-KONTAKT 42

Information for the Rubber Industry

Selected Processing Additives

in NBR

Content

1. Introduction

2. T
 est Equipment, Methods
and Parameter

3. E
 ffects of different
Processing Additives
in NBR-Compounds

4. U
 se and Rating of Processing
Additives
in NBR-Compounds

5. A
 ppendix –
Complete Overview of all
Test Series

DOG 08007_Kontakt_42_E_rz.indd 1 01.10.2008 12:44:17 Uhr

 -KONTAKT 42
Inhalt
 Seite
1. Introduction 3
1.1 Product Survey 3
2. Test Equipement,
Methods and Parameter 3
3. Effects of different Processing
Additives in NBR-Compounds 4
3.1 Conventional, black
NBR-Compound (SEV-System) 4
3.1.1 Influence on the
processing properties 4
3.1.2 Influence on the
physical properties 5
3.2 NBR/PVC-Blend 6
3.2.1 Influence on the
processing properties 7
3.2.2 Influence on the
physical properties 8
3.3 Conventional, light coloured
NBR-Compound (SEV-System) 8
3.3.1 Influence on the
processing properties 9
3.3.2 Influence on the
physical properties 10
DOG 08007_Kontakt_42_E_rz.indd 2
 Seite
3.4 Effects of Plasticizer
and Processing Additives
on swelling properties
in a heat resistant, black
NBR-Compound (EV-System) 11
3.4.1 Influence on the
processing properties 12
3.4.2 Influence on the
physical properties 12
4. Use and Rating
of Processing Additives
in NBR-Compounds 14
5. Appendix – Complete
overview of all Test Series 15
5.1 Conventional, black
NBR-Compound 15
5.2 Conventional, light coloured
NBR-Compound 16
5.3 NBR/PVC-Blend 18
5.4 Heat resistant,
black NBR-Compound 19
Imprint
Editor:
DOG Deutsche Oelfabrik
Gesellschaft für chemische Erzeugnisse mbH & Co. KG
www.dog-chemie.de, info@dog-chemie.de
Authors:
Dr. Bernd Bornemann, Manfred Heide, Simone Materlik,
Ralph Mehl, Stephan Müller, Stefan Oettlein,
Andre Rittmann
Layout/ Production:
EHRENBERG WERBUNG
www.ehrenberg-werbung.de, info@ehrenberg.de
01.10.2008 12:44:17 Uhr
 1. Introduction

Nitrile Rubber (NBR) is a synthetic polymer
which is much appreciated for its resistance
against mineral oil and fuels. Kontakt 42 is
dedicated to conventional Nitrile Rubber and
does not cover special modifications such as
HNBR or XNBR.
NBR is available in a variety of different grades
which are corresponding to a large number of
different processing methods, e.g. Injection
Moulding, Extrusion or Calendering. The use
of Processing Additives in NBR-Compounds
facilitates the economical manufacturing pro-
cess – sometimes processing is even not possible
without specific Processing Additives.
The main benefits of specific Processing Addi-
tives for NBR can be seen in improved flow
properties, easier dispersion and adjusted tack
of unvulcanized compounds. To achieve those
properties, DOG offers a range of specific
additives and provides an application-oriented
guidance through the combinations of rubber,
additives and processing conditions. Our rub-
ber technologists in Hamburg look forward to
start the dialogue with you.
The brochure Kontakt 42 – Selected Processing
Additives in NBR – introduces Dispergum®,
Deogum®, Deoflow® and Deosol® and pro-
vides additional information on our tackifier
grades Deotack® and Homogenisator®.
Furthermore, we would like to draw your
attention on our Factice which is, as well an
important ingredient for many recipes, e.g. for
the production of low-hardness compounds.
Detailed information regarding DOG Factice1)
are published with our brochure Kontakt 38.
Kontakt 42 replaces the previous Kontakt 30.

1.1 Product Survey

Deoflow® A based on a mixture of fatty alcohols and fatty acid esters

Deoflow® S based on calcium salts of fatty acids and amides
Deoflow® 821 based on pentaerythritol-tetrastearate
Deosol® H emulsion based lubricant and dispersing agent
Deogum® 80 special Processing Additive for a broad range of applications
Dispergum® PT pure zinc soap for general use
Dispergum® GT combination of zinc soap with fatty acid esters

2. Test Equipment, Methods and Parameter

Compounding
Internal Mixer Farrel BR Banbury / volume 1.6 l
Open Mill Laboratory Roller Mixer/260 mm/friction 1:1.1

Test equipment for unvulcanized compounds

Mooney Viscosimeter Montech V-MV 3000
Rheometer MDR 2000
Göttfert Rheovulkameter

Test methods for vulcanized compounds

Tensile Strength/Elongation at break DIN 53504, test specimen S 2
Tear Resistance DIN ISO 34-1, test specimen A
Hardness Shore A DIN 53505
Rebound DIN 53512
DIN Abrasion DIN 53516
Compression Set DIN ISO 815

1) In this brochure, the term of Factice is solely used as a product description as it is commonly used in the relevant literature.

DOG 08007_Kontakt_42_E_rz.indd 3 01.10.2008 12:44:18 Uhr

 -KONTAKT 42

3. Effects of different Processing Additives in NBR-Compounds

3.1 Conventional, black NBR-Compound (SEV-System)

Recipe 458 A Control Deoflow Dispergum PT Deoflow A Deogum Deoflow S Deosol H

821 80
NBR 3445 100 100 100 100 100 100 100 100 100 100 100 100
Carbon Black N 550 30 30 30 30 30 30 30 30 30 30 30 30
Carbon Black N 772 40 40 40 40 40 40 40 40 40 40 40 40
Plasticizer DINP 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5
ZnO 5 5 5 5 5 5 5 5 5 5 5 5
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
TMQ 2 2 2 2 2 2 2 2 2 2 2 2
Deoflow 821 – 2 – – – – – – – – – –
Dispergum PT – – 2 4 – – – – – – – –
Deoflow A – – – – 2 4 – – – – – –
Deogum 80 – – – – – – 2 4 – – – –
Deoflow S – – – – – – – – 2 4 – –
Deosol H – – – – – – – – – – 2 4
CBS 1 1 1 1 1 1 1 1 1 1 1 1
Deovulc TBzTD-80 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Sulphur 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Total phr 188 190 190 192 190 192 190 192 190 192 190 192

3.1.1 Influence on the processing properties

Control Control
Mooney ML 1+4, 100 °C 2 phr Mooney Scorch 130 °C, t5 2 phr
80 76 4 phr 30 4 phr
71 27.4
69 70 68 68 66 70 68
70 65
62 64 25
22.2 21.9
60
20 19.1
50 17.5
15.9 16.0 16.9 16.4 15.7 16.4 16.2
min
MU

40 15
30
10
20
5
10
0 0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control Control
Scorch Time t10 2 phr Optimum Cure Time t90 2 phr
1,4 Rheometer MDR 2000, 180 °C 4 phr 2,5 Rheometer MDR 2000, 180 °C 4 phr

1,2 2.00
1.06 2,0
1,0 1.71 1.69
0.92 0.88 0.92 1.55 1.58
0.84 0.81 0.83 0.81 0.79 0.81 0.80 1.48 1.45 1.48 1.45 1.39 1.44 1.41
0,8 0.78 1,5
min

min

0,6 1,0
0,4
0,5
0,2

0,0 0,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Injected Volume after 70 s Injected Volume after 70 s

4 5,0 Injection Moulding Test 3,5 Capillary Rheometer Test at 90 °C
4,5 4.2 2.9
3.9 3,0
4,0 2.6 2.6
2.5
3,5 2,5 2.2 2.3
3.0 3.0 2.9 2.0
3,0 2.8 2.8 1.9
2,0 1.7
2.4 1.7
cm3

cm3

2,5 2.2 1.6

2.1 2.1
DOG 08007_Kontakt_42_E_rz.indd 4 1,5 01.10.2008 12:44:18 Uhr
2,0 1.7 1.2
 1.06 2,0
1,0 1.71 1.69
0.92 0.88 0.92 1.55 1.58
0.84 0.81 0.83 0.81 0.79 0.81 0.80 1.48 1.45 1.48 1.45 1.39 1.44 1.41
0,8 0.78 1,5

min

min
0,6 1,0
0,4
0,5
0,2

0,0 0,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control Control
Injected Volume after 70 s 2 phr Injected Volume after 70 s 2 phr
5,0 Injection Moulding Test 4 phr 3,5 Capillary Rheometer Test at 90 °C 4 phr
4,5 4.2 2.9
3.9 3,0
4,0 2.6 2.6
2.5
3,5 2,5 2.2 2.3
3.0 3.0 2.9 2.0
3,0 2.8 2.8 1.9
2,0 1.7
2.4 1.7
cm3

cm3
2,5 2.2 1.6
2.1 2.1
2,0 1,5
1.7 1.2
1,5 1,0
1,0
0,5
0,5
0,0 0,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Compared with the control compound all test- Deoflow 821 acts as an external lubricant and
ed Processing Additives provide a significant has, in addition to the good flowing effect,
decrease of the Mooney Viscosity. also a positive impact to the demoulding prop-
erties without having a significant influence to
Even with a dosage of 2 phr a reduction of the cross-linking. At this point it has to be
6 to 8 Mooney units can be achieved. With a mentioned that due to the lower solubility
quantity of 4 phr Dispergum PT it is possible Deoflow 821 was only tested with 2 phr.
to obtain a diminution of 14 Mooney units.
However, an enhanced retarding effect must Deogum 80 is, beside Deoflow 821, the most
be taken into account as indicated by the vul- efficient product at lower dosages.
canization time t10 and t90.
Dispergum PT highly improves the flowability
The results of the Rheovulkameter Tests show and ought to be applied when an extension
the most distinct increase of the injection vol- of the scorch time is acceptable or even
ume with Deoflow 821 followed by Dispergum PT requested.
and Deogum 80. Our products Deoflow A and
Deosol H can be used in higher dosages to im-
prove the flow properties without any obvious
effect on the vulcanization characteristics.

3.1.2 Influence on the physical properties

Control Control
Hardness Shore A 2 phr Tensile Strength 2 phr
4 phr 4 phr
70 15,5
67 67 67 66 65 67 66 67 66 15.1 15.1
65 65 15.0 15.0
64 15,0 14.7 14.6 14.8 14.8 14.8
14.6
14,5 14.3
60 14.2
Shore A

14,0
MPa

13,5
50
13,0

12,5

40 12,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

The physical Modulus

properties are 300
only% slightly affect- Compression
and there is hardly any noticeable Set influence on
14 13.8 35
ed by the addition
12.9
of
13.4 Processing
13.0
Additives. The the tensile strength. 24 h / 100 °C
12.7 12.7 31 31
compression
13
set remains12.1
almost
12.3 unchanged,
12.3 12.2 30 29
28
29
30 30 30 30 30
11.9 28
12 11.6 27

11 25
MPa

10 20
9 5
15
8

7 10
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H
DOG 08007_Kontakt_42_E_rz.indd 5 01.10.2008 12:44:18 Uhr
 Hardness Shore A Tensile Strength
70 15,5
67 67 67 66 65 67 66 67 66 15.1 15.1
65 65 15.0 15.0
64 15,0 14.7 14.6 14.8 14.8 14.8
14.6
14,5 14.3
60 14.2

Shore A
-KONTAKT 42 14,0

MPa
13,5
50
13,0

12,5

40 12,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control Control
Modulus 300 % 2 phr Compression Set 2 phr
14 13.8 4 phr 35 4 phr
13.4 24 h / 100 °C
12.9 13.0 31 31
13 12.7 12.7 30 30 30 30 30
12.3 12.3 12.2 30 29 29
12.1 11.9 28 28
12 11.6 27

11 25
MPa

%
10 20
9
15
8

7 10
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

3.2 NBR / PVC-Blend

Recipe 463 A Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol

821 PT A 80 S H
NBR 2845 70 70 70 70 70 70 70
Emulsion PVC 30 30 30 30 30 30 30
PVC Stabilizer 0.9 0.9 0.9 0.9 0.9 0.9 0.9
Vulkasil A1 30 30 30 30 30 30 30
Carbon Black N 772 40 40 40 40 40 40 40
Plasticizer DINP 10 10 10 10 10 10 10
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5
ZnO 3.5 3.5 3.5 3.5 3.5 3.5 3.5
Wingstay 100 1 1 1 1 1 1 1
Deoflow 821 – 2 – – – – –
Dispergum PT – – 2 – – – –
Deoflow A – – – 2 – – –
Deogum 80 – – – – 2 – –
Deoflow S – – – – – 2 –
Deosol H – – – – – – 2
CBS 0.7 0.7 0.7 0.7 0.7 0.7 0.7
Deovulc TBzTD-80 0.3 0.3 0.3 0.3 0.3 0.3 0.3
Sulphur 1.1 1.1 1.1 1.1 1.1 1.1 1.1
Total phr 188 190 190 190 190 190 190

To improve the chemical and ozone resistance, The following tests demonstrate that the use
Nitrile Rubber is commonly blended with Poly- of Processing Additives is very beneficial in
vinylchloride (PVC). Blends containing PVC NBR/PVC blends.
lead to higher viscosities and complicated
processing conditions.

DOG 08007_Kontakt_42_E_rz.indd 6 01.10.2008 12:44:18 Uhr

 3.2.1 Influence on the processing properties

Control Control
Mooney MS 1+4, 100 °C 2 phr Scorch Time t10 2 phr
80 0,7 Rheometer MDR 2000, 180 °C
70 68 0.60
0,6 0.55
60 61 59 61 61 0.52
60 56 0.49 0.49 0.49 0.51
0,5
50
0,4

min
MU

40
0,3
30
0,2
20
10 0,1

0 0,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control Control
Optimum Cure Time t90 2 phr Injected Volume after 70 s 2 phr
2,5 Rheometer MDR 2000, 180 °C 2,5 Injection Moulding Test

2,0 1.94 2,0

1.75 1.77 1.8
1.70
1.62
1,5 1.37 1,5
1.25
min

cm3

1.1
1.0 1.0 1.0
1,0 1,0 0.9
0.7

0,5 0,5

0,0 0,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control The positive impact of the tested Processing

Injected Volume after 70 s 2 phr
Additives is clearly demonstrated by the
1,8 Capillary Rheometer Test at 90 °C
1,6 1.5 1.5
decrease of the Mooney Viscosity. The slight
1,4
1.4
retarding effect of Dispergum PT improves the
1.2 1.2
1,2 1.1 processing safety and this leads to the highest
1,0 volume in the Injection Moulding Test.
cm3

0.8
0,8 The results of the Capillary Rheometer Test
0,6
confirm again the significant improvement of
0,4
the flow properties using Deoflow 821 or
0,2
0,0
Dispergum PT.
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H

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 -KONTAKT 42

3.2.2 Influence on the physical properties

Control Control
Hardness Shore A 2 phr Tensile Strength 2 phr
80 14,0
13.5 13.5
76 76 76 13,5 13.3
75 75
75 74 74 13,0 12.8
12.6
12,5 12.2
Shore A

12.0

MPa
70 12,0
11,5
65 11,0
10,5
60 10,0
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

Control Control
Modulus 300 % 2 phr Compression Set 2 phr
11,0 75 24 h / 100 °C
10.2 70
9.8 9.9 9.8
10,0 70 67
9.3 9.4 67 67
9.1 65 66
9,0 65 63
8,0 60
MPa

7,0 55

6,0 50

5,0 45

4,0 40
Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol Control Deoflow Dispergum Deoflow Deogum Deoflow Deosol
821 PT A 80 S H 821 PT A 80 S H

All DOG Processing Additives have a minor ef- The values for the compression set at 100 °C
fect on hardness. When using Deoflow A or show throughout an enhancement for all DOG
Deosol H all physical properties remain almost Processing Additives, Dispergum PT in particular
unchanged. has a stabilizing effect on the PVC-Component.

3.3 Conventional, light coloured NBR-Compound (SEV-System)

Recipe 466 A Control Dispergum Dispergum Deoflow Deosol Deoflow Deogum

PT GT A H 821 80
NBR 3345 100 100 100 100 100 100 100
Silica (BET 125 m²/g) 30 30 30 30 30 30 30
Clay 50 50 50 50 50 50 50
Plasticizer DINP 10 10 10 10 10 10 10
ZnO 5 5 5 5 5 5 5
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Dusantox 86 1 1 1 1 1 1 1
Dispergum PT – 2 – – – – –
Dispergum GT – – 2 – – – –
Deoflow A – – – 2 – – –
Deosol H – – – – 2 – –
Deoflow 821 – – – – – 2 –
Deogum 80 – – – – – – 2
MBTS 1 1 1 1 1 1 1
Deovulc TBzTD-80 0.75 0.75 0.75 0.75 0.75 0.75 0.75
Sulphur 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Total phr 199.75 201.75 201.75 201.75 201.75 201.75 201.75

DOG 08007_Kontakt_42_E_rz.indd 8 01.10.2008 12:44:19 Uhr

 3.3.1 Influence on the processing properties

Control Control
Mooney ML 1+4, 100 °C 2 phr Scorch Time t10
10
2 phr
64
64 63
63 1,2
1,2 Rheometer
Rheometer MDR
MDR 2000.
2000. 180
180 °C
°C
62
62 1,0 0.97
0.97
1,0 0.91
0.91 0.89
0.89
0.81 0.84
0.84 0.85
0.85 0.82
0.82
60
60 0.81
0,8
0,8
58
58
58
58 57
57 57
57 57
57 57
57

min
MU

0,6
0,6
56
56 55
55
0,4
0,4
54
54

52
52 0,2
0,2

50
50 0,0
0,0
Control
Control Dispergum
Dispergum Dispergum
Dispergum Deoflow
Deoflow Deosol
Deosol Deoflow
Deoflow Deogum
Deogum Control Dispergum Dispergum
Control Dispergum Dispergum Deoflow
Deoflow Deosol
Deosol Deoflow
Deoflow Deogum
Deogum
PT
PT GT
GT AA HH 821
821 80
80 PT
PT GT
GT AA HH 821
821 80
80

Control Control
Optimum Cure Time t90
90
2 phr Injected Volume after 70 s 2 phr
2,5
2,5 Rheometer
Rheometer MDR
MDR 2000,
2000, 180
180 °C
°C 3,5
3,5 Injection
Injection Moulding
Moulding Test
Test
2.97
2.97
3,0
3,0
2,0
2,0 1.93
1.93
1.71
1.71 2.49
2.49
1.58 2,5
2,5 2.29
2.29 2.23
2.23
1.55
1.55 1.52
1.52 1.58
1.44
1.44 1.43
1.43 2.07
2.07 2.05
2.05
1,5
1,5 2,0
2,0 1.72
1.72
min

cm33

1,0
1,0 1,5
1,5

1,0
1,0
0,5
0,5
0,5
0,5

0,0
0,0 0,0
0,0
Control Dispergum
Control Dispergum Dispergum
Dispergum Deoflow
Deoflow Deosol
Deosol Deoflow
Deoflow Deogum
Deogum Control
Control Dispergum
Dispergum Dispergum
Dispergum Deoflow
Deoflow Deosol
Deosol Deoflow
Deoflow Deogum
Deogum
PT
PT GT
GT AA HH 821
821 80
80 PT
PT GT
GT AA HH 821
821 80
80

Control All tested DOG products show a positive

Injected Volume after 70 s 2 phr
influence on the processing properties.
5,0
5,0 Capillary
Capillary Rheometer
Rheometer Test
Test at
at 90°
90° CC
4,5
4,5 4.31
4.31 Especially Deoflow 821 indicates a significant
4,0
4,0 improvement. Beside its effect as a lubricant
3,5
3,5 it also facilitates the dispersion of white,
3,0
3,0
2.54
2.54 2.42
2.42
2.67
2.67 active fillers and leads to an exceptional
cm33

2,5
2,5
2,0
2,0 1.69
1.69
1.86
1.86 1.94
1.94 optimization of the flow properties. The
1,5
1,5 Dispergum zinc soaps provide an improvement
1,0
1,0 on the flow rating on one hand and a positive
0,5
0,5
effect on the processing safety on the other.
0,0
0,0
Control Dispergum
Control Dispergum Dispergum
Dispergum Deoflow
Deoflow Deosol
Deosol Deoflow
Deoflow Deogum
Deogum
PT
PT GT
GT AA HH 821
821 80
80

DOG 08007_Kontakt_42_E_rz.indd 9 01.10.2008 12:44:20 Uhr

 -KONTAKT 42

3.3.2 Influence on the physical properties

Control Control
Modulus 300 % 2 phr Hardness Shore A 2 phr
6 66
5.3 64 64
64 63 63 63
5 4.7 4.7 4.5 62 62
4.5 4.4
4.3 62
4
60

Shore A
MPa

3 58
56
2
54
1
52
0 50
Control Dispergum Dispergum Deoflow Deosol Deoflow Deogum Control Dispergum Dispergum Deoflow Deosol Deoflow Deogum
PT GT A H 821 80 PT GT A H 821 80

Control Control
Tensile Strength 2 phr Compression Set 2 phr
18 16.7 16.8 17.0 52 24 h / 100 °C
15.8 16.2
16 15.1 50 49 49 49
48
13.6 48 47 47
14 46
46
12 44
10 42
MPa

8 40
6 38
36
4
34
2 32
0 30
Control Dispergum Dispergum Deoflow Deosol Deoflow Deogum Control Dispergum Dispergum Deoflow Deosol Deoflow Deogum
PT GT A H 821 80 PT GT A H 821 80

The physical properties like hardness, modulus achieved, other DOG Processing Additives lead
and tensile strength remain at a comparable to similar or slightly increased values compared
level to the control. With Deoflow A to the control.
advantages in the compression set are

10

DOG 08007_Kontakt_42_E_rz.indd 10 01.10.2008 12:44:20 Uhr

 3.4 Effects of Plasticizers and Processing Additives on swelling
properties of a heat resistant, black NBR-Compound (EV-System)

NBR-Compounds can be used without or with Chapter 3.4 describes the advantages of our
very low quantities of plasticizer for applica- products in comparison to common Phthalate
tions with particular requirements on heat and Plasticizers (DINP).
oil resistance.

Recipe 464A Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow

P sator 501 PT A 821
5 phr 5 phr 5 phr 2.5 phr 2.5 phr 2.5 phr
NBR 3345 50 50 50 50 50 50 50
NBR 3330 50 50 50 50 50 50 50
Carbon Black N 772 40 40 40 40 40 40 40
Carbon Black N 550 20 20 20 20 20 20 20
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5
ZnO 5 5 5 5 5 5 5
TMQ 1.5 1.5 1.5 1.5 1.5 1.5 1.5
MMBI 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Plasticizer DINP – 5 – – – – –
Deotack P – – 5 – – – –
Homogenisator 501 – – – 5 – – –
Dispergum PT – – – – 2.5 – –
Deoflow A – – – – – 2.5 –
Deoflow 821 – – – – – – 2.5
CBS 1 1 1 1 1 1 1
Deovulc TBzTD-80 2.5 2.5 2.5 2.5 2.5 2.5 2.5
ZBEC (80%) 1 1 1 1 1 1 1
Deovulc CLD-80 E 1 1 1 1 1 1 1
Sulphur S 80 0.4 0.4 0.4 0.4 0.4 0.4 0.4
Total phr 174.4 179.4 179.4 179.4 176.9 176.9 176.9

11

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 -KONTAKT 42

3.4.1 Influence on the processing properties

Even the conventional plasticizer DINP shows a DOG Processing Additives. They can be used in
relatively strong decrease in Mooney Viscosity, lower dosages and are still more effective.
but the relevant data for the production – Particularly Deoflow 821 leads to a consider-
Injection Moulding and Capillary Rheometer able improvement of flow and processing
Test – are more significantly improved by behaviour.

Control Control
Mooney ML 1+4, 100 °C 2,5 phr Mooney Scorch 130 °C, t5 2,5 phr
80 5 phr 10 5 phr
73 9.0
70 67 67 66 9
64 64
61 8
60
7
50 6 5.5 5.7 5.5 5.6 5.8
4.9

min
MU

40 5
30 4
3
20
2
10 1
0 0
Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow
P sator 501 PT A 821 P sator 501 PT A 821

Control Control
Scorch Time t10 2,5 phr Optimum Cure Time t90 2,5 phr
0,8 5 phr 1,6 5 phr
Rheometer MDR 2000, 180 °C Rheometer MDR 2000, 180 °C
0,7 1,4 1.33
0.62
0,6 1,2
0.48 0.97 1.00
0,5 0.47 0.47 0.46 0.47 1,0 0.94 0.95 0.93
0.43 0.86
min

min

0,4 0,8
0,3 0,6
0,2 0,4
0,1 0,2
0,0 0,0
Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow
P sator 501 PT A 821 P sator 501 PT A 821

Control Control
Injected Volume after 70 s 2,5 phr Injected Volume after 70 s 2,5 phr
4 5 phr 6 5 phr
Injection Moulding Test Capillary Rheometer Test at 90 °C
5.1
3.2 5
3
4

1.9
cm3

cm3

2 1.7 3
1.5 1.4 1.4 2.2
1.3
2 1.7
1.4
1 1.1
1.0 0.9
1

0 0
Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow Control DINP Deotack Homogeni- Dispergum Deoflow Deoflow
P sator 501 PT A 821 P sator 501 PT A 821

3.4.2 Influence on the physical properties

Regarding the physical data, all products re- Probably due to a slight activation, the use of
duce the hardness as expected. Dispergum PT Dispergum PT leads to an optimization of the
shows a benefit due to the low influence on compression set values.
the modulus and the tensile strength.

12

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 Control Control
Hardness Shore A 2,5 phr Tensile Strength 2,5 phr
66
66 5 phr 18
18 5 phr
65
65
65
65 17
17 16.8
16.8 16.6 16.7
16.7
16.4 16.6
16.4
16.1
16.1 15.9
64 16 15.9
64 16 15.4
15.4
Shore AA

63 63 63 63

MPa
63 63 63 63

MPa
Shore

63
63 15
15
62
62 62
62
62
62 14
14

61
61 13
13

60
60 12
12
Control
Control DINP
DINP Deotack Homoge
Deotack Homogeni- Dispergum Deoflow
ni- Dispergum Deoflow Deoflow
Deoflow Control
Control DINP
DINP Deotack Homoge
Deotack Homogeni- Dispergum Deoflow
ni- Dispergum Deoflow Deoflow
Deoflow
PP sator
sator 501
501 PT
PT A
A 821
821 PP sator
sator 501
501 PT
PT A
A 821
821

Control Control
Modulus 300 % 2,5 phr Compression Set 2,5 phr
12
12 5 phr 27
27 24 h
h // 125
125 °C
°C 5 phr
11.0
11.0 10.9
10.9 24
10.2
10.2 10.1
10.1
10 9.5 26
26
10 9.3
9.3 9.5
8.6
8.6 25
25 25
25 25
25 25
25
25
25
8
8 24
24 24
24
24
24
MPa
MPa

6
%
6
% 23
23
4
4 22
22
22
22
2
2 21
21
0
0 20
20
Control
Control DINP
DINP Deotack
Deotack Homoge
Homogeni-ni- Dispergum
Dispergum Deoflow
Deoflow Deoflow
Deoflow Control
Control DINP
DINP Deotack
Deotack Homoge
Homogeni-ni- Dispergum
Dispergum Deoflow
Deoflow Deoflow
Deoflow
PP sator 501
sator 501 PT
PT A
A 821
821 PP sator 501
sator 501 PT
PT A
A 821
821

Control Control
Swelling in ASTM Oil No. 1 2,5 phr Swelling in IRM Oil 903 2,5 phr
1,0
1,0 72 5 phr 22
22 5 phr
72 h
h // 100
100 °C
°C 72
72 h
h // 100
100 °C
°C
0,5 20
20
0,5 0.1 0.2
0.2 17.9
17.9
0.1 18
18
%

0,0 15.9
Volume %

Volume %

0,0 14.9 15.9

-0.2 16
16 14.9 14.3
14.3
in Volume

in Volume

-0,5
-0,5 -0.2 13.3
14
14 13.0
13.0 13.3
-1,0
-1,0 12 11.4
11.4
12
-1,5 -1.3
-1.3 10
10
Change in

Change in

-1,5
-1.6
-1.6 8
Change

Change

-2,0
-2,0 -1.8
-1.8 8
6
6
-2,5
-2,5 4
4
-3,0
-3,0 -3.0 2
-3.0 2
-3,5
-3,5 0
0
Control
Control DINP
DINP Deotack Homoge
Deotack Homogeni- Dispergum Deoflow
ni- Dispergum Deoflow Deoflow
Deoflow Control
Control DINP
DINP Deotack Homoge
Deotack Homogeni- Dispergum Deoflow
ni- Dispergum Deoflow Deoflow
Deoflow
PP sator
sator 501
501 PT
PT A
A 821
821 PP sator
sator 501
501 PT
PT A
A 821
821

The charts illustrate the impact of plasticizer taining DINP shows again, that the plasticizer
and DOG Processing Additives on the swelling will be extracted totally. The high solubility
properties of the vulcanizates aged in ASTM of the conventional plasticizer may lead to
Oil No. 1 and IRM Oil 903. difficulties in the application due to negative
swelling, respectively shrinkage. The use of
The swelling with ASTM Oil No. 1 is com- Deotack P and Homogenisator 501 shows
paratively low, therefore mainly light soluble advantages because the products are
ingredients will be extracted in this test. The almost not extractable.
conventional plasticizer shows disadvantages
caused by the complete extraction. Deotack P The volume changes of the DOG Processing
obviously demonstrates its benefit as a hard- Additives prove again their low oil solubility.
to-extract plasticizer. Extremely low volume The Dispergum or Deoflow types are especially
changes are achieved by using the Processing recommended to avoid shrinkage. The DOG
Additives Deoflow 821 or Dispergum PT. Processing Additives are hardly extractable
and are therefore better suited for higher
Since the IRM Oil 903 has a stronger swelling requirements regarding swelling resistance.
effect to the polymer, there is a balance
between the swelling of the polymer and the
extractable ingredients. The comparison
between the control and the compound con-

13

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 -KONTAKT 42

4. Use and Rating of Processing Additives in NBR-Compounds

Deoflow Deoflow Deoflow Deosol Deogum Dispergum Deogum

A / AM S 821 H 80 PT / GT 294

Comprehensive Survey

Conventional, black QQ Q QQQ QQ QQQ QQQ QQ

NBR-Compound

NBR / PVC-Blend QQ QQ QQ QQ QQ QQQ

Conventional, light coloured QQ Q QQQ QQ QQ QQ
NBR-Compound

Heat resistant QQ QQQ QQ QQ QQQ

NBR-Compound

QQQ excellent QQ good Q possible

Deoflow Deoflow Deoflow Deosol Deogum Dispergum Deogum Homog. Deotack

A / AM S 821 H 80 PT / GT 294 501 P

Main Effects

Flow Improvement QQ Q QQQ QQ QQQ QQQ QQ Q Q

Extraction Resistance Q QQQ QQ QQ QQ QQQ1) QQQ1)

Release QQQ QQ QQQ

Tack QQ QQQ

Dispersion QQ Q QQQ QQ QQ QQQ QQQ QQ

1) High compatibility QQQ excellent QQ good Q possible

14

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 5. Appendix – Complete Overview of all Test Series
5.1 Conventional, black NBR-Compound

458A 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

Krynac 3445 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100
Carbon Black N 550 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
Carbon Black N 772 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40
Plasticizer DINP 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5 7.5
ZnO 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5 5
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
TMQ 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2
Dispergum PT – 2 4 – – – – – – – – – – – – –
Deoflow A – – – 2 4 – – – – – – – – – – –
Deoflow S – – – – – 2 4 – – – – – – – – –
Deosol H – – – – – – – 2 4 – – – – – – –
Deogum 80 – – – – – – – – – 2 4 – – – – –
Deoflow 821 – – – – – – – – – – – 2 – – – –
Deogum 294 – – – – – – – – – – – – 2 – – –
Dispergum GT – – – – – – – – – – – – – 2 – –
Homogenisator 501 – – – – – – – – – – – – – – 4 –
Deotack P – – – – – – – – – – – – – – – 4
CBS 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
Deovulc TBzTD-80 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Sulphur 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Total phr 188 190 192 190 192 190 192 190 192 190 192 190 190 190 192 192
Mooney Viscosity
ML 1 + 4 100 °C [MU] 76 70 62 71 65 68 66 70 68 68 64 69 69 68 65 65
Mooney Scorch 130 °C
Time t5 [min] 15.9 22.1 27.4 16.0 16.9 16.4 15.7 16.4 16.2 19.1 21.9 17.5 16.7 20.6 18.1 17.8
Rheometer MDR 2000 180 °C / 6 min
S' min [Nm] 1.64 1.61 1.42 1.58 1.52 1.50 1.47 1.55 1.57 1.60 1.61 1.66 1.66 1.54 1.28 1.39
S' max [Nm] 17.75 18.38 16.49 16.71 16.11 16.57 16.51 16.59 16.39 17.59 17.12 17.11 16.91 17.56 14.54 15.75
t10 [min] 0.78 0.92 1.06 0.81 0.83 0.81 0.79 0.81 0.80 0.88 0.92 0.84 0.82 0.91 0.87 0.85
t90 [min] 1.55 1.71 2.00 1.45 1.48 1.45 1.39 1.44 1.41 1.58 1.69 1.48 1.44 1.63 1.53 1.53
Vulcanization: 30 min/155 °C, specimen 6 mm
Hardness [Shore A] 67 67 64 66 65 67 66 67 66 65 65 67 68 65 64 64
Rebound [%] 31 31 31 32 30 31 30 31 30 30 30 29 30 31 29 30
Vulcanization: 20 min/155 °C, S2-specimen
Tensile Strength [MPa] 15.0 14.6 14.7 14.6 15.1 15.0 14.8 14.8 15.1 14.8 14.3 14.2 14.8 15.7 15.1 14.7
Elongation at Break [%] 344 345 381 371 444 406 375 382 401 389 383 353 361 385 413 395
Modulus 300 % [MPa] 13.8 13.4 12.1 13.0 11.6 12.3 12.7 12.7 12.2 12.3 11.9 12.9 12.9 12.9 11.6 12.1
Tear Resistance [N/mm] 12.4 12.5 13.2 13.1 13.7 14.2 12.9 13.5 14.1 13.4 12.4 13.8 12.6 12.6 13.6 14.3
Hot Air Ageing 72 h/100 °C
Retention TS [%] 99 102 100 98 99 96 92 104 101 102 93 104 96 92 100 103
Retention EB [%] 75 72 79 71 73 68 69 77 73 72 67 76 71 68 75 81
Change in Hardness [Shore A] +3 +4 +4 +4 +4 +4 +6 +3 +4 +4 +4 +4 +3 +4 +2 +4
Compression Set
24 h/70 °C [%] 12 11 12 13 13 16 18 14 14 10 13 11 10 10 12 12
24 h/100 °C [%] 29 29 28 30 30 31 30 30 31 27 30 28 29 29 32 31
DIN Abrasion
Abrasion [mm³] 120 121 122 123 126 132 125 119 127 124 118 125 116 123 134 129
Rheovulkameter Injection Moulding Test, pressure 50 bar, injection time 70 s, capillary/piston 100 °C, mould 180 °C
Volume after 70 s [cm³] 1.70 2.80 4.22 2.12 2.99 2.08 2.38 2.22 2.81 2.86 3.85 3.02 2.90 2.89 2.29 2.18
Volume Speed [mm³/s] 31 44 68 37 50 37 42 39 46 46 61 48 47 45 38 34
Rheovulkameter Capillary Test, pressure 30 bar, injection time 70 s, capillary/piston 90 °C
Volume after 70 s [cm³] 1.18 2.02 2.58 1.65 2.55 1.63 1.87 1.67 2.29 2.19 2.92 2.47 1.94 2.00 1.19 1.49
Volume Speed [mm³/s] 18 30 39 25 38 25 28 25 34 32 44 37 29 30 18 22

15

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 -KONTAKT 42

5.2 Conventional, light coloured NBR-Compound

466A 1 2 3 4 5 6 7 8 9 10

Krynac 3345 100 100 100 100 100 100 100 100 100 100

Silica Perkasil KS 300 30 30 30 30 30 30 30 30 30 30
Clay 50 50 50 50 50 50 50 50 50 50
Plasticizer DINP 10 10 10 10 10 10 10 10 10 10
ZnO 5 5 5 5 5 5 5 5 5 5
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Dusantox 86 1 1 1 1 1 1 1 1 1 1
Dispergum PT – 2 4 – – – – – – –
Dispergum GT – – – 2 4 – – – – –
Deoflow A – – – – – 2 4 – – –
Deosol H – – – – – – – 2 4 –
Deoflow S – – – – – – – – – 2
Deoflow 821 – – – – – – – – – –
Deogum 80 – – – – – – – – – –
Deotack P – – – – – – – – – –
Deotack 70 DL – – – – – – – – – –
Homogenisator 501 – – – – – – – – – –
MBTS 1 1 1 1 1 1 1 1 1 1
Deovulc TBzTD-80 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75

Sulphur 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Total phr 199.8 201.8 203.8 201.8 203.8 201.8 203.8 201.8 203.8 201.8

Mooney Viscosity
ML 1 + 4 100 °C [MU] 63 57 54 57 55 57 54 58 58 56
Mooney Scorch 130 °C
Time t5 [min] 21.6 27.4 32.9 25.1 28.8 20.2 18.7 20.4 21.3 15.9

Rheometer MDR 2000 180 °C / 6 min
S' min [Nm] 1.81 1.27 1.13 1.36 1.19 1.51 1.48 1.52 1.80 1.39

S' max [Nm] 16.80 13.40 12.36 13.72 12.54 14.67 14.19 13.67 14.99 13.58

t10 [min] 0.81 0.97 1.09 0.91 1.03 0.84 0.81 0.85 0.87 0.74

t90 [min] 1.55 1.93 2.06 1.71 1.98 1.44 1.40 1.52 1.51 1.25

Vulcanization: 30 min/155 °C, specimen 6 mm
Hardness [Shore A] 64 62 61 63 61 64 64 63 63 63
Rebound [%] 35 35 36 34 34 34 34 35 32 35
Vulcanization: 20 min/155 °C, S2-specimen
Tensile Strength [MPa] 16.7 16.8 15.5 15.8 15.7 17.0 15.3 16.2 15.2 17.2

Elongation at Break [%] 711 750 767 714 758 760 742 791 758 744

Modulus 300 % [MPa] 5.3 4.5 4.1 4.7 4.2 4.7 4.5 4.3 4.4 4.5
Tear Resistance [N /mm] 17.5 19.9 18.0 18.8 19.2 19.1 18.9 19.3 19.9 18.7

Hot Air Ageing 72 h/100 °C
Retention TS [%] 98 92 98 97 96 90 90 95 95 89
Retention EB [%] 84 83 84 86 89 78 80 77 76 79
Change in Hardness [Shore A] +5 +4 +4 +4 +5 +6 +6 +4 +4 +3
DIN Abrasion
Abrasion [mm³] 142 166 177 161 161 169 154 149 163 155

Compression Set
24 h/70 °C [%] 29 33 26 33 34 27 27 29 26 29
24h/100 °C [%] 47 49 43 47 50 46 45 49 46 46
Rheovulkameter Injection Moulding Test, pressure 60 bar , injection time 70 s, capillary/piston 100 °C, mould 180 °C

Volume after 70 s [cm³] 1.72 2.07 2.58 2.05 2.40 2.29 2.86 2.23 2.68
2.02
Volume Speed [mm³/s] 33 36 46 36 42 42 54 40 49 38
Rheovulkameter Capillary Test, pressure 60 bar, injection time 70 s, capillary/piston 90 °C
Volume after 70 s [cm³] 1.69 1.86 2.09 1.94 2.13 2.54 3.69 2.42 3.23 1.87

Volume Speed [mm³/s] 25 28 32 29 32 38 55 36 48 28

16

DOG 08007_Kontakt_42_E_rz.indd 16 01.10.2008 12:44:22 Uhr

 11 12 13 14 15 16 17 18 19 20 21

100 100 100 100 100 100 100 100 100 100 100
Krynac 3345
30 30 30 30 30 30 30 30 30 30 30
Silica Perkasil KS 300
50 50 50 50 50 50 50 50 50 50 50 Clay
10 10 10 10 10 10 10 10 10 10 10
Plasticizer DINP
5 5 5 5 5 5 5 5 5 5 5 ZnO
0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Stearic Acid
1 1 1 1 1 1 1 1 1 1 1
Dusantox 86
– – – – – – – – – – –
Dispergum PT
– – – – – – – – – – –
Dispergum GT
– – – – – – – – – – –
Deoflow A
– – – – – – – – – – – Deosol H
4 – – – – – – – – – –
Deoflow S
– 1 2 – – – – – – – –
Deoflow 821
– – – 1 2 – – – – – –
Deogum 80
– – – – – 3.5 7 – – – –
Deotack P
– – – – – – – 5 10 – –
Deotack 70 DL
– – – – – – – – – 3.5 7
Homogenisator 501
1 1 1 1 1 1 1 1 1 1 1 MBTS
0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75
Deovulc TBzTD-80
1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 Sulphur
203.8 200.8 201.8 200.8 201.8 203.3 206.8 204.8 209.8 203.3 206.8
Total phr
Mooney Viscosity
55 58 57 58 55 56 53 58 59 55 53 [MU] ML 1 + 4 100 °C
Mooney Scorch 130 °C
12.6 20.0 19.5 22.4 22.9 22.5 25.9 24.5 29.9 23.2 24.6 [min] Time t5
Rheometer MDR 2000 180 °C / 6 min
1.31 1.61 1.51 1.45 1.38 1.45 1.34 1.53 1.67 1.27 1.18 [Nm] S' min
13.02 14.67 14.16 14.14 14.30 14.35 13.38 14.20 14.93 12.82 11.70 [Nm] S' max
0.68 0.82 0.82 0.89 0.89 0.83 0.89 0.88 0.96 0.83 0.86 [min] t10
1.12 1.44 1.43 1.62 1.58 1.57 1.67 1.66 1.82 1.55 1.62 [min] t90
Vulcanization: 30 min / 155 °C, specimen 6 mm
61 63 63 62 62 62 60 63 64 61 59 Hardness [Shore A]
34 34 34 34 35 33 32 34 32 32 30 Rebound [%]
Vulcanization: 20 min / 155 °C, S2-specimen
14.9 17.1 15.1 17.3 13.6 16.6 16.2 14.7 16.6 16.9 17.5 [MPa] Tensile Strength
786 756 736 778 711 759 758 732 764 753 790 [%] Elongation at Break
3.5 4.7 4.4 4.7 4.5 4.8 4.7 4.8 4.9 4.7 4.6 [MPa] Modulus 300 %
17.6 18.8 18.8 19.8 18.1 19.4 19.1 20.3 20.6 18.2 18.3 [N/mm] Tear Resistance
Hot Air Ageing 72 h / 100 °C
95 87 87 97 102 100 99 108 89 101 101 [%] Retention TS
84 78 77 81 80 80 80 86 78 86 84 [%] Retention EB
+4 +4 +5 +5 +3 +4 +5 +4 +4 +3 +5 [Shore A] Change in Hardness
DIN Abrasion
180 149 156 156 166 177 170 150 167 157 158 [mm³] Abrasion
Compression Set
27 30 30 29 29 31 33 33 35 32 33 [%] 24h/70 °C
47 48 49 48 48 47 48 47 49 48 48 [%] 24h/100 °C
Rheovulkameter Injection Moulding Test, pressure 60 bar, injection time 70 s, capillary/piston 100 °C, mould 180 °C
2.15 2.37 2.97 2.19 2.49 2.17 2.53 1.94 2.15 2.17 2.52 [cm³] Volume after 70 s
40 44 53 40 45 40 46 35 41 39 42 [mm³/s] Volume Speed
Rheovulkameter Capillary Test, pressure 60 bar, injection time 70 s, capillary/piston 90 °C
1.99 2.52 4.31 2.26 2.67 2.19 2.56 1.99 2.16 1.95 2.20 [cm³] Volume after 70 s
30 38 67 34 40 33 39 30 33 30 33 [mm³/s] Volume Speed

17

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 -KONTAKT 42

5.3 NBR/PVC – Blend

463A 1 2 3 4 5 6 7 8

Europrene N 2845 70 70 70 70 70 70 70 70
Vestolit E 7004 30 30 30 30 30 30 30 30
Baeropan MC 8553 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
Vulkasil A1 30 30 30 30 30 30 30 30
Carbon Black N 772 40 40 40 40 40 40 40 40
Plasticizer DINP 10 10 10 10 10 10 10 10
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
ZnO 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5
Wingstay 100 1 1 1 1 1 1 1 1
Dispergum PT – 2 – – – – – –
Dispergum GT – – 2 – – – – –
Deoflow A – – – 2 – – – –
Deoflow S – – – – 2 – – –
Deoflow 821 – – – – – 2 – –
Deogum 80 – – – – – – 2 –
Deosol H – – – – – – – 2
CBS 0.7 0.7 0.7 0.7 0.7 0.7 0.7 0.7
Deovulc TBzTD-80 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3
Sulphur 1.1 1.1 1.1 1.1 1.1 1.1 1.1 1.1
Total 188 190 190 190 190 190 190 190
Mooney Viscosity
MS 1 + 4 100 °C [MU] 68 56 58 61 61 60 59 61
Mooney Scorch 130 °C
Time t5 [min] 6.59 10.17 9.15 6.34 6.47 6.76 7.65 6.91
Rheometer MDR 2000 180 °C / 6 min
S' min [Nm] 2.57 1.78 1.93 2.30 2.16 2.18 2.03 2.28
S' max [Nm] 13.82 12.06 12.13 12.91 12.57 12.67 12.16 12.67
t10 [min] 0.49 0.60 0.58 0.49 0.52 0.49 0.55 0.51
t90 [min] 1.94 1.25 1.25 1.75 1.62 1.70 1.37 1.77
Vulcanization: 30 min/155 °C, specimen 6 mm
Hardness [Shore A] 76 74 74 75 76 76 74 75
Rebound [%] 22 23 22 22 22 22 22 22
Vulcanization: 20 min/155 °C, S2-specimen
Tensile Strength [MPa] 13.5 12.6 12.7 13.3 12.2 12.8 12.0 13.5
Elongation at Break [%] 477 489 498 480 470 461 471 506
Modulus 300 % [MPa] 10.2 9.3 9.4 9.9 9.4 9.8 9.1 9.8
Tear Resistance [N/mm] 18.2 15.8 15.8 17.0 16.1 17.5 16.9 17.3
Hot Air Ageing 72 h/100 °C
Retention TS [%] 110 101 105 110 117 109 118 111
Retention EB [%] 69 71 73 67 77 69 79 71
Change in Hardness [Shore A] +3 +1 +2 +3 +1 +3 +2 +1
DIN Abrasion
Abrasion [mm³] 142 168 161 150 151 150 146 141
Compression Set
24 h/70 °C [%] 42 42 42 40 40 43 43 42
24 h/100 °C [%] 70 63 64 67 66 67 65 67
Rheovulkameter Inject. Moulding Test, press. 70 bar , inject. time 70 s, capillary/piston 100 °C, mould 180 °C
Volume after 70 s [cm³] 0.68 1.84 1.52 1.01 1.04 1.04 1.14 0.93
Volume Speed [mm³/s] 21 41 37 29 30 29 28 26
Rheovulkameter Capillary Test, pressure 85 bar, injection time 70 s, capillary/piston 90 °C
Volume after 70 s [cm³] 0.81 1.46 1.34 1.22 1.05 1.45 1.35 1.23
Volume Speed [mm³/s] 16 22 20 19 18 22 20 19

18

DOG 08007_Kontakt_42_E_rz.indd 18 01.10.2008 12:44:23 Uhr

 5.4 Heat resistant, black NBR-Compound

464A Control DINP Deotack H' Dispergum Deoflow Deogum

P 501 PT GT A 821 80 294
Krynac 3345 50 50 50 50 50 50 50 50 50 50
Krynac 3330 50 50 50 50 50 50 50 50 50 50
Carbon Black N 772 40 40 40 40 40 40 40 40 40 40
Carbon Black N 550 20 20 20 20 20 20 20 20 20 20
Stearic Acid 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
ZnO 5 5 5 5 5 5 5 5 5 5
TMQ 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
MMBI 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5
Processing Additive – 5 5 5 2.5 2.5 2.5 2.5 2.5 2.5
CBS 1 1 1 1 1 1 1 1 1 1
Deovulc TBzTD-80 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5 2.5
ZBEC (80 %) 1 1 1 1 1 1 1 1 1 1
Deovulc CLD-80 E 1 1 1 1 1 1 1 1 1 1
Sulphur S 80 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4
Total phr 174.4 179.4 179.4 179.4 176.9 176.9 176.9 176.9 176.9 176.9
Mooney Viscosity
ML 1 + 4 100 °C [MU] 73 61 64 67 67 66 68 64 69 68
Mooney Scorch 130 °C
Time t5 [min] 4.87 5.53 5.74 5.48 8.97 5.58 6.67 5.76 5.25 8.09
Rheometer MDR 2000 180 °C / 6 min
S' min [Nm] 1.41 1.14 1.16 1.17 1.34 1.37 1.41 1.29 1.42 1.40
S' max [Nm] 16.71 14.92 14.68 14.69 16.77 15.74 16.36 14.55 15.99 16.19
t10 [min] 0.43 0.47 0.48 0.47 0.62 0.46 0.51 0.47 0.46 0.60
t90 [min] 0.86 0.97 0.94 0.95 1.33 0.93 1.04 1.00 0.93 1.22
Vulcanization: 30 min/155 °C, specimen 6 mm
Hardness [Shore A] 65 62 62 63 63 63 63 63 65 62
Rebound [%] 29 32 28 25 29 28 28 28 28 31
Vulcanization: 20 min/155 °C, S2-specimen
Tensile Strength [MPa] 16.8 16.1 16.4 16.6 16.7 15.4 16.0 15.9 16.1 16.0
Elongation at Break [%] 470 519 515 509 480 486 493 530 514 450
Modulus 300 % [MPa] 11.0 9.3 9.5 10.2 10.9 10.1 9.3 8.6 9.8 10.8
Tear Resistance [N/mm] 14.2 13.6 13.5 14.2 11.1 14.0 12.4 13.4 12.6 10.3
Hot Air Ageing 72 h/125 °C
Retention TS [%] 107 103 101 107 99 108 102 106 100 98
Retention EB [%] 78 71 71 72 60 73 65 71 63 72
Change in Hardness [Shore A] +4 +5 +4 +4 +4 +5 +5 +5 +4 +4
Compression Set
24 h/100 °C [%] 16 15 16 15 14 14 14 15 14 15
24 h/125 °C [%] 25 25 24 25 22 24 23 25 24 24
Swelling in ASTM-Oil No. 1, 72 h/100 °C
Hardness [Shore A] 64 64 63 63 65 65 63 62 64 65
Change in Volume [%] 0.1 -3.0 -1.6 -1.8 -0.2 -1.3 -0.8 0.2 -0.3 -0.2
Swelling in IRM Oil 903, 72 h/100 °C
Hardness [Shore A] 57 55 54 54 56 55 55 53 55 55
Change in Volume [%] 14.9 11.4 13.0 13.3 15.9 14.3 14.8 17.9 16.2 17.0
Rheovulkameter Inject. Moulding Test, press. 60 bar, inject. time 70 s, capillary/piston 100 °C, mould 180 °C
Volume after 70 s [cm³] 1.32 1.51 1.38 1.39 1.87 1.74 1.92 3.20 2.80 1.89
Volume Speed [mm³/s] 28 32 28 28 30 32 34 54 49 31
Rheovulkameter Capillary Test, pressure 60 bar, injection time 70 s, capillary/piston 90 °C
Volume after 70 s [cm³] 0.97 1.39 1.13 0.91 1.72 2.16 2.05 5.09 4.32 1.82
Volume Speed [mm³/s] 15 21 17 14 26 32 30 85 67 28

19

DOG 08007_Kontakt_42_E_rz.indd 19 01.10.2008 12:44:23 Uhr

 add efficiency
... in more than 70 countries worldwide

• Hamburg

Deoflow, Dispergum, Deogum and Deovulc are registered

Issue: Oktober 2008; Subject to changes and alterations.

trademarks of DOG Deutsche Oelfabrik.

Europe Asia America Africa Australia
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• Use of text and pictures – even in extracts – is subject to approval of
the editor and is illegal to copyright. This also applies to copies, translations,
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The and names especially sales to third parties.
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without any committal – even with regard to any third party’s rights – and
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will not dispense from the clients examination of the products supplied by
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Sri
us. Processing operations, application and use of our products will be the
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l Latvia goods, as defined in our general terms of sale and delivery.

DOG Deutsche Oelfabrik Gesellschaft für chemische Erzeugnisse mbH & Co. KG
Ellerholzdamm 50 • 20457 Hamburg • Germany • Post Box 11 19 29 • D - 20419 Hamburg • Germany
Phone + 49(0)40 /31 18 05 0 • Fax + 49 (0)40 /31 18 05 88 • info@dog-chemie.de • www.dog-chemie.de

DOG 08007_Kontakt_42_E_rz.indd 20 01.10.2008 12:44:17 Uhr