CH117L: PHYSICAL CHEMISTRY 2 LABORATORY

2ND Quarter SY 2019-2020

CHEMICAL KINETICS
ORTEGA, MARY ALYSSA T. – GROUP 6
AUGUST 22, 2019

Introduction

Objectives

Results and Discussion

A. Determination of Hydrolysis Rate at Room Temperature and Lower Concentration of HCl

Moles of Concentration
Estimated Time of Actual Volume of Concentration
Acetic of Methyl
Reaction Withdrawal Reaction NaOH of Acetic Acid,
Acid in Acetate Left,
Time, min of Aliquot Time, min used, mL mol/L
Aliquot mol/L
0 - 0.567 3.4 0.003568 0.032436 0
10 - 10.27 3.5 0.003673 0.03339 0.000954
20 - 20.05 3.6 0.003778 0.034344 0.001908
30 - 30.04 3.7 0.003883 0.035298 0.002862
40 - 40.04 3.9 0.004093 0.037206 0.00477
50 - 50.04 4.0 0.004198 0.03816 0.005724
60 - 60.38 4.1 0.004303 0.039114 0.006678
80 - 80.04 4.2 0.004407 0.040068 0.007632
100 - 100.3 4.5 0.004722 0.04293 0.010494
120 - 120.04 4.6 0.004827 0.043884 0.11448

Concentration of HCl is reaction mixture, mol/L = ____________________________

B. Determination of Hydrolysis Rate at Room Temperature and Higher Concentration of HCl

Moles of Concentration
Estimated Time of Actual Volume of Concentration
Acetic of Methyl
Reaction Withdrawal Reaction NaOH of Acetic Acid,
Acid in Acetate Left,
Time, min of Aliquot Time, min used, mL mol/L
Aliquot mol/L
0 - 0.39 6.5 6.8x10-3 0.0425 -
10 - 10.22 6.9 7.2x10-3 0.0450 2.5x10-3
20 - 20.18 7.2 7.6x10-3 0.0475 5.0x10-3
30 - 30.15 7.3 7.7x10-3 0.0481 5.6x10-3
40 - 40.17 7.5 7.9x10-3 0.4940 6.9x10-3
50 - 50.16 7.6 8.0x10-3 0.0500 7.5x10-3
60 - 60.24 7.8 8.2x10-3 0.0512 8.7x10-3
80 - 80.14 8.0 8.4x10-3 0.0525 0.01
100 - 100.21 8.2 8.6x10-3 0.0538 0.0113

1
 120 - 120.19 8.5 8.9x10-3 0.0557 0.0132

Concentration of HCl is reaction mixture, mol/L = ____________________________

C. Determination of Hydrolysis Rate at High Temperature and Lower Concentration of HCl

Moles of Concentration
Estimated Time of Actual Volume of Concentration
Acetic of Methyl
Reaction Withdrawal Reaction NaOH of Acetic Acid,
Acid in Acetate Left,
Time, min of Aliquot Time, min used, mL mol/L
Aliquot mol/L
0 - 2.58 3.3 0.003463 0.031482 0
10 - 11.10 3.7 0.003883 0.035298 0.003816
20 - 20.23 4.1 0.004303 0.039114 0.007632
30 - 30.02 4.3 0.004512 0.041022 0.00954
40 - 40.05 4.4 0.004617 0.041976 0.010494
50 - 50.01 4.7 0.004932 0.044838 0.013356
60 - 60.03 4.6 0.004827 0.043884 0.012402
80 - 80.02 4.6 0.004827 0.043884 0.012402
100 - - - - - -
120 - - - - - -

Concentration of HCl is reaction mixture, mol/L = _______________________

Acid-dependent rate constant at low HCl concentration = 0.5698/min

Acid-dependent rate constant at high HCl concentration = 0.6121/min

Order of reaction with respect to HCl concentration = First Order

Eact of the reaction = -5469.9351 J/mol

ΔH° of the reaction = -5469.9351 J/mol

ΔS° of the reaction = 18.34625 J/mol K

Conclusions

Appendix

Sample Computation:
For Table C:
Moles of Acetic Acid in Aliquot (MW) at 0 minute
nAcetic Acid=𝑉𝑁𝑎𝑂𝐻 𝑀𝑁𝑎𝑂𝐻
3.3 𝑚𝐿 1.0494 𝑚𝑜𝑙 1 𝑚𝑜𝑙 𝐶𝐻3𝐶𝑂𝑂𝐻
nAcetic Acid= (1000 𝑚𝐿NaOH) ( NaOH) ( )
𝐿 1 𝑚𝑜𝑙 𝑁𝑎𝑂𝐻

nAcetic Acid=0.003463mol
Concentration of Acetic Acid (mol/L) at 0 minute

2
 𝑛𝐶𝐻3 𝐶𝑂𝑂𝐻
CCH3COOH= 𝑉𝑇𝑜𝑡𝑎𝑙
0.003463 𝑚𝑜𝑙
CCH3COOH= 0.16 𝐿

CCH3COOH= 0.031482 M
Concentration of Methyl Acetate left (mol/L) at 10 minutes
CCH3COOH= CCH3COOH(t=10) - CCH3COOH(t=0)
CCH3COOH= 0.035298-0.031482
CCH3COOH= 0.003816 M
Initial Concentration of Methyl Acetate, 𝐶𝑜
𝑔 1 𝑚𝑜𝑙
𝑉𝐶3 𝐻6 𝑂2 𝜌𝐶3𝐻6 𝑂2 𝑀𝑊𝐶3 𝐻6 𝑂2 (10𝑚𝑙) (0.9273 𝑚𝑙 ) (74.08 𝑔)
𝐶𝑜 = =
𝑉𝑡𝑜𝑡𝑎𝑙 0.11 𝐿
C0= 1.138 M C3H6O2
Acid Dependent rate constant at low HCl concentration (35°C), K
𝐶 0.003816
ln (𝐶 ) ln ( )
𝐾=− 𝑜
=− 1.1380
𝑡 10
K1=0.5698/min
Acid Dependent rate constant at high HCl concentration (25°C), K
ln(𝐶𝐶 ) ln(0.0025 )
K= − 𝑡
𝑜 = − 1.1380
10
K2=0.6121/min
Enthalpy of Reaction, ∆𝐻
∆𝐻=Ea
𝑘 0.6121
𝑅𝑙𝑛(𝑘2 ) (8.314)𝑙𝑛(0.5698)
1
Ea= 1 1 = 1 1
−
𝑇1 𝑇2
−
308.15 298.15

Ea= -5469.9351 J/mol

Entropy of Reaction, ∆𝑆
𝐽
∆𝐻 −5469.9351𝑚𝑜𝑙
∆𝑆=− =−
𝑇 298.15 𝐾
∆𝑆= 18.34625 J/mol K