases in Liquids
( l) Effect of change of temperature on solubility of gas:
(2 ) Effect of change of pressure on solubility of gases: S a P (H enry's law: Solubility of a gas in liquid a t
con stant te mpera ture is propo rti o n a l to th e pressure of the gas a bove th e solution) .
(3) Effect of addition of soluble salt on solubility of gas : Solubility of disso lved gas is s uppressed w hen a
solubl e sal t is a dd ed to th e s oluti o n of gc1s .
Solid Solutions
olid solution of two or more m c taJs or o f a m e ta l or m e tal s with o n e or more non -m e ta ls is cal led an alloy or
id solu tion .
. Stainless s tee l (Stee l + C r+ Ni) , Dura lumin (Al +Cu+ Mg+ Mn) , Spiege leise n, (5 -20% Mn in Iron) e tc.
Colligative Properties
• These are prope rties of solu tion th a t d e p e nd s o nly on t h e number of solute particles in the solutions a nd not on
the nature of t h e solu te particles. These a re :-
(a) Lowering of Vapour Pressure:
(1) Va pour pressure of liquid = Press u re exe rted by the gaseous state of that substance when it is in equation
with solid or Ii uid hase .
44
L·rram ·s .illfT-CET rChemi.sr,)
As m
-- - - - - - -- - - - - -~
r
I
w RT
IT½
w, RT
rcV = -2 - or TT½ = - --
,rV
IM>tonic solution: l\vo or more solution exerting th e same osmotic pressure.
I (iv)
Hypertonic solution: A solution havtng osmotic pressure higher than that of another solution.
I (V)
I
Hypotonic solution: A solution having osmotic pressurt> lower th an that of another solution.
(vi)
I (vii)
Laws of osmotic pressure:
van ·cHq_[f Boyle's law:
At constant T . TCV = constant
or TC = constant
C (in m o! L- 1 )
Van 't Ho.ff Charle's law:
TC
At constant C. T = constant
TC = ~ RT or 7t = CRT
V
(viii} van't Hoff - Avgadro's law:
Equal volumes of isotonic solution contains an equal number of solute particles at the given temperature.
Hence,
a = M (theoretical) - M (observed)
M (observed) (n' - 1)
• Relation between van 't Hoff factor and degree of aaaoclatlon:
a=~
1
1- -
n
000