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87228208
87228208
87228208
INTRODUCTION
This specification is not intended for the selection of materials, but only as a means to call out
plastic materials to be used for the manufacture of parts. The selection of these materials is to be made
by personnel with expertise in the plastics field where the environment, inherent properties of the
materials, performance of the parts, part design, manufacturing process, and economics are
considered. This specification does not specify the source of the resin to be used for the fabrication
of any given article.
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This specification is under the jurisdiction of ASTM Committee D20 on For referenced ASTM standards, visit the ASTM website, www.astm.org, or
Plastics and is the direct responsibility of Subcommittee D20.15 on Thermoplastic contact ASTM Customer Service at service@astm.org. For Annual Book of ASTM
Materials. Standards volume information, refer to the standard’s Document Summary page on
Current edition approved December 1, 2004. Published December 2004. Origi- the ASTM website.
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nally approved in 1995. Last previous edition approved in 2004 as D 4976 - 04. Withdrawn.
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Available from United States Department of Transportation, National Highway
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Available from Standardization Documents Order Desk, Bldg. 4 Section D, 700 Traffic Safety Administration, Office of Public Affairs and Consumer Participation,
Robbins Ave., Philadelphia, PA 19111-5094, Attn: NPODS. 400 7th St., SW, Washington, DC 20590.
NOTE 5—Use the following terms in describing polyethylene plastics: bent surgical cotton placed 305 mm [12 in.] below the test specimen;
Class 1 (0.910 to 0.925) = low density, (e) Does not have any specimens with glowing combustion that persists
Class 2 (>0.925 to 0.940) = medium density, for more than 60 s after the second removal of the test flame.
Class 3 (>0.940 to 0.960) = high density, 3 = When burned vertically in accordance with Test Method D 568, the mate-
rial:
Class 4 (>0.960) = high density, and
(a) Does not have any specimens that burn with flaming combustion for
While Class 3 has been divided into two ranges of density, (Classes 3 and more than 30 s after either application of the test flame;
4), both are still described by the term “high density.” (b) Does not have a total flaming combustion time exceeding 250 s for
the 10 flame applications for each set of five specimens;
5. Suffixes (c) Does not have any specimens that burn with flaming or glowing
combustion up to the holding clamp;
5.1 When using the call-out for the materials covered by this (d) Does not have any specimens that drip flaming particles that ignite
specification, the following suffixes may be used for specific the dry absorbent surgical cotton located 305 mm [12 in.] below the test
specimen;
requirements of the material for the application intended. In (e) Does not have any specimens with glowing combustion that persists
general, the suffix letter indicates the requirement needed; the for more than 60 s after the second removal of the test flame.
first number (digit) indicates the test condition, and the second 4 = When burned vertically as described in Test Method D 568, the material:
(a) Does not have any specimens that burn with flaming combustion for
number (digit) indicates the specimen requirement. The suf- more than 10 s after either application of the test flame;
fixes are as follows: (b) Does not have a total flaming combustion time exceeding 50 s for
5.1.1 E = Electrical requirements as designated by the the 10 flame applications for each set of five specimens;
(c) Does not have any specimens that burn with flaming or glowing
following digits: combustion up to the holding clamp;
(d) Does not have any specimens that drip flaming particles that ignite
First Digit the dry absorbent surgical cotton located 305 mm [12 in.] below the test
0 =To be specified by user. specimen;
1 =Specimens preconditioned 40 h at 23°C and 50 % relative humidity, (e) Does not have any specimens with glowing combustion that persists
then 14 days in distilled water at 23 6 1°C. for more than 30 s after the second removal of the test flame.
Second Digit 5 = When burned vertically in accordance with Test Method D 568, the mate-
0 =To be specified by user. rial:
1 =Volume resistivity, permittivity, and dissipation factor meet property (a) Does not have any specimens that burn with flaming or glowing
limits as shown as follows. These are electrical limits usually applied combustion for more than 60 s after the fifth flame;
to unreinforced polyethylene plastics when control of their electrical (b) Does not have any specimens that drip particles.
properties is required. 6 = Has a burn rate less than 100 mm/min.
Practice D 6360, using a humidity controlled apparatus. (This test shall be measurement or test, shall be rounded in accordance with the
used only if necessary for comparison with historical data. In all other
cases, tests shall be in accordance with Numbers 1 or 4 of this section.)
rounding method in Practice E 29 to the nearest unit in the last
3 = Specimens exposed to fluorescent-UV-condensation type light source, in right-hand place of figures used in expressing the specified
accordance with Practice D 4329, Cycle A, Type UVB 313 lamps. (This limiting value. The value obtained is compared directly with
condition shall only be used if necessary for comparison with historical
data. Condition 4 shall be used in all other cases.) the specified limiting value. Conformance or nonconformance
4 = Specimens exposed to fluorescent-UV-condensation type light source, in with the specification is based on this comparison.
accordance with Practice D 4329, Cycle A, Type UVA 340 lamps. The irra-
diance level shall be 0.70 W/(m2•nm) at 340 nm.
Specimens for Conditions 1, 2, 3 and 4 above shall be Test Method D 638, 9. Sampling
Type IV tensile bars. 9.1 Unless otherwise agreed upon between the user and the
Second Digit
0 = To be specified by user. supplier, the materials shall be sampled in accordance with the
1 = 200-h exposure. sampling procedure in Practice D 1898. Adequate statistical
2 = 500-h exposure.
3 = 1000-h exposure.
sampling shall be considered an acceptable alternative. A batch
4 = 2000-h exposure. or lot of resin shall be considered as a unit of manufacture as
5 = 4000-h exposure. prepared for shipment and may consist of a blend of two or
6 = 6000-h exposure.
7 = 8000-h exposure.
more production runs of material.
8 = 10000-h exposure.
10. Specimen Preparation
10.1 Unless otherwise specified, test specimens shall be
NOTE 6—The exposure duration shall be that necessary to produce a
substantial change in the property evaluated on testing a product known to compression molded in accordance with Annex A1, Procedure
give poor performance in the application of interest. This requirement will C of Practice D 4703.
provide a duration of sufficient length to identify an unacceptable material. 10.2 The specimen type and dimensions shall comply with
5.1.3.1 The exposed specimens shall not exhibit surface those described in the test method section. Die-cut specimens
changes (such as, dulling and chalking) or deep-seated changes are recommended; however, machine-cut specimens are ac-
(such as, checking, crazing, warping, and discoloration). The ceptable.
tensile strength after exposure must be no less than 50 % of the
original. 11. Conditioning
5.1.4 Z = Other special requirements (for example, internal 11.1 Conditioning—Once specimens are molded, they shall
mold release agent) not covered by existing call-out capabili- be moved to a standard laboratory atmosphere or a controlled
ties may be assigned by the user. These shall be spelled out in laboratory atmosphere. For natural unfilled polyethylene plas-
detail and identified in sequence, that is, 01 UV-stabilized, 02 tics the controlled laboratory atmosphere shall be 23 6 2°C.
special color, and 03 etc. Test specimens, 7 mm or under in thickness, shall be condi-
5.2 Additional suffixes will be added to this specification as tioned for a minimum of 40 h immediately prior to testing. Test
test methods and requirements are developed or requested, or specimens over 7 mm in thickness shall be conditioned for 88
both. h. For filled and reinforced polyethylene plastics or polyethyl-
5.3 Additional suffixes that may be used are listed in Table ene plastic blends, which contain a hydrophilic co-monomer,
3 of Classification D 4000. These use the two-letter, three-digit pigment, or modifier the specimens shall be conditioned in a
suffix system as established for the classification system for standard laboratory atmosphere of 23 6 2°C and 50 6 5 %
plastic materials. relative humidity (see Practice D 618, Procedure A). For all
materials to be conditioned for electrical testing, conditioning
6. Basic Requirements shall comply with the requirements of the standard test
6.1 Basic requirements from property or cell tables, as they methods for electrical testing. In all cases the laboratory shall
apply, are always in effect unless these requirements are report both the temperature and humidity conditions during the
superseded by specific suffix requirements, that always take conditioning period.
precedence. 11.2 Test Conditions—Natural unfilled polyethylene plas-
tics shall be tested in a controlled laboratory atmosphere of
7. Chemical Composition 23 6 2°C. For filled and reinforced polyethylene plastics and
7.1 The plastic composition shall be uniform and shall polyethylene plastic blends, which contain a hydrophilic co-
conform to the requirements specified herein. The color and monomer, pigment, or modifier the specimens shall be condi-
form of the material shall be as agreed upon between the tioned in a standard laboratory atmosphere of 23 6 2°C and
supplier and the user. Specification changes due to the effects 50 6 5 % relative humidity. For all materials to be tested for
of colorants should be noted by both parties and, when electrical properties, the laboratory shall comply with the
necessary, covered by suffixes. requirements of the standard test methods for electrical testing.
In all cases the laboratory shall report both the temperature and
8. Other Requirements humidity conditions during testing.
8.1 Test specimens for the various materials shall conform 11.3 Dispute—In cases of dispute, conditioning and testing
to the requirements prescribed in Table PE and Cell Tables A shall be conducted in accordance with Procedure A of Practice
and B, and to suffix requirements as they apply. D 618.
the absence of other tests, indicate uniformity of other properties and vice these two conditions.
versa. Igepal concentration for all testing is 100%. F50 shall be
The melt viscosity of polyethylene plastics, in common with that of reported. F50 is the time required for failure of 50 % of the
most high polymers, is non Newtonian, that is, dependent on the rate of
shear. The degree of departure from Newtonian behavior depends on the
specimen tested in accordance with the graphical method
nature and molecular constitution of the individual sample. Additional described in Test Method D 1693.
characterization of the sample can be obtained if other conditions are used. 12.1.6 Slow Crack Growth Resistance, Test Method
Especially recommended as an adjunct to Condition 190°C/2.16 kg is F 1473—The average failure time from two test specimens
Condition 190°C/10.0 kg or Condition 190°C/21.6 kg. shall meet the minimum requirement shown (in Cell Table B)
12.1.2 Density—Test Method D 1505 or alternate methods for the appropriate cell classification when tested in accordance
of suitable accuracy, as described in Method A or Method B of with Test Method F 1473 at 80°C and at 2.4 MPa stress.
Test Methods D 792 or Test Method D 4883. Perform duplicate Specimen shall be prepared in accordance with the procedures
density determinations using two specimens taken from the described in Test Method F 1473. A specimen with a nominal
same molding or one specimen taken from each of two thickness of 10 mm shall be used. Test at least four specimens
moldings. in case of a dispute.
12.1.3 Tensile Stress at Yield, Nominal Strain at Break, Test 12.1.7 Thermal Stress Crack Resistance, Test Method
Method D 638—The speed of grip separation shall be 500 mm D 2951—Specimen dimensions shall be in accordance with
[20 in.]/min for specimens of densities of 0.925 g/cm3 or less Test Method D 2951. Each specimen being nominally 127 by
and 50 mm [2 in.]/min for densities greater than 0.925 g/cm3. 6.4 by 1.27 mm [5 by 0.25 by 0.05 in.]
Specimens shall conform to the dimensions given for Type IV
in Test Method D 638 with thickness of 1.9 6 0.2 mm 13. Packaging and Package Marking
[0.075 6 0.008 in.]. Percentage elongation at break shall 13.1 For packing, packaging, and package marking, the
include the cold-drawing distance. Test results for specimens provisions of Practice D 3892 apply.
that break outside the gage marks after extensive cold drawing
need not be discarded unless the break occurs between the 14. Keywords
contact surfaces of a grip. 14.1 molding and extrusion materials; polyethylene
SUPPLEMENTARY REQUIREMENTS
The following supplementary items may become part of this specification, when applicable, as
agreed upon between the user and the supplier.
SUMMARY OF CHANGES
Committee D20 has identified the location of selected changes to this standard since the last issue,
D 4976 - 04, that may impact the use of this standard. (December 1, 2004)
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