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Igcse Chem Model Answers
Igcse Chem Model Answers
Igcse Chem Model Answers
Chemistry
for Cambridge IGCSE SECOND EDITION
Sample answers
Doing questions from past papers is a great way to revise. It gives you practice
in applying what you have learned, in different contexts. And often, exam
questions combine several topics. It is helpful to get used to this too.
In the exam, how you tackle each exam question can make a big difference to
your results. So remember …
1 Read the question carefully. Some students look at key words and think
they know what a question is about, and then write the wrong answer!
2 Pay attention to the instructions: Describe, Explain, and so on. Then follow
them.
3 Note the marks available for each question part. If the mark is 1 point, you
do not need to give 5 extra pieces of information. You will lose time which
you could use on other questions.
4 When you have written your answer, read it again to check that it really
does answer the question.
Below are ten questions from past exam papers. The sample answers that
follow have been written by the author to help you see the points above in
action.
They are questions that some students found difficult. The comments show
what to watch out for – and you will notice that the key message is: Read the
question carefully.
The first five questions are from Paper 3 (Core curriculum). Even if you are
taking Paper 4, you will find them helpful. The remaining five questions are
from Paper 4 (Extended curriculum).
most volatile
least volatile
[1]
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Sample answers 2
[4]
c The apparatus shown below is used to electrolyse concentrated aqueous
sodium chloride.
concentrated aqueous
sodium chloride
electrode A electrode B
+ –
Model Answer
a The order is:
methane
water
copper
b silver – yes
sodium chloride – soluble
sulfur – insoluble
copper sulfate – no
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Sample answers 3
Comment
a Volatile means evaporates readily. Volatile substances have low boiling
points, and this fact will help you answer the question.
ii If you know the general rules for the electrolysis of solutions (page 105
of your textbook), you should be able to work out the products for any
solution, using inert electrodes.
iii Remember PA – Positive Anode.
iv Remember that electrons carry the current in the wires, but ions carry
the current in the electrolyte. If the ions cannot move (as in solid
sodium chloride) the substance cannot conduct.
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Sample answers 4
Model Answer
a hydrogen
b i to make sure all the acid reacted
ii by filtering
c Heat to evaporate water, then leave the solution to cool. Filter off the
crystals that form, and allow them to dry on filter paper.
d i You could give any one of these: the reaction between sulfuric acid and
magnesium carbonate /magnesium hydroxide/magnesium oxide
OR the displacement reaction between magnesium and the solution of
a sulfate of a less reactive metal.
ii Give the word equation to match your answer in i). For example:
sulfuric acid 1 magnesium carbonate → magnesium sulfate 1
water 1 carbon dioxide;
sulfuric acid 1 magnesium hydroxide → magnesium sulfate 1 water;
sulfuric acid 1 magnesium oxide → magnesium
sulfate 1 water
OR e.g. magnesium 1 copper sulfate → magnesium sulfate 1 copper
iii Contaminants might make people ill/cause side effects.
e 6g
f 97.5 %
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Sample answers 5
Comment
a You are asked for the name of the gas, not the symbol or formula.
b i Answers such as ‘to keep the reaction going’ or ‘to speed up the
reaction’ will be incorrect.
c You are asked to describe the method to give dry crystals. So the question
has two marks: one is for the evaporation step, and the other for drying.
The answer ‘crystallisation’ will not answer the question.
d i Note the word other in the question.
ii Note that you are asked for a word equation, not a balanced symbol
equation.
e Don’t forget to add the correct unit, in answers to calculations (in this
case g).
f It asks for the percentage purity, not impurity. So the answer 2.5% will not
be correct.
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Sample answers 6
6
pH
5
3
0 10 20 30 40 50
time / minutes
a Describe how the acidity in the student’s mouth changes after she has
eaten the sweet. [2]
b i Chewing a sweet stimulates the formation of saliva. Saliva is
slightly alkaline. Use this information to explain the shape of
the graph. [2]
ii State the name of the type of reaction which occurs when an acid
reacts with an alkali. [1]
c Many sweets contain citric acid. The formula of citric acid is shown below.
CO2H
CH2
HO C CO2H
CH2
CO2H
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Sample answers 7
Model Answer
a The acidity increases at first, then decreases.
b i The sweet is acidic. As saliva is gradually produced, it neutralises
the acid.
ii neutralisation
c i You should circle the –OH group.
ii carboxylic acid group (iii) CH3 COOH
d i A gas (carbon dioxide) is given off.
ii
filter funnel
filter paper
precipitate
(calcium citrate)
flask
filtrate
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Sample answers 8
Comment
a The question asks about how acidity changes, not pH. So you should use
the word acidity in your answer.
b ii State the name means only one word is needed in the answer.
d ii The drawing above is sufficient. There is no need to show liquid
pouring into the funnel from a beaker. (You need to demonstate that
you can show and label the precipitate and filter.)
When you are revising, practice drawing the apparatus for separation
techniques. Do not forget the labels!
iv If you are asked to describe a method, it is not enough just to name it.
So the answer crystallisation will not be sufficient.
And remember that evaporation is a key stage in this method.
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Sample answers 9
metal observations
calcium many bubbles produced rapidly with much spitting
copper no bubbles formed
iron a few bubbles produced very slowly
magnesium many bubbles produced rapidly with no spitting
[1]
b Zinc is between iron and magnesium in its reactivity.
Suggest what observations are made about how fast the bubbles
are produced when zinc reacts with dilute hydrochloric acid. [1]
c Magnesium is extracted by the electrolysis of molten magnesium
chloride.
anode (+)
inert gas
molten magnesium
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Sample answers 10
d In some old magnesium manufacturing plants, coal gas is blown over the
surface of the magnesium.
The list shows the main substances in coal gas.
carbon monoxide ethene hydrogen
hydrogen sulfide methane
i Draw the structure of ethene showing all atoms and bonds. [1]
ii Suggest two hazards of using coal gas by referring to two specific
substances in the list.
substance
hazard
substance
hazard [2]
e Carbon monoxide can be removed from coal gas by mixing it with steam
and passing the mixture over a catalyst of iron(III) oxide at 400°C.
CO 1 H2O CO2 1 H2
i Write a word equation for this reaction. [1]
ii What does the symbol mean? [1]
iii Iron(III) oxide reacts with acids to form a solution containing
iron(III) ions.
Describe a test for aqueous iron(III) ions.
test
result [2]
[Total: 13]
Model Answer
a calcium, magnesium, iron, copper
b bubbles produced faster than with iron, and more slowly than with
magnesium
c i The magnesium is floating on top of the magnesium chloride.
ii Magnesium is more reactive than carbon.
iii to prevent magnesium reacting with the oxygen in air
iv Any one of: nitrogen/helium/neon/argon/krypton/xenon/radon.
d i H H
C C
H H
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Sample answers 11
Comment
b Questions often ask you to predict what you will observe. Do not just
repeat the listed observations.
c i Look carefully at the diagram, for this kind of question.
ii It is not enough to write that magnesium oxide does not react with
carbon. You have to explain why.
iii Remember, inert means unreactive. Molten metals are likely
to react with the oxygen in air, and a stream of inert gas will
prevent this.
iv Note that the question asks for a gaseous element, not a compound
such as carbon dioxide.
d i Here structure means structural formula. You do not need to show the
electrons and bonding.
ii You are asked to refer to substances in the list.
e i It asks for a word equation, so do not give symbols.
iii Make sure you learn those laboratory tests!
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Sample answers 12
CH3 CH2
C
H
C
H2C CH2
H2C CH
C
CH3
a On the formula above, draw a circle around the bonds which make
limonene an unsaturated compound. [1]
b Write the molecular formula for a molecule of limonene. [1]
c Describe the colour change which occurs when excess limonene
is added to a few drops of bromine water. [2]
d Limonene can be extracted from lemon peel by steam distillation.
X
water
lemon peel
C
heat
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Sample answers 13
Model Answer
a You should draw the circle around the two C5C bonds.
b C10H16
c The colour change is orange to colourless.
d i A, thermometer; B, condenser; C, measuring cylinder.
ii Arrangement: the particles are far apart.
ii Movement: they move randomly in all directions, colliding with other
particles.
e i combustion in an insufficient supply of oxygen
ii It combines with haemoglobin in the blood and prevents it carrying
oxygen around the body (so it can kill).
f i A ii C iii B
Comment
This question is about a substance you will not have heard of. Do not panic!
You have met the ideas already. Just apply them in this new context. (There
may be surprises like this in your own exam.)
b This is just a matter of counting the atoms carefully.
d i Make sure you know the names of common pieces of laboratory
equipment. Questions often ask you to identify them.
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Sample answers 14
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Sample answers 15
steel
Explain, by mentioning ions and electrons, why the exposed steel does
not rust. [3]
c Zinc electrodes have been used in cells for many years, one of the first
was the Daniel cell in 1831.
voltmeter
zinc sulfate(aq)
copper(II) sulfate(aq)
porous pot - stops
solutions from mixing
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Sample answers 16
Model Answer
a i It is roasted in air.
ii 2ZnO (s) 1 C (s) → 2Zn (s) 1 CO2 (g)
b Zinc is more reactive than iron, the main ingredient in steel. So it gives
up electrons more readily than iron to form zinc ions: Zn → Zn21 1 2e2.
This means the zinc is oxidised instead of the iron.
c i The zinc atoms from the electrode go into solution as zinc ions.
Copper ions from the copper(II) sulfate solution gain electrons to
form copper atoms, which are deposited on the copper electrode.
ii ions; electrons
Comment
b You must use the terms ions and electrons in your answer, as instructed.
Note that there are 3 marks, which suggests that you need to make three
different points.
c i You must use the terms atoms and ions in your answer, as instructed.
ii Be prepared for a question like this, about how the current is carried.
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Sample answers 17
Model Answer
a i The concentration of the reactants (CO and Cl2) increases. The
concentration of the product (COCl2) decreases.
ii A decrease in pressure favours the side of the equation with more
molecules (or moles) of gas.
b The forward reaction is exothermic. “Cool” over the forward arrow shows
that it is favoured by reducing the temperature.
c 1 hydrochloric acid (HCl)
2 carbonic acid (H2CO3)
d The diagram is:
Cl
C
O
Cl
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Sample answers 18
Comment
a i Remember, if the concentration of the reactants increases, the
concentration of the products decreases, and vice versa. And a shift to
the left always means that the concentration of the reactants increases.
b The only way to answer this is using the information above and below the
arrows. As you can see, the back reaction needs heat so it must be
endothermic.
d You are asked to show only the valency (outer-shell) electrons. For this type
of question make sure you:
– write the symbol for the atom in the centre of its circle
– follow the instructions for using x, o and •
– show the correct number of valency electrons for each atom
– show the electrons in pairs
– draw neatly.
Don’t worry about the effect of repulsion between electron pairs on the shape
of the actual molecule. Just draw it symmetrical as here.
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Sample answers 19
conical flask
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Sample answers 20
Model Answer
a Repeat the titration without indicator, adding the same volume of
acid as before. Then heat the solution to evaporate some of the water.
Allow to cool, then filter off the crystals that have formed. Dry them
using filter paper.
b number of moles of NaOH used 5 0.025 3 2.24 5 0.056;
maximum number of moles of Na2SO4.10H2O that could be
formed 5 0.028;
mass of one mole of Na2SO4.10H2O 5 322g;
maximum yield of sodium sulfate–10–water 5 9.02 g
percentage yield 5 42.8%
Comment
a Keep your instructions short and simple. The number of marks indicates
how many points you need to cover. Be sure to put your points in the
correct order.
(Note: it is also correct to say that carbon could be added to remove
the indicator, instead of repeating the titration; the carbon must then be
filtered off.)
b Take care when working out the Mr for a hydrated salt such as this.
For example there are 14 oxygen atoms and 20 hydrogen atoms in the
formula. Check that.
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Sample answers 21
Model Answer
a The two forms of oxygen have different boiling points. So you could cool
the mixture until it forms a liquid, then warm it up. The form with the
lowest boiling point will boil off first, and can be collected.
b i The solution will go from colourless to red-brown.
ii This change is an oxidation because the iodine ions lose electrons:
2I2 → I2 1 2e2
iii Ozone brings about the oxidation of the iodide ions, so it is the oxidant.
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Sample answers 22
c i
H H
H C S C H
H H
Comment
a This question may seem difficult since ozone is not on your syllabus.
But what you learned about separating the gases in air (by fractional
distillation) might have given you a clue.
b i You are asked what you would see, not for an explanation of it.
ii Remember OILRIG. You need to mention electron transfer.
c i See the comments for question 7(d) above.
d ii Organic compounds form carbon dioxide and water when they burn in
a good supply of oxygen. This compound also contains sulfur so sulfur
dioxide will form too.
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Sample answers 23
Model Answer
a i 35 cm3; 40 cm3
ii Carbon monoxide is formed. This gas is lethally poisonous because it
prevents blood from carrying oxygen around the body.
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Sample answers 24
C C
H H
H C C C C OH
H H H H
or butan-2-ol H H OH H
H C C C C H
H H H H
H C C C Cl H C C C H
H H H H H H
Comment
a i Remember, the volume ratio in which gases react is the same as the
mole ratio. (This is because 1 mole of every gas occupies the same
volume at the same temperature and pressure.) From the equation, the
mole ratio of butane to oxygen is 1: 6.5, so 10 cm3 of butane will react
with 65 cm3 of oxygen. That leaves 35 cm3 of oxygen unreacted.
Using the same logic, 10 cm3 of butane will form 40 cm3 of carbon
dioxide.
Be prepared for equations like this one, where some numbers are not
whole numbers.
iii A further substitution reaction for chlorobutane does not answer the
question, which asks about butane.
c i Remember, the structural formula of poly(propene) should contain no
double bonds. It is a saturated compound.
iii There’s no need to give the name of the product – the question doesn’t
ask for it.
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