Page # 18 STOICHIOMETRY - II

Exercise - I (Only one option is correct)

1. The equivalent weight of MnSO 4 is half its 10. How many equivalents are there per mol of H2S in
molecular weight when it is converted to : its oxidation to SO2 ?
(A) Mn2O3 (B) MnO2 (A) 2 (B) 4
(C) MnO4– (D) MnO42– (C) 6 (D) 8
2. Given the equation S2O82– + 2e–  2SO42– , Mn2+
+ 4H2O  MnO4– + 8H+ + 5e– . How many moles of 11. 3 mol of a mixture of FeSO4 and Fe2(SO4)3 required
S2O82– ions are require to oxiDes 1 mole of Mn2+: 100 mL of 2M KMnO4 solution is acidic medium .
(A) 0.4 (B) 0.5 Hence mol fraction of FeSO4 in the mixture is:
(C) 2.5 (D) 1.0 (A) 1/3 (B) 2/3
(C) 2/5 (D) 3/5
3. A solution of 10 ml 0.1 M FeSO4 was titrated with
KMnO4 solution in acidic medium. The amount of
KMnO4 used will be: 12. In a reaction 4 moles of electron are transferred
(A) 5 ml of 0.1 M (B) 10 ml of 0.1 M to one mole of HNO3. When acted as an oxidant.
(C) 10 ml of 0.5 M (D) 10 ml of 0.02 M The possible reduction product is :
(A) 1/2 mole of N2 (B) 1/2 mole of N2O
4. NH2OH reacts with ferric sulphate as follows : (C) 1 mole of NO2 (D) 1 mole of NH3
2NH2OH + 4 Fe3+  N2O + H2O + 4 Fe2+ 4H+. The
eq. wt. of NH2OH in this reaction is : 13. One mole of N2H4 loses ten moles of electrons to
(A) (mol. wt.)/1 (B) (mol.wt.)/2 from a new Compound y. Assuming that all the
(C) (mol.wt.)/3 (D) (mol.wt.)/4 nitrogen appears in the new compound. What is
the oxidation state of nitrogen in y. There is no
5. 20 ml of 0.1 M solution of metal ion reaCteD with change in the oxidation state of hydrogen:
20 ml of 0.1 M SO2 solution. SO2 reacted according (A) –1 (B) –3
to the equation. SO2 + 2H2O  SO42– + 4H+_ + 2e–
(C) + 3 (D) +5
. If the oxidation no. of metal ion was +3, the
new oxidation number of the metal would be: 14. 1 g equiv of a substance is the weight of that
(A) 0 (B) +1 amount of a substance which is equivalent to :
(C) +2 (D) None of these (A) 0.25 mol of O2 (B) 0.50 mol of O2
(C) 1 mol of O2 (D) 8 mol of O2
6. How many ml of 0.150 M Na2CrO4 will be required
to oxidize 40 ml of 0.5 M Na2S2O3. 15. Which of the following changes requires reducing
CrO42– + S2O32– Cr(OH)4– + SO42–. agent?
(A) 225 ml (B) 355 ml (A) CrO42–  Cr2O72– (B) BrO3–  BrO–
(C) 455 ml (D) 555 ml (C) H2AO3  HAsO4 2–
(D) Al(OH)3 Al(OH)4–

7. Number of moles of electrons take up when 1 16. Which of the following is a disproportonation
mole of NO3– ions is reduced to 1 mole of NH2OH reaction?
is: (A) CaCO3 + 2H+  Ca2+ + H2O + CO2
(A) 2 (B) 4 (B) 2CrO42– + 2H+  Cr2O72+ + H2O
(C) 5 (D) 6
(C) Cr2O42– + 2OH–  2CrO42– + H2O
(D) Cu2O + 2H+  Cu + Cu2+ + H2O
8. The number of moles of thiosulphate (S2O32–) that
will required to react completely with one mole I2 in
alkaline medium (where it gets oxidised to SO42–) is : 17. If equal volumes of 1M KMnO4 and 1M K2Cr2O7
(A) 1/4 (B) 4 solutions are allowed to oxidise Fe2+ in acidic
(C) 8 (D) 1/8 medium.
The amount of iron oxidised will Be :
9. The number of moles of oxalate KHC 2 O 4 . (A) more by KMnO4 solution
H2C2O4.2H2O oxidised by one mole of permanganate (B) more by K2Cr2O7 solution
ion is: (C) equal in both the cases
(A) 3/4 (B) 1
(D) cannot be determined
(C) 5/4 (D) 6/4

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 STOICHIOMETRY - II Page # 19

18. In the following reaction (unbalanced), equivalent 26. When 0.75 gm of a substance was kjeldalised, it
wt. of As2S3 is related to molecular wt. M By: produced NH3. Which neutralizes 30 ml of 0.25 N
As2S3 + H+ NO3–  NO + H2O + AsO43– + SO42– sulphuric acid. The percentage of nitrogen in the
(A) M/2 (B) M/4 organic compound is :
(C) M/28 (D) M/24 (A) 14 (B) 11
(C) 1 (D) None
19. Mass of KHC2O4 (potassium acid oxalate) required
to reduce 100 mL of 0.02 M KMnO4 in acidic medium 27. 15 mol of KMnO4 are treated with excess H2C2O4
(to Mn2+) is x g, and to neutralise 100 mL of 0.05 in H2SO4 medium. How many moles of CO2 will be
M Ca(OH)2 is y g then : formed and how many moles of H2C2O4 will be
(A) x = y (B) 2x = y consumed?
(C) x = 2y (D) None is CorreCt
(A) 75, 37, 5. (B) 3, 15

20. 100 mL of 1 M KMnO4 oxidised 100 mL of H2O2 in (C) 3, 6 (D) 75, 150
acidic medium (when MnO4– is reduced to Mn2+) ;
volume of same KMnO4 required to oxidise 100 mL
28. An equimolar mixture of NaHC2O4 and H2C2O4
of H2O2 in basic medium (when MnO4– is reduced
consumes 20 ml 0.3 M NaOH solution for complete
to MnO2) will be:
neutralization. The same mixture requires V ml.
(A) (100/3) mL (B) (500/3) mL 0.05 M KMnO4 solution in acidic medium for
(C) (300/5 ) mL (D) 100 mL oxidation.
The value of V is :
21. 1 mol of ferric oxalate is oxidised by x mol of
MnO4– and also 1 mol of ferrous oxalate is oxidised (A) 160 ml (B) 32 ml
By y mol of MnO4– in acidic medium. The ratio (x/ (C) 24 ml (D) None of these
y) is:
Question No. 29 to 32 (4 questions)
(A) 2 : 1 (B) 1 : 2
(C) 3 : 1 (D) 1 : 3 30cc of a solution containing 9.15 gm of salt KxHY
(C2O4)z. nH2O per litre required 27cc of 0.12 N
NaOH for neutralization. The same quantity of
22. 0.7 gm of Na2CO3.xH2O is dissolved in 100 ml, 20 solution was also found to require 36cc of 0.12 N
ml of which required 19.8 ml of 0.1 N HCl. The KMnO4 solution for complete oxidation.
value of x is:
(A) 4 (B) 3 29. What is the value of X
(C) 2 (D) 1 (A) 1 (B) 2
(C) 3 (D) 4
23. A metal is burnt in oxygen and all the products
of combustion are weighed. It is found that the
wt. of the metal seems to have increased by 24%. 30. What is the value of Y
The equivalent wt. of the above metal. (A) 4 (B) 3
(A) 25 (B) 24
(C) 2 (D) 1
(C) 33.34 (D) 76

24. When one gm mole of KMnO4 reacts with HCl, the 31. What is the value of Z
volume of chlorine liberated at NTP will be: (A) 4 (B) 1
(A) 11.2 litre (B) 22.4 litre
(C) 2 (D) 3
(C) 44.8 litre (D) 56.0 litre

25. 10.78 g of H3PO4 in 550 mL solution is 0.40 N. 32. What is the value of n
Thus this acid:
(A) 4 (B) 3
(A) has been neutralised to HPO42–
(C) 1 (D) 2
(B) has been neutralised to PO43–
(C) has been reduced to HPO32–
(D) has been neutralised to H2PO4–

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 Page # 20 STOICHIOMETRY - II

Question No. 33 to 35 (3 questions) 36. Concentration of NaHCO3 in gm/lit.

A steel sample is to be analysed for Cr and Mn (A) 0.312 (B) 2.62
simultaneously. By suitable treatment Cr is oxidized
as Cr2O72– and the Mn to MnO4–. (C) 3.12 (D) 26.208
Cr  Cr2O72–
Mn  MnO4– 37. Amount of NaOH that should be added to convert
A 10 gm sample of steel is used to produce 250.0 all bicarbonate into carbonate in 100 ml stock
mL of a solution containing Cr2O72– and MnO4–. A solution
10 mL portion of this solution is added to a BaCl2
solution and by proper adjustment of the acidity, (A) 1.248 gm (B) 0.312 gm
the chromium is completely precipitated as BaCrO4 (C) 3.12 × 10–2 gm (D) 7.8 × 10–3 gm
; 0.0549 g is obtained.
2– H
Cr2 O 7  BaCrO 4

38. Millimoles of NaHCO3 present in stock solution
A second 10 mL portion of this solution requires
exactly 15.95 mL of 0.0750 M standard Fe2+ (A) 0.624 (B) 2.16
solution for its titration (in acid solution) (C) 1.536 (D) 7.8
33. % of chromium in the steel sample
(A) 1.496 (B) 2.82
Question No. 39 to 41 (3 questions)
(C) 1.96 (D) 5
1.16 g CH3(CH2)n COOH was burnt in excess air
and the resultant gases (CO2 and H2O) were passed
34. Equivalent of Fe2+ required for reduction of MnO4– is through excess NaOH solution. The resulting
(A) 5.44 × 10–4 (B) 0.544 × 10–2 solution was divided in two equal parts. One part
(C) 1.196 × 10–3 (D) 11.96 × 10–4 requires 50 mL of 1 N HCl for neutralization using
phenolphthalein as indicator. Another part required
80 mL of 1 N HCl for neutralization using methyl
35. Amount of BaCl2 required for conversion of Cr2O72– orange as indicator.
to BaCrO4 in steel sample
39. Produced mole of the CO2
(A) 0.045 (B) 0.0549
(C) 1.125 (D) 2.82 (A) 0.1 (B) 0.01
(C) 0.06 (D) None of these

Question No. 36 to 38 (3 questions)

25 ml from a stock solution containing NaHCO3 40. What is the value of n
and Na2CO3 was diluted to 250 ml with CO2 free (A) 4 (B) 3
distilled water. 25 ml of the diluted solution when
(C) 2 (D) 1
titrated with 0.12 M HCl required 8 ml., when
phenolphthalein was used as an indicator.

HPh
41. Amount of excess NaOH solution taken initially.
Na2CO3 + HCl   NaHCO3
(A) 3.2 gm (B) 6.4 gm
When 20 ml of diluted solution was titrated with
same acid it required 18 ml when methlyorange (C) 1.2 gm (D) None of these
was used as an indicator.

Na2CO3 + 2HCl MeOH

 2NaCl + H2O + CO2

MeOH
NaHCO3 + HCl  
 NaCl + H2O + CO2

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 STOICHIOMETRY - II Page # 21

Exercise - II (One or more than one option correct)

1. In the titration of K2Cr2O7 and ferrous sulphate, 9. A 110 % sample of oleum contains
following data is obtained: V1 ml of 1.0 M1 K2Cr2O7 (A) 44.4% of SO3
requires V2 ml of 1.0 M2 FeSO4. Which of the (B) 55.6% of sulphuric acid
following relations is/are true for the above (C) 55.6% of SO3
titration ? (D) 44.4% of sulphuric acid
(A) 6 M1V1 = M2V2 (B) M1V1 = 6 M2V2 10. A mixture of 1 mole each of FeSO4 and FeC2O4
(C) N1V1 = N2V2 (D) M1V1 = M2V2 are taken then :
(A) nmoles of KMnO4 required to oxidise Fe2+ to
2. Cr2O72 is reduced to Cr3+ by Fe2+. Identify the Fe3+ in acidic medium is 0.4
incorrect statement from the following :
(A) 6 moles of Fe2+ are oxidised to Fe3+ ions. (B) nmoles of KMnO4 required to oxidise SO24 is 6/5
(B) The solution becomes yellow (C) nmoles of KMnO4 required to oxidise oxalate
(C) The solution becomes green ion is 0.4
(D) 3 moles of Fe2+ get oxidised to Fe3+ (D) The total number of moles of KMnO4 required
to completely oxidise the mixture is 0.8
3. 15 g of KMnO4 in acidic medium equal to
(A) 0.095 moles 11. 100 ml of 0.06 M Ca(NO3)2 is added to 50 ml of
(B) 0.477 g equivalents 0.06 M Na2C2O4. After the reaction is complete
(C) 9.54 L of 0.05 N KMnO4 (A) 0.003 moles of calcium oxalate will get
(D) 10 ml of 0.05 M KMnO4 precipitated
(B) 0.003 M of excess of Ca2+ will remain in
4. Which of the following statements are correct ? excess
(A) One mole of Cl2 means 8 equivalents of chlorine (C) Na2C2O4 is limiting reagent.
(D) Ca(NO3)2 is excess reagent.
when Cl2  Cl– + ClO 4
12. To 25 ml of H2O2 solution, excess of acidified
(B) One mole of Cl2 means 6 equivalents of chlorine solution of KI was added. The iodine liberated
when Cl2  Cl– + ClO 4 required 20 ml of 0.1 N Na2S2O3 solution. Calculate
(C) When one mole of As2S3 is oxidised to As2O5 + the % of H2O2 solution.
SO2 then it mean 22 equivalents of As2S3 are (A) 0.0136 % (B) 0.136 %
oxidised. (C) 0.0068 % (D) 0.068 %
(D) The equivalent weight of As2S3 is always = mol. 13. 10 g mixture of KI and NaClO3 treated with 200
wt./22.
N
cc HCl gives a gas which absorbes in 40 ml of
5. 27 g of Al will react completely with 10
(A) 24 g of O2 (B) 0.75 mole of O2 sodium thiosulphate solution. Then the correct
(C) 16.8 L of O2 at STP (D) 1 mole of O2 statement is/are
(A) equivalent weight of iodine in the reaction is M/2
6. 10.78 g of H3PO4 in 550 ml solution is 0.40 N. (B) percentage of KI in the mixture is 66.4%
Thus this acid (C) sodium thiosulphate converted into Na2S4O6.
(A) has been neutralized to HPO42– (D) percentage of NaClO3 is 66.4%
(B) has been neutralized to PO43–
(C) has been reduced to HPO32– 14. H2C2O4 and NaHC2O4 behave as acids as well as
(D) has been neutralized to H2PO4– re du cin g age nts . Which is /ar e cor re ct
statement(s) ?
7. Which of the following contains equal number of (A) Equivalent wt. of H2C2O4 and NaHC2O4 are
atoms ? equal to their molecular weights when behaving
(A) 11.2 ml of N2 and 0.015 g of nitric oxide as reducing agent
(B) 22.4 L of nitrous oxide and 22.4 L of CO2 (B) 100 ml of 1 N solution of each is neutralised
(C) 1 mole of HCl and 0.5 mole of H2S by equal volumes of 1 M Ca(OH)2
(D) 1 mole of H2O2 and 1 mole of H2SO4 (C) 100 ml of 1 N solution of each is neutralised
by equal volumes of 1 N Ca(OH)2
8. When 100 ml of 0.1 M KNO3, 400 ml of 0.2 M HCl (D) 100 ml of 1 M solution of each is oxidised by
and 500 ml of 0.3 M H2SO4 are mixed. Then in the equal volumes of 1 M KMnO4
resulting solution
(A) The molarity of K+ = 0.01 M 15. 100 ml of 0.15 N H2O2 is completely oxidized by
(A) 150 ml of 0.1 N KMnO4 solution
(B) The molarity of SO24 = 0.15 M (B) 2.5 × 10–3 moles of K2Cr2O7 in acidic medium
(C) The molarity of H+ = 0.38 M (C) 15 × 10–3 moles of KMnO4 in basic medium
(D) The molarity of NO3– = 0.08 M and Cl– = 0.01 M (D) 15 moles of O3 in acidic medium

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