LAMPIRAN A

HASIL PERHITUNGAN

A.1 Perhitungan Membuat Larutan

1. Pembuatan Larutan Ca(OH)2 0,3 N
N = M x Valensi
N
M =
Valensi
0,3 eq/l
=
2 eq/mol

mol
= 0,15
l
= 0,15 M
W = M x BM x V
= 0,15 mol/l x 74 gr/mol x 0,1 l
= 1,11 gram
= 1,11 gram
2. Pembuatan Larutan HCl 0,3 M
ml
% x bj x 1000
l
M HCl =
BM
gr ml
37 % x 1,19 ml x 1000 l
= gr
36,5 mol

mol
= 12,06
l

= 12,06 M
Jadi, volume CH3COOH yang dipipet adalah:
V1 x C1 = V1 x C2
V1 x 12,06 M = 100 ml x 0,3 M
100 ml x 0,3 M
V1 =
12,06 M

V1 = 2,49 ml
LAMP. A-1
 LAMP. A-2

A.2 Perhitungan pH Larutan

V Ca(OH)2 = 100 ml
Konsentrasi Ca(OH)2 = 0,15 M
Konsentrasi HCl = 0,3 M
1. Untuk penambahan HCl 0 ml
[OH-] = b x Mb
eq
=2 x 0,15 M
mol

= 0,3
pOH = - log [OH-]
= - log 0,3
= 0,5229
pH = 14 – 0,5229
= 13,4771
2. Untuk penambahan HCl 5 ml
mmol Ca(OH)2 =M.V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M.V
mmol
= 0,3 x 5 ml
ml

= 1,5 mmol
Volume total = (100 + 5) ml = 105 ml
Ca(OH)2 + 2 HCl → CaCl2 + 2H2O
Awal 15 mmol 1,5 mmol - -
Reaksi 0,75 mmol 1,5 mmol 0,75 mmol 1,5 mmol
Sisa 14,25 mmol - 0,75 mmol 1,5 mmol
[OH-] = b x Mb
14,25
=2 x
105
= 2 x 0,1357
= 0,2714
pOH = - log [OH-]
 LAMP. A-3

= - log (0,2714)
= 0,5664
pH = 14 – pOH
= 14 – 0,5664
= 13,4336
3. Untuk penambahan HCl 10 ml
mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
mmol
= 0,3 x 10 ml
ml

= 3 mmol
Volume total = (100 + 10) ml = 110 ml
Ca(OH)2 + 2 HCl → CaCl2 + 2H2O
Awal 15 mmol 3 mmol - -
Reaksi 1,5 mmol 3 mmol 1,5 mmol 3 mmol
Sisa 13,5 mmol - 1,5 mmol 3 mmol
[OH-] = b x Mb
13,5
=2 x
110
= 2 x 0,1227
= 0,2454
pOH = - log [OH-]
= - log (0,2454)
= 0,6101
pH = 14 – pOH
= 14 – 0,6101
= 13,3899
4. Untuk penambahan HCl 15 ml
mmol Ca(OH)2 =M .V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
 LAMP. A-4

mmol HCl =M.V

mmol
= 0,3 x 15 ml
ml

= 4,5 mmol
Volume total = (100 + 15) ml = 115 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 4,5 mmol - -
Reaksi 2,25 mmol 4,5 mmol 2,25 mmol 4,5 mmol
Sisa 12,75 mmol - 2,25 mmol 4,5 mmol
[OH-] = b x Mb
12,75
=2 x
115
= 2 x 0,1108
= 0,2218
pOH = - log [OH-]
= - log (0,2218)
= 0,654
pH = 14 – pOH
= 14 – 0,654
= 13,346
5. Untuk penambahan HCl 20 ml
mmol Ca(OH)2 =M.V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
mmol
= 0,3 x 20 ml
ml

= 6 mmol
Volume total = (100 + 20) ml = 120 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 6 mmol - -
Reaksi 3 mmol 6 mmol 3 mmol 6 mmol
Sisa 12 mmol - 3 mmol 6 mmol
 LAMP. A-5

[OH-] = b x Mb
12
=2 x
120

= 2 x 0,1
= 0,2
pOH = - log [OH-]
= - log (0,2)
= 0,699
pH = 14 – pOH
= 14 – 0,699
= 13,301
6. Untuk penambahan HCl 25 ml
mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol CH3COOH = M . V
mmol
= 0,3 x 25 ml
ml

= 7,5 mmol
Volume total = (100 + 25) ml = 125 ml
Ca(OH)2 + HCl → CaCl2 + 2H2O
Awal 15 mmol 7,5 mmol - -
Reaksi 3,75 mmol 7,5 mmol 3,75 mmol 7,5 mmol
Sisa 11,25 mmol - 3,75 mmol 7,5 mmol
[OH-] = b x Mb
11,25
=2 x
125
= 2 x 0,09
= 0,18
pOH = - log [OH-]
= - log (0,18)
= 0,744
 LAMP. A-6

pH = 14 – pOH
= 14 – 0,744
= 13,256
7. Untuk penambahan HCl 30 ml
mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol CH3COOH = M . V
mmol
= 0,3 x 30 ml
ml

= 9 mmol
Volume total = (100 + 30) ml = 130 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 9 mmol - -
Reaksi 4,5 mmol 9 mmol 4,5 mmol 9 mmol
Sisa 10,5 mmol - 4,5 mmol 9 mmol
[OH-] = b x Mb
10,5
=2 x
130

= 2 x 0,081
= 0,162
pOH = - log [OH-]
= - log (0,162)
= 0,7905
pH = 14 – pOH
= 14 – 0,7905
= 13,2095
8. Untuk penambahan HCl 35 ml
mmol Ca(OH)2 =M.V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
 LAMP. A-7

mmol
= 0,3 x 35 ml
ml

= 10,5 mmol
Volume total = (100 + 35) ml = 135 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 10,5 mmol - -
Reaksi 5,25 mmol 10,5 mmol 35 mmol 70 mmol
Sisa 9,75 mmol - 35 mmol 70 mmol
[OH-] = b x Mb
9,75
=2 x
135
= 2 x 0,0722
= 0,1461
pOH = - log [OH-]
= - log (0,1461)
= 0,85
pH = 14 – pOH
= 14 – 0,85
= 13,15
9. Untuk penambahan HCl 40 ml
mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
mmol
= 0,3 x 40 ml
ml

= 12 mmol
Volume total = (100 + 40) ml = 140 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 12 mmol - -
Reaksi 6 mmol 12 mmol 6 mmol 12 mmol
Sisa 9 mmol - 6 mmol 12 mmol
[OH-] = b x Mb
 LAMP. A-8

9
=2 x
140
= 2 x 0,0643
= 0,128
pOH = - log [OH-]
= - log (0,128)
= 0,8907
pH = 14 – pOH
= 14 – 0,8907
= 13,1038
10. Untuk penambahan HCl 45 ml
mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
mmol
= 0,3 x 45 ml
ml

= 13,5 mmol
Volume total = (100 + 40) ml = 140 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 13,5 mmol - -
Reaksi 6,75 mmol 13,5 mmol 6,75 mmol 13,5 mmol
Sisa 8,25 mmol - 6,75 mmol 13,5 mmol
[OH-] = b x Mb
8,25
=2 x
145
= 2 x 0,056
= 0,112
pOH = - log [OH-]
= - log (0,112)
= 0,9507
pH = 14 – pOH
= 14 – 0,9507
= 13,0492
 LAMP. A-9

11. Untuk penambahan HCl 50 ml

mmol Ca(OH)2 =M . V
mmol
= 0,15 x 100 ml
ml

= 15 mmol
mmol HCl =M . V
mmol
= 0,3 x 50 ml
ml

= 15 mmol
Volume total = (100 + 50) ml = 150 ml
Ca(OH)2 + 2HCl → CaCl2 + 2H2O
Awal 15 mmol 15 mmol - -
Reaksi 7,5 mmol 15 mmol 6 mmol 12 mmol
Sisa 7,5 mmol - 6 mmol 12 mmol
[OH-] = b x Mb
7,5
=2 x
150
= 2 x 05
= 0,1
pOH = - log [OH-]
= - log (0,1)
= 1
pH = 14 – pOH
= 14 – 1
= 13