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Construction and Building Materials 228 (2019) 116818

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Review

A review on thermoelectric energy harvesting from asphalt pavement:


Configuration, performance and future
Xingyi Zhu a, Yue Yu a, Feng Li b,⇑
a
Key Laboratory of Road and Traffic Engineering of Ministry of Education, Tongji University, Shanghai 200092, PR China
b
School of Transportation Science and Engineering, Beihang University, No. 37 Xueyuan Road, Haidian District, Beijing 100191, PR China

h i g h l i g h t s

 Harvesting thermoelectric energy from asphalt pavement can reduce road temperature.
 Four methods are proposed to increase the generation power.
 The SSE has good prospects in harvesting thermoelectric energy from asphalt pavement.

a r t i c l e i n f o a b s t r a c t

Article history: Reducing the use of fossil fuels and generating renewable energy have always been important to society.
Received 10 January 2019 Asphalt pavements cover a high percentage of urban surface areas and store huge thermal energy due to
Received in revised form 15 July 2019 high solar radiation. The thermoelectric effect can convert thermal energy into electric energy if there
Accepted 26 August 2019
exist thermal gradients. The use of thermoelectric effect in asphalt pavement, on the one hand, can
Available online 5 September 2019
reduce the temperature of the road surface and relieve the damage caused by high temperature; on
the other hand, can collect clean electric energy used for LED (light-emitting diode) lamps, in-suit mon-
Keywords:
itoring sensors, and other apparatus. The present paper introduces the principle of thermoelectric effect,
Thermoelectric effect
Energy harvesting
discusses the asphalt pavement temperature field and investigates the configurations of thermoelectric
Asphalt pavement energy harvesting system used in asphalt pavements. The methods for improving efficiency are discussed
Temperature control and future research recommendations are proposed. This review shows that by means of thermoelectric
spin Seebeck effect effect to harvest energy from asphalt pavements is feasible, but more effort should be made to improve
Thermoelectric generator the thermoelectric device efficiency.
Ó 2019 Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
2. Thermoelectric technology . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2.1. The Seebeck effect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2.2. Thermoelectric materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
2.3. Thermoelectric generators . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
3. Asphalt pavement temperature field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
4. The configuration of SHTE-AP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5

Abbreviations: LED, light-emitting diode; SHTE-AP, the system harvesting


thermoelectric energy from asphalt pavement; TEG, thermoelectric generator;
NASA, national aeronautics and space administration; RWIS, road weather infor-
mation system; PP, pipe pavement; PVC, polyvinyl chloride; PP-TEG system, pipe-
pavement-thermoelectric generator system; MPPT, maximum power point track-
ing; P&O, perturb & observe; ESC, extremum seeking control; SSE, spin Seebeck
effect; ISHE, inverse-spin-Hall effect; LSSE, longitudinal spin Seebeck effect.
⇑ Corresponding author.
E-mail address: lifeng98@buaa.edu.cn (F. Li).

https://doi.org/10.1016/j.conbuildmat.2019.116818
0950-0618/Ó 2019 Elsevier Ltd. All rights reserved.
2 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

Nomenclature

a Seebeck coefficient T the average temperature between cold junction and hot
V voltage value junction
DT temperature difference between the hot source and the k thermal conductivity
cold source q electrical resistivity
Tc cold junction temperature L Lorentz number
Th hot junction temperature

4.1. Liquid system . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5


4.2. Solid system. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
5. Performance of SHTE-AP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
6. Methods for efficiency improvement of SHTE-AP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
6.1. Improving the conversion efficiency of TEGs. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
6.2. Optimizing the design of SHTE-AP . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
6.3. Changing the thermal-electric properties of the pavement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
6.4. Using maximum power point tracking algorithm in conjunction with DC/DC converter. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
7. Future research recommendations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
7.1. The spin Seebeck effect . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
7.2. Economy analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
7.3. Other recommendations . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
8. Conclusions. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Declaration of Competing Interest . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12

1. Introduction control the temperature of asphalt pavements and transfer thermal


energy from asphalt pavements to other usable energy.
The pollution of fossil fuels and other traditional energy sources Among all the energy sources which can be collected from
has always been a worldwide issue. The increasing depletion of asphalt pavements (thermal energy, mechanical energy and wind
fossil energy sources makes the use of renewable and sustainable energy), thermal energy stands out because the pavement temper-
energy even more urgent. At present, in order to reduce the use ature can be reduced when generating thermal energy. Thermo-
of fossil fuels and mitigate associated pressures on environment, electric technology is an effective way of utilizing the thermal
a series of methods have been developed to utilize the renewable energy generated by solar radiation on the road surface [8,9]. In
and sustainable energy, including solar energy, wind power, tidal low latitudes, such as Virginia, United States, the asphalt pavement
power, geothermal heat, etc. surface temperature can reach 59 °C. However, in 13 cm depth of
Pavements, one of the major civil infrastructures, cover 29%- the pavement, the temperature is around 40 °C (see Section 3).
45% of the urban surface [1]. Asphalt pavements are the primary The temperature gradient between surface and deep layer of the
type of pavements, especially urban roads and highways. Due to pavement (or other place with low temperatures, such as soil
exposure to vehicle loading and solar radiation, asphalt pavements and water) can be used to generate electric energy by thermoelec-
store a huge amount of energy. Therefore, many different tech- tric generators (TEGs). The system for harvesting thermoelectric
niques have been developed to harvest energy from asphalt pave- energy from asphalt pavement is abbreviated as SHTE-AP. On the
ments, including thermoelectric [2], geothermal [3], piezoelectric one hand, the electric energy generated by TEGs can be stored in
[4] and electromagnetic [5,6] energy harvesting. a battery or used for other devices, such as LED and in-suit wireless
It should be mentioned that asphalt pavements face some prob- monitoring sensors. One of the main limitations of wireless moni-
lems in summer. Asphalt pavements have a high rate of solar toring sensor is energy supply, which can be solved through SHTE-
absorption thus converting huge solar energy into thermal energy, AP. On the other hand, SHTE-AP will decrease the asphalt pave-
which results in higher surface temperatures. In midsummer, the ment surface temperature, thus mitigating urban heat island effect,
surface temperature of asphalt pavement can reach 70 °C. How- delaying the oxidation of the asphalt mixture, and alleviating pave-
ever, the huge thermal energy stored in asphalt pavement usually ment rutting.
is wasted. Even worse, it will bring some negative effects, for Many researchers have done lots of work about SHTE-AP, both
example, the urban heat island effect, aging of asphalt mixture, research papers [7,10] and review papers [11,12]. However, few
etc. During the summer, the pavement is generally 20 °C higher review provides a comprehensive introduction to the application
than surrounding areas [7]. When surroundings getting cooler, of thermoelectric technology in asphalt pavements. The objective
the heat generated by asphalt pavement will release, exacerbating of this paper is to make a comprehensive review of SHTE-AP and
the urban heat island effect. Besides, the continuous high temper- propose future research recommendations. The review focuses on
ature will accelerate the oxidation of asphalt mixture, which can several important aspects of SHTE-AP, such as Seebeck effect,
lead to the crack and other damages. Meanwhile, at high tempera- asphalt pavement temperature field, configuration design, and
tures, the stiffness of the asphalt mixture is significantly decreased, field performance. Furthermore, since the generation power from
aggravating pavement rutting. Therefore, it is quite essential to thermoelectric generations is quite limited, it is important to
X. Zhu et al. / Construction and Building Materials 228 (2019) 116818 3

explore the influence factors on generation power. Thus, the meth- 2.2. Thermoelectric materials
ods for efficiency improvement of SHTE-AP are also discussed. In
the end, future research recommendations are proposed such as Obviously, people are more concerned about the quality of ther-
using thermoelectric generators based on the spin Seebeck effect moelectric materials, which is described by a dimensionless figure
in asphalt pavements. ZT. ZT is defined by Eq. (3),

a2
ZT ¼ T ð3Þ
2. Thermoelectric technology kq

Thermoelectric effect is a physical phenomenon that a thermo- where k is the thermal conductivity, q is the electrical resistivity [8].
couple can convert temperature differences to electric voltage and It can be known from Eq. (3) that in order to increase ZT, it is nec-
vice versa. This effect received a lot of attention around 1960 essary to increase the Seebeck coefficient a and reduce the thermal
because it succeeded in achieving long-term power generation conductivity k and electrical resistivity q. A low electrical resistivity
on spacecraft. In recent years, thermoelectric generators have can minimize the Joule heat, thus decreasing the energy lose. A low
shown good application prospects not only in military and high- thermal conductivity can hold more heat, thus making the material
tech, but also in civil use. Thermoelectric effect includes the See- temperature drop more slowly. A high Seebeck coefficient, obvi-
beck effect, Peltier effect and Thomson effect [13]. Since this ously, can produce a high voltage. In isotropic metal, k is dominated
review is focused on generating electric energy from pavements, by the electron thermal conductivity ke. We cannot arbitrarily
we only discuss about the Seebeck effect. adjust the thermal conductivity k and electrical resistivity q of an
isotropic metal because of the Wiedemann–Franz law. Wiede-
mann–Franz law can be described by Eq. (4),
2.1. The Seebeck effect
ke q ¼ Le T ð4Þ
In 1774, Italian scientist Alessandro Volta first discovered the
where Le is the electronic Lorentz number [19].
Seebeck effect [14], but the Baltic German physicist Thomas Johann
In the case of semiconductor materials, k has two contributions,
Seebeck independently discovered and named this effect in 1821
one is electron thermal conductivity ke, and one is lattice thermal
[15]. The Seebeck effect means that the temperature gradient in
conductivity kl. Usually, kl is greater than ke. Therefore, using ther-
thermoelectric materials will cause the carriers in the material
moelectric semiconductor materials can change this situation in a
(conductors and semiconductors [16]) to move so as to realize
conventional way, thus greatly improving the conversion efficiency
the transition from thermal energy to electric energy, as shown
of thermoelectric effect and providing possibilities for practical
in Fig. 1 [17]. Under the action of a temperature gradient, holes
applications [16,20].
in the hole-rich material (p-type) diffuse toward the electron-
Getting a high ZT value has always been a research goal. If the ZT
rich material (n-type), and electrons in the electron-rich material
value increases, it will bring huge economic benefits [21]. In the
(n-type) diffuse into the hole-rich material (p-type) thus forming
beginning, between 1950 and 1960, scientists found three impor-
an electromotive force.
tant materials with high ZT values, they are bismuth telluride (Bi2-
The Seebeck effect is characterized by the Seebeck coefficient a,
Te3) used in refrigeration, lead telluride (PbTe) and silicon
which is defined by Eq. (1),
germanium used for high temperatures [22].
a  V=DT ð1Þ Table 1 shows the characteristic of several thermoelectric mate-
rials. The type means the materials belong to n-type or p-type. The
where V refers to the voltage value, DT is the temperature differ- ZT values of these materials are around 1.0 [22]. Additionally, due
ence between the hot source and the cold source (see Fig. 1). For to high Seebeck coefficient, good thermal stability and easiness for
doped semiconductors, a can be expressed by Eq. (2), large-scale synthesis, metal oxides and nitrides (such as n-type
materials: NaxCoO2, Ca3Co4O9, GaN, and p-type materials: ZnO-
8p2 kB
2  p 2=3 based, SrTiO3, InN) are good quality thermoelectric materials, espe-
a¼ 2
m T ð2Þ cially for high temperature [23–25].
3eh 3n
From 1995 to the present, the National Aeronautics and Space
where kB, e, h m* and n are, respectively, the Boltzmann constant, Administration (NASA) has conducted a new study looking for a
the carrier charge, the Planck’s constant, the effective mass of the new generation of thermoelectric materials, which should have
charge carrier and the carrier concentration [18]. small-size, but large ZT value, such as 3 or 4 [21,26].

2.3. Thermoelectric generators

People use TEGs based on the Seebeck effect to convert thermal


energy into electricity. The earliest use of TEGs was on the NASA

Table 1
The characteristic of thermoelectric materials [22].

Temperature (°C) Type Thermoelectric materials ZT values


< 150 p Bi2Te3 0.8
n Bi2Te3 0.8
150–500 p Zn4Sb3 –
p,n PbTe 0.7–0.8
p TeAgGeSb (TAGs) 1.2
500–700 p CeFe4Sb12 1.1
n CoSb3 0.8
700–900 p,n SiGe 0.6–1.0
p LaTe 0.4
Fig. 1. Schematic diagram of the Seebeck effect.
4 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

Transit navigation satellite (1961). The main advantages of TEGs


are as follows:

- The principle is simple and does not require complicated


configuration;
- Long lifespan;
- Can work in extreme environments such as outer space or high-
temperature environment;
- Can be integrated to provide greater voltage;
- Can be implanted inside other objects such as human body, Fig. 3. The thermoelectric generator (TEG) [16].

pavement;
- No noise.
3. Asphalt pavement temperature field
For a long time, the module that can be used industrially to
Due to the high absorption of solar radiation, the asphalt pave-
make TEGs is the Bismuth Telluride (Bi2Te3) module [27]. Nowa-
ment temperature can reach 70 °C. Therefore, the asphalt pave-
days, many new modules have been developed, such as half heus-
ments which cover a quite high percentage of the urban surface
ler, oxides, and magnesium silicide.
store incalculable thermal energy. However, this renewable ther-
Evident Thermoelectrics, a company, has developed two half
mal energy is always ignored. The thermoelectric effect is an effec-
heusler modules called TEG-HH-8 and TEG-HH-15. The power of
tive way of generating the thermal energy from the asphalt
the TEG-HH-8 and TEG-HH-15 at a temperature difference of
pavements. And the existence of temperature difference in the
500 °C is 7.2w and 15w [28]. Chen and Ren summarized the com-
pavement structure is the prerequisite for the application of ther-
prehensive approach for optimizing individual parameters to
moelectric effect. Under the same kind of TEG, the temperature
enhance the thermoelectric performance based on half-Heuslers,
gradient determines the output power. Since the temperature dif-
such as doping and energy filtering at grain boundaries to increase
ference plays an important role in thermoelectric effect, it is neces-
Seebeck coefficient. They also pointed out using metallic phase
sary to discuss the asphalt pavement temperature filed at first.
nanoinclusions as dopants to enhance electrical conductivity [29].
The pavement temperature is dependent on the environmental
TECTEG MFR, another company, sells two oxides modules,
factors including solar radiation, air temperature, wind speed,
CMO-32-62S and CMO-32-62S CASCADE (see Fig. 2) [30]. In the
humidity, and the thermal properties of asphalt pavement
temperature difference of 750 °C, the voltage of CMO-32-62S is
[36,37]. The Analysis shows that among many environmental fac-
6.4 V. In the temperature difference of 435 °C, the voltage of
tors, air temperature has the most significant effect on pavement
CMO-32-62S CASCADE is 9.75 V. The price of these two modules
temperature. Solar radiation is the main factor that causes the ris-
in 2018 is about 375 US dollars and 590 US dollars. It is difficult
ing of pavement temperature during the day, and it is also the most
to make a large-scale application for its expensive price.
important factor in addition to air temperature. Humidity only
Alphabet Energy developed magnesium silicide module named
affects pavement temperature under certain weather conditions
Power Modules. The thermoelectric materials are tetrahedrite (p-
and humidity has a correlation with air temperature and solar radi-
type) and magnesium silicide (Mg2Si) (n-type) which provide the
ation, which can be reflected by air temperature and solar radia-
average ZT around 1. The E1 thermoelectric generator, a kind of
tion. Most of the time, pavement temperature is almost
magnesium silicide modules provided by Alphabet Energy, consist-
synchronous with air temperature. However, the conduction of
ing of 32 Power Modules, can provide 850 W in the 350–600 °C
heat along the depth direction takes some time, so environmental
temperature range [31].
factors cannot immediately affect the deep layer of the pavement
In order to increase the voltage generated by the Seebeck effect,
structure. As the depth increases, there would be lags between
many II-structured thermocouples which are composed of two dif-
pavement temperature and air temperature. In general, pavement
ferent materials with different Seebeck coefficients, as shown in
temperature is not only closely related to air temperature and solar
Fig. 3, are usually assembled into one TEG. Finding new materials
radiation, but also dependents on the cumulative effect of the two
[32] and using nanotechnology [33–35] are ways of greatly
over a period of time.
increasing the efficiency of thermoelectric conversion.

Fig. 2. (a) CMO-32-62S (b) CMO-32-62S CASCADE [30].


X. Zhu et al. / Construction and Building Materials 228 (2019) 116818 5

Table 2
Different pavement temperature in several latitudes.

Name of the town Latitude Longitude Average maximum daily pavement temperature in July Maximum daily pavement temperature in July
Wedena, Minnesota 46.4 95.1 48.6 °C 55.3 °C
Plano, Iowa 40.7 93.0 56.5 °C 63.7 °C
Clarksville, Virginia 36.2 78.5 55.6 °C 59.6 °C
Dharan 26.2 50.0 \ 72 °C [43]

Due to the difference of air temperature and solar radiation all 4. The configuration of SHTE-AP
over the world, pavement temperature is different. America has
developed road weather information system (RWIS) to collect The heat stored in asphalt pavement needs to be conducted to
and transmit weather and road condition information. According the TEGs. According to the difference of conducting methods, there
to the data collected from RWIS, we calculated the average daily are two main configurations of SHTE-AP. One is using liquid system
maximum pavement temperature in July in different latitudes, to conduct heat. A pipeline system is placed in the pavement and
showing in the first three rows of Table 2. In general, the lower lat- uses the heat collected by the pavement to heat the liquid (mainly
itudes, the higher air temperature and the greater the amount of water) in the pipeline. Power is generated by the temperature dif-
solar radiation. Therefore, the pavement at lower latitudes has ference between hot liquid and cold liquid. The second is using
higher temperature. In addition, as shown in Table 2, pavement solid system to conduct heat. The heat generated by asphalt pave-
temperature is easily to reach around 50 °C. High pavement tem- ments is conducted from solid (mainly aluminum plate) to TEGs
perature provides the basis for the use of thermoelectric technol- which are embedded in the road or the roadside. Power is gener-
ogy to collect electric energy from roads. ated by the temperature difference between aluminum and cold
Actually, pavement temperature profile is equally important in source, such as the deeper structure of pavement.
the application of thermoelectric technology in asphalt pavement.
Fig. 4 shows the pavement temperature profile of a road in Egle- 4.1. Liquid system
tons (University of Limoges, France) (26 July 2012) [38]. This Fig-
ure aimed to compare numerical and experimental temperature, In 1979, Wendel started to study the use of pipes placed in the
but here, we only focused on the experimental temperature. As road to collect and store heat [44]. This technique is called pipe-
we can see in Fig. 4, there are large temperature differences among pavement (PP) and is mainly used to ease the urban heat island
different depth. For example, at 15 pm, the temperature difference effect and melt snow/ice on the road surface. The main composi-
between pavement surface and the depth of 13 cm is around 18 °C. tion of PP is shown in Fig. 5. Metallic or nonmetallic pipes are
TEGs can use this temperature difference to generate energy from placed under the surface of PP. The inner structure of PP with high
roads. temperature will heat the fluid in the pipes, and a heat exchanger
In addition to measuring pavement temperature, many scholars will generate and store the energy from the fluid in the pipes. In
have established many models to predict pavement temperature order to improve the efficiency of PP, many researches have been
profile. These models can be divided into two categories, the theo- conducted to study the influence factors, such as materials of pipe,
retical analysis model [39,40] and the statistical analysis model diameter of pipe, rate of flow, space of pipe, depth of pipe and ther-
[36,41,42]. The theoretical analysis model has a strong universal- mal property of pavement. The results are summarized in Table 3.
ity. However, with development of data processing technology, As long as a cold source is found, the temperature difference
the statistical analysis model has become more popular [41]. The between the liquid in pipes and the cold source can be used to gen-
development of prediction models for asphalt pavement will sup- erate electricity. Hasebe et al. first designed this system that used
port the application of thermoelectric technology in asphalt pipes to collect electric energy in 2006 [53]. He used the high tem-
pavement. perature of the road to heat the liquid and used the temperature

Fig. 4. Temperature evolutions of different depth in pavement structure [38].


6 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

Fig. 5. The main composition of PP [45].

Table 3
Influence factors of PP.

Factors Methods Conclusion


Materials of pipe Compare two kinds of materials of pipes: metal and polymer Polymer pipes and metal pipes both can be used [46]
Test the heat collection efficiency of solar collectors with three pipe The daily efficiency of the steel pipe is higher than the
materials: Galvanized steel, propyleneglycol and polyvinyl chloride other two plastic pipes [47]
(PVC)
Diameter of pipe Conduct large-scale experiments and perform a numerical simulation 25 mm has the best effect, but the difference between
to test four kinds of diameter of pipe: 6.4 mm, 12.5 mm, 19 mm, 25 mm and 19 mm is small [48]
25 mm
Rate of flow The rate of flow is determined in three conditions: 70L/h, 80L/h and An increase in rate of flow will increase the efficiency
100L/h of heat collection [45]
Space of pipe Use finite element method to study different spaces of pipe: 100 mm, The results show that reducing the space of pipe can
150 mm, 200 mm improve the efficiency of the system [49]
Depth of pipe Use numerical model to study different depth of pipe: 0.06 m, When the total heating time and lost energy rate are
0.075 m, 0.09 m, 0.105 m, 0.12 m lowest, the depth of pipe is recommended as 0.06 m
[50]
Find the proper depth of pipe for collecting heat Pipe should be embedded at the surface of road based
on the thermal conductivity of pavement [51]
Thermal property of pavement Explore the effect of adding conductive fillers (limestone powder and Adding conductive fillers increases the heat collection
graphite) on the heat collection efficiency in asphalt concrete efficiency [52]

difference between the high-temperature liquid and the water in temperature difference between the road surface and the environ-
the river to generate electricity through TEGs (see Fig. 6). The road ment produced airflow that could generate a certain amount of
temperature can reduce from 60 °C to 30 °C and the generated energy by wind turbines, which lowered the temperature of the
power can reach 0.3 W. This system is called pipe-pavement- pavement in summer. However, Garcia and Partl did not use TEGs
thermoelectric generator system (PP-TEG system) [54]. to generate electricity, but this study provided a good idea to solve
However, it cannot be ignored that the PP-TEG system has some the inadequacies of the PP-TEGs system.
limitations:
4.2. Solid system
- Pipes placed in the road will affect the strength of the pavement
structure [55]; In addition to studying air ducts, there are other ideas to solve
- Because pipes are buried in the road, maintenance and repair the deficiencies of the PP-TEGs system mentioned above which are
costs are high; directly using the TEGs in the road surface or to find alternative
- If pipes are broken, water or other liquid inside the pipe will heat conducting modules (such as the aluminum sheet) to replace
seep out, which will reduce the service life of the road. pipes.
In 2012, Wu and Yu [57] launched the earliest research in this
To avoid these problems, Garcia and Partl [56] studied an air area. They made holes in the middle of the asphalt concrete sam-
duct. They created artificial gaps in the road surface, and the ple. An aluminum bar was passed through the hole and a TEG
X. Zhu et al. / Construction and Building Materials 228 (2019) 116818 7

Fig. 6. Pipe-pavement-thermoelectric generator system (PP-TEG system) [53].

was placed on the top of the aluminum bar. The temperature dif- density of the thermoelectric device was 44 per square meter. At
ference between the TEG and the aluminum bar was used to gen- this depth and density, the thermoelectric device got the highest
erate electricity. Because the power of the TEG was small, they voltage. The rutting test verified that the thermoelectric device
used charge pump IC S-882Z to increase the voltage, which can could still work normally under the vehicle loadings.
reach 2 V to supply the LED lamp. This is just an early exploration Although Zhang et al. showed that TEGs could work under vehi-
of TEGs used in asphalt pavement. Although the thermoelectric cle loads, there are still deficiencies when TEGs are directly buried
conversion efficiency, optimal structure and the impact of vehicle in the road. For example, the maintenance of thermoelectric mod-
load on the thermoelectric module have not been analyzed, it pro- ules is difficult, and the insertion of thermoelectric modules will
vides ideas for the following research. reduce the service life of the road. Therefore, researchers have con-
Further, Wu and Yu [58] used computer-aided design to find the sidered not directly placing TEGs below the road surface, but col-
optimal structure of this power collection device. The width of the lecting the heat at the road surface through the heat conducting
heat collection sheet, the length of the aluminum strip, and the device (mostly, aluminum sheet) and conducting the heat to the
heat transfer process were analyzed to examine the influence of TEGs outside the road surface.
these factors on the output stability of the apparatus, thereby Hu et al. [60] designed a SHTE-AP that used a heat-conducting
determining the optimal structure of the apparatus. The output aluminum sheet as a heat transfer body (see Fig. 7) which could
power of the device was 0.02w at the optimal structure avoid the disadvantages of burying TEGs directly in the road. The
(4 cm  4 cm  0.5 cm aluminum sheet and 59 cm aluminum system consists of a solar collector system (thermally conductive
sheet length), and 1000 J of heat could be produced in one day. This asphalt concrete and aluminum sheets for heat conducting), a
study systematically researches the efficiency of the heat collection power generation system (multiple TEGs), and an electric energy
device designed by Wu and Yu and the optimal structure of the storage and conversion system (boost converter and battery pack).
system, but does not consider the effect of the placement of the Through dynamic simulation and field test, it was found that the
device on the road performance. embedded aluminum sheets could play a role in heat conduction.
Zhang et al. [59] used the EC1-12705 thermoelectric generator. When the temperature difference across TEGs was 25 °C, the sys-
The aluminum sheet was placed on the top of the thermoelectric tem’s output open circuit voltage was 1.1 V. The system could
generator, and the heat sink was placed on the bottom of the reduce the asphalt road surface temperature and provide power
TEG. Both upper and lower parts were coated with silicone grease for city road lighting.
to form a thermoelectric device. The thermoelectric device was Datta et al. [2] also studied the use of metals to conduct heat,
buried 2  3 cm depth from the road surface, and the laying but they used ‘‘Z” shaped metal sheets whose size was obtained

Fig. 7. The energy harvesting system [60].


8 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

by finite element simulation, as shown in Fig. 8. They analyzed two could be reduced by 9 °C in summer and the peak voltage in sum-
slightly larger TEGs and four smaller TEGs. The modules were mer was 0.564 V. This study focuses on the cooling of the road sur-
placed on shoulders. They also assessed the cost of the TEGs. The face, and the results are verified by experiments. It should be
cost of the 2 TEGs and 4 TEGs (excluding installations) was $94 mentioned that the scale of the field testing in this study is small
and $190. In the hot weather conditions of southern Texas, a and more accurate results require a extensive field testing.
64 mm  64 mm TEG could generate 10mW of electricity a day Jiang et al. [61] paid more attention to the exploration of power
for eight hours. Datta et al.’s research is more systematic and ana- generation ability. The system’s heat conducting material and TEGs
lyzes the cost of the system. Using multiple TEGs to expand this were the same as those discussed above. The test results in this
prototype can generate enough power to continuously supply paper showed that the output voltage of the system was 0.6 to
power for the LED lights in the remote area and self-powered elec- 0.7 V in the summer when the temperature difference was 25–
tronic road signs. But, the cost of TEGs is high and the materials of 30 °C. This means that on a 1 km long and 10 m wide road, this sys-
metal plate need further research. tem can produce 160kWh of electricity for 8 h.
Jiang et al. [7] did not use the roadbed as a cold source, but arti- Tahami et al. [10] recently developed a new configuration of
ficially set the water tank as the cold source of the system. The rest SHTE-AP. The main structure of the configuration was similar to
of the design was similar to Datta’s. The heat collection system is Datta’s study, except the heat sink changed to a coolant module
shown in Fig. 9. Jiang et al. chose aluminum (size which consisted of phase change materials (PCM), aerogel cover,
300 mm  60 mm  3 mm) as the heat transfer medium consider- foam box and PVC box. Finite element simulations and field testing
ing that the strength of aluminum could withstand road loads and showed that optimized configuration of SHTE-AP could enhance
it had a good heat transfer coefficient. This study used TEG-199 as a the efficiency of thermoelectric power generation.
TEG to conduct experiments to test the operational effectiveness of As mentioned above, researchers have done lots of efforts in this
the system. The results showed that the system could effectively area, but there are still many challenges. First of all, the cost of
reduce the temperature of the road. The maximum temperature SHTE-AP is expensive and the economy analysis will be discussed

Fig. 8. Schematic of the thermoelectric energy harvesting prototype in pavement [2].

Fig. 9. The heat collection system [7].


X. Zhu et al. / Construction and Building Materials 228 (2019) 116818 9

in depth in Section 7.2. Secondly, the efficiency of SHTE-AP is not


satisfactory and the generation power is low. Finally, long-term
performance of SHTE-AP has hardly been studied.
In recent years, researchers have also combined piezoelectric
technology with thermoelectric effect to enhance the efficiency
of the power generator system. Meddad’s research [62] was based
on the PZT (P188) quartz silica which could be a thermoelectric
converter [63]. The TEGs (TEC 112706) was used to excite the
piezoelectric module for energy conversion. The actual data acqui-
sition was done by the ChipKIT Max32. The PZT-TEG system has a
75% increase in harvest power compared to the conventional tech-
nologies. This provides another idea for the application of TEGs.
Fig. 11. Relationship between time and power of SHTE-AP [61].

5. Performance of SHTE-AP

To reveal the performance of SHTE-AP, which mainly means the


efficiency of energy harvesting and temperature controlling, repre-
sentative research results are discussed in this section.
Hasebe et al. first designed PP-TEG system for collecting electric
energy and discussed the performance of PP-TEG system. The rela-
tion between the electronic load and power output is shown in
Fig. 10 [53]. It should be noted that the temperature of cool water
was 297.2 K, and the temperature of hot water was 308.7 K,
323.1 K and 337.7 K, respectively. The output power is related to
the temperature of cool and hot water. However, the value is a lit-
tle low.
Guo and Lu [54] got a more interesting result based on the
Hasebe’s and other scholars’ research. According to Guo’s research,
the PP-TEG system in the Florida pavement network could obtain Fig. 12. The temperature of the traditional asphalt pavement and thermoelectric
energy output of 55GWh per day. The absorption coefficient of asphalt pavement (May 26th, 2017) [61].
asphalt concrete pavements chose 0.85. The efficiency of a pipe
system collecting thermal energy chose 0.15 [64]. Guo assumed SHTE-AP on pavement temperature reduction, as shown in
the performance of thermoelectric is 8% which was lower than Fig. 12. In May, the maximum temperature drop could reach
Kraemer’s research [65]. The energy output of the PP-TEG system 10 °C, it can be concluded that the cooling effect was distinct.
in the Florida pavement network was quite impressive. However, As we can see from the above discussion, the performance of
the calculation process is a little idealized, and more actual condi- SHTE-AP becomes better and better. This is because of the
tions need to be considered. It is better to conduct field experiment improvement of materials and design of SHTE-AP.
to verify the calculation results.
As for using solid to conduct heat, Datta et al. did some
researches. As mentioned above, they used metal to conduct heat. 6. Methods for efficiency improvement of SHTE-AP
The output of the prototype in the field experiment was tested and
the output reached its peak at around 3:50 pm which was about Generally, the generation power of TEGs is not high. When the
15.2mW [2]. temperature difference is 350 °C, the power of CMO-25-42S (a kind
Recently, Jiang [7,61] did a lot of studies. The relationship of TEG) is 1.37w. Usually, we can get a higher generated power
between time and power of SHTE-AP is shown in Fig. 11. It showed from four levels. One is to improve the conversion efficiency of
that the maximum of power could achieve 0.045 W which was TEGs; the second is how to set the optimal structure of SHTE-AP
higher than Upal’s research. Jiang also studied the effect of when the TEGs has been selected; and the third is to change the
properties of the pavement, such as porosity, etc., thus increases
the thermoelectric conversion efficiency indirectly by improving
the thermal conduction process. The last is using maximum power
point tracking algorithm in conjunction with DC/DC converter.

6.1. Improving the conversion efficiency of TEGs

To improve the conversion efficiency of TEGs, three aspects can


be considered:

(1) Increasing ZT, namely, looking for a material with high ZT;
(2) Finding cheap materials, so that a TEGs can be embedded
with many II-structured thermocouples, thus increasing
power;
(3) Raising the working temperature difference of the material,
so that the material can work in a large temperature differ-
ence environment. However, the temperature difference in
Fig. 10. The relation between the electronic load and power output [53]. asphalt pavement is quite limited.
10 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

The first two aspects can be solved by discovering new TEGs 6.4. Using maximum power point tracking algorithm in conjunction
materials. Many researches have been conducted to find new and with DC/DC converter
high performance materials [26]. One successful direction of devel-
oping new performance materials is the reduction of lattice ther- The TEGs can generate electric energy, however, the rectifica-
mal conductivity. The thermoelectric oxides, filled skutterudites tion and storage of electric energy cannot be ignored. The effects
and clathrates are candidate new performance materials. And sci- of rectification and storage also affect thermoelectric conversion
entists believe that low-dimensional structures (including quan- efficiency. An electrical converter is needed to store electric energy
tum wells, quantum wires and quantum dots) are the direction in batteries or capacitors.
of resulting in high ZT [66]. And it is reported that when 1% cerium Electrical converter is mainly DC/DC converters, and its conver-
or ytterbium is added to Bi2Te3, the performance of thermoelectric sion efficiency should be closer to 1 as possible. Selecting specific
modules increases 25%. This phenomenon is explained by cerium DC/DC converters should depend on the voltage of the TEGs and
or ytterbium affecting the crystalline structure of alloy and opti- the requirements of the application equipment. ‘‘Maximum power
mizing Seebeck effect [26]. point tracking” (MPPT) or ‘‘maximum efficiency point tracking”
algorithms are generally used to maximize the power extracted
from TEGs [27]. We compare four kinds of MPPT algorithms, which
6.2. Optimizing the design of SHTE-AP are perturb & observe (P&O), extremum seeking control (ESC),
open-circuit voltage method and fractional short-circuit MPPT.
For PP-TEGs, the configuration refers to the pipe diameter, pipe During four kinds of MPPT method mentioned above, P&O
laying depth, pipe spacing, water velocity, water temperature, etc. method is widely used because it is easy to operate [71]. Yu and
Nasir et al. [67] considered two road conditions (urban roads, Chau [72] used P&O in the waste heat energy recovery system.
rural roads) using numerical methods to explore the influence of The MMPT conversion efficiency can achieve 97% when using
four factors (pipe diameter, pipe laying depth, water flow rate P&O method [73]. The power conditioning system in Yu’s study
and temperature of water) on the heat collection and road surface is shown in Fig. 13. The power conditioning system includes TEGs,

temperature reduction. The study found the increase of pipe diam- C uk converter, battery and MPPT control. In their study, the power
eter and inlet water flow will improve the surface temperature conditioning system works stably.
reduction. However, the study also pointed out that the pipe diam- Phillip et al. [74] compared the merits of the P&O with ESC. The
eter and inlet water flow rate were unnecessary greater than results showed that the output powers of P&O and ESC were sim-
0.05 m and 1.25 m/s. ilar. However, the output power when using ESC method con-
Gao et al. [45] explored the effect of the slab solar collection verged faster. Othman et al. [75] also compared P&O with the
process. The results showed that, within a certain range, systems ESC. They found the advantages of ESC were not obvious. Monte-
with small pipe spacing obtained a large efficiency of heat collec- cucco et al. [76] used another MPPT algorithm, which was the
tion, which could reach 42%. Pipe layout and fluid parameters open-circuit voltage method. The tests showed that the converter
had a great influence on the heat collection effect. based on the open-circuit voltage method could set the optimum
For a system which using solid to conduct heat, the influence of operating point almost instantaneously. More important, it does
the buried density and depth of TEGs on the thermoelectric conver- not require significant computational power. Laird and Lu [77] pre-
sion efficiency is investigated. Zhang et al. [59] embedded TEGs sented a fractional short-circuit MPPT algorithm which could get a
(TEC1-12705) in asphalt concrete sample with different buried more stable output. Experimental results showed the converter has
depths (10 mm, 20 mm, 30 mm, 40 mm, 50 mm) and compared a high gain over the P&O algorithm.
their output voltage values. The highest voltage value was found These MPPT methods also can be combined [78]. The overall
when the buried depth was 20 mm and 30 mm. It is found that optimization must be studied to make the MPPT algorithm match
for the size of the plate (300mm300 mm), it would be better to the structure of the TEGs and load requirements of the TEGs.
embed four TEGs. Li et al. [68] studied the temperature field in Besides, when choosing the MPPT algorithm and DC/DC converter,
asphalt pavement and found that the optimal depth of TEGs is 2– the cost must be considered [79].
3 cm, which was the same as Zhang’s conclusion.

7. Future research recommendations


6.3. Changing the thermal-electric properties of the pavement
7.1. The spin Seebeck effect
Air void content (porosity) can affect the heat conducting prop-
erties of asphalt concrete [69]. Hassn et al. [70] measured the ther- Advances in science and technology have led people to dis-
mal conductivity and specific heat capacity of asphalt mixture cover a new phenomenon that can be used in thermoelectric
slabs with different air void contents. The results showed that effect. In 1988, the giant magnetoresistive effect was discovered
the higher the air void content in the asphalt mixture, the higher by scientists which was considered to be the beginning of spin-
the steady-state temperature and the faster the heating and cool- based electronics [80,81]. Spin-based electronics refers to the
ing rates could achieve. The main reason was that asphalt mixture addition of spin degrees of freedom to conventional charge-
slabs with a high air void content will have low thermal conductiv- based electronics. It can increase data processing speed, reduce
ity and specific heat capacity. power consumption, and increase the integration density com-
Therefore, the dense asphalt mixture has a high thermal con- pared to conventional semiconductor devices [82]. Based on
ductivity, which is favorable for the TEGs to collect heat. the discovery of spin-based electronics, the spin Seebeck effect
Ghahari et al. [33] explored concrete with thermoelectric prop- (SSE), of which driving power is electron spin, is investigated
erties. They found that the addition of ZnO nanoparticles improved [83]. SSE means a spin current can be generated by placing
the thermoelectric properties of the cement paste which was due the magnetic material in the temperature gradient. The spin cur-
to the formation of Zn(OH)2. The results showed that the Seebeck rent can be converted into an electromotive force via inverse-
coefficient of cement particles increased by 17% after the nanopar- spin-Hall effect (ISHE). The advantage of SSE over Seebeck effect
ticles were added to the mixture. Using thermoelectric effect in is that it can generate electric energy from insulators, because
concrete pavement is also a good choice. SSE also appears in magnetic insulators [84].
X. Zhu et al. / Construction and Building Materials 228 (2019) 116818 11

Fig. 13. The power conditioning system in Yu’s study [72].

Fig. 14. Developing LSSE-based TEG ((a) flexible device; (b) multilayer films) [16].

There are two mainly device structures based on SSE, the longi- effect in asphalt pavement is a potential method for the road
tudinal configuration (so-called longitudinal SSE (LSSE)) and trans- energy harvesting and temperature controlling.
verse configuration. LSSE is suitable for thermoelectric generators
for its structure is simple and versatile [16]. There are three main 7.2. Economy analysis
advantages of thermoelectric generators based on LSSE. The first
one is the device-design easily. The LSSE-based TEG is combined On the one hand, the Levelized Cost of Energy (LCOE) can be
with magnetic insulators and conductive films and does not used to assess the cost of thermoelectric generation of SHTE-AP.
require careful thermal design. The second is the LSSE-based TEG The LCOE provides a simple and decisive way for both nonrenew-
output can be increased simply by extending the LSSE-based TEG able energy sources and renewable sources that compares capital
area because the amount of spin current enlarges with the device costs, operations and maintenance (O&M) and so on. The LCOE
area extending [85]. The third is the LSSE is not subject to ($/kWh) is defined by Eq. (5).
Wiedemann-Franz law, because heat and charge current flow in
Annualized Capital Expenditure þ O&M
magnetic and adjacent metal respectively [86]. LCOE ¼ ð5Þ
Based on these advantages of LSSE-based TEGs, some new kinds Annual System Output
of structures of LSSE-based TEGs have been developed, such as The LCOE of thermoelectric generation of SHTE-AP in [10] is 0.9
flexible devices and multilayer films (see Fig. 14(a) and (b)). As $/kWh. The unit cost of electricity generated from fossil fuels con-
we know, the conventional thermoelectric generators almost are sists of two parts, one is unit sale price, and the other is the social
rigid. In contrast, LSSE-based TEGs can be flexible by spraying a fer- cost of carbon dioxide emissions. In [10], the unit cost of electricity
rimagnetic thin film on a flexible polyimide substrate and sputter- generated from fossil fuels is estimated at 0.2 $/kWh. In conclu-
ing a metal film (mostly, Pt film) on the ferrimagnetic thin film [87] sion, thermoelectric generation from asphalt pavement is not eco-
(see Fig. 14(a)). In order to increase the performance of LSSE-based nomically competitive with traditional power generation.
TEGs, multilayer systems have been investigated. The voltage of On the other hand, Table 4 shows the energy output, cost and
multilayer LSSE-based TEG increases significantly with the num- revenue of SHTE-AP which were calculated based on the typical
bers of layer increasing [88]. configuration reported in [2]. As shown in Table 4, SHTE-AP has
The flexible and multilayer LSSE-based TEGs are suitable for the low efficiency and high cost. It needs at least six years to cover
application in asphalt pavement. On the one hand, flexible LSSE- investment cost.
based TEGs provide more forms of SHTE-AP. The asphalt pavement However, it should be mentioned that the application of ther-
will settle due to the load, which may cause damage to the conven- moelectric technology in asphalt pavement is still in the early stage
tional rigid TEGs. On the other hand, multilayer LSSE-based TEGs of development. Technology readiness level (TRL) is used to repre-
can provide more amount of power. This is significate because sent the maturity of SHTE-AP [89,90]. TRL is based on a scale from
the efficiency of SHTE-AP is low. Therefore, the flexible and multi- 1 to 9 with 9 meaning the most mature technology. The TRL of
layer LSSE-based TEGs will facilitate applications of SHTE-AP in SHTE-AP is 3 [6]. Therefore, SHTE-AP needs further research and
roads. It can be concluded that the utilization of the spin Seebeck its potential cannot be ignored.
12 X. Zhu et al. / Construction and Building Materials 228 (2019) 116818

Table 4
Energy output, cost and revenue of SHTE-AP.

System configuration Energy output Cost Revenue


Four TEGs (64 mm  64 mm) 1.07 KWh/lane-mile/year $1.19 million/lane-mile $0.214 million/lane-mile/year

7.3. Other recommendations direction. Application of thermoelectric technology in asphalt


pavement is still in the early stage of development, and it needs
Based on the comprehensive review, other future research rec- further research.
ommendations are proposed:
Declaration of Competing Interest
(1) When embedding TEGs in the road, it will cause stress con-
centration and the decrease of road performance. Therefore, None.
the integrity between energy harvesting and road perfor-
mance must be taken into account. In addition, the traffic
Acknowledgements
loading and some weather conditions (mostly, moisture)
will cause damage to the TEGs embedded in the road. Some
The work described in this paper is supported by the National
methods need to be developed to prevent this.
Key R&D Program of China (2018YFB1600200), National Natural
(2) The output power is one of the most important parts of
Science Foundation of China (No. U1633116), Shanghai Pujiang
SHTE-AP. However, the generation power of TEGs is not
Program, and the Fundamental Research Funds for the Central
high. A configuration to enlarge the temperature difference
Universities.
between the hot side and cold side of TEGs should be
designed, thus the TEGs can provide a higher voltage. Other-
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