Resonence® Educating for better tomorrow _JEE (Main) 2019 COMPUTER BASED TEST (CBT) Memory Based Questions & Solutions Date: 09 April, 2019 (SHIFT-1) | TIME: 09.30 A.M. to 12.30 P.M. Duration: 3 Hours | Max. Marks: 360 SUBJECT: CHEMISTRY Resonance Eduventures Ltd. Ragisnrea 8 corporate Of: CG Tony, A 5, Ast ry Manda oad ot Pa) 2008 ela Oa 620777, 0108, 01222 ss Tel 22) © O80 ‘eben omnatee acral conavtarare acy |GM: UPS OOTP G20A Resonsence” Educating for better tomorrow aay ANALG 05 WEEKS COMPACT COURSE (CC) Target: JEE (Advanced) 2019 Compact f i MUTE LTT eyele e [ ‘ : LAST DATE OF APPLYING JMNM CLASSES STARTING FROM 13.04.2019 = 15.04.2019 (Saturday) ! (Monday) aE Pe ee LR OA UePAVBSSC02058" | see (main) 2019 | DATE : 09.04.2019 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY PART : CHEMISTR' Straight Objective Type (HN TeYPrS HT) This section contains 27 multiple choice questions. Each question has 4 choices (1), (2), () and (4) forts newer, ut of which Only One is correct. Wa Ges 4 27 agree WET Evade wer & 4 famed (1), (2), (3) ce (4), re a AR ew ae a) 1. The product ofthe following reaction i on 1? 2KOHle) “ 9 @ 2 ® a “ on fre in amr ear, = pe Bona) "Oe =O WO 8 8 ou 6 Ans. (4) sol. Se 1.70, Om a, Z KOH) Rona) 2. Which ofthe following the major product of give reaction Aa ogy te a MA~Non BALCH ARNO AA Which of the following is the major product of give reaction: Og stir S yor seg Pr Har 8 8? Ht W~Now DAL CHO RO OAR Ans. (1) Resonance Eduventures Ltd. orp Reg. Ofc: CG Tower, 46 & 52, PIA, Nea City Mall, Jhalavar Road Kota (Ra) » 324005 PhNo.:+91-7443012222, 635555 | FAXN. 9102235167222 Toknow ore: ss RESO S67 | Weta: wn resonance cin Em: ora resoraceacin| I: UBDXODRP007P.CO24029 Tall ree: 1800 258 S598 [9 Oaose4s59 Efoomncnsecnees” EJoseranmcnecen Efeenermarymes LJtnrorr ee This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE #1TINBESOR205S" | see quainy 2019 | DATE : 09.06.2019 (SHIFT-A) | PAPER | MEMORY BASED | CHEMISTRY Nos 3 ol CH \Write the IUPAG name of given compound (1) f-Choro 2-methyl :ntro benzene (2) 2.Chioro 1-methyl 4nitro benzene (3) 3-Chloro 4-methy! t-nito benzene (4) 5:Chioro 4-methyl tno benzene NOs ol CH ‘Re ge shes wr IUPAC TH frat (1) treet 2s Somreehtts (2) 2 meta 1 Art 4-ameghtet (@) Sorat 4. ARR treet (4) 5: a 4 Br aera ans. (2) Sol 4. Arrange the following compounds in the corect increasing rate of aromatic electrophilic substitution. “ © Wy AcBeced™ ()D > ol A a) a a a a a) €1g offre am sere Pe bat ea D1 oo oe 6b > DG 1 0 (2) 8) (4) Ans. (1) Lean ar a, Pekar . " 0 n a (2) (3) (4) a OH OH cl cr ee gern Aven) aETT e oS oO (3) 4) a OH OH cl Ans. (1) Sek SIE LxoHuentn LI GS reese cr Gate Bray Resonance Eduventures Ltd. Corp. & Reg Office 6 Tower, A468 52, PLA, Near Cty Mall hala Road Kota(Ra) = 224005 Pho, :¥91-7443012272, 6635555 | FAKN: 910223015722 Tekno more: ss ESO a7 | Webate: an esoance cn Ema coat resonance ac in|: URE2022007.O?40 Tall roe: 1000 258 5508 {9 Oseoeea359 Efoomronreceees” E]seerowmece’ Efomyamt armen PSone This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE #5[ESOQEOSS’ | Jee (MAIN) 2019 | DATE : 09-04-2049 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY. Ans. Sol. 12. Ans. Sol. 13. He iver “eaananor” X X is mixed with a mixture of phenol and aniline in acidic medium. The product obtained is: (0{Q)-N-n-{O)-Ne @(O)-n-n-{O)-o# @(Q)-n-n-0-{O) (O)-nen-e-{O) Me ain ‘cis RaNO” X Pre Xe orca sma 3 Attar ca ght & Pear eeu Fea we sre seme a 19{O)-nen-{O)-Ht @(O)-n-n-{O)-oH 2(pv.ne-0) 6@)-v-(6) a HH NHe In CuSO«SH.0 how many molecules of water are indirectly connected to Cu CuSO. SH-O% ore far omy CUR smicaet wa aI e— ws @4 @2 at ln CuSO«5HO, Four water molecules form coordinate bond with Cu ion while one water molecule is associated with H-bond, CuSO. SHO 4 ora Bare my Cut ora a armies de gre aes BY Bora ew os wT aM Hear gre ae a & [n= concentration of reactant and tbe the time Le t t Identity the order is correct option for order (1) 1 ando (2)2and3 (9) 3and2 (4) 0and2. Resonance Eduventures Ltd. Corp. & Rog. Office: CG Tower, A-46& 52, IPI, Near City Mal, Jhalawar Read, Kota (Raj) - 324005, Pho, :491-744-3012222, 6635555 | FAKNo. : 491-022-39167222 ToKnow more: sms RESO at 5677 | Website ww esenance cin | Ema conact@resonance acin| CIN: UB0302812007P1c024029 Tall Free : 1800 258 S555 [s)0500 414251 Esonmontonae [oenramtonnraea, Flornyare eran Ere This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 6[AVRESCOEOEE” | see (main) 2019 | DATE : 09-04-2010 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY = freee are wen tT ‘iq “~ T T ft onkadt & fog ara wae feng eae ee (1) 10 (@20n3 (3) Seen 2 ()omen2 Ans. (1) Sol. For zero ordor Cy" Ca, Ht for frst order Cy =Cye™ Ca or, In SA ait or, In Cp= Ina, == or, Gam InGa,—kt Sol qu ae & fee C,.= Cee sa ie 2 fe oF, In Ca—InCp, = kt of, In Cy=InGa, Kt 14, The vapour pressure of pure liquid M & N are 700 mm of Hg and 450 mm of Hy respectively, Which of the following option is correct? Given : Xu, Xu = mole fraction of N & Min liquid phase Yu, Yu = mole fraction of N & Min vapour phase Ye (1) Xat= Xn > Y= Yn aa (@ Yar= Vo > (1) Xu=Xu> Yur¥ @ tose Xu Yu Xu Ya oye te ans.) Sol. Mole fraction of more volatile component increase in vapour phase. (Pj Zn® + Cu Ifthe standard emis Egqy= 20 V & F = 965006 Find AG? kd mol (1) = 388 (2) +388. (3)-194 (4) +194 sftfirea Zn + Cu —> Zn’ + Cu frame afere | af& APE emt, E5.,= 2.0 V8 Ta F 96500 © AAG mod 3 APT (1) -388 (2) + 388. (3)-194 (4) +194 Ans. (1) Sol, AG*=—nF EG, 2 % 98500 » 2.0 « 10 =-388 ki/mol 16. A Solution of X¥ (100% ionised) has osmotic pressure equal to four imes the osmotic pressure of 0.01 M BaCla (100% ionised). Find the molarity of XY (1)6* 102M (@)3« 102M (9) 4 102M (412x102 XY (100% araPrey & ar FRY ay HeTEEN Ta 0.01 M BaCle (100% safe) Ree were era aR pn) aa XV at stan ara aT (1)6« 102M 3 102M (4 102M (4) 12102 Ans. (1) Sol. = Atpact KY] = 4 «ix [Ba] 324 KY] 2430.01 = IXY]=0.06M 17, What is the ratio of Av = = ymax ~ vam for spectral lines corresponding to lyman & Balmer series for hydrogen (gra (4:9 5:7 @7:5 rggiorn & fang erg eT wear Aotel) erae eege Rea RE AV= vee — vn wT ST AT BT (esd @ar9 @5:7 (7:5 Ans. (1) cwsngman, “(4 weal aan lee) Sol. al-bi= alo 18. Which ofthe folowing are path functions aw (2) (ChQ+W ()H-TS (1) Aand D- (2)AandB (3) A, Band D (4) A,C and D- Pret a 8 wen gy wos aw (BQ (a+ OH-TS (VAmD (QAaNB (3) A, 8D (ACAD Ans. (2) Sol. W, Qare path unctons; d+ W = AE, H~TS =G are state function Sol, W,Qrer wort #106 W~ AEH TSG seen ro 1 Resonance Eduventures Ltd. Corp. & Reg, Office: CG Tower, A868 52, PIA, Nea City Mall nalaar Road, Kota(Rsk) ~ 324005 PhNo,:#91-744-3012222, 6635555 | FAKN,: ¥91.02239167222 Toknow more ss RESO at S667 | Website: wa esnonce in| Ema contact@ resonance ac n| CN: US090212007P.C024029 ats 4268 Ed mina foment er nonearr PAGE #8TBESORENSE" | see (MAIN) 2019 | DATE : 09.04.2019 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY 19. Given a and b values for Xe, Kr, Ar and He are xe | kr | Ar | He albarimor) | 41 | 23 | 13 | 003 o(umo | 01 | 0.04 | 0.03 | 0.02 The gas with highest Te is (xe Kr (Ar (He Xe, kr, Aran He @ feng agen ba ra fa ora xe | kr | Ar | He a(tbarimot) | 41 | 23 | 13 | 003 viumo | 04 | 004] 003 | 002 ‘sear sift Ta Te wey are fe B — (1) Xe (2) kr (3) Ar (4) He ane) so. te» (2) 20, Consider he graph ay P| G 1 Vv Identity correct option- (1) AUs= AUp, Q. > Op (2) AU > AUs, Qu = Qe (9) AUs = AUs, Qs < Op (8) AU < AUs, Qs = Qo Frey ste ae foe afer u Vv Bo Reon a em aifiny — (1) AUs = AUs, Q.> Os (2) AUs > AUs, Qs = Qe ()AUs = AUs, Qa < Oo (4) AUs < AUs, Qu = Qy Ans. (1) Sol. AU state function (Therefore, AU: Us) (Sinco, [Ws| > We, So, Ws < Ws) Resonance Eduventures Ltd. Corp. & Rog. Office: CG Tower, A-46 & 52, IPI, Near City Mal Jhalawar Read, Kota (Raj) - 324005, Pho. :491-744-3012222, 6635555 | FAKNo.: 491-022-39167222 ToKnow more: sms RESO at 5677 | Website uw. esenance cin | Ema: contact@resonanceacin| CIN: U80302812007P1C024029 Toll Free : 1000 258 S555 (9 0000 425) Fsem mnie, [Joewentoroces, Fnvantacennnnts [barrier This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE #9[AVRESCOEOEE” | see (main) 2019 | DATE : 09-04-2010 (SHIFT-1) | PAPER-1 | MEMORY BASED | CHEMISTRY 21. Outof C2, Fa,O2, NO, Which will be stabilized ater forming anion ? Cz, Fee NO, 9 aha acoers Fnfor bse senea ser we? (1") Ce Fe (9) (NO Ans. (1) Sol. Cz : (ots) (o"ts}? (02s)? (0°25) (22p% = 20%) oF KK (05)? (0°25) (x2p% = x2p%) o2P'2 Bond order: 4 (9-4)=26 (Of : (ots)® (6°18) (a2)? (0°28)? (o2p (nap = x2p%) (np « y) FE lol (19? C25 (25 (2? = 0) tp = 2%) 0h sondcrée: 4 10-2)=08 NO>: (18)? (a"18)? (28)? (0°28)? (o2pz)? (n2p% = x2p%y) (n*2ps! sondarse: 4 10-6)=20 border Sby 204) 22. Arrange in the increasing order of oxidation state of nitrogen for following nitrogen oxides. N:0, NOz,NO, NzOs Fr agian silemge 8 argglor A sett save & age apy A arate Nay AF. 25. Which of the folowing will have highest ciference betwoen IE and IE2? ‘Fret a @ fiber feng IE; can [Ee & Fe aiftten aie eT? Ans. (1) ‘fre, 4S wr were Bfaera eee 7 af A l ! * af A l I Sot fan a snows ota activity io srangement IM(AA) ache} mete fren ae & 27. Witch ofthe folowing orbitals are degenerate for [Or(H,0},} orto), fry Fra @ ed war re (dogonorato) were #1 (1) dp dy (21) day dye 2) bp pSye (8) bday ans. (2) Sol. _[Cr(H,0),}” has o°sp* hybridisation. dxy, dy, ds orbitals are degenerate [erlH,0),P* , dsp? samen tam &, dey, dyz, des Hare erm & Resonance Eduventures Ltd. orp. Reg. Ofc: CG Tower, 46 & 52, PIA, New iy Mall, hala Road ota (Ra) ~ 324005 PhNo.:+91-7443012222, 635555 | FAXNo 9102235167222 Toko ore: sr RESO 3657 | Webte: wn ecoonce cin Ema one resoranceacin |: UBDRODRPO07P.CO24029 Tall ree: 1800 258 S598 [9 Oaroscsssd Efoomncnsacnees” EJomeranmcrcn Efemereceymae, EJenrorm This solution was download from Resonance JEE (MAIN) 2019 Solution portal PAGE # 11Success at JEE Advanced 2018 JX Resonence® ene rete Pa aa ae THEY LET THEIR RESULTS DO THE TALKING. -- oe Studentsin | "J studentsin [CRP Studentin | ! AIRTop-5 | SJ AIRTop-50 | # AIRTop-100 F 42% 21" APRIL 2019 [ALL FROM CLASSROOM PROGRAM ean Resonance Eduventures Limited Registered & Corporate Office: CG Tower, A-46 & 52, PIA, Near City Mall, Jhalawar Road, Kota Rajasthan) - 324005 Tel, No: 0744-2777777, 2777700 | CIN: UBO3O2RJ2OOTPLCO24025 een