Use the '-tbin' option.

Let's say your 24-hour RINEX obs file is named

'site0170.14o' -- for the data of 17 Jan 2014. Then run:

teqc +obs + -tbin 1h site site0170.14o

This should create the 24 hourly files 'site017a.14o', 'site017a.14o', ...,

'site017x.14o'. See 3.1.5 and 3.2.5 of
http://facility.unavco.org/software/teqc/doc/UNAVCO_Teqc_Tutorial.pdf

Now you can do the same thing with the RINEX nav files:

teqc +nav + -tbin 1h site site0170.14n

teqc +nav -,+ -tbin 1h site site0170.14g

but the results may not be what you are expecting, especially with the
GPS navigation messages in the .YYn files because the navigation messages
tend to cluster at the 00h, 02h, 04h, ..., 22h epoch times.