Comprehension based qs

The term mole was first used by Ostwald to refer to ratio of mass of a substance inn gram and
its molecular weight. 1 mol of a gaseous compound occupies 22.4 liter at NTP and contains
6.022 X 1023 molecules of gas.

1. Weight of 1 atom of hydrogen is

a) 1.66 X 10-24 amu
b) 3.32 X 10-24 gm
c) 1.66 X 10-24 gm
d) 3.32 X 10-24 amu
2. Amount of sulphur required to produce 100 mol of H2SO4 is
a) 3200 gm
b) 32.65 gm
c) 32 gm
d) 3.2 gm
3. The hydrated salt Na2SO4.nH2O undergoes 56% loss of weight on heating and becomes
anhydrous. Value of n is
a) 5
b) 3
c) 7
d) 10
Assertion reason
a. A is correct but R is wrong
b. A is wrong but R is correct
c. Both A and R are correct and R is a correct explanation of A
d. Both A and R are correct and R is NOT a correct explanation of A

Assertion Reason
4. Equivalent weight of an element may have more Equivalent weight depends
than one value on the nature of chemical
reaction shown by an
element.
5. Hydrogen has 1 electron in its orbit but it shows There are many excited
more than one spectral lines. energy levels available for
different H atom when
spectra of H2 gas are
studied.
6. The possible number of electrons in a subshell is The possible number of
4l+2 orientations of a subshell is
 2l+1.

7. In a compound C, H, N atoms are present in a ratio of 9:1:3.5 by weight. Molecular

mass of the compound is 108. Molecular formula is:
a) C2H6N2
b) C3H4N
c) C6H8N2
d) C9H12N3
8. 6.02 X 1020 molecules of urea are present in 100 ml of solution. What is the
concentration of urea solution?
a) 0.1 M
b) 0.1 M
c) 0.02 M
d) 0.001 M
9. how many moles of magnesium phosphate will contain 0.25 mol of oxygen atoms?
a) 0.02
b) 0.03125
c) 0.0125
d) 0.025
10. Density of 2.05 M solution of acetic acid in water is 1.02 g/ml. molality of the same
solution is:
a) 1.64
b) 1.8
c) 1.22
d) 1.45
11. the normality of 0.3 M phosphorous acid H3PO4 is
a) 0.1
b) 0.9
c) 0.6
d) 0.3
12. an aqueous solution of oxalic acid (COOH)2.2H20 is made upto 250 ml. the volume of
0.1 N NaOH required to neutralize 10 ml of this solution is?
a) 40 ml
b) 20 ml
c) 10 ml
d) 4 ml
13. If 1/6 instead of 1/12, mass of carbon atom is taken to be the relative atomic mass
unit, mass of one mole of a substance will
 a) Decrease twice
b) Increase twice
c) Remains unchanged
d) Be a function of molecular mass of the substance

14. Number of atoms in 558.5 gm of Fe is

a) Twice that in 60 g C
b) 6.022 X 1022
c) Half in 8 g of He
d) 558.5 X 6.022 X 1023
15. What volume of hydrogen gas at 273K and 1 atm pressure will be consumed in
obtaining 21.6 g of elemental boron from the reduction of boron trichloride with
hydrogen is
a) 44.8 liter
b) 22.4 liter
c) 89.6 liter
d) 67.2 liter

16. 25 ml of a solution of barium hydroxide on reaction with 0.1 M solution of HCl

required 35 ml HCl solution. Molarity of barium hydroxide solution is
a) 0.28
b) 0.35
c) 0.07
d) 0.17
17. To neutralize completely 20 ml of 0.1 M aqueous solution of H 3PO3 acid the volume
of 0.1 M KOH required is
a) 60 ml
b) 20 ml
c) 40 ml
d) 10 ml
18. For an ideal gas, number of moles per liter in terms of pressure, temperature and
gas constant is
a) PT/R
b) PRT
c) P/RT
d) RT/P
19. In van der waals equation constant b is a measure of
a) Intermolecular collisions per unit volume
 b) Intermolecular attractions
c) Volume occupied by molecules
d) Intermolecular repulsions

20. A gas will approach ideal behavior at

a) Low temperature, low pressure
b) Low temperature, high pressure
c) High temperature, low pressure
d) High temperature, high pressure
21. Compressibility factor for an ideal gas is
a) 1.5
b) 1.0
c) 2.0
d) infinite
22. In a hydrogen atom, if energy of an electron in ground state is -13.6 eV, than that in
2nd excited state is
a) -1.51 eV
b) -3.4 eV
c) -6.04 eV
d) -13.6 eV
23.uncertainity in position of a particle of mass 25 g is 10 -5. The uncertainty in velocity in
m/s is:
a) 2.1 X 10-34
b) 0.5 X 10-34
c) 2.1 X 10-28
d) 0.5 X 10-23
24. de Broglie wavelength of a tennis ball mass 10 g moving with a velocity of 10 m/s is
approx:
a) 10-16 m
b) 10-25 m
c) 10-33 m
d) 10-31 m
25. which of the following sets of ions represents a collection of isoelectronic species?
a) K+, Cl-, Ca+, Sc3+
b) Ba2+, Sr2+, K+, Ca2+
c) N3-,O2-, F-, S2-
d) Li+, Na+, Mg2+, Ca2+
26. Ionisation energy of hydrogen atom is 1.312 X 106 J/mol. Energy required in J/mol to
excite electron from n=1 to n=2:
a) 8.51 X 105
b) 6.56 X 105
c) 7.56 X 105
d) 9.84 X 105
27. A 3p orbital has
a) 2 spherical nodes
b) Two non-spherical nodes
c) 1 spherical and 1 non-spherical node
d) 1 spherical and 2 non-spherical node
28. Which has maximum number of unpaired electrons?
a) Mg2+
b) Ti3+
c) V3+
d) Fe2+
29. For a d electron orbital angular momentum is
a) √ 6 h
b) √ 2 h
c) h
d) 2 h
30. The first use of quantum theory to explain the structure of atom was given by
a) Heisenberg
b) Bohr
c) Planck
d) Einstein