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Designation: D 4976 – 04a

Standard Specification for


Polyethylene Plastics Molding and Extrusion Materials1
This standard is issued under the fixed designation D 4976; the number immediately following the designation indicates the year of
original adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. A
superscript epsilon (e) indicates an editorial change since the last revision or reapproval.

INTRODUCTION

This specification is not intended for the selection of materials, but only as a means to call out
plastic materials to be used for the manufacture of parts. The selection of these materials is to be made
by personnel with expertise in the plastics field where the environment, inherent properties of the
materials, performance of the parts, part design, manufacturing process, and economics are
considered. This specification does not specify the source of the resin to be used for the fabrication
of any given article.

1. Scope* of this standard to establish appropriate safety and health


1.1 This specification provides for the identification of practices and determine the applicability of regulatory limita-
polyethylene plastics molding and extrusion materials in such tions prior to use.
a manner that the supplier and the user can agree on the 1.6 For information regarding plastic pipe materials see
acceptability of different commercial lots or shipments. The Specification D 3350. For information regarding wire and
tests involved in this specification are intended to provide cable materials, see Specification D 1248. For information on
information for identifying materials in accordance with the polyethylenes with densities below 0.910 g/cm3, see Classifi-
groups, classes, and grades covered. It is not the function of cation D 5593.
this specification to provide specific engineering data for NOTE 2—There is no similar or equivalent ISO standard.
design purposes.
1.2 Other requirements may be necessary to identify par- 2. Referenced Documents
ticular characteristics important to specialized applications. 2.1 ASTM Standards: 2
These shall be agreed upon between the user and the supplier, D 257 Test Methods for D-C Resistance or Conductance of
by using the suffixes given in Section 1.3. Insulating Materials
1.3 Ethylene plastic materials, being thermoplastic, are D 568 Test Method for Rate of Burning and/or Extent and
reprocessable and recyclable (see Note 1). This specification Time of Burning of Flexible Plastics in a Vertical Position3
allows for the use of those ethylene plastic materials, provided D 618 Practice for Conditioning Plastics for Testing
that any specific requirements as governed by the producer and D 635 Test Method for Rate of Burning and/or Extent and
the end user are met. Time of Burning of Self-Supporting Plastics in a Horizon-
NOTE 1—See Guide D 5033 for information and definitions related to tal Position
recycled plastics. D 638 Test Method for Tensile Properties of Plastics
D 790 Test Methods for Flexural Properties of Unreinforced
1.4 The values stated in SI units are regarded as the
and Reinforced Plastics and Electrical Insulating Materials
standard.
D 792 Test Methods for Density and Specific Gravity (Rela-
1.5 The following precautionary caveat pertains to the test
tive Density) of Plastics by Displacement
method portion only, Section 12, of this specification. This
D 883 Terminology Relating to Plastics
standard does not purport to address all of the safety concerns,
D 1238 Test Method for Flow Rates of Thermoplastics by
if any, associated with its use. It is the responsibility of the user

1 2
This specification is under the jurisdiction of ASTM Committee D20 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Materials. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved December 1, 2004. Published December 2004. Origi- the ASTM website.
3
nally approved in 1995. Last previous edition approved in 2004 as D 4976 - 04. Withdrawn.

*A Summary of Changes section appears at the end of this standard.


Copyright © ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.
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D 4976 – 04a
Extrusion Plastometer Federal Motor Vehicle Safety Standard 302, Flammability
D 1248 Specification for Polyethylene Plastics Molding and of Interior Materials5
Extrusion Materials
D 1505 Test Method for Density of Plastics by the Density- 3. Terminology
Gradient Technique 3.1 Definitions—For definitions of technical terms pertain-
D 1531 Test Methods for Relative Permittivity (Dielectric ing to plastics used in this specification, see Terminology
Constant) and Dissipation Factor by Fluid Displacement D 883 and Terminology D 1600.
Procedures 3.2 Historical usage and user group conventions have re-
D 1600 Terminology for Abbreviated Terms Relating to sulted in inconsistent terminology used to categorize and
Plastics describe polyethylene resins and compounds. The following
D 1693 Test Method for Environmental Stress-Cracking of terminology is in use in ASTM specifications pertaining to
Ethylene Plastics polyethylene:
D 1898 Practice for Sampling of Plastics3 3.2.1 Specification D 1248:
D 2565 Practice for Xenon Arc Exposure of Plastics In- 3.2.1.1 Type (I, II, III, IV) = density ranges (same, respec-
tended for Outdoor Applications tively, as Classes 1, 2, 3, and 4 in Specification D 4976).
D 2951 Test Method for Resistance of Types III and IV 3.2.1.2 Class (A, B, C, D) = composition and use.
Polyethylene Plastics to Thermal Stress-Cracking 3.2.1.3 Category (1, 2, 3, 4, 5) = melt index ranges (same as
D 3350 Specification for Polyethylene Plastics Pipe and Grade in Specification D 4976).
Fitting Materials 3.2.1.4 Grade (E, J, D, or W followed by one or two digits)
D 3892 Practice for Packaging/Packing of Plastics = specific requirements from tables.
D 4000 Classification System for Specifying Plastic Mate- 3.2.2 Specification D 3350:
rials 3.2.2.1 Type (I, II, III) = density ranges (same as Types I, II,
D 4329 Practice for Fluorescent UV Exposure of Plastics and III in Specification D 1248 and Classes 1, 2, and 3 in
D 4703 Practice for Compression Molding Thermoplastic Specification D 4976).
Materials into Test Specimens, Plaques, or Sheets 3.2.2.2 Class = a line callout system consisting of “PE”
D 4883 Test Method for Density of Polyethylene by the followed by six cell numbers from Table 1 plus a letter (A, B,
Ultrasound Technique C, D, E) denoting color and UV stabilizer.
D 5033 Guide for the Development of Standards Relating to 3.2.2.3 Grade = simplified line callout system using “PE”
the Proper Use of Recycled Plastics followed by density and slow crack growth cell numbers from
D 5593 Classification for Thermoplastic Elastomers— Table 1.
Olefinic (TEO) 3.2.3 Specification D 4976:
D 6360 Practice for Enclosed Carbon Arc Exposures of 3.2.3.1 Group (1, 2) = branched or linear polyethylene.
Plastics 3.2.3.2 Class (1, 2, 3, 4) = density ranges (same, respec-
E 29 Practice for Using Significant Digits in Test Data to tively, as Types I, II, III, and IV in Specification D 1248).
Determine Conformance with Specifications 3.2.3.3 Grade (1, 2, 3, 4, 5) = melt index ranges (same as
F 1473 Test Method for Notch Tensile Test to Measure the Category in Specification D 1248).
Resistance to Slow Crack Growth on Polyethylene Pipes
4. Classification
and Resins
2.2 Military Standard: 4.1 Unreinforced polyethylene plastic materials are classi-
MIL-STD-105 Sampling Procedures and Tables for Inspec- fied into groups in accordance with molecular structure. These
tion by Attributes4 groups are subdivided into classes and grades as shown in
2.3 DOT Standard: Table PE (Basic Property Table).

5
Available from United States Department of Transportation, National Highway
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4
Available from Standardization Documents Order Desk, Bldg. 4 Section D, 700 Traffic Safety Administration, Office of Public Affairs and Consumer Participation,
Robbins Ave., Philadelphia, PA 19111-5094, Attn: NPODS. 400 7th St., SW, Washington, DC 20590.

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D 4976 – 04a

TABLE PE Basic Requirement of Polyethylene Plastics


Flexural Modulus at
Flow Rate, D 1238, Tensile Stress at Yield, Nominal Strain at
Group Description Class Description Grade 2 % Strain, D 790,
g/10 min D 638, min, MPa Break, D 638, min, %
min, MPa
1 Branched 1 low density 1 >25 8 70 100
... 2 >10 to 25 8 90 125
0.910–0.925 3 >1 to 10 8.5 100 125
... 4 >0.4 to 1 9.5 300 125
... 5 to 0.4 9.5 400 150
... 0 ... ... ... ...
2 medium density 1 >25 8 40 200
... 2 >10 to 25 11 50 200
>0.925–0.940 3 >1 to 10 11 70 200
... 4 >0.4 to 1 11 200 250
... 5 to 0.4 12 400 300
... 0 ... ... ... ...
0 ... 0 ... ... ... ...
2 Linear 1 low density 1 >25 10 300 300
... 2 >10 to 25 10 300 325
0.910–0.925 3 >1 to 10 10 300 350
... 4 >0.4 to 1 10 400 350
... 5 to 0.4 12 500 400
... 0 ... ... ... ...
2 medium density 1 >25 14 90 500
... 2 >10 to 25 14 100 500
>0.925–0.940 3 >1 to 10 14 100 550
... 4 >0.4 to 1 15 200 600
... 5 to 0.4 19 400 600
... 0 ... ... ... ...
3 high density 1 >25 17 10 400
... 2 >10 to 25 17 50 400
>0.940–0.960 3 >1 to 10 18 200 450
... 4 >0.4 to 1 19 400 500
... 5 to 0.4 20 600 600
... 0 ... ... ... ...
4 high density 1 >25 24 10 500
... 2 >10 to 25 24 10 600
>0.960 3 >1 to 10 25 30 800
... 4 >0.4 to 1 28 300 900
... 5 to 0.4 28 400 1000
... 0 ... ... ... ...
0 0 ... 0 ... ... ... ...
Cell Table A Detail Requirements for Polyethylene Plastics

Designation Or- Cell Limits


Property
der Number 0 1 2 3 4 5 6 7 8 9
1 Tensile Stress at Yield, Test Method D 638, MPa, min unspecified 4 8 12 16 21 30 35 ... specify value
2 Nominal Strain at Break, Test Method D 638, %, min unspecified 25 50 200 400 600 800 1000 ... specify value
3 Secant Flexural Modulus at 2 % Strain, D 790, MPa, min unspecified 50 100 200 400 600 800 1000 ... specify value
4 Thermal stress-crack resistance, D 2951, hours without crack- unspecified 24 48 96 168 ... ... ... ... specify value
ing, min
5 Environmental stress-crack resistance, D 1693, min F50, h unspecified 24 48 96 168 336 672 1008 ... specify value
Cell Table B Detail Requirements for Polyethylene Plastics

Designation Or- Cell Limits


Property
der Number 0 1 2 3 4 5 6 7 8 9
1 Tensile Stress at Yield, D 638, MPa, min unspecified 4 8 12 16 21 30 35 ... specify value
2 Nominal Strain at Break, D 638, %, min unspecified 25 50 200 400 600 800 1000 ... specify value
3 Secant Flexural Modulus at 2 % Strain, D 790, MPa, min unspecified 50 100 200 400 600 800 1000 ... specify value
4 Thermal stress-crack resistance, D 2951, hours without crack- unspecified 24 48 96 168 ... ... ... ... specify value
ing, min
5 Slow Crack Growth Resistance, PENT-Test Method F 1473, h, unspecified 0.3 1 3 10 30 100 300 ... specify value
min

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D 4976 – 04a
NOTE 3—An example of this classification system is as follows: The First digit
designation PE 112 would indicate PE, polyethylene as found in Termi- 0 = To be specified by user.
nology D 1600, 1 (group) branched, 1 (class) low density, 2 (grade) >25 1 = Product is 3.05-mm thickness, min.
melt index. 2 = Product is 1.47-mm thickness, min.
3 = Product is 0.71-mm thickness, min.
4.2 Cell Tables A or B shall be used to specify the physical 4 = Product is 0.38-mm thickness, min.
property requirements that shall be shown by a five-digit 5 = Motor Vehicle Safety Standard 302.
Second Digit
designation. The designation shall consist of the letter A and 0 = To be specified by user.
the five digits comprising the cell numbers for the property 1 = When burned horizontally in accordance with Test Method D 635, a mate-
requirements in the order they appear in Cell Table A. rial:
(a) Does not have a burning rate exceeding 38.1 mm/min over a
4.2.1 Although the values listed are necessary to include the 76.2-mm span for specimens of 3.05 to 12.7-mm thickness; or
range of properties available in the existing materials, users (b) Does not have a horizontal burning rate exceeding 76.2 mm/min
over a 76.2-mm span for specimens of less than 3.05-mm thickness; or
should not infer that every possible combination of the (c) Ceases to burn, horizontally, before the 102-mm reference mark.
properties exist or can be obtained. 2 = When burned vertically in accordance with Test Method D 568, the mate-
rial:
NOTE 4—It is recognized that some high-density polyethylene plastics (a) Does not have any specimens that burn with flaming combustion for
of very high molecular weight may have densities slightly less than 0.960, more than 30 s after two applications of the test flame:
yet in all other respects they are characteristic of Class 4 materials. (b) Does not have a total flaming combustion time exceeding 250 s for
Similarly, there are other polyethylene plastics of very high molecular 10 flame applications for each set of five specimens;
weight having densities slightly less than 0.941 that, in all other respects, (c) Does not have any specimens that burn with flaming or glowing
combustion up to the holder clamp;
are more characteristic of Class 2 than of Class 3 materials. (d) Has specimens that drip flaming particles that ignite the dry absor-
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NOTE 5—Use the following terms in describing polyethylene plastics: bent surgical cotton placed 305 mm [12 in.] below the test specimen;
Class 1 (0.910 to 0.925) = low density, (e) Does not have any specimens with glowing combustion that persists
Class 2 (>0.925 to 0.940) = medium density, for more than 60 s after the second removal of the test flame.
Class 3 (>0.940 to 0.960) = high density, 3 = When burned vertically in accordance with Test Method D 568, the mate-
rial:
Class 4 (>0.960) = high density, and
(a) Does not have any specimens that burn with flaming combustion for
While Class 3 has been divided into two ranges of density, (Classes 3 and more than 30 s after either application of the test flame;
4), both are still described by the term “high density.” (b) Does not have a total flaming combustion time exceeding 250 s for
the 10 flame applications for each set of five specimens;
5. Suffixes (c) Does not have any specimens that burn with flaming or glowing
combustion up to the holding clamp;
5.1 When using the call-out for the materials covered by this (d) Does not have any specimens that drip flaming particles that ignite
specification, the following suffixes may be used for specific the dry absorbent surgical cotton located 305 mm [12 in.] below the test
specimen;
requirements of the material for the application intended. In (e) Does not have any specimens with glowing combustion that persists
general, the suffix letter indicates the requirement needed; the for more than 60 s after the second removal of the test flame.
first number (digit) indicates the test condition, and the second 4 = When burned vertically as described in Test Method D 568, the material:
(a) Does not have any specimens that burn with flaming combustion for
number (digit) indicates the specimen requirement. The suf- more than 10 s after either application of the test flame;
fixes are as follows: (b) Does not have a total flaming combustion time exceeding 50 s for
5.1.1 E = Electrical requirements as designated by the the 10 flame applications for each set of five specimens;
(c) Does not have any specimens that burn with flaming or glowing
following digits: combustion up to the holding clamp;
(d) Does not have any specimens that drip flaming particles that ignite
First Digit the dry absorbent surgical cotton located 305 mm [12 in.] below the test
0 =To be specified by user. specimen;
1 =Specimens preconditioned 40 h at 23°C and 50 % relative humidity, (e) Does not have any specimens with glowing combustion that persists
then 14 days in distilled water at 23 6 1°C. for more than 30 s after the second removal of the test flame.
Second Digit 5 = When burned vertically in accordance with Test Method D 568, the mate-
0 =To be specified by user. rial:
1 =Volume resistivity, permittivity, and dissipation factor meet property (a) Does not have any specimens that burn with flaming or glowing
limits as shown as follows. These are electrical limits usually applied combustion for more than 60 s after the fifth flame;
to unreinforced polyethylene plastics when control of their electrical (b) Does not have any specimens that drip particles.
properties is required. 6 = Has a burn rate less than 100 mm/min.

Electrical Properties: 5.1.3 W = Weatherability requirements as designated by the


following digits:
Test
Methods
First Digit
Permittivity, max D 1531 2.30
0 = To be specified by user.
Dissipation factor, max D 1531 0.001
1 = Specimens exposed to xenon-arc type light source, in accordance with
Volume resistivity, min D 257 1 3 1015
Practice D 2565, Cycle 1, except that the irradiance shall be 0.70
V-cm
W/(m2•nm) at 340 nm. (For comparison to historical data it is permissible
Water immersion stability D 1531 shall meet the dielectric
to use the D 2565, Cycle 1 irradiance of 0.35 W/(m2•nm) at 340 nm. If
constant and dissipation
used, this shall be noted in the results report.)
factor requirements

5.1.2 F = Flammability requirements6 as designated by the 6


By publication of this specification and its use of flammability ratings, ASTM
following digits: does not suggest that their use in any way reflects hazards presented under actual fire
conditions.

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D 4976 – 04a
2 = Specimens exposed to carbon-arc type light source, in accordance with 8.2 Observed or calculated values obtained from analysis,
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Practice D 6360, using a humidity controlled apparatus. (This test shall be measurement or test, shall be rounded in accordance with the
used only if necessary for comparison with historical data. In all other
cases, tests shall be in accordance with Numbers 1 or 4 of this section.)
rounding method in Practice E 29 to the nearest unit in the last
3 = Specimens exposed to fluorescent-UV-condensation type light source, in right-hand place of figures used in expressing the specified
accordance with Practice D 4329, Cycle A, Type UVB 313 lamps. (This limiting value. The value obtained is compared directly with
condition shall only be used if necessary for comparison with historical
data. Condition 4 shall be used in all other cases.) the specified limiting value. Conformance or nonconformance
4 = Specimens exposed to fluorescent-UV-condensation type light source, in with the specification is based on this comparison.
accordance with Practice D 4329, Cycle A, Type UVA 340 lamps. The irra-
diance level shall be 0.70 W/(m2•nm) at 340 nm.
Specimens for Conditions 1, 2, 3 and 4 above shall be Test Method D 638, 9. Sampling
Type IV tensile bars. 9.1 Unless otherwise agreed upon between the user and the
Second Digit
0 = To be specified by user. supplier, the materials shall be sampled in accordance with the
1 = 200-h exposure. sampling procedure in Practice D 1898. Adequate statistical
2 = 500-h exposure.
3 = 1000-h exposure.
sampling shall be considered an acceptable alternative. A batch
4 = 2000-h exposure. or lot of resin shall be considered as a unit of manufacture as
5 = 4000-h exposure. prepared for shipment and may consist of a blend of two or
6 = 6000-h exposure.
7 = 8000-h exposure.
more production runs of material.
8 = 10000-h exposure.
10. Specimen Preparation
10.1 Unless otherwise specified, test specimens shall be
NOTE 6—The exposure duration shall be that necessary to produce a
substantial change in the property evaluated on testing a product known to compression molded in accordance with Annex A1, Procedure
give poor performance in the application of interest. This requirement will C of Practice D 4703.
provide a duration of sufficient length to identify an unacceptable material. 10.2 The specimen type and dimensions shall comply with
5.1.3.1 The exposed specimens shall not exhibit surface those described in the test method section. Die-cut specimens
changes (such as, dulling and chalking) or deep-seated changes are recommended; however, machine-cut specimens are ac-
(such as, checking, crazing, warping, and discoloration). The ceptable.
tensile strength after exposure must be no less than 50 % of the
original. 11. Conditioning
5.1.4 Z = Other special requirements (for example, internal 11.1 Conditioning—Once specimens are molded, they shall
mold release agent) not covered by existing call-out capabili- be moved to a standard laboratory atmosphere or a controlled
ties may be assigned by the user. These shall be spelled out in laboratory atmosphere. For natural unfilled polyethylene plas-
detail and identified in sequence, that is, 01 UV-stabilized, 02 tics the controlled laboratory atmosphere shall be 23 6 2°C.
special color, and 03 etc. Test specimens, 7 mm or under in thickness, shall be condi-
5.2 Additional suffixes will be added to this specification as tioned for a minimum of 40 h immediately prior to testing. Test
test methods and requirements are developed or requested, or specimens over 7 mm in thickness shall be conditioned for 88
both. h. For filled and reinforced polyethylene plastics or polyethyl-
5.3 Additional suffixes that may be used are listed in Table ene plastic blends, which contain a hydrophilic co-monomer,
3 of Classification D 4000. These use the two-letter, three-digit pigment, or modifier the specimens shall be conditioned in a
suffix system as established for the classification system for standard laboratory atmosphere of 23 6 2°C and 50 6 5 %
plastic materials. relative humidity (see Practice D 618, Procedure A). For all
materials to be conditioned for electrical testing, conditioning
6. Basic Requirements shall comply with the requirements of the standard test
6.1 Basic requirements from property or cell tables, as they methods for electrical testing. In all cases the laboratory shall
apply, are always in effect unless these requirements are report both the temperature and humidity conditions during the
superseded by specific suffix requirements, that always take conditioning period.
precedence. 11.2 Test Conditions—Natural unfilled polyethylene plas-
tics shall be tested in a controlled laboratory atmosphere of
7. Chemical Composition 23 6 2°C. For filled and reinforced polyethylene plastics and
7.1 The plastic composition shall be uniform and shall polyethylene plastic blends, which contain a hydrophilic co-
conform to the requirements specified herein. The color and monomer, pigment, or modifier the specimens shall be condi-
form of the material shall be as agreed upon between the tioned in a standard laboratory atmosphere of 23 6 2°C and
supplier and the user. Specification changes due to the effects 50 6 5 % relative humidity. For all materials to be tested for
of colorants should be noted by both parties and, when electrical properties, the laboratory shall comply with the
necessary, covered by suffixes. requirements of the standard test methods for electrical testing.
In all cases the laboratory shall report both the temperature and
8. Other Requirements humidity conditions during testing.
8.1 Test specimens for the various materials shall conform 11.3 Dispute—In cases of dispute, conditioning and testing
to the requirements prescribed in Table PE and Cell Tables A shall be conducted in accordance with Procedure A of Practice
and B, and to suffix requirements as they apply. D 618.

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D 4976 – 04a
12. Test Methods 12.1.4 Secant Flexural Modulus at 2 % Strain—Test Meth-
12.1 Determine the properties enumerated in this specifica- ods D 790, using Procedure B, with a 51-mm [2-in.] span, and
tion in accordance with the ASTM methods as they apply, testing speed of 12.7 mm/min [0.5 in./min]. Test each 3.2 by
unless otherwise stated in this specification. 12.7-mm [0.125 by 0.5-in.] specimen flatwise and calculate the
12.1.1 Flow Rate—Test Method D 1238, using Condition average value of the secant modulus at 2 % strain in the outer
190°C/2.16 kg unless otherwise directed, (see Note 5). Make fibers.
duplicate determinations on the material in the form of powder, 12.1.5 Environmental Stress-Crack Resistance, Test Method
granules, or pellets. No conditioning is required. D 1693—The materials resistance shall meet the minimum
requirement shown for the appropriate cell classification (in
NOTE 7—Although the flow rate of polyethylene plastics may be Cell Table A) when tested in accordance with Test Method
measured under any of the conditions listed for it under 6.2 of Test Method
D 1238, only measurements made at Condition 190°C/2.16 kg may be
D 1693. Polyethylene materials with densities less than or
identified as “melt index.” equal to 0.925 shall be tested in accordance with Test Method
This method of test serves to indicate the degree of uniformity of the D 1693, Condition A. Polyethylenes with densities greater than
flow rate of the polymer of a single manufacturer as made by an individual 0.925 shall be tested in accordance to Test Method D 1693,
process and in this case may be indicative of the degree of uniformity of Condition B.
other properties. However, uniformity of flow rate among various poly-
mers of various manufacturers as made by various processes does not, in NOTE 8—The specimen dimensions and notch depths are different for
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the absence of other tests, indicate uniformity of other properties and vice these two conditions.
versa. Igepal concentration for all testing is 100%. F50 shall be
The melt viscosity of polyethylene plastics, in common with that of reported. F50 is the time required for failure of 50 % of the
most high polymers, is non Newtonian, that is, dependent on the rate of
shear. The degree of departure from Newtonian behavior depends on the
specimen tested in accordance with the graphical method
nature and molecular constitution of the individual sample. Additional described in Test Method D 1693.
characterization of the sample can be obtained if other conditions are used. 12.1.6 Slow Crack Growth Resistance, Test Method
Especially recommended as an adjunct to Condition 190°C/2.16 kg is F 1473—The average failure time from two test specimens
Condition 190°C/10.0 kg or Condition 190°C/21.6 kg. shall meet the minimum requirement shown (in Cell Table B)
12.1.2 Density—Test Method D 1505 or alternate methods for the appropriate cell classification when tested in accordance
of suitable accuracy, as described in Method A or Method B of with Test Method F 1473 at 80°C and at 2.4 MPa stress.
Test Methods D 792 or Test Method D 4883. Perform duplicate Specimen shall be prepared in accordance with the procedures
density determinations using two specimens taken from the described in Test Method F 1473. A specimen with a nominal
same molding or one specimen taken from each of two thickness of 10 mm shall be used. Test at least four specimens
moldings. in case of a dispute.
12.1.3 Tensile Stress at Yield, Nominal Strain at Break, Test 12.1.7 Thermal Stress Crack Resistance, Test Method
Method D 638—The speed of grip separation shall be 500 mm D 2951—Specimen dimensions shall be in accordance with
[20 in.]/min for specimens of densities of 0.925 g/cm3 or less Test Method D 2951. Each specimen being nominally 127 by
and 50 mm [2 in.]/min for densities greater than 0.925 g/cm3. 6.4 by 1.27 mm [5 by 0.25 by 0.05 in.]
Specimens shall conform to the dimensions given for Type IV
in Test Method D 638 with thickness of 1.9 6 0.2 mm 13. Packaging and Package Marking
[0.075 6 0.008 in.]. Percentage elongation at break shall 13.1 For packing, packaging, and package marking, the
include the cold-drawing distance. Test results for specimens provisions of Practice D 3892 apply.
that break outside the gage marks after extensive cold drawing
need not be discarded unless the break occurs between the 14. Keywords
contact surfaces of a grip. 14.1 molding and extrusion materials; polyethylene

SUPPLEMENTARY REQUIREMENTS

The following supplementary items may become part of this specification, when applicable, as
agreed upon between the user and the supplier.

S1. Approval S2. Infrared Spectrophotometry or Thermal Analysis, or


S1.1 Material submitted by a new supplier must be ap- Both
proved by the user. Material or test specimens submitted by the S2.1 At the option of the user, infrared or thermal analysis,
supplier and intended for evaluation shall be accompanied by or both may be conducted on material/parts supplied to this
the supplier’s laboratory test report. specification. The curves established for initial approval shall
S1.2 New Sources—The user may elect to temporarily constitute the reference standard and shall be kept on file at the
accept shipment on the supplier’s certification.

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D 4976 – 04a
user’s laboratory. All samples shall produce curves that corre- specific use requirements. This is discussed in Sections 7 and
spond to the reference standard within agreed upon tolerances 8 of Practice D 1898, with reference to MIL-STD-105. In the
when tested under the same conditions as those specified on the absence of contrary requirements, the following values shall
master set of curves. apply:
S2.2 In the event such tests are to be designated as require-
ments to be tested by the supplier, this must appear on the part Testing (polymer, unfabricated) IL AQL
drawing or purchase contract, or both. S-1 ...

S3. Quality Assurance Provisions for Government/


Military Procurement
NOTE S00012—Inspection Level (IL) samples shall be drawn from the
S3.1 Selection of Acceptable Quality Level (AQL) and of required number of units and pooled for preparation of molded samples
Inspection Level (IL) shall be made with consideration of the for property evaluation.

SUMMARY OF CHANGES

Committee D20 has identified the location of selected changes to this standard since the last issue,
D 4976 - 04, that may impact the use of this standard. (December 1, 2004)

(1) Updated weathering standards in 2.1. (2) Revised 5.1.3 on weatherability.

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in this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the risk
of infringement of such rights, are entirely their own responsibility.

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Copyright ASTM International 7


Copyright by ASTM Int'l (all rights reserved);
Provided by IHS under license with ASTM Sold to:LADTECH, INC., W0355264
No reproduction or networking permitted without license from IHS Not for Resale,2006/9/25 21:13:10 GMT
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