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2019-Jee-Advanced Question Paper-2_Key & Solutions

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2019-Jee-Advanced Question Paper-2_Key & Solutions
PHYSICS Max Marks: 62
SECTION-1 (Maximum Marks : 32)
 This section contains EIGHT (08) questions
 Each question has FOUR options. ONE MORE THAN ONE of these four option(s) is(are) correct answer(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : + 3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 2 If three or more options are correct but ONLY two options are chosen and both of which
are correct ;
Partial Marks : + 1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
Choosing ONLY (A), (B), and (D) will get +4 marks ;
Choosing ONLY (A) and (B) will get +2 marks ;
Choosing ONLY (A) and (D) will get +2 marks ;
Choosing ONLY (B) and (D) will get +2 marks ;
Choosing ONLY (A) will get +1 marks;
Choosing ONLY (B) will get +1 marks;
Choosing ONLY (D) will get +1 marks;
Choosing no option (i.e. the question is unanswered) will get 0 marks ; and
Choosing any other combination of options will get -1 mark.
Question ID: 337911170
1. A free hydrogen atom after absorbing a photon of wavelength  a gets excited from the
state n = 1 to the state n = 4. Immediately after that the electron jumps to n=m state by
emitting a photon of wavelength  e . Let the change in momentum of atom due to the
1
absorption and the emission are pa and pe , respectively. If  a /  e  , which of the
5
option (s) is /are correct ?
[Use hc = 1242 eV nm; 1 nm = 10-9 m, h and c are Planck’s constant and speed of light,
respectively]
1
1) pa / p e 
2
1
2) The ratio of kinetic energy of the electron in the state n = m to the state n = 1 is
4
3) m = 2
4)  e = 418 nm
Key: 2,3

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2019-Jee-Advanced Question Paper-2_Key & Solutions
1  1
Sol:  R 1 
a  16 

1 1 1
 R  2  2 
e  m 4 
1 
 2  12 
a  m 4  1
 
e 15 5
16
1 1 3
2
 2
m 4 16
1 1
2
 m 2
m 4
1
 Kinetic energy 
n2
Km 1 1
 2 1 
K1 2 4
 1 1  1242
13.6   
 4 16  e
 3  1242
13.6  
16  e
Question ID: 337911165
2. A small particle of mass m moving inside a heavy, hollow and straight tube along the
tube axis undergoes elastic collision at two ends. The tube has no friction and it is
closed at one end by a flat surface while the other end is fitted with a heavy movable
flat piston as shown in figure. When the distance of the piston from closed end is L =
L0 the particle speed is v = v0. The piston is moved inward at a very low speed V such
dL
that V << v0, where dL is the infinitesimal displacement of the piston. Which of the
L
following statement(s) is/are correct ?

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2019-Jee-Advanced Question Paper-2_Key & Solutions
dL
1) If the piston moves inward by dL, the particle speed increases by 2v
L
2) After each collision with the piston, the particle speed increases by 2V
3) The rate at which the particle strikes the piston is v/L
4) The particle’s kinetic energy increases by a factor of 4 when the piston is moved
1
inward from Lo to L0
2
Key: 2,4

Sol:
Before the collision speed is v.
After the collision speed is v + 2V.
Change in speed is 2V.
If V1 is the instantaneous speed and ‘x’ remaining distance then V1x = constant.
V 1 = 2v.
Question ID: 337911167
3. A mixture of ideal gas containing 5 moles of monatomic gas and 1 mole of rigid
diatomic gas is initially at pressure P0, volume V0, and temperature T0. If the gas
mixture is adiabatically compressed to a volume V0/4, then the correct statement(s)
is/are, (Given 21.2 = 2.3 ; 23.2 9.2 ; R is gas constant)
1) The work W done during the process is 13RT0
2) The final pressure of the gas mixture after compression is in between 9P0 and 10P0
3) Adiabatic constant of the gas mixture is 1.6
4) The average kinetic energy of the gas mixture after compression is in between 18RT0
and 19RT0
Key: 1,2,3
5 RTo
Sol: P1 
Vo

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2019-Jee-Advanced Question Paper-2_Key & Solutions
RTo
P2 
Vo

5R  7R
6 RTo 5  1 
P1  P2  Po  2  2 

Vo 3R  5R 
5  1 
5C  1CP  2
1 11
2
 mixture  P1
5CV  1CV
11
32
  1.6
20
V
9.2 Po  o  PV
2 2  PV
PV o o
 W 1 1
 4
PV  constant 1  1  1.6
PoVo1.6  PVo / 4
1.6
2.3 1 PV 1.3 6 RTo
 o o

P  Po 4  Po  2 
1.6 3.2 0.6 0.6
W  13RTo
P  9.2 Po
Question ID: 337911163
4. A thin and uniform rod of mass M and length L is held vertical on a floor with large
friction. The rod is released from rest so that it falls by rotating about its contact-point
with the floor without slipping. Which of the following statement(s) is/are correct,
when the rod makes an angle 600 with vertical ?
[g is the acceleration due to gravity]
Mg
1) The normal reaction force from the floor on the rod will be
16
2g
2) The angular acceleration of the rod will be
L
3g
3) The angular speed of the rod will be
2L
3g
4) The radial acceleration of the rod’s center of mass will be
4
Key: 1,3,4
l  ml 2
Sol: 
 mg  sin 60  
 2  3

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2019-Jee-Advanced Question Paper-2_Key & Solutions

3g l 3 3g
  
4 3 4l
2
l 1 ml 2
 mg 1 cos60  
2 2 3
g l 2
 
4 6
3g
2 
2l
l
 radial acceleration a   2
2
3g
a
4
 3g 1 3 3g 3 
 Mg  N  M     l 
 4 2 4l 2 
3 9 
Mg  N  Mg   
 8 16 
15Mg Mg
N  Mg  
16 16
Question ID: 337911166
p0  
5. An electric dipole with dipole moment
2
 
i  j is held fixed at the origin O in the

presence of an uniform electric field of magnitude E0. If the potential is constant on a


circle of radius R centered at the origin as shown in figure, then the correct
statements(s) is/are :
( 0 is permittivity of free space. R >>dipole size)

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2019-Jee-Advanced Question Paper-2_Key & Solutions


1) Total electric field at point B is E B  0

2) Total electric field at point A is E A  2E0 i  j  
3) The magnitude of total electric field on any two points of the circle will be same
1/3
 p0 
4) R  
 4 0 E0 
Key: 1,4

B A

Sol:
At ‘B’ electric field due to dipole is
KP
EB  3o
R
KPo
3
 Eo
R
1
 P 3
R   o

 4 E
o o  
E A  Eo  2 Eo  3Eo

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911168
6. Three glass cylinders of equal height H = 30 cm and same refractive index n = 1.5 are
placed on a horizontal surface as shown in figure. Cylinder I has a flat top, cylinder II
has a convex top and cylinder III has a concave top. The radii of curvature of the two
curved tops are same (R = 3 m). If H1, H2, and H3 are the apparent depths of a point X
on the bottom of the three cylinders, respectively, the correct statement(s) is/are :

1) 0.8 cm < (H2 – H1) < 0.9 cm


2) H 3 > H1
3) H 2 > H1
4) H 2 > H3
Key: 3,4

Sol: (I)
H  2 2  30
H1    20 cm
3 3

(II)

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2019-Jee-Advanced Question Paper-2_Key & Solutions
1 1.5 1 1.5
 
V H R
1 1 1.5
 
V 2 3 0.3
1 1
 5
V 6
1 29

V 6
6
V  0.1935
29

(III)
1 1
 5
V 6
6
V
31
Question ID: 337911164
7. A block of mass 2M is attached to a massless spring with spring-constant k. This block
is connected to two other blocks of masses M and 2M using two massless pulleys and
strings. The acceleration of the blocks are a1, a2 and a3 as shown in the figure. The
system is released from rest with the spring in its unstretched state. The maximum
extension of the spring is x0. Which of the following option(s) is/are correct ?
[g is the acceleration due to gravity. Neglect friction]

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2019-Jee-Advanced Question Paper-2_Key & Solutions
x0
1) At an extension of of the spring, the magnitude of acceleration of the block
4
3g
connected to the spring is
10
x
2) When spring achieves an extension of 0 for the first time, the speed of the block
2
M
connected to the spring is 3g
5k
4Mg
3) x 0 
k
4) a 2 – a1 = a1 – a3
Key: 4

Sol:
a2  a1  a1  a3
4M 2M  8M
Effective mass of pulley-block system is  .
3M 3
16Mg
xo 
3K
xo
xo  2 A  A 
2
A 2  4Mg  k  3 2 g
Acceleration of block is    
2  3k  14M 7
xo 3k 8Mg 3K
Speed = A   
2 14 M 3K 14M
Question ID: 337911169
8. In a Young’s double slit experiment, the slit separation d is 0.3 mm and the screen
distance D is 1 m. A parallel beam of light of wavelength 600 nm is incident on the
slits at angle  as shown in figure. On the screen, the point O is equidistant from the
slits and distance PO is 11.0 mm. Which of the following statement(s) is/are correct ?

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2019-Jee-Advanced Question Paper-2_Key & Solutions

1) Fringe spacing depends on 


0.36
2) For   degree, there will be destructive interference at point O.

3) For   0 , there will be constructive interference at point P.
0.36
4) For   degree, there will be destructive interference at point P.

Key: 4
Sol: d sin   x
2
0.36  36 10
d   0.3103   6107
5 180 180
 D 6 107 1
Fringe width   2 mm
d 3104

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2019-Jee-Advanced Question Paper-2_Key & Solutions
SECTION-2 (Maximum Marks : 18)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric
keypad in the place designated to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the correct numerical value is entered.
Zero Marks : +0 In all other cases
Question ID: 337911172
1. A 10 cm long perfectly conducting wire PQ is moving with a velocity 1 cm/s on a pair
of horizontal rails of zero resistance. One side of the rails is connected to an inductor
L = 1 mH and a resistance R = 1  as shown in figure. The horizontal rails, L and R lie
in the same plane with a uniform magnetic field B = 1 T perpendicular to the plane. If
the key S is closed at certain instant, the current in the circuit after 1 millisecond is
x  10-3A, where the value of x is _____
[Assume the velocity of wire PQ remains constant (1 cm’s) after key S is closed.
Given: e-1 = 0.37, where e is base of the natural logarithm]

Key: 0.63 (0.62 – 0.64)


1
Sol: EMF = BVl =  1102 101  103 V
V
3
L 110
Time constant =   1m.sec
R 1
i  io 1 e 
t /5

3
i
10
1
1 e 
1

3
 10  0.63  0.63 mA

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911171
2. A ball is thrown from ground at angle  with horizontal and with an initial speed u0.
For the resulting projectile motion, the magnitude of average velocity of the ball up to
the point when it hits the ground for the first time is V1. After hitting the ground, the
ball rebounds at the same angle  but with a reduced speed of u 0 /  . Its motion
continues for a long time as shown in figure. If the magnitude of average velocity of
the ball for entire duration of motion is 0.8 V1, the value of  is _____

Key: 4
u sin 2
2
Sol: R1  0
g

1  u02 sin 2  R1
R2  2  
  g   2

2u0 sin 
t1 
g
t
t2  1 ........

 

1  t
T  t1  t2  .....  t1    1
1 1   1
  

R1
Average speed =
t1
R
Average speed =
T
  4.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911176
3. An optical bench has 1.5 m long scale having four equal divisions in each cm. While
measuring the focal length of a convex lens, the lens is kept at 75 cm mark of the scale
and the object pin is kept at 45 cm mark. The image of the object pin on the other side
of the lens overlaps with image pin that is kept at 135 cm mark. In this experiment, the
percentage error in the measurement of the focal length of the lens is _____
Key: 1.39 (1.35 - 1.45)
1 1 1
Sol:  
v u f

1 1 1
   f  20 cm
60 30 f
df dv du
2
 2 2
f v u
Question ID: 337911174
4. A perfectly reflecting mirror of mass M mounted on a spring constitutes a spring-mass
4M
system of angular frequency  such that  1024 m 2 with h as Planck’s
h
constant. N photons of wavelength   8  106 m strike the mirror simultaneously at
normal incidence such that the mirror gets displaced by 1 m . If the value of N is
x  1012, then the value of x is ______
[Consider the spring as massless]

Key: 1

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2019-Jee-Advanced Question Paper-2_Key & Solutions
K
Sol: 
m
K

M
2h
Momentum change for single photon =

2Nh
Momentum change =

2 Nh
A  MV 

2 Nh
MA 

 45M  
2 1012  2 N
 h 
N  10
12

Question ID: 337911173


5. A monochromatic light is incident from air on a refracting surface of a prism of angle
75 0 and refractive index n0 = 3 . The other refracting surface of the prism is coated by
a thin film of material of refractive index n as shown in figure. The light suffers total
internal reflection at the coated prism surface for an incidence angle of   600 . The
value of n2 is

Key: 1.5
Sol: 1 sin 60  3  sin r1

1
sin r1   r1  30o
2
r2  45
o

1
 3  n  sin 90  n  1.5
o 2

2
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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911175

6. Suppose a 226 222


88 Ra nucleus at rest and in ground state undergoes  -decay to a 86 Rn

nucleus in its excited state. The kinetic energy of the emitted  particle is found to be

4.44 MeV. 222


86 Rn nucleus then goes to its ground state by  -decay. The energy of the

emitted  photon is ____ keV.

[Given : atomic mass of 226 222


88 Ra = 226.005 u, atomic mass of 86 Rn = 222.000 u,

atomic mass of  particle = 4.000 u, 1 u = 931 MeV/c2, c is speed of the light]


Key: 135 (130 – 140)
Ra 86 Rn 2 He
226 222 4
Sol: 88

m  mRa  mRn  m 
 226.005   222  4  0.005 u
4.44  4
Q-Value = 5103  931 MeV  4.655 MeV ,K.E. of 222
86 Rn   0.08
222
Energy of    4.655  4.52 MeV  135 KeV

SECTION-3 (Maximum Marks : 12)


 This section contains TWO (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice Questions.
 Each List-Match set has two lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Questions based on List-I and List-II and ONLY ONE of these four
options satisfies the condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the option corresponding to the correct combination is chosen ;
Zero Marks : +0 If none of the options is chosen (i.e., the question is unanswered)
Negative Marks : -1 In all other cases
Question ID: 337911177
1. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
A musical instrument is made using four different metal strings 1, 2, 3 and 4 with mass
per unit length ,2,3 and 4 respectively. The instrument is played by vibrating the
strings by varying the free length in between the range L0 and 2L0. It is found that in
string-1 (  ) at free length L0 and tension T0 the fundamental mode frequency is f0.
List-I gives the above four strings while list-II lists the magnitude of some quantity.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List-I List-II
I) String-1 (  ) P) 1
II) String-2 (2  ) Q) 1/2

III) String-3 (3  ) R) 1 / 2

IV) String-4 (4  ) S) 1 / 3
T) 3/16
U) 1/16
If the tension in each string is T0, the correct match for the highest fundamental
frequency in f0 units will be,
1) I  P, II  Q, III  T, IV  S 2) I  Q, II  P, III  R, IV  T
3) I  P, II  R, III  S, IV  Q 4) I  Q, II  S, III  R, IV  P
Key: 3
To 1
Sol: fo  
 2 Lo

f1  f o
fo
f2 
2
f
f3  o
3
f
f4  o
2
Question ID: 337911178
2. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
A musical instrument is made using four different metal strings 1, 2, 3 and 4 with mass
per unit length  ,2 ,3 and 4 respectively. The instrument is played by vibrating the
strings by varying the free length in between the range L0 and 2L0. It is found that in
string-1 (  ) at free length L0 and tension T0 the fundamental mode frequency is f0.
List-I gives the above four strings while list-II lists the magnitude of some quantity.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List-I List-II
I) String-1 (  ) P) 1
II) String-2 (2  ) Q) 1/2

III) String-3 (3  ) R) 1 / 2

IV) String-4 (4  ) S) 1 / 3
T) 3/16
U) 1/16
3L0 5L0 7L0
The length of the strings 1, 2, 3 and 4 are kept fixed at L0, , , and ,
2 4 4
respectively. Strings 1, 2, 3, and 4 are vibrated at their 1st, 3rd, 5th, and 14th harmonics,
respectively such that all the strings have same frequency. The correct match for the
tension in the four strings in the units of T0 will be
1) I  P, II  Q, III  T, IV  U
2) I  T, II  Q, III  R, IV  U
3) I  P, II  Q, III  R, IV  T
4) I  P, II  R, III  T, IV  U
Key: 1
1 To
Sol: fo 
2 Lo 

1 To
f1 
2 Lo 
T2 2
f 2  3 
2 2  3Lo
T3 4
f3  5 
3 2  5 Lo

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911179
3. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
In a thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed
by the gas is given by T X , where T is temperature of the system and X is the
infinitesimal change in a thermodynamic quantity X of the system. For a mole of
3  T  V 
monatomic ideal gas X  R ln   R ln  V  . Here R is gas constant, V is
2  TA  A

volume of gas TA and VA are constants.


The List-I below gives some quantities involved in a process and List-II gives some
possible values of these quantities.
List-I List-II
1
I) Work done by the system in process1  2  3 P) RT ln 2
3 0
1
II) Change in internal energy in process 1  2  3 Q) RT
3 0
III) Heat absorbed by the system in process 1  2  3 R) RT0
4
IV) Heat absorbed by the system in process 1  2 S) RT0
3
1
T) RT  3  ln 2
3 0
5
U) RT
6 0
If the process carried out on one mole of monatomic ideal gas is as shown in figure in
1
the PV-diagram with P0V0 = RT , the correct match is,
3 0

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2019-Jee-Advanced Question Paper-2_Key & Solutions

1) I  Q, II  R, III  P, IV  U 2) I  Q, II  R, III  S, IV  U
3) I  Q, II  S, III  R, IV  U 4) I  S, II  R, III  Q, IV  T
Key: 2

Sol:
Work done in 1  2 = PoVo
23=0
Total work in 1  2  3 = P0V0
4
Q in 1  2  3 = RTo
3
U in 1  2  3 = RTo
Question ID: 337911180
4. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
In a thermodynamic process on an ideal monatomic gas, the infinitesimal heat absorbed
by the gas is given by TX , where T is temperature of the system and X is the
infinitesimal change in a thermodynamic quantity X of the system. For a mole of
3  T  V 
monatomic ideal gas X  R ln   R ln  V  . Here R is gas constant, V is
2  TA  A
volume of gas TA and VA are constants.
The List-I below gives some quantities involved in a process and List-II gives some
possible values of these quantities.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List-I List-II
1
I) Work done by the system in process1  2  3 P) RT0 ln 2
3
1
II) Change in internal energy in process 1  2  3 Q) RT0
3
III) Heat absorbed by the system in process 1  2  3 R) RT0
4
IV) Heat absorbed by the system in process 1  2 S) RT0
3
1
T) RT0  3  ln 2
3
5
U) RT0
6
If the process on one mole of monatomic ideal gas is as shown in the TV-diagram with
1
P0V 0 = RT0 , the correct match is,
3

1) I  P, II  R, III  T, IV  S 2) I  P, II  T, III  Q, IV  T
3) I  S, II  T, III  Q, IV  U 4) I  P, II  R, III  T, IV  P
Key: 4
RTo
Sol: Work done in 12 = ln 2
3
230
U in 1  2 = 0
RTo
O in 1  2 = W  ln 2
3

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2019-Jee-Advanced Question Paper-2_Key & Solutions
CHEMISTRY Max Marks: 62
SECTION-1 (Maximum Marks : 32)
 This section contains EIGHT (08) questions
 Each question has FOUR options. ONE MORE THAN ONE of these four option(s) is(are) correct answer(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : + 3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 2 If three or more options are correct but ONLY two options are chosen and both of which
are correct ;
Partial Marks : + 1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
Choosing ONLY (A), (B), and (D) will get +4 marks ;
Choosing ONLY (A) and (B) will get +2 marks ;
Choosing ONLY (A) and (D) will get +2 marks ;
Choosing ONLY (B) and (D) will get +2 marks ;
Choosing ONLY (A) will get +1 marks;
Choosing ONLY (B) will get +1 marks;
Choosing ONLY (D) will get +1 marks;
Choosing no option (i.e. the question is unanswered) will get 0 marks ; and
Choosing any other combination of options will get -1 mark.
Question ID: 337911182
1. With reference to aqua regia, choose the correct options(s)
1) Reaction of gold with aqua regia produces NO2 in the absence of air
2) Reaction of gold with aqua regia produces an anion having Au in +3 oxidation state
3) Aqua regia is prepared by mixing conc. HCl and conc. HNO3 in 3 : 1 (v/v) ratio
4) The yellow colour of aqua regia is due to the presence of NOCl and Cl2
Key: 2,3,4
Sol: Aquaregia is a mixture of conc.HCl and conc.HNO3 in 3:1 ratio.
When gold dissolves in aquaregia, the species formed is AuCl4 in which gold is in +3
oxidation state.
In the absence of air the reaction between gold and aquaregia

Au  HNO3  4 HCl  H    AuCl4   2 H 2O  NO
NO2 will not be produced. Yellow colour is due to the presence of NOCl and Cl2.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911181
2. The cyanide process of gold extraction involves leaching out gold from its ore with
CN- in the presence of Q in water to form R. Subsequently, R is treated with T to
obtain Au and Z. Choose the correct option(s)
1) Q is O2
2) T is Zn
3) Z is [Zn(CN)4]2-
4) R is [Au(CN)4]-
Key: 1,2,3
Sol: Gold extraction:
4 Au  8 NaCN  2 H 2O  O2  4 Na  Au CN 2   4 NaOH
Q  R
4 Na  Au CN 2   2Zn  2 Na2  Zn CN 4   4 Au
 R T  Z 
Question ID: 337911185
3. Which of the following reactions produce(s) propane as a major product ?

1)

2)

3)

4)
Key: 1,3
Sol:
H3C ONa NaOH H3C CH3
CaO,Δ
O

H3C ONa H2O CH3


H3C
electrolysis
O
Zn
H3C H3C CH3
dil.HCl
Cl
Br
Zn
H3C H3C CH2
Br

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911188
4. Choose the correct option(s) from the following.
1) Nylon-6 has amide linkages
2) Cellulose has only  -D-glucose units that are joined by glycosidic linkages
3) Teflon is prepared by heating tetrafluoroethene in presence of a persulphate catalyst
at high pressure
4) Natural rubber is polyisoprene containing trans alkene units
Key: 1,3
Sol: Nylon-6 has amide linkages.
Cellulose has only β-D-glucose units that are joined by glycosidic linkages.
Teflon is prepared by heating tetrafluoromethane in presence of a persulphate catalyst
at high pressure.
Natural rubber is polyisoprene containing cis alkene units
Question ID: 337911186
5. Choose the correct option(s) that give(s) an aromatic compound as the major product.

1)

2)

3)

4)
Key: 2,3
Br
NaOEt
Anti aromatic
Sol:

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2019-Jee-Advanced Question Paper-2_Key & Solutions
CH3
Br
1.alcKOH
H3C
2.NaNH2
Br 3.redhot iron tube,873K H3C CH3
Aromatic
- Na+
NaOMe

Aromatic
Cl
Cl Cl
+ Cl 2 (excess) UV,500K
Cl Cl
Cl
Non aromatic
Question ID: 337911184
6. The ground state energy of hydrogen atom is – 13.6 eV. Consider an electronic state 
of He+ whose energy, azimuthal quantum number and magnetic quantum number are –
3.4 eV, 2 and 0, respectively. Which of the following statement(s) is (are) true from the
state  ?
1) It is a 4d state
2) It has 3 radial nodes
3) It has 2 angular nodes
4) The nuclear charge experienced by the electron in this state is less than 2e, where e
is the magnitude of the electronic charge
Key: 1,3
22
Sol: E  13.6  2
 3.4
n
22
13.6  2  3.4
n
n 4
2 2
n4
Wave function corresponds to 4,2,0 represents 4d z2 – orbital which has only one radial

nodes and two angular nodes. It experiences nuclear change of 2e units.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911187
7. Choose the correct option(s) for the following reaction sequence

Consider Q, R and S as major products.

1)

2)

3)

4)
Key: 1,4
Sol:
CHO 2+
i)Hg ,dilH2SO4
MeO C C CH2 MeO C CH2 CH2
O CHO
ii)AgNO3 NH4OH

MeO CH2 CH2 CH2 iii)Zn-Hg.conc.HCl


MeO C CH2 CH2
COOH O COOH
'Q'
i)SOCl2 pyridine

ii)AlCl3 Zn-Hg
MeO CH2 CH2 CH2 conc.HCl
MeO MeO
COCl
'R' O 'S'

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911183
8. Consider the following reactions (unbalanced)
Zn + hot conc. H2SO4  G + R + X
Zn + conc. NaOH  T + Q
G + H2S + NH4OH  Z (a precipitate) + X + Y
Choose the correct option(s)
1) The oxidation state of Zn in T is + 1
2) Bond order of Q is 1 in its ground state
3) Z is dirty white in colour
4) R is a V-shaped molecule
Key: 2,3,4
Sol: Zn  H 2 SO4  G  R  X
Hot & Conc.
Zn  H 2 SO4  ZnSO4  SO2  2 H 2O
G   R X 

Zn  Conc.NaOH  Na2 ZnO2  H 2


T  Q

ZnSO4  H 2 S  NH 4OH  ZnS   NH 4 2 SO4  H 2O


G  Z  X 
Y 
1) Oxidation state of Zn in Na2ZnO2 is +2
2) Bond order of Q is one for H2(Q)
3) ZnS is white in colour
4) SO2 is angular in shape
SECTION-2(Maximum Marks : 18)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric
keypad in the place designated to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the correct numerical value is entered.
Zero Marks : +0 In all other cases
Question ID: 337911190
1. Total number of cis N – Mn – Cl bond angles (that is Mn – N and Mn – Cl bonds in cis
positions) present in a molecule of cis –[Mn(en)2Cl2] complex is ___
(en = NH 2CH2CH2NH 2)
Key: 6

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2019-Jee-Advanced Question Paper-2_Key & Solutions
CH 2 CH 2

3 NH 2 1
NH 2
Cl

Mn 2
4
H2N Cl
NH 2

CH 2  CH 2
Sol:
Similarly from bottom N-there will be another (2).
Total N – Mn – Cl angle are 6.
Question ID: 337911189
2. The amount of water produced (in g) in the oxidation of 1 mole of rhombic sulphur by
conc.HNO3 to a compound with the highest oxidation state of sulphur is ____ (Given
data : Molar mass of water = 18g mol-1) s
Key: 288 (288.00 – 288.30)
Sol: S8 + HNO3  H 2SO4 + NO2 + H2O
Rhombic sulphur
Balancing the equation
S8 + 48HNO3  8H 2SO4 + 48NO 2 + 16H 2O
Rhombic sulphur
1 mole S8 produces 16 x 18 gm of H2O i.e. 288 gms of H2O.
Question ID: 337911191
3. The decomposition reaction 2 N 2O5  g  

 2 N 2O4  g   O2  g  is started in a closed
cylinder under isothermal isochoric condition at an initial pressure of 1 atm. After
Y 103 s the pressure inside the cylinder is found to be 1.45 atm. If the rate constant of
the reaction is 5 104 s1 , assuming ideal gas behavior, the value of Y is __
Key: 2.30
Sol: 
2 N 2O5  g    2 N 2O4  g   O2  g 
4 1
Given rate constant of the reaction = 5 10 sec
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2019-Jee-Advanced Question Paper-2_Key & Solutions
1 dPN 2O5
 K overall PN 2O5
2 dt
dp N 2O5
  2 K overall PN2O5
dt
2 N 2O5  g   2 N 2O4  g   O2  g 
1x x x /2

x
1  1.45
2
x  0.90 atm
3 2.303 1
y 10  4
log
2  510 0.1
23.03
y  2.30
10
Question ID: 337911193
4. Total number of hydroxyl groups present in a molecule of major product P is ___

Key: 6
OH
HO
i)H2,Pd-BaSO4,quinoline OH
ii)dil.KMnO4(excess),273K
HO

OHOH

Sol:
Question ID: 337911194
5. Total number of isomers, considering both structural and stereoisomers of cyclic ethers
with the molecular formula C4 H 8O is____
Key: 10
O
O O O O O
* * H3C * * CH3 H3C
CH3 H3C
CH3
Sol: CH3

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911192
6. The mole fraction of urea in an aqueous urea solution containing 900g of water is 0.05.
If the density of the solution is 1.2g cm-3, the molarity of urea solution is ___
(Given data: Molar masses of urea and water are 60g mol-1 and 18g mol-1, respectively)
Key: 2.98 (2.80 – 3.05)
Sol: X urea = 0.05 Mass of water = 900 gm
900
Number of moles of water = nH 2O   50 Let moles of urea = nU
18
nU
 0.05
nU  50
50
nU 
19
50
Mass of urea =  60
19
Given density (d) of solution = 1.2 g/ml.
50 60
900 
mass of solution 19
Vsolution  
density  g / cc  1.2

 50 
 
nU  19 
M 1000   2.98
Vml  50  60 
 900  1000 
 19 
 
 1.2 
 
SECTION-3(Maximum Marks : 12)
 This section contains TWO (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice Questions.
 Each List-Match set has two lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Questions based on List-I and List-II and ONLY ONE of these four
options satisfies the condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the option corresponding to the correct combination is chosen ;
Zero Marks : +0 If none of the options is chosen (i.e., the question is unanswered)
Negative Marks : -1 In all other cases

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911195
1. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
Consider the Bohr’s model of a one – electron atom where the electron moves around
the nucleus. In the following List – I contains some quantities for the nth orbit of the
atom and List – II contains options showing how they depend on n
List – I List – II
(I) Radius of the nth orbit (P)  n2
(II) Angular momentum of the electron in the nth orbit (Q)  n1
(III) Kinetic energy of the electron in the nth orbit (R)  n0
(IV)Potential energy of the electron in the nth orbit (S)  n1
(T)  n 2
(U)  n1/ 2
Which of the following options has the correct combination considering List – I and
List – II?
1. (II), (R) 2. (II), (Q) 3. (I), (P) 4. (I), (T)
Key: 4
n2
Sol: r
Z
L n
2
Z
KE  2
n
Z 2
PE  2
n
Question ID: 337911196
2. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
Consider the Bohr’s model of a one – electron atom where the electron moves around
the nucleus. In the following List – I contains some quantities for the nth orbit of the
atom and List – II contains options showing how they depend on n
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2019-Jee-Advanced Question Paper-2_Key & Solutions
List – I List – II
(I) Radius of the nth orbit (P)  n2
(II) Angular momentum of the electron in the nth orbit (Q)  n1
(III) Kinetic energy of the electron in the nth orbit (R)  n 0
(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
(U)  n1/2
Which of the following options has the correct combination considering List – I and
List – II?
1. (III), (S) 2. (IV), (Q) 3. (III), (P) 4. (IV), (U)
Key: 3
2
n
Sol: r
Z
L n
Z2
KE 
n2
Z 2
PE  2
n
Question ID: 337911197

3. Answer the following by appropriately matching the lists based on the information

given in the paragraph List – I includes starting materials and reagents of selected

chemical reactions. List – II gives structures of compounds that may be formed as

intermediate products and/ or final products from the reactions of List – I

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List – I List – II

(I) (P)

(II) (Q)

(III) (R)

(IV) (S)

(T)

(U)
Which of the following options has correct combination considering List – I and List –
II?
1. (I), (S), (Q), (R) 2. (II), (P), (S), (U)
3. (I), (Q), (T), (U) 4. (II), (P), (S), (T)
Key: 2

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Sol:

CN i)DIBAL-H CHO NaBH


4
ii)dilHCl
O OH
CHO
O OH
iii)conc.
H2SO4

CH2 O iii)NaBH OH
i)O3 4

ii)Zn,H2O
COOH COOH COOH

iv)conc.H2SO4

+
Cl i)KCN CN ii)H3O ,Δ COOH iii)LiAlH4

COOCH3 OH
COOCH3 COOH
OH
iv)conc.H2SO4

OH
COOMe
i)LiAlH4 OH iI)conc.H2SO4 O
=
COOMe O

Question ID: 337911198


4. Answer the following by appropriately matching the lists based on the information
given in the paragraph List – I includes starting materials and reagents of selected
chemical reactions. List – II gives structures of compounds that may be formed as
intermediate products and/ or final products from the reactions of List – I

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List – I List – II

(I) (P)

(II) (Q)

(III) (R)

(IV) (S)

(T)

(U)
Which of the following options has correct combination considering List – I and List –
II?
1. (IV), (Q), (R) 2. (IV), (Q), (U) 3. (III), (S), (R) 4. (III), (T), (U)
Key: 1

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Sol:

CN i)DIBAL-H CHO NaBH


4
ii)dilHCl
O OH
CHO
O OH
iii)conc.
H2SO4

CH2 O iii)NaBH OH
i)O3 4
ii)Zn,H2O
COOH COOH COOH

iv)conc.H2SO4

O
+
Cl i)KCN CN ii)H3O ,Δ COOH iii)LiAlH4

COOCH3 OH
COOCH3 COOH
OH
iv)conc.H2SO4

OH
COOMe
i)LiAlH4 OH iI)conc.H2SO4 O
=
COOMe O

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2019-Jee-Advanced Question Paper-2_Key & Solutions
MATHEMATICS Max Marks: 62
SECTION-1 (Maximum Marks : 32)
 This section contains EIGHT (08) questions
 Each question has FOUR options. ONE MORE THAN ONE of these four option(s) is(are) correct answer(s)
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 4 If only (all) the correct option(s) is(are) chosen;
Partial Marks : + 3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 2 If three or more options are correct but ONLY two options are chosen and both of which
are correct ;
Partial Marks : + 1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : -1 In all other cases.
 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
Choosing ONLY (A), (B), and (D) will get +4 marks ;
Choosing ONLY (A) and (B) will get +2 marks ;
Choosing ONLY (A) and (D) will get +2 marks ;
Choosing ONLY (B) and (D) will get +2 marks ;
Choosing ONLY (A) will get +1 marks;
Choosing ONLY (B) will get +1 marks;
Choosing ONLY (D) will get +1 marks;
Choosing no option (i.e. the question is unanswered) will get 0 marks ; and
Choosing any other combination of options will get -1 mark.
Question ID: 337911204
1. For a  , a  1, let

 
 
 
 1  2  ......  n
3 3
  54
lim  
n  
 7/3  1 1 1 
 
 n    ....  2 
 an  1 an  2 an  n 
2 2

Then the possible value(s) of a is/are
1. – 9 2. – 6 3. 7 4. 8
Key: 1,4
1/3 1
n 1 n r  1/3 3 4/3 1 3
 3
r    
n r 1  n 
x dx x l0
Sol: lim r 1
 lim = 1
0
 4  4  54
n  7/3 n 1 n  1 n 1 1 1 1 1
n   l
r 1 an  r
 
2
n r 1  r
2   a  x 2
dx
a  x 0 a  a  1
a   0
 n
 a  a  1  8  9  or   9  8  a  8 or  9

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911202
2. Let f :    be a function. We say that f has

f  h  f 0
PROPERTY 1 if lim exists and is finite, and
h 0
h

f  h  f 0
PROPERTY 2 if lim exists and is finite
h 0 h2
Then which of the following options is/are correct ?
1. f  x   x has PROPERTY 1

2. f  x  sin x has PROPERTY 2

3. f  x  x x has PROPERTY 2

4. f  x   x 2/3 has PROPERTY 1

Key: 1,4
h 0 sinh  0
Sol: If f x  x  lim  lim h  0 If f x  sin x  lim  D.E
h 0
h h 0 h0 h2

h h 0 h 2/3  0 1/3
If f x  x x  lim 2
 D.E If f x  x 2/3  lim 1/3
 lim h 0
h0 h h0
h h0

Question ID: 337911201


3. For non – negative integers n, let
n
 k  1   k  2 
 sin 

 n  2
 sin 
 
 n  2
 

f  n   k 0 n
 k  1 

k 0
sin 2 
 n  2 

Assuming cos-1x takes values in 0,  which of the following options is/are correct?
1. If   tan cos1 f 6 ,then  2  2  1  0
2. sin 7 cos1 f 5  0
3
3. f 4 
2
1
4. lim f n  
n 2

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Key: 1,2,3
n      2k  3  
 cos  n  2   cos  n  2   
k0
Sol: f n 
n   2k  2  
 1  cos  n  2   
k 0

  n  1  
sin 
    n  2   3 n 
  
n  1 cos   cos 

 
n 2    n  2 n  2
sin 
 n  2 

  n  1  
sin 
 n  2   2 n 
n 1 cos  
    n  2 n  2 
sin 
 n  2 

 
 n  2 cos  
n  2   
  cos  .
n2  n  2 

 
 f  6  cos      Tan  2  1   2  2  1  0
 8 8

 
sin 7 cos 1 f 5
    sin 7. 7   0
  3
f 4  cos   
6  2

lim f n  1
n 

Question ID: 337911205


4. Let f :    be given by f  x    x 1 x  2 x  5 . Define
x

F  x   f t  dt , x  0
0

Then when of the following options is/are correct?


1. F has a local minimum at x = 1
2. F  x   0 for all x  0,5

3. F has a local maximum at x = 2


4. F has two local maxima and one local minimum in 0,
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2019-Jee-Advanced Question Paper-2_Key & Solutions
Key: 1,2,3
Sol: F 1  x  f  x   x  1 x  2 x  5

At x  1 and x  5 F  x has local minima


At x  2 , F  x has local maxima and F  x  0x  0,5

1 2 5
Question ID: 337911199
5. Let
1 0 0  1 0 0  0 1 0
     
P1  I   0 1 0 , P2  0 0 1 , P3  1 0 0
     
 0 0 1  0 1 0  0 0 1
     
0 1 0  0 0 1  0 0 1
     
P4  0 0 1 , P5  1 0 0 , P6  0 1 0
     
1 0 0  0 1 0  1 0 0
     
 2 1 3
 6 
and X   Pk 1 0 2 PkT
 
k 1
 3 2 1
 
Where PkT denotes the transpose of the matrix Pk . Then which of the following options
is/ are correct?
1. X is a symmetric matrix
2. The sum of diagonal entries of X is 18
3. X – 30I is an invertible matrix
1 1
 
4. If X 1   1 , then   30
 
1 1
 
Key: 1,2,4

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2019-Jee-Advanced Question Paper-2_Key & Solutions
2 1 3 6
Sol: Let A  1 0 2  X   Pk APkT , Here Pk PkT  PkT Pk  I for all k =1,2,3,4,5,6.
k 1
 3 2 1 

 Pk  PkT  Pk1 & AT  A


6 6
T

X T   Pk APkT    Pk APkT  X
k 1 k 1

1 2 2 2  30  1


 6 6  6      
Let B  1  XB   PK APKT B   PK AB   PK  AB  2 2 2 AB  30  30 1  30 B
 K 1 K 1  K 1      
1 2 2 2  30  1

  30 and  X  30 I  is singular

 6 
Tr   Pk APkT   18
 k 1 

Question ID: 337911203


sin  x
6. Let f  x   ,x 0
x2
Let x1 < x2 < x 3 < …….. < x n <……. be all the points of local maximum of f
and y1 < y2 < y3 < ……. < yn < ….. be all the points of local minimum of f .
Then which of the following options is/are correct ?
1. x1  y1

2. xn1  xn  2

 1
3. xn   2n,2n   for every n
 2

4. xn  yn  1 for every n

Key: 2,3,4
 x 2 cos  x  2 x sin  x
Sol: f 1  x  ,x0
x4
x 
2 x cos  x   tan  x
 2 
 4  cos x  0
x

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2019-Jee-Advanced Question Paper-2_Key & Solutions
y

0 1/2 y1 3/2 x1 3y
2

Question ID: 337911200


7. Let x   and let
1 1 1  2 x x
   
P   0 2 2 , Q   0 4 0 and R  PQP1
   
 0 0 3  x x 6
   
Then which of the following options is/are correct?
 2 x x
 
1. det R  det  0 4 0  8 , for all x  
 
 x x 5
 
   0
   
2. For x = 1, there exists a unit vector i  j   
k for which R      0
   
    0
   
3. There exists a real number x such that PQ = QP
1  1
   
4. For x = 0, if R  a   6  a , then a + b = 5
   
b  b
   
Key: 1,4
2 x x
Sol: R  PQP 1

 Q  4 12  x 2
  2

 4 10  x  8  0 4 0  8
x x 5

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2019-Jee-Advanced Question Paper-2_Key & Solutions
If x  1  R  44  0        0

1 1 1   2 0 0  6 3 0 
1
For x  0  R   0 2 2  0 4 0 0 3 2 
6
 0 0 3   0 0 6  0 0 2 

12 6 4 
1
 0 24 8 
6 
 0 0 36 

 2
 4 1 3
 
4
R  6 I   0 2
 3
 
0 0 0
 

2b 4b
4  a   0, 2a  0
3 3
 b  3, a  2  a  b  5

If PQ = QP  no value of x .
Question ID: 337911206
8. Three lines

L1 : r  i,  

L2 : r  
k  j ,   

L3 : r i  j  vk, v  

are given . For which point(s) Q on L2 can we find a point P on L1 and a point R on L3
so that P, Q and R are collinear?
1 1
1. 
k 2. 
k  j 3. 
k  j 4. 
k  j
2 2
Key: 2,4
Sol: P   , 0, 0 , Q  0,  ,1 , R 1,1,  
   1
If P,Q,R are collinear   
  1 1 
1 1
   1     1, 0
 1 

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2019-Jee-Advanced Question Paper-2_Key & Solutions
SECTION-2 (Maximum Marks : 18)
 This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual numeric
keypad in the place designated to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value to TWO decimal places.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the correct numerical value is entered.
Zero Marks : +0 In all other cases
Question ID: 337911207
1. Suppose
 n n 
 k  Ck k 2 
n
 k 0 
det  n 0
k 0
 n n 
  Ck k  n
C 3k
 k 0 k 
 k 0 
n n
Ck
Holds for some positive integer n. The  k  1 equals____
k 0

Key: 6.20
n  n  1
n  n  1 2n 2  n2 n1
Sol: 2 0
n2n1 4 n

  n  1 2 2 n 1  n  n  1 2 2 n 3  n 2 n  2  0

 4  n  1  n  n  1  2n  0

 n 2  3n  4  0  n  4  n  0, n  N 
4
4
Ck 25  1 31

k 0 k  1

5

5
 6.20

Question ID: 337911210


2. The value of
 1 10  7 k    7  k  1  
sec1   sec  sec  
 4 k 0  12 2   12 2  
  3 
In the interval  ,  equals ___
 4 4 

Key: 0

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2019-Jee-Advanced Question Paper-2_Key & Solutions
10
 7 k   7 k  
Sol: S   sec    sec   
k 0
 12 2   12 2 2 
10  7 
  2 cos ec   k 
k0  6 
10
k 1 
 2  1 cos ec  
k 0
 6

 4  1  4

 5
 sec 1    sec 1 1  0
 4

Question ID: 337911211


3. The value of the integral
 /2
3 cos 
 d  equals ____
 
5
0 cos   sin 

Key: 0.5
 /2  /2
3 cos  3 sin 
Sol: I  5
d   5
d
0  cos   sin   0  sin   cos  
 /2  /2
3 3sec 2 
2I   4
d   4
d
0  sin   cos   0 1  Tan 
Put, Tan  t 2  sec 2  d  2tdt

6t
  1 1 
 dt  6 0  1  t  3 1  t  4  dt

0 1  t  4
 1  t  3 1  t  2   1 1  1
 I  3   l0  3   0  1   0  1   0.50
 3 2  3 2 2

Question ID: 337911209


4. Let X denote the number of elements in a set X. Let S= {1, 2, 3, 4, 5, 6} be a sample
space, where each element is equally likely to occur. If A and B are independent events
associated with S, then the number of ordered pairs (A, B) such that 1  B  A ,
equals ____

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Key: 422
Sol: If n(B) = 1, n(A) = 6  no. of ordered pairs (A, B) = 6
If n(B) = 2, n(A) = 3  no. of ordered pairs (A, B) = 180
If n(B) = 2, n(A) = 6  no. of ordered pairs (A, B) = 15
If n(B) = 3, n(A) = 4  no. of ordered pairs (A, B) = 180
If n(B) = 3, n(A) = 6  no. of ordered pairs (A, B) = 20
If n(B) = 4, n(A) = 6  no. of ordered pairs (A, B) = 15
If n(B) = 5, n(A) = 6  no. of ordered pairs (A, B) = 6
 Total number of ordered pairs (A, B) = 422.
Question ID: 337911208
5. Five persons A, B, C, D and E are seated in a circular arrangement. If each of them is
given a hat of one of the three colours red, blue and green, then the number of ways of
distributing the hats such that the persons seated in adjacent seats get different coloured
hats is ___
Key: 30
Sol: Total number of ways = 2  3  5  30
Question ID: 337911212
 
6. Let a  2i  j  
k and b i  2j  k be two vectors. Consider a vector
     
c   a   b, ,    . If the projection of c on the vector a  b is 3 2 , then the  
   
 
minimum value of c  a  b .c equals_____ 
Key: 18
Sol: a  b  3i  3 j

c. a  b  3 2    2
ab
2
 c  18  c . c  a b  18
 
SECTION-3 (Maximum Marks: 12)
 This section contains TWO (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice Questions.
 Each List-Match set has two lists : List-I and List-II.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Questions based on List-I and List-II and ONLY ONE of these four
options satisfies the condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme :
Full Marks : + 3 If ONLY the option corresponding to the correct combination is chosen ;
Zero Marks : +0 If none of the options is chosen (i.e., the question is unanswered)
Negative Marks : -1 In all other cases

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911214
1. Answer the following by appropriately matching the lists based on the information given
in the paragraph. Let f  x  sin  cos x and g  x  cos 2 sin x be two functions
defined for x > 0. Define the following sets whose elements are written in the increasing
order :
X   x : f  x   0, Y   x : f 1  x   0

Z   x : g  x   0 , W   x : g 1  x   0

List – I contains the sets X, Y, Z and W. List – II contains some information regarding
these sets.
List – I List – II
  3 
(I) X (P)   , ,4,7
 2 2 
(II) Y (Q) an arithmetic progression
(III) Z (R) NOT an arithmetic progression
  7 13 
(IV) W (S)   , , 
 6 6 6 

  2 
(T)   , , 
 3 3 
  3 
(U)  
 , 
 6 4 
Which of the following is the only CORRECT combination?
1. (IV), (P), (R), (S) 2. (III), (P), (Q), (U)
3. (III), (R), (U) 4. (IV), (Q), (T)
Key: 1
Sol: For x , f x  0  sin  cos x  0   cos x  n
 cos x  0 (or )1(or )  1

n
x ,n N
2

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2019-Jee-Advanced Question Paper-2_Key & Solutions
For Y, f  x  0   cos  cos x  sin x  0
1

 sin x  0 (or ) cos  cos x  0


 x  n , n  N (or )  cos x   2n  1 ,n N
2
1 1
 cos x  ,
2 2
 2
 x  2n  , 2n  , n  I , x  0
3 3

For Z, g  x  0  cos 2 sin  0  2 sin x  2n  1 , n  N
2
2 n  1 1 1 3 3
sin x   , , ,
4 4 4 4 4
For W, g 1  x  0  2 sin  2 sin  cos x  0
 sin  2 sin x  0  or  cos x  0


 x  2n  1 , n  N or  2 sin x  n
2
n 1
 sin x   1,  , 0
2 2

x  2n  1 , n , n  N
2
n  n   
n , n  1 , n  1  
6  6 

Question ID: 337911213


2. Answer the following by appropriately matching the lists based on the information
given in the paragraph
Let f  x  sin  cos x and g  x  cos 2 sin x be two functions defined for x > 0.
Define the following sets whose elements are written in the increasing order :
X   x : f  x   0 , Y   x : f 1  x   0

Z   x : g  x  0 , W   x : g 1  x   0

List – I contains the sets X, Y, Z and W. List – II contains some information regarding
these sets.

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2019-Jee-Advanced Question Paper-2_Key & Solutions
List – I List – II
  3 
(I) X (P)  
 , ,4,7
 2 2 
(II) Y (Q) an arithmetic progression
(III) Z (R) NOT an arithmetic progression
  7 13 
(IV) W (S)   , , 
 6 6 6 
  2 
(T)   , , 
 3 3 

  3 
(U)   , 
 6 4 
Which of the following is the only CORRECT combination?
1. (I), (P), (R) 2. (I), (Q), (U) 3. (II), (R), (S) 4. (II), (Q), (T)
Key: 4
Sol: For x , f x  0  sin  cos x  0   cos x  n
 cos x  0 (or )1(or )  1

n
x ,n N
2
For Y, f 1  x  0   cos  cos x  sin x  0
 sin x  0 (or ) cos  cos x  0


 x  n , n  N (or )  cos x   2n  1 ,n N
2
1 1
 cos x  ,
2 2
 2
 x  2n  , 2 n  , n  I , x  0
3 3

For Z, g  x  0  cos 2 sin  0  2 sin x  2n  1 , n  N
2
2n  1 1 1 3 3
sin x   , , ,
4 4 4 4 4
For W, g 1  x  0  2 sin  2 sin  cos x  0

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2019-Jee-Advanced Question Paper-2_Key & Solutions

 sin  2 sin x  0  or  cos x  0  x  2n  1 , n  N or  2 sin x  n
2
n 1  n  n   
 sin x   1,  , 0 x  2n  1 , n , n  N n , n  1 , n  1  
2 2 2 6  6 
Question ID: 337911215
3. Answer the following by appropriately matching the lists based on the information
given in the paragraph.
Let the circles C1 : x 2  y 2  9 and C2 :  x  3   y  4  16 , intersect at the points
2 2

X and Y. Suppose that another circle C3 :  x  h   y  k   r 2 satisfies the


2 2

following conditions :
(i) Centre of C3 is collinear with the centres of C1 and C2
(ii) C1 and C2 both lie inside C3 , and
(iii) C3 touches C1 at M and C2 at N
Let the line through X and Y intersect C3 at Z and W, and let a common tangent of C1
and C3 be a tangent to the parabola x2  8 y .
There are some expressions given in the List – I whose values are given in List – II
below
List – I List – II
(I) 2h  k (P) 6
Length of ZW
(II) (Q) 6
Length of XY
Area of triangle MZN 5
(III) (R)
Area of triangle ZMW 4
21
(IV)  (S)
5
(T) 2 6
10
(U)
3
Which of the following is the only CORRECT combination?
1. (I), (U) 2. (II), (T) 3. (II), (Q) 4. (I), (S)

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Key: 3
Sol:
Y
W (3,4)
N

O(0,0) X
M Z

C1  x 2  y 2  9  O 0, 0
2 2
C2   x  3   y  4  16  x 2  y 2  6 x  8 y  9  0  C 2 3, 4
2 2
C3   x  h   y  k   r 2

Let the centre of C3 be C.


 9 12 
 OC : CC2  3: 2  C   , 
 5 5 

 2h  k  6, 2r  3  5  4  12  r  6
Eq. of common chord of C1 and C2 is 3x+4y-9=0. Let P be the point of intersection of
OC1 and common chord.
6 12 6 24
 CP  , ZP  WP  , MP 
5 5 5
81 24
XY  2 9  
25 5
ZW
  6
XY
MZN  5

ZMW 4
10
Equation of the common chord of C1 and C3 is 3x  4 y  15  0    .
3

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Question ID: 337911216
4. Answer the following by appropriately matching the lists based on the information
given in the paragraph

Let the circles C1 : x 2  y 2  9 and C2 :  x  3   y  4  16 , intersect at the points


2 2

X and Y. Suppose that another circle C3 :  x  h   y  k   r 2 satisfies the


2 2

following conditions :
(i) Centre of C3 is collinear with the centres of C1 and C2
(ii) C1 and C2 both lie inside C3 , and
(iii) C3 touches C1 at M and C2 at N
Let the line through X and Y intersect C3 at Z and W, and let a common tangent of C1
and C3 be a tangent to the parabola x2  8 y .
There are some expressions given in the List – I whose values are given in List – II
below
List – I List – II
(I) 2h  k (P) 6
Length of ZW
(II) (Q) 6
Length of XY
Area of triangle MZN 5
(III) (R)
Area of triangle ZMW 4
21
(IV)  (S)
5
(T) 2 6
10
(U)
3
Which of the following is the only INCORRECT combination?
1. (III), (R) 2. (IV), (U) 3. (IV), (S) 4. (I), (P)
Key: 3

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2019-Jee-Advanced Question Paper-2_Key & Solutions
Y
W (3,4)
N

O(0,0) X
M Z

Sol:
C1  x 2  y 2  9  O 0, 0
2 2
C2   x  3   y  4  16  x 2  y 2  6 x  8 y  9  0  C 2 3, 4
2 2
C3   x  h   y  k   r 2

Let the centre of C3 be C.


 9 12 
 OC : CC2  3: 2  C   , 
 5 5 

 2h  k  6, 2r  3  5  4  12  r  6
Eq. of common chord of C1 and C2 is 3x+4y-9=0. Let P be the point of intersection of
OC1 and common chord.
6 12 6 24
 CP  , ZP  WP  , MP 
5 5 5
81 24
XY  2 9  
25 5
ZW
  6
XY
MZN  5

ZMW 4
10
Equation of the common chord of C1 and C3 is 3x  4 y  15  0    .
3

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