Jeeadv 19 Paper

Sri Chaitanya IIT Academy Question Paper-1_Key & Solutions
PHYSICS
SECTION-I
SINGLE ANSWER TYPE
SECTION 1 (Maximum Marks: 12)
• This section contains FOUR (04) questions.
• Each question has FOUR options. ONLY ONE of these four options is the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme: Full Marks : +3 If ONLY the
correct option is chosen; Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered); Negative
Marks : —1 In all other cases.
Question ID: 337911112
1. In a radioactive sample, 1940 K nuclei either decay into stable 40 20 Ca nuclei with decay
constant 4.5  1010 per year of into stable 1840 Ar nuclei with decay constant 0.5  1010 per
year. Given that in this sample all the stable 4020 Ca and 1840 Ar nuclei are produced by the
40 9 40 40
19 K nuclei only. In time t  10 years, if the ratio of the sum of stable 20 Ca and 18 Ar
40
nuclei to the radioactive 19 K nuclei is 99, the value of r will be [Given: ln10  2.3 ]
1) 4.6 2) 2.3 3) 9.2 4) 1.15
Ans: 3
Sol:  eff  1   2   4.5  0.5 10 10  5  10 10 per year
lt0 N0 N0
N  N 0 e  and given that N   N 0 e   t0
100 100
2n10 2  2.3
10 2  et0   t 0  t0  10
 9.2  109 Years  t  109 Years
 5  10
2. Consider a spherical gaseous cloud of mass density   r  in a free space where r is the
radial distance from its centre. The gaseous cloud is made of particles of equal mass m
moving in circular orbits about their common centre with the same kinetic energy K.
The force acting on the particles is their mutual gravitational force. If   r  is constant
with time. The particle number density n  r  =   r  /m is:
[ G is universal gravitational constant]
K 3K K K
1) 2) 3) 4)
 r m2 G
2
 r 2 m2 G 6 r 2 m 2G 2 r 2 m 2G
Ans: 4
GM  r  m mv 2
Sol: M(r) = mass of gas in a sphere of radius r. Can any particle, Fg  Fcp 
r2 r
m
v
r
2K
GM (r) m = 2(K) r  M r  r
Gm
Sri Chaitanya IIT Academy

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dM 2 K
On differentiating w.r.t r,  ................ (1)
dr Gm
Here dM = mass of gas in a spherical shell of radius r and thickness dr.
 dM     r    dv      r   4 r 2 dr ............... (2) Substitute (2) in (1)
   r  4 r 2 dr 2 K K  r K
  r  nr  
dr Gm 2 r 2Gm m 2 r 2Gm 2
3. A current carrying wire heats a metal rod. The wire provides a constant power P to the
rod. The metal rod is enclosed in an insulated container. It is observed that the
temperature (T) in the metal rod changes with time (t) as T(t)=T0 1  t1/4 
Where  is a constant with appropriate dimensions while T0 is a constant with
dimensions of temperature. The heat capacity of metal is
3 2 4
4P T  t   T0  4P T  t   T0  4P T  t   T0  4P T  t   T0 
1) 2) 3) 4)
 4T04  4T02  4T03  4T05
Ans: 1
dT d
Sol: P  ms
dt
 H
dt 

T0 1  t1/ 4 
 
HT0  3/4
 t ................ (1) T  T0 1  t 1/4 
4
3
T T0  T0 
 1  t1/4  t 1/ 4   t 3/4   .............. (2)
T0 T  T0  T  T0 
3
HT   3T03 4 P T  T0 
Substitute (2) in (1) P  0 3
H 
4 T  T0   4T04
4. A thin spherical insulating shell of radius R carries a uniformly distributed charge such
that the potential at its surface is V0. A hole with a small area  4 R 2   1 is made on
the shell without affecting the rest of the shell. Which one of the following statement(s)
is correct?
V0
1) The magnitude of electric field at the centre of the shell is reduced by
2R
1
2) The ratio of the potential at the centre of the shell to that of the point at R from
2
1 
centre towards the hole will be
1  2
3) The magnitude of electric field at a point, located on a line passing through the hole
and shell’s center, on a distance 2R from the center of the spherical shell will be
V0
reduced by
2R
4) The potential at the center of the shell is reduced by 2V0

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Ans: 2
KQ K  4 r 2
Sol: v0   At center, v1  v0 - (potential due to removed element)
R R
Kq K
 v0 
R
 v0 
R
 
 4 R 2  v0  v0  v0 1   
At mid point between center and hole is

kq
V2  V0   V0  2V0  V0 1  2 
R/2
V1 V0 1    1 
    2 is correctOption A : Einitial =0
V2 V0 1  2  1  2
Kq k 4 R 2 V0 V V
Efinal = z  2
 Ei  E f  0 i.e E will decrease by 0 i.e. (C) is wrong
R R R R R
K  4 R 2
Option D: Vinitial = V0Vfinal  V0   V0  V0
R
 Vcenter decreases by V0 . i.e. (D) is wrong
Ans: 2
SECTION-II
ONE OR MORE TYPE
(Maximum Marks: 32)
• This section contains EIGHT (08) questions.
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : —1 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options
will get —1 mark.

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1. A thin convex lens is made of two materials with refractive indices n1 and n2, as shown
in figure. The radius of curvature of the left and right spherical surface are equal. f is
the focal length of the lens when n1  n2  n . The focal length is f  f when
n1  n and n2  n  n . Assuming n   n  1 and 1  n  2 , the correct statement(s)
is/are,
n1 n2
n f
1) If  0 then 0
n f
2) For n=1.5, n  103 and f  20 cm, the value of f will be 0.02cm (rounded off to
2nd decimal place).
f n
3) The relation between and remains unchanged if both the convex surfaces are
f n
replaced by concave surface of the same radius of curvature.
f n
4) 
f n
Ans: 1,2,3
n n+dn
12
R
Sol: f  ____ 1
2  n  1
1 n  1  n  dn  1 1 1 dn
In 2nd case,    
f  df R R f  df f R
1
Clearly, if dn  0, R.H.S value is less than  df  0 i.e (1) is correct
f
Option(2)
R 1 1 dn
f   R  20cm ,  
2 1.5  1 f  df f R

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1 1 dn 1 1
  =  1  dn
20  df 20 20  df  20
20 1  
 20 
df
1  1  dn  df  20dn  20  103 cm
20
 df  0.02cm (2) is correct
Option(3): If convex surfaces are replaced with concave surfaces, sign of R will change
 R 
f 
1 1 dn 1 dn  2  n  1 
     
 df  f R f 2 f  n  1  1 1 
f 1    
 f   R 2 f  n  1 
df  
1  
f 1 dn df  dn  1
 1      As this is independent of R, (3) is
f f   1  f  n  1
2n  1   2 1  
  n    n
df dn 1  1
correct. Option (4):  For the range 1 < n < 2, 2 1   is always
f n  1  n
2 1  
 n
df dn
greater than 1 i.e,  (4) is wrong
f n
2. A charged shell of radius R carries a total charge Q. Given  as the flux of electric field
through a closed cylindrical surface of height h, radius r and with its center same as that
of the shell. Here, center of the cylinder is a point on the axis of the cylinder which is
equidistant from its top and bottom surfaces. Which of the following options is/are
correct?
[ 0 is the permittivity of free space]
1) If h  8R / 5 and r  3R / 5 then   0
2) If h  2 R and r  R then   Q / 0
3) If h  2 R and r  3R / 5 then   Q / 5 0
4) If h  2 R and r  4 R / 5 then   Q / 5 0
Ans: 1,2,3

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8R 3R
Sol. Option-1: If h  and r  , the cylindrical surface just fits into the sphere. If
5 5
8R q 0
h , the cylindrical surface will be well inside the sphere.   in   0
5 0 0
 (1) is correct
3R
5
+ +
4R +
+
R
5
+
+ +
+
Q
Option -2: If h>2R and r>R the sphere will be well inside the cylinder.  
0
+ +
+
+
h  2R
R
+ +
+
rR
 (2) is correct
Q 4 Q qin Q
Option -3: qin   QAB  2  1  cos    2  Q 1      
2  5 5 0 5 0
 (3) is correct
r  3R / 5
+
+A B
+
+
 +
R
h  2R
+ +
+
B'
A'
+ +
Q
Option -4: qin  1  cos53º  2  2Q 5 Q  2Q 5 
2 0
 (4) is wrong

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3. Two identical moving coil galvanometers have 10 resistance and full scale deflection
at 2 A current. One of them is converted into a voltmeter of 100mV full scale reading
and the order into an Ammeter of 1mA full scale current using appropriate resistors.
These are then used to measure the voltage and current in the Ohm’s law experiment
with R=1000  resistor by using an ideal cell. Which of the following statement(s)
is/are correct?
1) If the ideal cell is replaced by a cell having internal resistance of 5 then the
measured value of R will be more than 1000
2) The measured value of R will be 978  R  982
3) The resistance of the Voltmeter will be 100k
4) The resistance of the Ammeter will be 0.02 (round off to 2nd decimal place)
Ans: 2,4
Sol: Option 4:  I g  G   I   RA   2  10 10  1  10  R
6 3
A
 Resistance of ammeter RA  0.02 (4) is correct

V 101
Option 3: V   I g  RV  RV   6
 5  10 4   50k  (3) is wrong
Ig 2  10
Option 2:
RV
V
RA
A
R
V1 V2
R.RV
R1  , R  RA Reading of ammeter = I
R  RV 2
Reading of voltmeter V = IR
V
Measured value of resistance is Rm   R1
I
R.RV 103  5  104 5  10 4
  3   980.4   2 is correct
R  RV 10  5  10 4 M
Option 1: measured value of R depends on R and RV only, but independent of RA, r

values. Measured value of resistance will again be 980.4 only

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4. A conducting wire of parabolic shape, initially y  x2 is moving with velocity
    y 

V  V0 i in a non – uniform magnetic field B  B0  1     k , as shown in figure. If
  L 
V0 .B0 , L and  are positive constants and  is the potential difference developed
between the ends of the wire, then the correct statement(s) is/are
y

B
L 
V  V0 i
0 x
L
1
1)   B0V0 L for   0
2
2)  is proportional to the length of the wire projected on the y-axis.
3)  remains the same if the parabola wire is replaced by a straight wire, y=x initially,
of length 2L
4
4)   B0V0 L for   2
3
Ans: 2,3,4
B 1 
  yB   y    
Sol:    V0 B0 1     .dy , B0V0  4      ,  B0V0   
        
0
   1
   2  4
 B0V0     0    2 0V0  ,   2    B0V0   
   1   3

5. Let consider a system of units in which mass and angular momentum are dimensionless.
If length has dimensions of L, which of the following statement(s) is/are correct?
1) The dimension of linear momentum is L1
2) The dimension of power is L5
3) The dimension of energy L2
4) The dimension of force is L3
Ans: 1,3,4
Sol:  mass    M º Lº T º   Angular momentum    M º Lº T º 
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 r.M .V    M º Lº T º   m  rV    M º Lº T º 
2 1
 M º Lº T º   L ' L 'T 1    M º Lº T º   L   T 
2
1  mv 2  1 1
 P    mv    m v    r   L1  power    1 2 t    m   r   r 2   L4
       
2
1 1 mv 1 1
 Energy    1 2 mv 2    2   M   r   L2  Force   t    m   2   L2   L3
        
6. One mole of a monatomic ideal gas goes through a thermodynamics cycle, as shown in
the volume versus temperature V  T  diagram. The correct statement(s) is/are: [R is
the gas constant]
V
3
2V0 2
V0
4 1
T0 / 2 T0
T
3T0 / 2 2T0
1
1) Work done in this thermodynamic cycle 1  2  3  4  1 is W  RT0
2
Q1 2 5
2) The ratio of heat transfer during processes 1  2 and 2  3 is 
Q23 3
Q1 2 1
3) The ratio of heat transfer during processes 1  2 and 3  4 is 
Q3 4 2
4) The above thermodynamic cycle exhibits only isochoric and adiabatic processes.
Ans: 1,2
Sol:  i  W  Area
p
nRT0 1 2
V0
nRT0 4 3
2V0
v
n 1
 nRT0  1 RT Q12 nC p T 5 Q12 nC p T1
 V   ii     iii   2
 2V0  2
0 0
Q13 nCV T 3 Q34 nC p T2
 iv isochoric and adiabatic

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7. A cylindrical capillary tube of 0.2mm radius is made by joining two capillaries T1 and
T2 of different materials having water contact angles of 0º and 60º, respectively. The
capillary tube is dipped vertically in water in two different configurations, case I and II
as shown in figure. Which of the following option(s) is(are) correct?
[ surface tension of water =0.075N/m, density of water =1000kg/m3, take g=10m/s2]
1) For case II, if the capillary joint is 5cm above the water surface, the height of water
column raised in the tube will be 3.75cm. (Neglect the weight of the water in the
meniscus)
2) For case I, if the capillary joint is 5cm above the water surface, the height of water
column raised in the tube will be more than 8.75cm. (Neglect the weight of the water in
the meniscus)
3) The correction in the height of water column raised in the tube, due to weight of
water contained in the meniscus, will be different for both cases.
4) For case I, if the joint is kept at 8cm above the water surface, the height of water
column in the tube will be 7.5cm. (Neglect the weight of the water in the meniscus)
Ans: 1,3,4
2  0.075cos 0º
Sol: 1  0º  2  60º h1   0.075m  7.5cm
 0.2  103  103  10
2  0.075  cos 60º
h2   3.75cm Case -1 : If point is 5 cm above (5 Cm < 7.5 cm)
0.2  10 3  103  10
h = 5cm + 3.75 cm = 8.75 case 2 : 5 cm > 3.75 cm h = 3.75 cm
8. In the circuit shown, initially there is no charge on capacitors and keys S1 and S2 are
open. The values of the capacitors are C1  10 F , C2  30 F and C3  C4  80 F .
Which of the statement(s) is/are correct?

Page-11

1) If key S1 is kept closed for long time such that capacitors are fully charged, the
voltage across the capacitor C1 will be 4V.
2) At time t=0, the key S1 is closed, the instantaneous current in the closed circuit will
be 25mA.
3. If key S1 is kept closed for long time such that capacitors are fully charged, the
voltage difference between points P and Q will be 10V.
4) The key S1 is kept closed for long time such that capacitors are fully charged. Now
key S2 is closed, at this time, the instantaneous current across 30 resistor (between
points P and Q) will be 0.2A (round off to 1st decimal place)
Ans: 1, 2, 4
40  10
Sol: C net =  8 F  Q  40C
40  10
1 V 30
2
4v  
 1 V
 2
70 30
10v
100
40C
V across C1   4V (at steady state)
10 F
5
Just after S1 is closed, i   25mA
30  70  100
Long time after S1 is closed, VPQ  VC 1  4V Just after S 2 is closed
i1    
i1  i2 i2
 
  
 

 
100
10  30  i1  i2   4  70i,  0 10  30  i1  i2   1 2  5  30i2  100i2  1 2  0

30i2  100i1  6 60i2  30i1  6 i1  i2  0.05 A
SECTION-III
DECIMAL INTEGER TYPE
(Maximum Marks: 18)
• This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal
places, truncate/round-off the value to TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme: Full Marks : +3 If
ONLY the correct numerical value is entered; Zero Marks : 0 In all other cases.

Page-12

1. A block of weight 100N is suspended by copper and steel wires of same cross
sectional area 0.5cm2 and, length 3 m and 1m, respectively. Their other ends are
fixed on a ceiling as shown in figure. The angles subtended by copper and steel wires
with ceiling are 30º and 60º, respectively. If elongation in copper wire is  lC  and
l
elongation in steel wire is  lS  , then the ratio C is___
lS
[Young’s modulus for copper and steel are 1  1011 N / m 2 and 2  1011 N / m 2 ,
respectively.]
Ans: 2
60º TS sin 60
30
TCu sin 30
TS
TCu
60 30
TS cos60 TCu cos  30
Sol: 100
TS 3
TS cos60  Tcell cos30  TCu
2 2
TS  3TCu TS sin 60  TCu sin 30  100
3 TCu
3TCu    100 2TCu  100
2 2
TCu  100 TCu  50 N
lCu T
TS  3  50 N  Elongation in Cu wire   Cu
lCu Ar ycel
TCu
lCu  lCu  elongation in steel wire
AyCu
lCTCu
lsTS lC A yCu l T 3  50  2  10
ls    Cu Cu Ystell  =2
A yS lS lS TS yCu lSTS 1  1011  1  3  50
A ystell

Page-13

2. A planar structure of length L and width W is made of two different optical media of
refractive indices n1  1.5 and n2  1.44 as shown in figure. If L  W , a ray entering
from end AB will emerge end CD only if the total internal reflection condition is met
inside the structure. For L  9.6m , if the incident angle  is varied, the maximum time
taken by a ray to exit the plane CD is t  109 s, where t is___
Ans: 50 (49 - 51)

d C

x
Sol:
K 2 MnO4 
 KMnO4
 w X 
24 x
MnO42  MnO4
 Z

Y 
25 d
25 x 25
d  distance travelled by light ray   9.6  10m
24 24
d
Time taken by ray to travel=
speedin med n1
10 1.5  10
 5
 5  108 S .  50  109 S
 C  3  10
 
1.5
3. A train S1, moving with a uniform velocity of 108 km/h approaches another train S2
standing on a platform. An observer O moves with a uniform velocity of 36km/h
towards S2 as shown in figure. Both the trains are blowing whistles of same frequency
120Hz. When O is 600m away from S2 and distance between S1 and S2 is 800m, the
number of beats heard by O is_____
[ Speed of the sound =330m/s]
108 km/h
S2 S1
800m
600m
36 km/h

Page-14

Ans: 8.12 (7.00 -10.00)
Sol:
800
S2 S1
2
600
1
800 4
tan 1     53º  2  37º  Freq. Heared form train at S 2  f 2
600 3 1
 V  V0   330  10  340
f2   fs   fs  f s  1.030 f s
 V   330  330
 V  V0 cos 1 
 freq. Heared from train at S1  f1 f1   fs
 V  Vs cos  2 
 3
330  10 
 5 f  336 
 f1   f  1.098 f s
4 s  306  s
 330  30  
5
 Beat fieq  1.098 f s  1.030 f s  0.068 f s  0.068  120  8.16  8
Question ID:337911121
4. A particle is moved along a path AB-BC-CD-DE-EF-FA, as shown in figure, in

presence of a force F   yi  2 x j N , where x and y are in meter and   1Nm 1 .
 

The work done on the particle by this force F will be ___ Joule.
Ans: 0.75
Sol:
 
F   yi2 x j AB : y  const F  i  2 x j

Page-15

  
dr  dx j
1
WAB   F .dr
x0
1
   dx WAB  1
0

BC:x=const F   yi  2 j

dr  dy j
0.5
WBC   2 dy
y 1
WBC  1 CD: y const

 
F  0.5 j  2 x j d r  dx 66i
0.5
WCD   0.5dx WCD  0.25 J
1

DE: x=const F   yi  j

dr  dyi
0
WDE    dy
y  0.5
 0.5 EF:

Y=0 F  2 x j

d r  dx j W 0
FA: W = 0 Wnet  1  1  0.25  0.5  0.75

5. A liquid at 30ºC is poured very slowly into a Calorimeter that is at temperature of
110ºC. The boiling temperature of the liquid is 80ºC. It is found that the first 5gm of
the liquid completely evaporates. After pouring another 80gm of the liquid the
equilibrium temperature is found to be 50ºC. The ratio of the Latent heat of the liquid
to its specific heat will be ___ºC.
[ Neglect the heat exchange with surrounding)
Ans: 270
Sol: Step 1:Heat lost by calorimeter  mcal Scal  30
Heat gained by liq  5  Sliq .50  mL mCal SCal 30  Seiq 50  5L f ___ 1
Step 2: Heat lost by calorimeter = mcal Scal  30
Heat gained by liq = 80  Sliq  20 mCal SCal  30  80 S eiq 20 ___  2
Lf 1350
1600 Sliq  250Sliq  5L f 1350 Sliq  5L f   270
Sliq 5

Page-16

Question ID:337911124
6. A parallel plate capacitor of capacitance C has spacing d between two plates having
area A. The region between the plates is filled with N dielectric layers, parallel to its
d
plates, each with thickness   . The dielectric constant of the mth layer is
N
 m  K 0 A 
 N
 
K m  K 1   . For a very large N  103 , the capacitance C is  
 d ln 2 
. The
value of  will be___[ 0 is the permittivity of free space]

Ans: 1 (0.99 – 1.01)
x

Sol: dx
 mn 
K 1   A
K 0 A x D  N 0
dc   
dx m N dx
d
 Nx   x
K 1   A 1 ln 1  
 DN  0 d dx 1  D0
dc   
dx Ceq x0  x  K 0 A  1
K 0 A  1    
 D D
1 D K 0 A
0
 ln  2 Ceq  K=1
Ceq K 0 A D ln 2

Page-17

Chemistry
SECTION-I
SINGLE ANSWER TYPE
• Answer to each question will be evaluated according to the following marking scheme: Full Marks : +3 If ONLY the
correct option is chosen; Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered); Negative
Marks : —1 In all other cases.
Question Id: 337911129
1. Molar conductivity (  m ) of aqueous solution of sodium stearate, which behaves as a
strong electrolyte is recorded at varying concentration(C) of sodium stearate. Which
one of the following plots provides the correct representation of micelle formation in
the solution?
(Critical micelle concentration (CMC) is marked with an arrow in the figures)
m m
CMC CMC
1) C 2) C
CMC CMC
m m
3) C 4) C
Ans: 4
Sol: Conceptual
2. Calamine, malachite, magnetic and cryolite, respectively, are
1) ZnCO 3, CuCO3Cu(OH)2, Fe3O4, Na3AlF6
2) ZnSO4, Cu(OH)2, Fe3O4, Na3AlF6
3) ZnSO4,CuCO3, Fe2O3, AlF3
4) ZnCO 3,CuCO 3,Fe2O 3,Na3AlF6
Ans: 1
Sol: Calamine  ZnCO3 Malachite  CuCO3 .Cu  OH  2
Magnetite  Fe3O4 Cryalite  Na3 AlF6
3. The green colour produced in the borax bead test of a chromium(III) salt is due to
1) Cr2(B4O 7)3 2) Cr2O3 3) Cr(BO2)3 4) CrB
Ans: 3
Page-18

 
Sol: Na2 B4O7 .10 H 2O 
 Na2 B4O7 
 Na2 NO2  B2O3
Cr2 O3  3 B2O3  2Cr  BO2 3 Chromium meta borate.
4. The correct order of acid strength of the following carboxylic acid is
O
O H O OH
OH
H MeO H3C
OH H OH O
I II III IV
1) I > II > III > IV 2) II > I > IV > III
3) I > III > II > IV 4) III > II > I > IV
Ans: 1
Sol: Electronegative order sp  C   sp 2  C   sp 3  C  .
O
O O
OH
CH C OH > OMe >
> CH2 CH OH OH
O
SECTION-II
ONE OR MORE TYPE
(Maximum Marks: 32)
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme
Full Marks : +4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen and both of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : —1 In all other cases.
• For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;
choosing no option (i.e. the question is unanswered) will get 0 marks; and choosing any other combination of options
will get —1 mark.

Page-19

1. Which of the following statement(s) is(are) true?
1) Oxidation of glucose with bromine water gives glutamic acid
2) Hydrolysis of sucrose gives dextrorotatory glucose and laevorotatory fructose
3) The two six-membered cyclic hemiacetal forms of D-(+)-glucose are called
anomers
4) Monosaccharides cannot be hydrolysed to give polyhydroxy aldehydes and ketones
Ans: 2,3,4
H2O
Sucrose Glucose + Fructose
Br
+ -
Sol: (1) Glucose 
H O
 Gluconic acid.
2
2
(2)
CH2OH
CH2OH O
O OH
OH
OH
OH OH
OH
(3) HO and HO are anomers
(4) Mono saccharioles do not undergoes further hydrolysis is due to absence of ether
linkage.
2. Fusion of MnO2 with KOH in presence of O2 produces a salt W alkaline solution of W
upon electrolytic oxidation yields another salt X. The manganese containing ions
present in W and X, respectively are Y and Z correct statement(s) is(are)
1) In both Y and Z,   bonding occurs between p-orbitals of oxygen and d-orbitals of
manganese
2) In aqueous acidic solution, Y undergoes disproportionation reaction to give Z and
MnO2
3) Both Y and Z are coloured and have tetrahedral shape
4) Y is diamagnetic in nature while Z is paramagnetic
Ans: 1,2,3

Sol: MnO2  2 KOH  KNO3   K 2 MnO4  H 2O
K 2 MnO4 
 KMnO4
 w X
MnO42  MnO4
Y  Z
1,2,3 are correct

Page-20

3. Choose the correct option(s) for the following set of reactions
i ) MeMgBr conc. HCl
C6 H10O ii ) H 2O
 Q   S
 major 
20% H 3 PO4 ,360K
i ) H 2 . Ni Hbr ,benzoylperoxide
T 
ii ) Br2 , hv
 R  
 U
 major   major   major 
Cl CH3 CH3 H3C Br
H3 C
Br Br
S U U T
1) 2)
H3 C Br CH3 CH3 H3C Br

Cl
Cl
U S S T
3) 4)
Ans: 1,2
Sol:
OH Cl
O
i) MeMgBr conc.HCl
ii) H2O
(Q) (S)
20% H3PO4 / 360 K
Br
Br
i) H2 - N HBr
ii) Br2 / h Bentoyl / peroxide
(T)
(R) (U)

Page-21

4. Choose the reaction(s) from the following options, for which the standard enthalpy of
reaction is equal to the standard enthalpy of formation
1
1) S8  s   O2  g   SO2  g  2) 2 H 2  g   O2  g   2H 2O  l 
8
3
3) O2  g   O3  g  4) 2C  g   3 H 2  g   C2 H 6  g 
2
Ans: 1,3
Sol: Enthalpy change observed when one mole of substance is formed from it constituent
elements in their reference states.
5. A tin chloride Q undergoes the following reactions(not balanced)
Q  Cl   X
Q  Me3 N  Y
Q  CuCl2  Z  CuCl
X is a monoanion having pyramidal geometry. Both Y and Z are neutral compounds.
Choose the correct option(s).
1) The oxidation state of the central atom in Z is +2
2) The central atom in Z has one lone pair of electrons
3) The central atom in X is sp3 hybridized
4) There is a coordinate bond in Y
Ans: 3, 4
Sol: SnCl2  Cl   SnCl3  X 
SnCl2  Me3 N  SnCl2  NMe3  Y 
Dative bond between N and Sn
SnCl2  CuCl2  SnCl4  CuCl  Z 
6. Each of the following options contains a set of four molecules. Identify the option(s)
where all four molecules posses permanent dipole moment at room temperature
1) BF3 , O3 , SF6 , XeF6 2) NO2 , NH 3 , POCl3 , CH 3Cl
3) SO2 , C6 H 5Cl , H 2 Se, BrF5 4) BeCl2 , CO2 , BCl3 , CHCl3
Ans: 2, 3
Sol:  value of BF3 , SF6 , BeCl2 , CO2 , BCl 3
Zero
7. Which of the following statement(s) is(are) correct regarding the root mean square
speed(U rms) of a molecule in a gas at equilibrium?
1)  av at a given temperature does not depend on its molecular mass
2) Urms is inversely proportional to the square root of its molecular mass
3) Urms is doubled when its temperature is increased four times
4)  av is doubled when its temperature is increased four times

Page-22

Ans: 1,2,3
3 1
Sol: Eav  RT Vrms  Vrms  T (absolute temp) Eqv  T (absolute temp)
2 M

8. In the decay sequence,
238  x1 234  x2 234
 x3 234  x4 230
92  90 Th  91
Pa  Z  90
Th
x1 , x2 , x3 and x4 are particles/radiation emitted by the respective isotopes. The correct
option(s) is(are)
1) Z is an isotope of uranium
2) x1 will deflect towards negatively charged plate
3) x3 is   ray
4) x2 is  
Ans: 1,2,4
238 234
Sol: 92 U 90 Th  24 He x1  
234 234
90 Th 91 Pa  01e x2  
234 234
91 Pa 92 Z  01e x3  
234 230
92 Z  90 Th  24 He x4  
SECTION-III
DECIMAL INTEGER TYPE
(Maximum Marks: 18)
1. For the following reaction, the equilibrium constant Kc at 298 K is 1.6×1017
 FeS  s
Fe2  aq   S 2  aq  
When equal volumes of 0.06 M Fe+2 (aq) and 0.2M S2-(aq) solutions are mixed, the
equilibrium concentration of Fe2+ (aq) is found to be Y  1017 M . The value of Y is

Page-23

Ans: 8.93
Sol:
Intial Fe2aq   S2aq   FeS s
(after mixing) 0.03 0.1
at equlibrium x 0.07 1
1.6  1017 
x  7  10 2
10 17 100
x 2
  10 17  8.9285  8.93
1.6  7  10 11.2
2. At143K, the reaction of XeF4 with O2F2 produces a xenon compound Y. The total
number lone pair(s) of electron present on the whole molecule of Y is___
Ans: 19.00
Sol: XeF4  O2 F2  XeF6  O2
Shape of XeF6 is distorted octahedral contain one lone pair e  s on central atom 3 lone
pair e  s on each F atom surrounded by Xe.
Total no.of lone pairs: 1 + 18 = 19.00
3. Consider the kinetic data given in the following table for the reaction
A  B  C  product.
Experiment [A] [B] [C] Rate of reaction
No. (mol dm-3) (Mol dm-3) (Mol dm-3) (Mol dm-3)
1 0.2 0.1 0.1 6.0×10-5
2 0.2 0.2 0.1 6.0×10-5
3 0.2 0.1 0.2 1.2 × 10-4
4 0.3 0.1 0.1 9.0×10-5
The rate of the reaction for[A] = 0.15 mol-3, [B] = 0.25 mol dm-3 and [C] = 0.15
mol dm -3 is found to be Y × 10-5 mol dm-3 s-1. The value of Y is _____
Ans: 6.75 (6.70 – 6.80)
x y 2
Sol: rate = K  A   B  C
From 1 & 2 Y=0
From 1 & 3 Z=1
From 1 & 4 X=1
6  10 5  K  0.2  0.1
K  3  10 13
Rate = 3  103  0.15  1  0.15  6.75  10 5

Page-24

4. On dissolving 0.5 g of a non-volatile non-ionic solute to 39 g of benzene, its vapour
pressure decreases from 650 mm Hg to 640 mm Hg. The depression of freezing point
of Benzene (in K) upon addition of the solute is_____
(Given data : Molar mass and the molal freezing point depression constant of benzene
are 78 g mol-1 and 5.12 K kg mol-1, respectively)
Ans: 1.03 (0.97 – 1.06)
10 nB
Sol:  nB  10
650 n A  nB
10  1000
n A  640 m
640  78
5.12  10  1000
t f   1.025  1.03
640  78
5. Among B2 H 6 , B3 N 3 H 6 , N 2O, N 2O4 , H 2 S2O3 , H 2 S2O8 , the total number of polecules
containing covalent bond between two atoms of the same kind is _____
Ans: 4.00
H H H
B2H6 B B
Sol: H H H
N 2O N N O or N=N=O
O O S
N2O4 N N
H2S2O3 S
O O
HO OH
H
H
B H
N N
O O B3N3H6
B B
H
H2S2O8 S S N
H
HO O O OH
O O H
Total no.of molecules containing covalent bond between two atoms of the same kind
are 4.
6. Schemes 1 and 2 describes the conversion of P to Q and R to S, respectively, scheme 3
describes the synthesis of T from Q and S. The total number of Br atoms in a molecule
of T is _______

Page-25

Scheme 1:
i) Br2  excess , H 2O
ii ) NaNO2 , HCl ,273K
iii)CuCN / KCN
Q
iv) H 3O ,  (major)
v) SOCl2 , pyridine
P
Scheme 2:
i)Oleum
ii) NaOH , 
S
iii ) H 
(major)
iv ) Br2 , CS2 , 273K
R
Scheme 3:
i) NaOH
S T
ii )Q (major)
Ans: 4.00
Sol: Scheme – I
Br Br
i) Br2 excess ii) NaNO2

H2N Br NH2 N N+ Br
H2O HCl, 273 K
-
Cl
Br Br
iii) CuCN/KCN
Br Br
OH
iv) H3O+
Br N Br

O
Br Br
v) SoCl2 / Py
Br
Cl
Br
Br
(Q)

Page-26

Scheme – II
O
i) Oleum ii) NaOH / 
S OH NaO
iii) H+
iv) Br2
HO Br HO
CS2 / 273 K
(S)
O Br
HO Br i) NaOH O C Br
ii) Q
Br
(S)
(T)
Br
Mathematics
SECTION – I
ONLY the correct option is chosen; Zero Marks : 0 If none of the options is chosen (i.e. the question is
unanswered); Negative Marks : —1 In all other cases.
Question ID : 337911146
 sin 4  1  sin 2   1
1. Let M   2 4    I  M
1  cos  cos  
Where      and      are real numbers, and I is the 2  2 identity matrix. If
 * is the minimum of the set    :  [0,2 ) and
 * is the minimum of the set     :  [0,2 ) . Then the value of  *   * is
29 37 31 17
1)  2)  3)  4) 
16 16 16 16
Key : 1
 sin 4  1  sin 2   1
Sol : M   2 4    I  M
1  cos  cos  

Page-27

Where      and      are real numbers
4

M   sin  cos    1  sin 2  1  cos 2   
2 2
 2  sin  cos   sin  cos  4 4
 M   I   M 1
 sin 4   
 1  sin 2    0    cos 4 

1  sin 2  
   2
sin 4  

2
1  cos  cos 4    0   M  1  cos 
Comparing on both side

sin 4     cos4  ___ (1)
M

1  sin 2  
M
 
1  sin 2      M _____ (2)
So         2  sin 2  cos 2   sin 4  cos 4  

37 
 *  Minimum of     at    
16 4
From (1) and (2)     sin   cos 
4 4
1
 1  2sin 2  cos 2   1  sin 2 2
2
1 1
 * = minimum of     1  
2 2
37 1 37  8 29
 *  *    
16 2 16 16
2. The area of the region  x, y  : xy  8,1  y  x  is 2
14 7 14
1) 8log e 2  2) 8log e 2  3) 16log e 2  6 4) 16log e 2 
3 3 3
Key : 4
Sol : The area of the region  x, y  : xy  8,1  y  x  2

Page-28

4 4
8   2 4 3/2 
Required area     y  dy  8ln y  y 
1
y   3 
 2 3/2   2 16 2 14
 8ln 4   4   8  0    16ln 2   = 16 ln 2 
 3   3 3 3 3
2 2
3. A line y  mx  1 intersects the circle  x  3   y  2  25 at the points P and Q. If
3
the midpoint of the line segment PQ has x-coordinate  , then which one of the
5
following options is correct ?
1) 4  m  6 2) 3  m  1 3) 6  m  8 4) 2  m  4
Key : 4
Sol :
3m  5
2
m 5  1
3
 3
5
3m  15
m  1 3m 2  15m  18  0
18
m 2  5m  6  0  m  2 m  3  0  m  2,3
4. Let S be the set of all complex numbers z satisfying z  2  i  5 . If the complex
1  1 
number z0 is such that is the maximum of the set  ; z  S  , then the
z0  1  z 1 
4  z0  z0
principal argument of is
z0  z0  2i
   3
1)  2) 3) 4)
2 4 2 4
Key : 1

Page-29

2 2
Sol : Z  2  i  5   x  2   y  1  5 where Z = x + iy
For Z 0  1 to be minimum, where Z 0  x0  iye is at point P on the circle (figure)
 4  Z0  Z0   4  2 x0   i  2  x0  
Arg   Arg  Arg
 Z 0  Z 0  2i   2iy  2i 
0
 y  1 
0
2  x0 
 Arg  i  where     (where   0 )
y0  1 2
SECTION - 2
(Maximum Marks: 32)
• Each question has FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct
answer(s).
only (all) the correct option(s) is(are) chosen; Partial Marks : +3 If all the four options are correct but ONLY
three options are chosen; Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen and both of which are correct; Partial Marks : +1 If two or more options are correct but ONLY one
option is chosen and it is a correct option; Zero Marks : 0 If none of the options is chosen (i.e. the question is
unanswered); Negative Marks : —1 In all other cases. • For example, in a question, if (A), (B) and (D) are the
ONLY three options corresponding to correct answers, then choosing ONLY (A), (B) and (D) will get +4
marks; choosing ONLY (A) and (B) will get +2 marks; choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks; choosing ONLY (A) will get +1 mark; choosing ONLY (B)
will get +1 mark; choosing ONLY (D) will get +1 mark; choosing no option (i.e. the question is unanswered)
will get 0 marks; and choosing any other combination of options will get —1 mark.
1. Define the collections  E1 , E2 , E3 ,...... of ellipses and  R1 , R2 , R3 ,....... of rectangles as
x2 y 2
follows : E1 :   1;
9 4
R1 : rectangle of largest area, with sides parallel to the axes, inscribed in E1 ;
x2 y 2
En : ellipse 2  2  1 of largest area inscribed in Rn 1 , n  1 ;
an bn
Rn : rectangle of largest area, with sides parallel to the axes, inscribed in En , n  1 .
Then which of the following options is/are correct?
5
1) The distance of a focus from the centre in E9 is
32
1
2) The length of latus rectum of E9 is
6
3) The eccentricities of E18 and E19 are NOT equal
N
4)   area of R   24 , for each positive integer N
n 1
n
Key : 2, 4
Page-30

2 2
x y 5
Sol : E1 :   1 (ellipse), e  R : Max. Rectangle inscribed having sides parallel to axes
9 4 3 1
B A
O R1
E1
C D
  3 3 
For this A   3cos  , 2sin   , where   i.e A   , 
4  2 2
 Sides: 3 2, 2 2 Area of R1  3 2 2 2   
 If a,b are semi axes of ellipse then a 2, b 2 are sides.
x2 y2 a b
For E2 : 2
 2
 1 i.e. semi axes are , .
 3   2  2 2
   
2 2
x2 y2
 E9 : 2
 2
 distance from centre to foucs of E9 = ae =
   
 3   2 
8 8

   2  
  2 
2
 
2 
2 8 4
3

5

5
L.L.R =
2b 2


  
2 

2
256 
1 16 1
 
8
3 3
 2 3 16 a
8
32 3 6
 2 16
Eccentricities for all ellipses are equal.

Also sum of areas  R1  R2  R3 ........ =4  Areas sum in Q1 
 
 3 2 3 2 3 2  1 1 1 
=4     ......   4 6     .......

2 2 2
2
2
2
2
3
     2
3
  
2 4 8 
1
N
 24  2  24    area of R n   24
1
1 n1
2

Page-31


2. Let L1 and L2 denote the lines r  i   i  2 j  2k ,   R and
 

r   2i  j  2k ,   R respectively. If L3 is a line which is perpendicular to both L1
 
and L2 and cuts both of them, then which of the following options describe(s) L3 ?
 2
1) r  2i  j  2k  t 2i  2 j  k , t  
   
9

2) r  t 2i  2 j  k , t  
 
 2
3) r  4i  j  k  t 2i  2 j  k , t  
   
9
 1
4) r  2i  k  t 2i  2 j  k , t  
   
3
Key : 1, 3, 4
Sol : L1 : r  i   i  2 j  2k  .............. (1)  R
L2 : r    2i  j  2k  ...................... (2)   R given lines
Drs if required line L3
P
900
900
Q
 1, 2, 2   2, 1, 2 i.e. 2, 2, -1
Let P on L1 be 1   , 2 , 2 
Q on be  2 ,  , 2   PQ   2, 2, 1
1    2  2   2  2 
  
2 2 1
Solving 3  3  1 ............. (1)   1/ 9
6   3  0 ......... (2)   2 / 9
 8 2 2  4 2 4
 P   , ,  ,Q   ,  , 
 9 9 9  9 9 9
From choices 1, 3, 4 are correct.
3. Let  and  be the roots of x 2  x  1  0 , with    . For all positive integers n,
 n  n
define an  , n 1
 
b1  1 and bn  an1  an 1 , n  2 .

Page-32


an 10
1)  10 n
 2) bn   n   n for all n  1
n 1 89

b 8
3)  nn  4) a1  a2  a3  ......an  an 2  1 for all n  1
n 1 10 89
Key : 1, 2, 4
Sol : Let  ,  roots of x 2  x  1  0 
Clearly  2    1  0 ........... (1)  2
  1 
2
    1  0 .......... (2)  2
   1
1 5 1 5  n  n
Solving   ,  Given an  ,n  1
2 2  
 n1   n 1  n1   n 1
Given b1  1 , Given bn  an 1  an 1  
   
 n 1  2  1   n 1   2  1  n1   2   n1    2 
 
   
 5 5  5 5
 n 1     n 1 
 2   2   5  1 
n 1 5  5

   n 1      2 
5  2   
  n 1      n 1      n   n  bn   n   n
n n

bn 
 n  n 
 

Also  n   n
     
n 1 10 n 1 10 
n 1 10
  
n 1 10
 
10 10   10      2 10 1  21  1 12
      
  10   10   100  10       100  10   1 89
1 1
10 10
n n

an 
n  n 1    
   1    

n 1 10
n

n 1      10
n
          
5  n 1 10 n 1 10 
 
5  10   10   

1  10       1  10  5  10
   Also a1  a2  a3  .......  an

5  100  10          5  89  89
1

  
   
       2   2   3   3  .......   n   n 
  
1

  
  
    2  .....   n     2  ...... n 
 
1

  
  
 1     2 ......   n  1     2 ....... n 
 
1   n 1  1  n 1  1  n  2   n  2
    1  an  2  1
      1   1   

Page-33

4. Let f :    be given by
 x 5  5 x 4  10 x 3  10 x 2  3x  1, x  0;

 x 2  x  1, 0  x  1;
 2 3 8
f  x   x  4 x2  7 x  , 1  x  3;
 3 3
 10
  x  2 log e  x  2  x  , x  3.
 3
1) f is onto 2) f is increasing on  ,0
3) f ' has a local maximum at x = 1 4) f ' is NOT differentiable at x = 1
Key : 1, 3, 4
Sol : Let f : R  R
 x5  5 x 4  10 x3  10 x 2  3 x  1
 , x0
 x2  x  1
 ,0  x  1
f  x   2 x3  4 x2  7 x  8
 3 3 ,1  x  3
 10 , x3
 x  2  ln  x  2   x 
 3
  x  15  2 x, x0

 x 2  x  1, 0  x 1

f  x   2 x3  4 x 2  7 x  8 , 1 x  3
 3 3
 10
 x  2 ln  x  2  x  , x3
 3
 5  x  1 4  2, x0

 2 x  1, 0  x 1
f 1  x   2
 2 x  8 x  7, 1  x  3
1  ln  x  2  1, x3

20  x  1 3 , x0

 2 0  x 1
f  x   4 x  8
11
1 x  3

 1
x3
 x  2

Page-34

f     
 Range = R f is onto
f     
 1 5 1
Clearly f 1      2  0  f  atx  
 2  32 2
Also f 11 1    2  0
f 11 1    0
 f 1  x has local maximum at x  1
1 1
 f  1    4  L.D  R.D  f 1
is not differentiable at x = 1

 
f 
1
1    2 
5. There are bags B1 , B2 and B3 . The bag B1 contains 5 red and 5 green balls, B2 contains
3 red 5 green balls, and B3 contains 5 red and 3 green balls, Bags B1 , B2 and B3 have
3 3 4
probabilities , and respectively of being chosen. A bag is selected at random
10 10 10
and a balls is chosen at random from the bag. Then which of the following options
is/are correct?
39
1) Probability that the chosen balls is green equals
80
5
2) Probability that the selected bag is B3 , given that the chosen ball is green, equals
13
3
3) Probability that the chosen ball is green, given that the selected bag is B3 , equals
8
3
4) Probability that the selected bag is B3 and the chosen ball is green equals
10
Key : 1, 3
5R 3R 5R
5G 5G 3G
B1 B2 B3
Sol :
Bi = Event for choosing bag Bi , i  1,2,3 . G = Event for choosing a green ball.
 G  G G
P  G   P  B1  P    P  B2  P    P  B3  P  
 B1   B2   B3 
3 5 3 5 4 3 3 3 3 39
          Option 1 correct
10 10 10 8 10 8 20 16 20 80

Page-35

4 3
B  P  B3  G  10  8 4
P 3     option 2 incorrect
G P G 39 13
80
G 3
P   option 3 is correct
 B3  8
G 4 3 3
P  B3  G   P  B3  .P      option 4 incorrect
 B3  10 8 20
6. Let B denote a curve y  y  x which is in the first quadrant and let the point 1,0 lie
on it. Let the tangent to B at a point P intersect the y  axis at YP . If PYP has length 1
for each point P on B, then which of the following options is/are correct?
 1  1  x2  2
 1  1  x2  2
1) y   log e    1 x 2) y  log e    1 x
 x   x 
3) xy ' 1  x 2  0 4) xy ' 1  x 2  0
Key : 2,3
YP
P  x, y 
Sol : Equation of tangent at P  x, y 

xdy
Xdy  Ydx  xdy  ydx .So Yp  y 
dx
2
2 dy  2 dy 1  x2
PYP  x  x    1  
 dx  dx x
1  x2  1  x2 
So  dy    dx    dx 
x  x 1 x
2

 xdx xdx 
   2   1  x 2  Let 1  x 2  t 2  xdx  tdt
2
 x 1 x
 tdt tdt  1 t 1 
So y        t     ln  t

 1  t .t
2
  2 t 1 
 1  1  x2  2
 1  1  x2  2
y   ln    1 x  c Or y  ln    1 x  C
 x   x 

Page-36

st
 1  1  x2 
Putting 1,0 c  0 but as function lies in 1 quadrant so y  ln    1 x
2
 x 
dy 1  x2
& 
dx x
7. In a non-right angled triangle PQR , let p, q, r denote the lengths of the sides opposite
to the angles at P, Q, R respectively. The median from R meets the side PQ at S, the
perpendicular from P meets the side QR at E, and RS and PE intersect at O. If
p  3, q  1 and the radius of the circumcircle of the PQR equals 1, then which of
the following options is/are correct?
1 3
1) Length of OE 
6
2) Radius of incircle of PQR 
2
2 3  
3 7
3) Area of SOE  4) Length of RS 
12 2
Key : 1, 2, 4
Sol :
3 3 1 1
 2  sin p  so P= 60º, 120º  2  sin Q  so Q = 30º, 150º
sin p 2 sin Q 2
Clearly P = 60º not possible. So P = 120º, Q = 30º, R = 30º
3
PQ  PR  1, QE  RE 
2
1 1 3 1
O must be centroid so OE  .PE  1   option 1 is correct
3 3 4 6
1 1 3 32
Area of PQR   3  
2 2 4
Semiperimeter  3  1  1 / 2 
2
 
3
So in radius of PQR  4 
3 2 3  
option 2 is correct
32 2
2

Page-37

1
2
PR  QR  2 PS 2 2 1 3  2 
RS   4 = 7 option 4 is correct
2 2 2
1 1 1
Area of  SOE  . Area of SPE   5 area of PQR
3 3 4
1 1 3 3
    option 3 is incorrect
6 2 4 48
0 1 a   1 1 1
8. Let M  1 2 3  and adj M   8 6 2  where a and b are real numbers.
   
 3 b 1   5 3 1
Which of the following options is/are correct?
1) a  b  3 2) det adjM 2  81  
  1 
4) If M      2  , then       3
1
3)  adjM   adjM 1
 M
   
    3 
Key : 1, 3, 4
T
 2  3b 8 b  6  2  3b ab  1 3  2 a
Sol : AdjM   ab  1 3a 3   8 3a a 
   
 3  2a a 1   b6 3 1 
Comparing b  6  5  b  1 3  2a  1  a  2
a  b  3 . Option 1 is correct M  8  2 1  6  2
2
adj M 2  M 2  4
 M  16 option 2 is correct
M
 adj M   adj M
1 1
 2.
M
  M option 3 is correct
    2  1 
M       2  3    2 So       1  2  2    1   1,   1
     
   3       3
So       3 option 4 is correct
SECTION - 3
(Maximum Marks: 18)

Page-38


1. Three lines are given by r   i,   
 
r   i  j ,    and r  v i  j  k , v   .
   
Let the lines cut the plane x  y  z  1 at the points A, B and C respectively. If the area
2
of the triangle ABC is  then the value of  6  equals______
Key : 0.75
Sol : Let A   ,0,0 B  ,  ,0 C  ,  ,  

 A, B, C are in the plane x  y  z  1  A1,0,0
1 1   1 1 1
B  , ,0 C , , 
2 2   3 3 3
1   1 1
Area of ABC  AB  AC    3
2 2 6
2
  6   3 / 4  0.75
2. Let the point B be the reflection of the point A  2,3 with respect to the line
8 x  6 y  23  0 . Let C A and CB be circles of radii 2 and 1 with centers A and B
respectively. Let T be a common tangent to the circles C A and C B such that both the
circles are on the same side of T. If C is the point of intersection of C and the line
passing through A and B, then the length of the line segment AC is ______
Key : 10
Sol :
2
1
A 2,3 B C
D
8 x  6 y  23  0
5
 distance from A to the line 8 x  6 y  23  0 is
2
5 x 2
 AB  5 , Let BC  x    x  5  AC  5  x  10
x 1
3. Let AP  a; d  denote the set of all the terms of an infinite arithmetic progression with
first term a and common difference d > 0. If AP 1;3  AP  2;5  AP  3;7   AP  a; d 
then a + d equals_______

Page-39

Key : 157
Sol : AP 1;3  1,4,7,10,.......... say S1
AP  2;5   2,7,12,17,.......... say S2
AP  3;5   3,10,17,24,.......... say S3
S1  S2   7,22,37,52,....... i.e., AP  7;15
To find the term common to AP (7; 15) and AP ( 3; 7)
4l
7  15l  3  7m  m   2l where l , m W  l can be 3 m=7
7
 S1  S2  S3  A.P  52;105  a  d  157
 /4
2 dx
4. If I   then 27 I 2 equals ____
  /4 1  e 
sin x

 2  cos 2 x
Key : 4

4 b b
2 dx
Sol : I  
  1  e 
sin x

 2  cos 2 x
Apply  f  x dx   f  a  b  x dx
a a
4
  
4 4 4
2 dx 2 dx 1 dx
I
 x 1  e sin x  2  cos 2 x 
 
2 I 
 x  2  cos 2 x
I 

 2 b 2  2cos 2 x  1  
4 4

1
2 sec 2 xdx
4
2 2 dt
  sec xdx  dt   2
 0 3sec2 x  2 
 0 3 t 1  2 
1
2 1  3t  2   2 4
  tan 1      0  I2   27 I 2  4
 3  1 0 3 3 3 3 27
5. Let S be the sample space of all 3  3 matrices with entries from the set  0,1 . Let the
events E1 and E2 be given by
E1   A  S ; Det A  0 and E2   A  S ; sum of entries of A is 7 .
If a matrix is chosen at random from S, then the conditional probability P  E1 | E2 

equals_____
Key : 0.5

Page-40

Sol : E1 : A  0 E2  a1  a2  .......  aa  7
 E  8  E1  E2  n  E1  E2 
P 1    E2 : 71' s,20' s  9 C7  2 C2  36
 E2  P  E2  n  E2 
1 1 1  1 1 1  1 1 1
E2 nE1 : 1 1 1  1 1 1  1 1 1 3 3
   
1 0 0   01 0   0 0 1
0 1 1  0 1 1 1 1 1
0 1 1 1 1 1 0 1 1 3 3
     
1 1 1  0 1 1 0 1 1
 E  18 1
n  E2   36, n  E1  E2   18 P 1   
 E2  36 2
6. Let   1 be a cube root of unity. Then the minimum of the set
 a  b  c 2 2

: a, b, c distinct non  zero int egers equals _________
Key : 3
2
2 2
 1 i 3   1 i 3 
Sol : a  b  c  a  b   C  2  2 
 2 2   
2 2
 b c i 3  b c 3 2
 a      b  c   a      b  c

 2 2 2 2 2 4
1 2 2
  2a  b  c  3  b  c   a, b, c  1,0,1
4 
1 2 2 12
Min value : a  1, b  1, c  0   2  1  31    3
4  4

Page-41


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Sri Chaitanya IIT Academy Question Paper-1_Key & Solutions

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

At mid point between center and hole is

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

 Resistance of ammeter RA  0.02 (4) is correct

Option 1: measured value of R depends on R and RV only, but independent of RA, r

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Question ID: 337911119

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Which of the statement(s) is/are correct?

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

10  30  i1  i2   4  70i,  0 10  30  i1  i2   1 2  5  30i2  100i2  1 2  0

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Ans: 50 (49 - 51)

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

WBC  1 CD: y const

Question ID: 337911125

Step 2: Heat lost by calorimeter = mcal Scal  30

Heat gained by liq = 80  Sliq  20 mCal SCal  30  80 S eiq 20 ___  2

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

value of  will be___[ 0 is the permittivity of free space]

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

1,2,3 are correct

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

20% H 3 PO4 ,360K

H3 C Br CH3 CH3 H3C Br

20% H3PO4 / 360 K

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Question Id: 337911136

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy

# 304, Kasetty Heights, Ayyappa Society, Madhapur, Hyderabad – 500081

Sri Chaitanya IIT Academy