Paper Chemistry II

(i) Which one of the following elements will not form peroxides?
(a) Na (b) Ba (c) Li (d) None
(ii) Which of the following compounds is not a Structural isomer of n-Pentane
(a) 2-Methy butane (b) 2,2-Dimethylpropane (c) 2-Methy propane (d) None
(iii) Which of the following does NOT exhibit geometric isomerism?
(a) 2-Hexene (b) 1-Hexene (c) 3- hexene (d) none of these
(iv) Which of the following is more basic
(a)Mg(OH)2 (b) Ca(OH)2 (c) Sr(OH)2 (d) Ba(OH)2
(v) What is used as a food preservative ?
(A)Ethanol (B) Propanone ( C)Formic acid (D)Acetic acid
(vi) The blood red colour confirms the presence of nitrogenand Sulphur in an
organic compound is due to the formation of
(A) Fe4[Fe(SCN)6]3 (B) Na4[Fe(CN)6] (C) NaCNS (D) Na4[Fe(CN)5NOS]
(vii) Which of the following sodium fusion extract of organic compound gives
black ppt with acetic acid and lead acetate solution?
(A)Urea (B) Thiourea (C) Benzoic acid (D) Aniline
(viii) Which one of the following alcohols is primary alcohol
(a) n –Pentyl alcohol (b) neo-Pentyl alcohol
(c) Ter- Butyl alcohol (d) Ethylene glycol
(ix) Oxidizing power of halogens depend upon
(A) Dissociation energy (B) Electron affinity (C) Valency (D) None of these

(x) Industrial waste water contains

a) Occluded & dissolved gases c) Pathogens
b) Inorganic salts & organic compounds d) All of these

(xi) The depletion in the Ozone layer is caused by

a) Carban monoxide b) Sulphur dioxide.
c) chlorofluorocarbons. d) ethane

(xii) Which of the following is a prime health risks associated with greater UV
radiation through the atmosphere due to depletion of stratospheric ozone?
a) Damage to digestive system b) Increased liver cancer
c) Neurological disorder d) Increased skin cancer

Section-B

(i) Sodium extract is heated with conc. Nitric acid before the detection of halogens. Why?
(ii)How will you 1-Butyne from the following compound
 (a) 1,1_Dichlorobutane (b) 1,2_Dichlorobutane

(iii) State the necessary conditions for a compound to show geometrical isomerism..Justify with examples.
(iv) Write the structural formula of the following compounds
(a)Anisole (b) Styrene (c) Durene
(v) Write the mechanism of Sulphonation of benzene.
Section-C
(i) What is smog? What are its types?
(ii) What is the importance of green house effect.
(iii) What is the role of tetraethyl lead in minimizing the air pollution?
(iv) Phenol is more acidic than ethyl alcohol.Why?
(v) How primary ,secondary and tertiary accohols are prepared by Grignard agent.
Section -D

Q.1 (a)How the following elements can be detected in the organic compound . 4
Nitrogen and sulphur,
(b) In what respects Be differ from the members of its own family.6

Q.2 (a) Write four different method of preparation of Phenol.6

(b) Write down different effects of acid rain. 4