[A] vs time for a 0 order reaction
0.20
Half life decreases
0.15 | | T _ with decreasing —
mol
L
0.10
0.05
0.00 20 40 60 80
Time, sec.
Concentration of Reactants
#@ conc. of reactants > Reactant particles 4
become more crowded > *# effective
collisions — 4 Reaction rate
Increase in
concentration
Reaciant particles are
more crowded
Reactant particles are
less crowdedA— product rate = KAP
rate _ M8 _ 4 a)
tap ae ~ ‘VAs “ar 7 KIAP
Ay gg [Alisthe concentration oA at any net
(Al, * [Aly is the concentration of A at time t=0
t when [A] = [Alo/2
1
Liege
HAlo
1
aL
7 aA)
Wee = MS. 11s 005° ar = HAL
a {Alis the concentration ofA a any time t
{Al is the concentration ofA at time 0
TAl= (Abe Inf] = Inf - kt
eae semanas aauey ® Explain how the nature of
eae reactants affects the rate of the
reaction in terms of the activity
5 a Se series of metals and hydrogen.
. -The elements have their diferent solublity
2 green eG
4 AM cing
3 A pig He
i Mg mpi >