12th Chemistry Question Paper Collections English Medium PDF

s as laalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.
N saaslaa
d
aa a
d a aad a
d a Padasalai
d
aa a
d a aa d ad a aad a
d
ww.P.P ww .P.P ww.P.P ww .P.P ww.P.P
w
ww w ww w w ww w w ww w w ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i
laalap-BLOCK ELEMENTS-I i i i
UNIT
d a
d saas-2 d a
d saaslaala d a
d saaslaala d ad saaslaala d a
d saaslaa
aa
.PBOOK
.P aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w BACK ANSWERS w ww
w w ww
w means change) w w
wand
w the different forms wwwof
w
ww ww ww ww ww
an element are called allotropes.
1.Writeathe N tet
eAnomalous properties N etof
et the Allotropes N eteoft carbon ;Diamond N e,tegraphite
t ,
i . i . N a i . i . N a i . i . N a i . i . N
first a s as lala
elements
a of p – block a sa aslala
a s as lala
fullerene
a , carbon a
nanotubessaaslala
a saaslaa
adad
.P.1.
P adad
.P.P adad
.P.P adad
.P.P adad
.P.P
www w Small size of the
ww w w
first member www w 3. Boron doeswww w
not react directly with
www w
ww ww ww ww ww
2.High ionisation enthalpy and high hydrogen. Suggest one method to
electronegativityi . N . etet
N i . N . etet
N prepare i . N . N
tet
ediborane from BF i3..N . etet
N
l a a i
asal of d orbitals inasatheir l a a i
asal valance l a a i
asal Boron does not react l al a i
asadirectly aslaa
3.
d a sa
Absence d d a sa d a sa with d a sa
a ad
.Pshell
.P a ad
.P.P a ad
.P.P a ad
.P.P a ad
.P.P
w w w w w w w w w hydrogen. w
However,
w w it forms a variety w w w
of
www www www www www
* The first member of the group 13, hydrides called boranes. The simplest
N
boron islaalia.metalloid
. etet
N while others i N
.are. etet
N borane i .N .
is N
tet
ediborane - B2H6.la i .N
Other . etelarger
N t
i a i a i i
d a
reactive
d saasametals d a
d saasal l a
d a
d
l
boranes
l a
saasa can be prepared d ad
asa
safrom l a
diborane. d a
d saaslaa
.P.Paa aa
.Pthe
.P aa
.P.P aa
.P.P aa
.P.P
w ww
w * In group w ww
14,
w first element w ww
w Treatment of w ww
gaseous
w boron trifluoride wwww
ww ww ww ww ww
carbon is strictly tet a nonmetal while other
tet with sodium tet hydride around 450 tet gives
K
N e
N
ia. i. metalloids (silicon N
ia. i. e
N . N e
N . N e
N
elements
a saaslaalare a sa aslaal& a aaslaaliai.
diborane.
s 𝟒𝟓𝟎𝒌 a saaslaaliai. a saaslaa
d d
germanium)
aa or metals d
(tin
aa d
& lead). d d
a a 2BF3 + 6NaH →.P.P d d
a a B2H6 + 6NaF.P.P aad d
ww.P.P ww .P.P ww.P.P ww ww
w
ww w * In group
ww w w
15 Nitrogen is a ww w w ww w w ww ww
diatomic gas unlike the other members of
N etet
N N etet
N 4. Give N N
tet uses of Borax Netet
ethe
the group.
s as
a
lalai . i .
s as
a
lalai . i .
s a a i . i .
lala is used for thesidentification
1.Borax
s aslaalia. i.N of s aslaa
a a
adagroup
d 16, the first element, a a
adad oxygen also .P.P a a
adadcoloured metal ions adad a a adada a
w .PIn
w . P w .P.P
w w w w w.P.P w .P.P
w
ww exists as a diatomic
ww ww wwgas in that group. Due ww ww ww ww ww
2. In the manufacture optical and ww
to its high electronegativity
etet it formset t etet glass, enamels and tet for
eglazes
i . N
i . N i . N
i . N e borosilicate
i . N
i . N i . N
i . N
hydrogens l
asal a abonds. s l
asala a s l
asal
pottery
a a s l
asala a s aslaa
d a a
a ad * The first element d a a
a ad of group 17, .P.P d a
a ad a d
a ad a a d
a ada a
w .P.P
w w .P.P
w w w 3. It is also used
w w P.P
.as a flux in metallurgy w .P.P
w
w
www fluorine the mostww w w wwww w w ww
electronegative element. and also actsww as a good preservativeww
It shows onlyet-1 et oxidation state while etethe
t etet etet
a i . N
i . N a i . N
i . N a i .Ni . N a i .Ni . N
d a
d aasal
othershalogens l a have +1, +3,
d a
d
+5
saasal l a
and +7
d a
d
l l a
saasa is catenationdad
5.What
l
asa l
?sadescribe
a
the d a
d saaslaa
aa
.Poxidation
.P states in addition a a to -1 state. The .P.P
.P.P aa aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w catenation property w ww
w of carbon wwww
ww fluorine also is the wwstrongest oxidising ww ww ww
Catenation is an ability of an element
agent and theemost
N tet reactive element N tet
eamong to form N etet of atoms
chain N etet
i . i . N i . i . N i . i . N i . i . N
the a
d d saaslaala
halogens.
d a
d saaslaala d a
d saaslaala possesses all dthe
Carbon ad
a
slala properties dadsaasla
saabelow a
.P.Paa aa
.P.P aa
.P.P .P aa
.P aa
.P.P
w ww
w w ww
w w ww
w and forms a w ww
wide
w range of compounds wwwwith
w
ww 2. .Describe briefly ww allotropism in p- ww ww ww
itself and with other elements such as H,
block elements
i . N . etetwith specific reference
N i . N . etet to
N O, N, i .
S N . etet halogens
N
and i . N . etet
N
carbon. a
aslala i a
aslala i a
lala
asthe i a i
alagreater than or asaaslaa
aslis
a sa a sa a sa
(i) valency of elementa sa
.P.Padad Some elements adaexist
.P.P d in more adad
.P.P adad
.P.P adad
.P.P
www w ww w w www w equal to two, www w www w
ww than one crystalline ww or molecular formswin w ww ww
t t (ii) element t should have an ability t to bond
the same physical e e t state. For example, e e t e e t e e t
carbon s as laalia.N
exists
i.N
as diamond ands aslaalia.Ni.N
graphite. s s
ia.N
withlalitself
a a i.N
s aslaalia.Ni.N
s aslaa
d a a
a adphenomenon is called d a a
a adallotropism (in .P.P d a
a ad a
(iii) the self bond d
a ad
must a a
be as strong as its d
a ada a
w .PThis
w .P w .P.P
w w w w w.P.P w .P.P
w
w
www greek 'allos' means wwww w w bond with wwww
other elements wwww
another and 'trope' ww
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d a
d saasal l a
d a
d saasal l a
d ad
l
saasa l a
1 dadsaaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w ww
w wwww
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N. Netet i . N . etet
N
alaala i alaala i alaala i alaala i alaa
dasas dasas dasas dasas dasas
s aslaalia. i.N s aslaalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
d
aa a
d a d
aa a
d a Padasalai d
aa a
d a aad a
d a d
aa ad
ww .P.P ww .P.P ww .P.P ww.P.P ww.P.P
w
ww w ww w w w
ww w www w ww w w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
(iv)
d a
d saaslaala inertness of catenated
kinetic d a
d saaslaala d a
d saaslaala3 behaves likedadsalewis
9.AlCl aslaala acid
d adsaaslaa
.Paa
.Pcompound .P.P aa .P.P aa aa
.P.statement
P .P.P aa
w ww
w towards w w
other
w w molecules w ww
w .Substantiatewthis ww
w w ww
w
ww ww ww ww ww
It behaves like a Lewis acid and
6. Writeaai.N note
. etet on Fisher tropsch
N i . N . etet
N forms i . N . etet compounds with
addition
N i . N . N
tet
eammonia,
aslala i a
aslala i a i
aslala and carbonyl a i
aslala etc... Eg. asaaslaa
a s
synthesis.
a a sa a s
phosphine
a a sa chloride
.P.P adad adad
.P.carbon
P .P.P adad .P.P adad .P.P adad
www w The reaction www w
of monoxide www w AlCl 3 .6NH 3 www w www w
ww ww ww ww ww
with hydrogen at a pressure of less than 50 AlCl3 + NH3 → [Al(NH3)Cl3]
atm using i . N
metal
. etet catalysts at 500 i-.N
N 700
. etetK
N i . N . etet
N i . N . etet
N
l a
al a
asaturatedi l
asala a i l al a
asaExplain i l a a i
asal of diborane asaaslaa
yields
d a sa s and unsaturated
d a sa d a sa
10. about a sa
structure
d
. a ad
.wPhydrocarbons
P .wP.P a ad .wP.P a ad . P. a ad
P . P. adad
P
www www www *In diborane w
wwwtwo BH2 units areww w
www
linked
ww ww ww ww
nCO + (2n+1) H2 → CnH(2n+2) + nH2o by two bridged hydrogens.
N e tet N e tet eteeight
t etet
nCO + l2n a i .Hi . N2 → CnH2n + nHla2lioa. i.N *It
a i .N .
has
i N B-H bonds. a i .Ni . N
d a
d saasa l a
d a
d saasa d a
d
l l a
saas*aDiborane has only d a
d sa12asal l a
valance d adsaaslaa
.P.P aa .P.P aa .P.P aa .P.P aa .P.P aa
w ww
w 7. Give the structure w ww
w of CO and CO w ww
w electrons and w ww
w
are not sufficient to w
form ww
w
ww ww 2ww ww ww
* CO hast at linear structure. In carbon normal covalent bonds.
i . N . ee
N i . N . etet
N i . N . N
tet
efour i . N . eteare
N t
monoxide, a i
three electron pairs are
a i shared *The
a i terminal B-H bondsi
d a
d
between
l l a
saasacarbon and oxygen. d a
d
l
saasa l a
d a
d
l l a
saasa covalent bonds
normal d a
d(two
l a
saasa centre - two dadsaaslaa
l a
w ww
w Structure ; refer w
figw2.9
w w in text book w ww
w electron bond w ww
w
or 2c-2e bond). w ww
w
ww ww ww ww ww
tet tet *The remaining
tet four electrons have
tet to
. N e
N . N e
N . N e
N . N e
N
a aaslaaliai. dioxide has aaliner
*Carbon
s sa
ai.
aslaalistructure a
used
sa
iai. the bridged bonds.
aslaalfor a sa
iai. two three
aslaali.e. a saaslaa
adadequal bond distance
.Pwith
. P .P.P adafor
d the both C-O .PP
. adadcentred B-H-B bonds .P.P adadutilise two electrons .P.P adad
w w
ww bonds. In this molecule w w
ww there is one C-O www w www w www w
ww ww ww each. ww ww
sigma bond. eInteaddition t there is 3c-4e etetbond * In diborne,
etet the boron is spe3tet
i . N . N
ai the three atoms.saslaalai
laalall i . N . N i
laalai. N . N N
i.N3
laalia.sp
covering
a saas a a a
hybridised.
saas Three of thesfour
a a as a saaslaa
d
a ad d
a aindtext book d
a adhybridised orbitals d
a ad d
a ad
w w.P.Structure
P ; refer fig 2.10
w w.P.P w w.P.P w .P.contains
w P single electron
w .P.P
w
w
www www w w
www and the fourth w w
wworbital is empty. www w
8. .Give Usesete oft silicones etet * Two eteoft the half filled hybridised etet
a i . N
i . N a i . N
i . N a i . N
i . N a i .Ni . N
1. Siliconesl
saasa l a are used for low l l a
temperature
saasa saasal
orbitals l a of each boron overlap
saasa l l a with the two saslaa
d
aa a
d d a
d
a a pumps, high d a
d
a a hydrogens to form d a
d
a a terminal 2c-2e .P.P adaada
ww . Plubrication
. P and in vacuum
ww . P. P ww . P. P ww. Pfour
. P ww
ww
ww temperature oil baths ww ww etc... ww
ww bonds, leaving wwwwone empty and one w ww
w
half
2. They areNused
i . . etet for making water
N i . N . etet
N
filled hybridised
i . N . etet
N
orbitals on each
i . N . eteboron.
N t
a i a i a i a i
proofing
d a
d
l l a
saasa clothes d a
d
l
saasa l a
d a
d saasal l a
*The Three centre
d a
d saasa
- l
two l a electron
d adsaaslaa
.P3.
.Pa aThey are used as insulting .P.P a a material in .P.P a a bonds), B-H-B bond .P.P aaformation involves .P.P aa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww electrical motor wand w other appliances ww overlappingwthe w half filled hybridised ww
4. They are.Nmixed
i . etet with paints and
N i . N . etet
N orbital N
i . ofN
. etone
et boron, the empty i . N . N
tet
ehybridised
enamels a
aslalto i
a make them resistant a a i
aslaltowards a i
aslala of the other boron
orbital asanda i
lala the half filled saslaa
a s a s a s a s
. P. P
high
a
adadtemperature, sunlight, . P. P
a
adaddampness and .P.P a
adad1s orbital of hydrogen. .P .Padad a
. P. adaada
P
wwww wwww wwww wwww wwww
ww chemicals. ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asal a a i l
asal a a i aslaa
d a sa d a sa d a sa d a sa d a sa
.P.P a ad .P.P a ad .P.P a ad .P.P a ad .P.P a ad
w w w w w w w w w w w w w w w
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
d a
d saasa l l a
2 d adsaaslaa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s as laalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
d
aa a
d a d
aa a
d a Padasalai
d
aa a
d a d
aa a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww.P.P ww.P.P
w
ww w ww w w ww w w ww w w wwww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d saaslaalaa short note on
11.daWrite d a
d saaslaala
hydroboration d a
d saaslaala15, nitrogen and
group d a
d
aslaala
saphosphorus are dadsaasla
a
.P.Paa aa
.P.to
P aa
.P.P .P.Paa aa
.P.P
w ww
w Diborane adds w won
w w alkenes and ww ww non metals and w warsenic
w w & antimonyww ww
are
ww ww ww w ww
alkynes in ether solvent at room metalloids. Inwgroup 16, oxygen, sulphur
temperature. N tet reaction is called
eThis N etet andaselenium N etet are non metals N etet
and
a i . i . N a i . i . N i . i . N a i . i . N
a s aslala and is highlyasaused
hydroboration
a aslalain a s aslala is a metalloid.
tellurium
a a sa aslalthe
All
a
elements a saaslaa
. adad
.Psynthetic
P .P.Padad adad
.P.P .P.Padad adad
.P.P
www w organic www w
chemistry, especially for
www w of group 17 and
www w
18 are non metals. www w
ww ww ww ww ww
anti Markovnikov addition.
B2H6 + 3RCH i . N 2N
. etet 2R → 2B(CH2-CH2iR)
=CH . N . e+te6H
3N
t 2 .
14. lComplete
i N . etet the followingi.reactions
N N . etet
N
l
asal a a i l
asal a a i asal a a i l
asal a a i aslaa
d a sa d a sa d a sa ∆ as
d a d a sa
a ad
.P12.Give
.P a ad
.Pfor
.P a adi) B (OH)3 +NH3 .P.→
.P.P P d + 3H2O
a aBN a ad
.P.P
w w w one examplew w w each of the w w w w w w w w w
www following www www ii)Na2B407 +ww Hw2SO4 + H2O → Naw2SO ww4 +
i) Icosogens i .N . e–teBoron
N t
i .N . etet
N
4H3BO3 etet
i .N . N i .N . etet
N
a i a i a i a i
d a
ii)Prictogen
d
l l a
saasa – Nitrogen dadsaasa l l a
d a
d
l l a
saasa2H6 + 2NaOH + 6H
iii)B
d a
d sa2O l
asa→ l a
d a
d saaslaa
aa
.Piii)Tetragen
.P .P.Paa a a 2Na[B(OH)4] + 6H
.P.P aa
.P.2P aa
.P.P
w ww
w – Carbon
w ww
w w ww
w w ww
w wwww
ww ww ww iv) B2H6 + CH ww3OH → 2B(OCH3)3w+w6H2O
iv)Chalcogens – Oxygen
i . N . etet
N i . N . etet
N v) BF3.N
i
+3H
. etet2O → H3BO3 + 3HF
N i . N . etet
N
i i i i
13.d a
d saaslaalaa note on metallic
Write d a
d saasla ala
nature of p- d a
d saaslaala
vi)HCOOH + H2SO4 →CO
d a
d saaslaal+a H2O + d a
d saaslaa
aa
.Pblock
.P .P.Paa a a H SO
.P.P .P.Paa aa
.P.P
w ww
w elements w ww
w w ww
w 2 4
w ww
w wwww
ww ww ww ww 330𝐾 ww
The tendency of an element to form a vii) SiCl 4 + NH3 → Cl-Si-NH-SiCl
N e tet N e tet N e tet N e tet 3
. N . N . N . N
aslaaliai. aslaaliai. liai. 4 + 6C2H5OH→ laaliai. 2H5)4 +
cation by loosing electrons is known as viii)
a sa a sa a saaslaaSiCl a sa asSi(OC a saaslaa
adad
electropositive
.Pcharacter
. P
or metallic
P.P
.theadadcharacter. This adad4HCl
.P.P .P.Padad adad
.P.P
www w depends www
on w ionisation energy.www w ix) 2B + 6NaOH w w
ww → 2Na3BO3 + 3Hw2w w
Oww w
ww ww ww ww
Generally on descending a group the 𝑅𝐸𝐷 𝐻𝑂𝑇
i . N . etet decreases and hence
N i . N . etetthe
N x) H2B.N
i 4O
. e7tet→
N 2B2O3 +
i . N .He2teOt
N
ionisation l
asal a a i
energy l
asal a a i l
asal a a i l
asal a a i aslaa
.P.Pa ad
metallic character a ad
increases.
.P.P a ad15. How will you.P.identify
.P.P a ad presence of .P.P
P a ad
www In p-block, www
the elements present inwww borate radical www www
lower left part are metals while the
i .N . etet
N i .N . etet
N When
i .N . eteboric
N t acid or borate i .N . etet is
salt
N
elements a in i the upper right part a i
are non a i i
d a
d saasal l a
d a
d saasal l a
d a
d
l l a
saasa with ethyl alcohol
heated d a
d
l a
saasina presence of dadsaaslaa
l a
ww.Pmetals.
.Paa
w w.P.Paa
w w
aa
.P.P conc. sulphuric w .P.P
acid,
w
aa
an ester, w w
aa
.P.P
w
ww w Elements of group w w
ww 13 have metallicww w w w w
wwis formed. The vapour ww
wwof this
trialkylborate
character except etet the first elementi.N boron
etet etetwith a green edged etet and
i . N
i . N i . N ester burns
i . N
i . N i . N
i .flame
N
which
d a
d saasislaalaametalloid, having d a
d
laala
saasproperties d a
d saaslaareaction
this la is used tod a
d saaslaala the
identify d a
d saaslaa
.Paa
.Pintermediate between.P the
.Pa ametal and aa
.P.P .P.Paa aa
.P.P
w ww
w w w
w w w w
w w presence of borate. w w
w w www w
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The atomic e teradius
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3 t t
e e3 C H
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a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
smallsand
a aaslalait has relatively high a sa
la
aslanuclear a aaslala2H5)3 + 3 H2O asaaslala
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In the subsequent etet groups the non- etet boron nitride etet etet
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i . N a i . N
i . N a i . N
i . N a i . N
i . N
metallic
a sa
l l a
asacharacter increases.sIn
a a
l l
asagroupa 14
a s
B(OH)
a
l a
asal 3 + NH3 → BNasa+as3H ∆ l a
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d
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w .Pelements,
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i .N . etet
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a i a i a i a i
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d a
d saasal l a
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d
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d a aad a
d a Padasalai
d
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i N . etet
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i i i i
d d saaslaala of ammonia at
atmosphere
a d a
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800-1200k d a
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d saaslaala d a
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aa
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w boron nitrideww ww wwww 3. What do you w wmeant
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ww ww ww ww ww
and other forms of borax with chemical
18. A hydride i . N . etetof 2nd period alkali
N i . N . N
tet
emetal formula i . N . etet
N i . N . etet
N
a
lala
asreactioni a i
aslalaof Boron a
aslala i a
aslala i aslaa
(A) a
onsa with a
compound sa a sa Borax contains, a s
tetranuclear
a units a sa
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ww .w This form is known www
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A , B and C. prismatic form. Borax also exists two other
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namely, a i . i . N
a sa
l a
asal 450𝐾 a saasal a
a sa
(Na
l a
asaBl O .5H O) and borax a sa
l
asalglassa
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d
a ad3 +6NaH → B2H d
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a ad 2 4 7 2 d
a ad d
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B-Boron trifluoride
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tt
iseinert pair effectlalia.N . etet
N
a i a i a i i
d a
d
l
saasa l a
d a
d saasal l a
d a
d
l l a
saasaIn heavier post-transition d a
d saasa metals, the dadsaaslaa
a aA double salt which
.P19.
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w ww
w w ww
w wwww outer s electrons w ww
w (ns) have a tendency w w
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w w
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tet aqueous solutionNof te(B) remain inert
tet and show reluctance tet take
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asBaCl part
s aslaainlia. ithe
. bonding, which
s
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K2SO4 .Al i . N .
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N → Ki . N .
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N i . N . etet
N i . N . etet
N
a
aslala 2i a
aslala i
2 5. Howa
aslala i does Silicon and a
boron i
aslala exist in asaaslaa
a sa a sa a sa a sa
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K2AL2(SO4)3.24H 2O + 2BaCl2(aq) → The oxides
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N N . etet are
N
2BaSO
s laala+i K2AlCl4
as4(S) s aslaalai aslaalaiin their acidic nature.
similar
s s aslaalaBoth i boron s aslaa
d
a ada a d
a ada a d a a
a adand silicon form covalent d a a
a ad hydrides that can d a
a ad a
w .P.P
w w .P.P
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w
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i . N . ee
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N i . N . eteelements
N t
a i → a i a i a i
CO + aFe
d a
d sasal l
2 aO 3 2Fe + 3CO
d a
d saasa
2 l l a
d a
d
are
saasal l a
readily hydrolysed
d a
d saasal l a
d a
d saaslaa
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.P.P .P.P aa aa
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w w w
w w wwww w w
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ww Book Inside ww ww 6. Why from wwaluminium to thallium ww
1.What is burnt etet alum etet there is e tet
marginal decrease in e tet
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i . N
i . N i . N
i . N i . N
i . N i . N
i . N
The
a aala
saaslaqueous saaslaaladue to
solution is acidic
a a saaslaala
energy a saaslaala a saaslaa
d d
a ahydrolysis of aluminium d d
a a sulphate it d d
a a This is due to .the aad d d
aa d
ww.Pthe
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wdw
w w
ww melts at 365 K on w w
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water of hydration
i . N . etet and swells up.i.N
N
The
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i . N . etet
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i . N . etet As a
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la is known as burnt
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Aluminium
i . N . etet chloride is obtained
N i . N . eteby
N t 7. What
i . N . N
tet important ores N
eare i . of. N
tet
eboron
heating l a a i
asalmixture of alumina l a a i
al coke in a
asand l a a i
asal - Na2[B4O5(OH) l a
asal 2O a i aslaa
d a sa d a sa d a s
Borax
a d a s
4a].8H
d a sa
a ad of chlorine. .P.P
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w w w w w w w ww w w w w w w
www Al2O3 +3C + 3Cl w2ww→ 2AlCl3 + 3CO2 www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d a
d saasal l a
d a
d saasal l a
d adsaasa l l a
4 d a
d saaslaa
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.P.P
w ww
w w ww
w wwww w ww
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w
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N
s aslaalia. i.N s aslaalia. i.N s aslaalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a d
aa ad a Padasalai
d
aa a
d a aad a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww .P.P ww .P.P
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ww w ww w w www w ww w w www w
i . N . etet
N i . N . etet
N 11.Difference
i . N . etet between graphite
N i . N . N
tet
eand
i i i i
8. dHow
a
d saaslaawill
la you prepare borax
d adsaaslaalabeads d d saaslaala
diamond
a d a
d saaslaala d a
d saaslaa
aa
.Pfrom
.P aa
.P.P aa
.P.P aa
.P.P .P.Paa
w ww
w borax w ww
w w ww
w w ww
w w ww
w
ww w w ww ww
On heating Boraxwforms a transparent w Diamond Graphite
borax beads. i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
a sa ∆ a sa a sa a s a a sa
.PNa
. ada2dB4O7.10H2O → .P.P
P
dad2B4O7 →
aNa adad It is hard .P.P
.P.P adad It is soft .P.Padad
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ww 2NaBO2 + B2O5ww www w www w www w www w
ww ww ww ww
i . N . ete-10H
N t 2O
i . N . etet
N It doesi . N . etetconduct It conducts
not
N i . N . etet
N
9.What l
asala a
are i necessary condition l
asala a i
for l
asala a i l
asala a i aslaa
d a sa d a sa d a selectricity
a d a s
electricity
a due to d a sa
a ad
.Pcatenation
.P a ad
.P.P a ad
.P.P a ad
.P.P .P.Pa ad
w w w w w w w w w w w w presence of w w w
www (i) the valency w w
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delocalised
or equal to two,
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N i . N . etet
N i . N . etet
N electrons i . N . etet
N
a i a i a i a i
(ii) a
d d
l
element l a
saasa should have an d ad
l
abilityl a
saasa to bond d a
d a
l l a
asa atom is
sCarbon d a
d
l l a
saasa atom is
Carbon d a
d saaslaa
a a itself
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.P aa
.P.P aa 3
.P.P aa 2
.P.P .P.Paa
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w w ww
w w ww
w sp hybridized w ww
w sp hybridized w ww
w
ww (iii) the self bond wwmust be as strong aswitsw ww ww
bond with other
i . N . etet elements
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d d saaslaala inertness of catenated
(iv)akinetic
d adsaaslaala d a
d aaslaalabond length is aC-C
sC-C d d saaslaabond
la length is
d a
d saaslaa
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.P.P
other a a 1.54 Ẵ
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w w w w w ww
w w ww
w w ww
w
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10.Write about
i . N . etet producer gas i.N.N
N etet It usedNfor
i . . etet
N It is used
i . N . N
teta
eas
a la i
aslaindustrial ala i
aslamonoxide a
aslala
sharpening i hard a i
aslala either on
lubricant aslaa
aOn
sa scale carbon
a sa is a sa a s a a sa
. adad
.Pproduced
P by the adaofdcarbon with
.P.P
reaction adadtools, cutting .P.P
.P.P adaits
d own or as a .PP
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ww air. The carbon monoxide ww formed will ww glasses, making ww graphited oilwww
contain nitrogen i . N . etet gas also and thei.mixture
N N . etet
N bores.N
i and
. eterock
N t
i . N . etet
N
l a a i
asal and carbon monoxide l a a i
asal is called l
asala a i l
asala a i aslaa
s
of dnitrogen
a a a sa a sdrilling.
a a s a a sa
a ad d
a ad d
a ad d
a ad d
a ad
w .Pproducer
w .P gas. w w.P.P w .P.P
w w .P.P
w w w.P.P
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www 2C + O2/N2 (air) w
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2 12. .Write about
i .N . etet
N i .N . etet
N 13.Explaini .N . etetabout fullerene and
N i .N . N
tet
ecarbon
a i a i a i a i
d a
d
l
saasa l a
d ad
l
saasa l a
d
l
saasa
nanotube
a
d
l a
d a
d saasal l a
d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
P.P
.ionisation .P.Paa
w ww
w w ww
w w ww
w 19.Explain about w ww
w enthalpyww ww
and
ww ww ww electronegativity
ww of P block elements ww
i . N . etet
N i . N . etet
N 20.Give i . N . N
tet examples of allotropes
esome i . N . etet for
N
i i i i
d a
d saaslaala d adsaaslaala d a
d saaslaalap block elements
given d a
d
laala
s–aasBoron , Carbon , d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.ALLOTROPES
P .P.Paa
w ww
w w ww
w w ww
w Tin SEE OTHER w ww
w w ww
w
ww ww ww ww ww
21. Explain the types of silicates
i . N . etet
N i . N . etet
N 22.Explaini . N . etetsilicones – preparation
N i . N . etet, types
N
a
aslala i a
aslala i a i
aslalaPreparation , physical a
aslala andi aslaa
a sa a sa a sa
Refer a s a a sa
.P.Padad adad
.P.P adad
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properties
ww uses of elements www w
ww ww ww ww ww
given in book
i . N . etet
N i . N . etet
N Mainly i . N . etet of heat , prearation
N
Action i . N . etet of
N
l
asala a i l
asala a i l
asala a i l
asala a i aslaa
d a sa d a sa d a sa
alum d a s a d a sa
.P.Pa ad a ad
.P.P a ad
.P.P a ad
P.P
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w w w w w w w w w Refer table w
2.2w, w , 2.4 w w w
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i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d ad
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
5 d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P .P.Paa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s as laalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a aad ad a Padasalaid
aa a
d a aad ad a d
aa a
d
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w
ww w ww w w www w ww w w ww w w
i . N . etet
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N i . N . etet
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N
aslaala i i i i
Oned a
d smarks
a d adsaaslaala d a
d10.
ala
saaslaWhich of the following
d adsaaslaaelements
la is/are dadsaasla
a
.P1.
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.in aa
.P.P aa
.P.P .P.Paa
w ww
w Group no 13 tow18 ww
w the periodic tableww ww non metals? ww ww w ww
w
ww w ww ww w
is ---elements. w a) Carbon , Nitrogen b) Phosphorus w ,
e t
e t e t e t e te t e te t
laalia.N laalia.N laalia.N laalia.N
a) s block b)i.Np block c) d block d)i.fNblock Oxygen i.N c) Sulphur and Selenium i.N d) All of
a s as
2.ad------and
a --------- made aa s as
revolutionary
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these
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ww ---------- areww w w
non
ww ww ww ww ww
a) Si and Al b) Si and Ge metals.
c) Cu and i .
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tet
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N t 16,17 c) 17,18
i . N . etd)
N et 13,14
l
asal a a i l
asawhicha i l
asal a a i l a a
asalis noti aslaa
a sa
3.----------------block
d a
elements
d sa show d a s a
12.-----------------compound d a sa d a sa
a ad
.Ponly
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w w w positive w
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w w state w w w undergoing w w
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a) s b) p c) d d) f a) Boron trifluoride b) Boron trichloride
4. Group i
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N
13 i .N . eistet
N c) Boron i .N . N
tet
etriiodide d) all i .N
of . N
tet
ethese
a i a i a i a i
d
calleda
d
l
saas--a l a
d adsaasal l a
d a
d13.
l l a
saasaWhich one of thedfollowing ad
l
saasa l a
is more d a
d saaslaa
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.P.P aa
.P.P .P.Paa
w ww
w Tetragens w ww
w b) w ww
w stable? w ww
w w ww
w
ww ww ww +4
ww +3 +
ww +2
Pnictogens t tet a) Ti b)
tet Ti c) Ti tet d) Ti
N e
N e t N e
N N e
N N e
N
.
aslaaliai.
.
aslaaliai. 14.alThe i. .Greek word ‘allos’ aslaaand
lia. i. ‘trope’
aalai
c) Chalcogens d) Icosagens
5. d a
d sa
Group no 14 in the d ad
periodicsa table is d a
d s a
meanss --------- and d adsa
--------------- d a
d saaslaa
.P.Paa .P.Paa aa
.P.P aa
.P.P .P.Paa
w ww
w called -- w ww
w w ww
w a) change& w ww
w
another b) different w &ww
w
ww ww ww ww ww
a) Tetragens t t b) Pnictogens tet similar c) another
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N e . N e
N . N e
N . N e
N
a aaslaaliai.
c) Chalcogens
s a aaslaaliai.
d) Icosagens
s a aaslaaliai.
these
s a saaslaaliai. a saaslaa
.P6.
. adaGroup
P d no 15 in the.periodic adad table is
P.P adad15. The simplest .borane
.P.P adad is ----------------.P.P
P.P adad
w w
ww called www w ww w w a) Diboraneww www w b) Triborane ww w w
ww ww ww ww
a) Tetragens et t b) et t c) Tetra e borane
tet d) Mono etet borane
i . N . N e i . N . N e i . N . N i . N . N
Pnictogens
a saaslaalai a saaslaalai a
16.
s a
alai acids have no reaction
aslaHalo a saaslaalai with ------- asaaslaa
d d
a aChalcogens d
a ad)d Icosagens d
a ad--------- d
a ad adad
w .wPc)
. P w .wP.P w .wP.P w .wP.P w .wP.P
ww 7. Group no 16 in
ww ww wthe
w periodic table is ww ww a) B b) C ww w
c)wZn d) w ww
Alw
called -- etet etet 17.Oxidising etet acids reacts with Boron
etet it
i . N
i . N i . N
i . N i . N
i . N i . N
i . N
d a
d saaslaala
a) Tetragens
d d aaslaala
b)sPnictogens
a d a
d saaslaala
gives
d adsaaslaala d a
d saaslaa
.P.Paa .P.Paa a a a) Boric acid
.P.P aa
.P.P b) H3BO3 .P.Paa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww c) Chalcogen ww d) Icosagens ww c) B(OH)3 ww d) All of w w
these
8.Generally on
i . N . etedescending
N t a group e
i . N . N
tetIE
the 18.---- iseessential
i . N . N
tet for the cell walls
i . N . etet of
N
i i i i
d d saaslaala, metallic character
decreases
a d ad
laala
saas------------- d a
d saaslaala
plants
d adsaaslaala d a
d saaslaa
.Pa)
.Pa aincreases .P.Pa a b) decreases a a a) B b) C c) Zn
.P.P aa
.P.P d) Al ww .P.Paa
w ww
w w ww
w w ww
w w ww
w w w
ww c) no change ww d) none of these ww 19. In the manufacture ww of Pyrex glass,..is ww
9.Which ofNthe
i . . etefollowing
N t elementsNN
i . . ete/ tare
is used. NN
i . . etet i . N . etet
N
metalloid? a
aslala i a
aslala i a i
lala acid
a)saasboric a i
aslalaoxide
b) aboric aslaa
a sa a sa a sa a sa
.Pa)
. adaArsenic,
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ww Silicon c) Boron, ww Germanium d) all of ww 20. ------------------isww used for the ww
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N identification
i . N . etet of coloured metal
N i . N . N
tet
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l
asal a a i l
asal a a i l a
al
asBorax a i l a a
asal acid i aslaa
d a sa d a sa d a s
a) a s
b)daBoric
a d a sa
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i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d adsaasal l a
d a
d saasa l l a
d ad
l
saasa l a
6 d a
d saaslaa
.P.Paa .P.Paa aa
.P.P aa
.P.P .P.Paa
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w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
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N
s as laalia. i.N s aslaalia. i.N s aslaalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a aad a
d a Padasalai
d
aa a
d a aad a
d a d
aa a
d
ww.P.P ww.P.P ww.P.P ww.P.P ww.P.P
w
i . N . etet
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i i i i
saaslaalaheated at red hot
21.daWhen d a aslaala acid
,saBoric d a30.
ala
saaslaMcAfee process is d a for aala preparation asaaslaa
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aa
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ww ww www ww ww www
a) boric acid b) boric oxide c) sodium w a) BF3 b) AlCl3 c) B2Hw 6
e te t e te t e t
e t e t
e t
lala.N i.N anhydride alaalia.N lalia.N laalia.N
borate d)aiboric i.N d) Ha3BO i.N3 i.N
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31.An
a aqueous solution a sa a
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it gives -------- a) acidic b) basic c) neutral d) none of
a) Boraxlab) i . N . etet
N
trialkylborate c) Sodiumi . N . etet
N these i . N . etet
N i . N . etet
N
a i
asd)alOctahedral boraxasaasal l a a i l a a i
asal solutions, ---------------exhibit l
asala a i aslaa
borate
d a sa d d a sa
32.In d a sa the d a sa
.Pa ad
.P23. P.Pa ad
.with a ad
.P.P .P.Pa ad a ad
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w w w Boric acid heated
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------------------ a) Potash alum b) Sodium alum
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b) . etet acid c) Sodium
N
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borate i
c) Ammonium.N . etet alum
N d)i .N .
all eteoft these
N
a i a i a i a i
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d
l l a
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d
l
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d a
d33.
l l a
saasaAt -----------------K, d a
d
l
asa
saPotashl a
alum is d a
d saaslaa
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usedww
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an eye lotion t tet a) 495 b) 365 c) 475 d) 500
i . N . e et
N i . N . e
N i . N . etet
N i . N . etet
N
a) Borax aslaala i
anhydride aslaalab) i Boric 34. i
---------------is
aslaala used for i
purification
aslaala of
d
acid a
d sa d a
d sa d a
d sa
water and styptic agentd a
d sa
to arrest bleeding d a
d saaslaa
.P.Paa .P.Paa aa
.P.P .P.Paa aa
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w d) Borax w www a) Potash alumw ww
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25. Diborane reacts with methyl alcohol to c) Zinc carbonate d) Borax
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a i
give -------------------
aslala a
aslala i a i
35.--------------is
aslala soft and a
conducts
aslala i aslaa
.Pa)
. adaBorax
P d .P.Padab)d trialkylborate .P.P adadelectricity with hexagonal .P.Padad net of sp 2
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w w
ww c) trimethyl borate w w
ww d) Octahedral borax ww ww hybridisation w w w
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26. Diboraneeadds tet on to alkenes and etet allotropeet t etet
i . N
i . N i . N
i . N i . N
i . N e i . N
i . N
alkynes s l
asal a
in a ether solvent is called
s l
asala a------------ a)
s l a
Diamond
asal a s l
b)
asala a
Fullerenes s aslaa
d
a ada a d
a ad a a d a a
a adc) Graphene d
a ada a d a
a ad a
w .P-------reaction
w .P w .P.P
w ww.P.P w .P.P
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d)
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w
www a) Substitution www w b) addition www w Graphite www w www w
c) hydroboration etet d) Markovnikov etet 36. .--------------is
etet hard and not econducts t
a i . N
i . N a i . N
i . N a i . N
i . N a i .Ni . Nespt 3
reaction
d a
d saasal l a
d a
d
l
saasa l a
d a
d
l
saasa l
electricitya with tetrahedral
d a
d saasal l
neta of
d a
d saaslaa
a aDiborane reacts with
.P27.
.P .P.Pa ammonia
a at high .P.P a a hybridisation of Carbon .P.Pa a allotrope aa
.P.P
w ww
w w ww
w w www w ww
w w ww
w
ww temperature , it gives------ ww ww a) Diamondww b) Fullerenes ww
a) Borazole etet b) Borazine etet c) Graphene etet d) Graphite etet
i . N
i . N i . N
i . N i . N
i . N i . N
i . N
d d saaslaala benzene dd)
c) Inorganic
a a
d
aslaaof
saall la these
d a
d saaslaala
37.-----------------have
d a
d saaslaala like tubes dadsaaslaa
graphite
a a3centre and 2 electron
.P28.
.P .P.Pa abonds present in .P.P a a with fullerene ends .P.Paand
a stronger than steel. aa
.P.P
w ww
w w ww
w w www w ww
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w
ww -------------------ww ww a) Diamondww b) Carbon nanotubes ww
a) Borax anhydride
i . N . etet
N b)NN
i . . etet c) Graphene
i . N . etet
N d) Graphite
i . N . etet
N
Diborane a
aslala i a
aslala i 38. a i
la mixture of carbon
aslaThe ala i
aslamonoxide and aslaa
.Pc)
. adaSodium
P d borate ww .P.Padad)d Borax adadnitrogen is called.P
.P.P Padad
-----------------
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.P.P
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ww 29. Thermal decomposition ww of benzeneww a) water gasww b) producer gas ww
diazonium.N
i . etet
tetrafluoro
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i . N . etet
N c) both.N.aN
i
tet b
eand d) none of
i . N . etet
these
N
l a a i l a a i l a a i l a a i aslaa
----dasaasal d a saasal
d a saasal
39.Methanoic acid react
d a sa asal sulphuric
with d a sa
.Pa) d
a aBF P.PaBadH .P.Pa adacid , it gives -----------------
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.P.P
w w w .P 3 b) BCl3www .c) 2 6 d) H3BO w 3ww
w w w w w w
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i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
7 d a
d saaslaa
.P.Paa .P.Paa .P.Paa .P.Paa aa
.P.P
w ww
w w ww
w w www w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s aslaalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a d
aa ad a Padasalai d
aa a
d a d
aa a
d a d
aa a
d
ww .P.P ww.P.P ww.P.P ww.P.P ww.P.P
w
ww w ww w w wwww wwww ww w w
i . N . etet
N i. N . etet
N i . N . etet
N i . N . etet
N
i i i i
a) dBFa
d sa3aslaala b) CO2 dadsac) aslaaBla2H6
d a
d saaslaala Mica are thedexample
49.Talc, a
d saaslaala for -------- dadsaaslaa
.Pd)
.Paa .P.P aa .P.P aa .P.P aa .P.P aa
w ww
w CO w ww
w wwww type of silicates wwww w ww
w
ww w ww ww ww
40. CO reacts withw chlorine , it gives ------- a) Phyllo silicates b) chain silicates
---- i . N . etet
N i . N . etet
N c) amphiboles
i . N . etet
N . N
d)aicyclic. etetsilicates
N
a i
aslala chloride a
aslalb)a i a i
aslala is an example a lala i aslaa
a s
a)adcarbonyl
a a sa a s
50.Quartz
a a sa s
for --------type of a sa
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. .P.P adad .P.P adad .P.P adad .P.P adad
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ww ww ww ww ww
c) both a and b d) none of these a) inosilicates b) tecto
41.At high i . N etet
N
temperature
. and pressure i . N . etaet
N silicates i . N . etet
N i . N . etet
N
l a a i
asaofl CO and Hydrogen l a
al a i
asgives--------- l a
al a i
asamphiboles l a a i
asd)alcyclic silicates asaaslaa
a
mixture
d sa d a sa d a
c)sa d a sa
.wPa)
. a ad
P . P. a ad
P . P.Pa ad . P. a ad
P . P.Padad
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c) methyl alcohol d) 2 butanol for the removal of permanent hardness of
N e tet N e tet etet etet
42. Ethene a i . iis.Nmixed with CO and a i . i.N water a i .Ni . N i .Ni . N
d a
Hydrogen
d
l l a
saasa gas to producedpropanal ad
l l a
saasa . This is d a
a)
d
l l a
saasInosilicates
a
d a
d
l a
saasb)a Tecto silicates dadsaaslaa
l a
aa
.Pcalled--------
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w w ww
w wwww c) Amphiboles wwww d) Zeolites w ww
w
ww ww ww ww ww
process.
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N i . N . etet
N i . N . etet
N i . N . etet
N
a) McAfee laala iprocess b) Oxo i
process i i
c) d a
d
Synsaasprocess d) d ad
Liquation saaslaalprocess
a
d a
d saaslaala d a
d saaslaala d a
d saaslaa
.P.Paa .P.P aa .P.P aa .P.P aa .P.P aa
w ww
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w
tetracarbonyl , Iron wwww wwww w ww
w
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pentacarbonyltand Chromium
i . N . e et
N i . N . etet
N i . N . etet
N i . N . etet
N
hexacarbonyl a
aslala i the oxidation state a
aslala ofi a
aslala i a
aslala i aslaa
. adad
.Ptransition
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w w
ww a) zero b) oneww w w
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ww ww ww
44.The critical etetemperature
t of Carbon etet etet etet
a i . N
i . N o
a i . N
i . N a i . N
i . N a i . N
i . N
dioxide
a sa
l
asalis a--------------------
a
C
sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
a a51d d
a ad d) 31 d
a ad d
a ad d
a ad
w w.Pa)
.P b) 45 c) 35
w .P.P
w ww.P.P ww.P.P w .P.P
w
w
www 45. Olivine is anwexample w
ww for ------------www w w
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type of silicates. etet etet etet etet
a i .Ni . N a i .Ni . N a i .Ni . N a i .Ni . N
a) Ortho
d a
d saasal l a
silicates b)
d a
Neso
d
l
saasa l a
silicates
d a
d saasal l a
d a
d
l
saasa l a
d a
d saaslaa
.Pc)
.Pa aboth a and b .Pd)
.Pa aIno silicates .P.P aa .P.P aa .P.P aa
w ww
w w ww
w wwww wwww w ww
w
ww 46. Beryl is an example ww for --------typewofw ww ww
silicates
i . N . etet
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N i . N . etet
N i . N . etet
N
i i i i
d d saaslaala
a) inosilicates
a b) chain
d ad saaslaasilicates
la
d a
d saaslaala d a
d saaslaala d a
d saaslaa
.Pc)
.Pa aamphiboles .Pd)
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w ww
w w ww
w wwww wwww w ww
w
ww 47. Spodumene w iswan example for -------- ww ww ww
type of silicates
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala
a) inosilicates i b) chain a a i
aslalsilicates a
aslala i a
aslala i aslaa
.Pc)
. adaamphiboles
P d .P.d)adacyclic
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ww 48. Asbestos is an ww example for --------type ww ww ww
of silicates.N.N
i etet i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l a a i
asal silicates l
asal a a i l
asala a i aslaa
a
d s
a) dinosilicates
a d b)
ad schain
a d a sa d a sa d a sa
.Pc)
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i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d ad
l
saasa l a
d a
d saasal l a
d a
d
l
saasa l a
8 d a
d saaslaa
.P.Paa .P.P aa .P.P aa .P.P aa .P.P aa
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w w ww
w wwww wwww w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s a slaalia. i.N s as laalia. i.N s aslaalia. i.N s as laalia. i.N saaslaa
d
aa ad a d
aa a
d a Padasalai
d
aa a
d a aad a
d a d
aa a
d
w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d adsaaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
.P.Paa .P.P aa aa
.P.P aa
.P.P aa
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w ww
w w www w ww
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w w ww
w
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i . N . etet
N MARKSi.N :115
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N i . N . etet
N MARKS i . N . ete:115
N t
a
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aslala:2hrsi a
aslala i ala
aslaTIME i aslaa
a sa a s
TIMEa a s a a sa :2hrs a sa
.P.Padad .P.P adad adad
.P.P adad
.P.P adad
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ww I.Answer the following ww questions 30×2=60 ww I.Answer theww following questions 30×2=60 ww
1. Write a short N tet on anamolous properties
enote N etet of 1. WriteNaeshort tet note on anamolousNproperties etet of
a i . i . N a i . i . N a i . i . N a i . i . N
the first
a sa
lal a
aselement of p-block.
a sa
l
asal a
athe
s a
l a
al element of p-block.
asfirst a sa
l
asal a
a saaslaa
dad
aDescribe d
a adin p- block d
a ad2. Describe briefly allotropism d
a ad in p- block .P.P d
a ad
w .P2.
w .P briefly allotropism
w .P.P
w w .P.P
w w .P.P
w w w
w
www elements with specific wwww reference to carbon www w elements withwspecific w
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3. Boron does not react directly with hydrogen. 3. Boron does not react directly with hydrogen.
Suggest one i .N . etet to prepare diborane
N
method i .N . etet BF3
N
from Suggest i .N .
oneetemethod
N t to prepare a i .N
diborane. etet from BF3
N
a i a i a i i
d a
4. AlCl
d
la l a
saa3sbehaves like a lewis d a
acid.
d
l l a
saasSubstantiate
a
d a
d4.saa
l l a
sa 3 behaves like a lewis
AlCl d a
d
l l
saasacid. a
a Substantiate
d a
d saaslaa
a astatement
.Pthis
.P .P.P aa a a this statement
.P.P aa
.P.P aa
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w ww
w w www w ww
w w ww
w w ww
w
ww 5. Write a short note wwon hydroboration ww 5. Write a short wwnote on hydroboration ww
6. Give one example
i . N . etet for each of the following
N i . N . etet
N
6. Give one
i . N . eteexample
N t for each of the following
i . N . etet
N
i i i i
d adsaaslaala (ii) tetragen (iii)dprictogen
(i) icosogens
a
d saaslaala (iv) d a
d
(i) laala
saasicosogens (ii) tetragen (iii)
d a
d
laala
saasprictogen (iv)
d a
d saaslaa
.P.Paa
chalcogen .P.P aa aa
.P.P chalcogen aa
.P.P aa
.P.P
w ww
w 7. Write a note on w www
metallic nature of p-block w ww
w 7. Write a note w
on wmetallic
w w nature of p-block w ww
w
ww ww ww ww ww
elements. elements.
8. How willi.you N . eteconvert
N t boric acid to iboron . N . etet
N 8. Howi.N will
. eteyou
N t convert boric acid.NtoN
i .
tet
eboron
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
s
nitride?
a a a sa a s
nitride?
a a sa a sa
. adahydride
.P9.A
P d of 2nd period adadmetal (A) on
.Palkali
. P adad9.A hydride of 2nd period
.P.P adadalkali metal (A) on .P.P
.P.P adad
w w
ww reaction with compound w w
ww of Boron (B) to givewaw ww w w ww w w w
wwa w
ww ww reaction with w w
compound of Boron (B) tow w
give
reducing agente(C).
N tet identify A , B and C. N etet reducing agent
N etet (C). identify A , Bi.and N eteC.t
a i . i . N a i . i . N a i . i . N a i . N
10. What
a sa
l
asal do a you meant by burnt
a salum
a
l
asal a
a
10.
s a
l
What
asal a do you meant by
a
burnt
sa
l
asal a
alum
a saaslaa
d
a ad
11.Write down chemical d
a ad
formula for ammonium d
a ad11.Write down chemical d
a ad
formula for ammonium d
a ad
w .Pand
w .P w .P.P
w w .P.P
w w .P.P
w w .P.P
w
w
www chrome alum wwww w
www and chrome alum
wwww www w
12.Explain McAfee Process 12.Explain McAfee Process
13.How will i .Nyou
. eteidentify
N t presence of iborate .N . etet
N 13.How i .N . eteyou
will
N t identify presence.NofN
i .
tet
eborate
a i a i a i a i
14. What
d ad
l l a
saasado you meant by prismatic d a
d
l l a
saasaform and d a
d
14. l
saasWhatl a
a do you meant byaprismatic
d d
l l a
saasa form and d a
d saaslaa
a a forms of borax with.P.chemical
.Pother
.P aa a a other forms of borax.P.with
.P.P aa aa
.P.P
w ww
w w www P formula
w ww
w w ww P chemical formula
w w ww
w
ww 15. What do you meant ww by inert pair effect ww 15. What do you wwmeant by inert pair effect ww
16. What do yout meant
i . N . e et andbyboron
N
catenation
i . N . etet
N
16. What dot you
i . N . N
meant by catenation t t
e etSilicon i .N . eine diagonal
N
a i a i a i and boronlaexist i
saaslaa
17.How does l l a Silicon exist l lin
a diagonal 17.Howl l a does l a
d adsaasa . Explain with statement
relationship d a
d saasa d a
d saasa
relationship . Explain d
with a
d saasa
statement d a
d
.Paa
.P18.Why P.P
.to aa aa
.P.P aa
.P.P aa
.P.P
w ww
w from aluminium w www thallium there is ww ww 18.Why from aluminium w ww
w to thallium there w ww
isw
ww marginal decrease w inwionisation energy
ww marginal decrease
ww in ionisation energy ww
19.What are.N
i . etet ores of boron i.N.N
important
N etet 19.What
i . N . eteimportant
are
N t ores of boron
i . N . etet
N
20.How a i
lala you prepare metal boron
aswill a i
aslalafrom boron a i
aslala will you prepare metal
20.How a i
la from boron
aslaboron aslaa
a sa a sa a s a a sa a sa
. adad
.Ptrichloride
P .P.P adad adadtrichloride
.P.P adad
.P.P adad
.P.P
w w
ww 21. How will you prepare w w
ww boron nitride fromww ww w w ww w w www w
ww ww 21. How will w w
you prepare boron nitride w w
from
boron and borictacid boron and boric
. N N t
e eaction . N etet
N . N N e t acid
etabout . N etet
N
22.Explain l a ia i
about. of acids on l i
boron
a a i . 22.Explain
l a ia i . action of acids l a i
on
a i .boron
aslaa
a
23.How sa al you prepare boraxabeads
aswill saasal from borax a s aasal will you prepare borax
23.How a sa
l
asabeads from borax a sa
d
a ad d
a ad d
a ad d
a ad d
a ad
w .P24.How
w .P will you prepare w wP.P
.boron trifluoride fromwww .P.P 24.How will youwprepare w .P.P
w boron trifluoride w w
from.P.P
w
w
www boric acid wwww www www www
boric acid
25. How will you
i .N . eteprepare
N t borax from boric
i .N . eteacid
N t 25. How will
i .N . etetyou prepare borax from
N i .N . N
tet acid
eboric
a i a i a i a i
26. How
d adsaasal l
willa you prepare boric
d a
d saasa
acid l l a
from
d a
d saasa
26. l
Howl a will you prepare
d a
d saasa
boric l l a
acid from
d a
d saaslaa
aa
.Pdiborane
.P .P.P aa a a diborane
.P.P aa
.P.P aa
.P.P
w ww
w 27.How does diborane w ww w
reacts with oxygen w ww
w 27.How does w ww
w
diborane reacts with oxygen w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
aa d a
d a aa d a
d a Padasalai
d
aa a
d a aa d ad a d
aa a
d
ww.P.P ww .P.P ww.P.P ww .P.P ww .P.P
ww
ww 28. How will you prepare w w
ww borazine ww w w w w w w
28. How will w w prepare borazine
you ww
29. How willNyou
i . . eteprepare
N t sodium aluminate
i. N . etetfrom
N 29. HowNwill
i . . etetyou prepare sodiumi.aluminate
N N . etet from
N
Alcl3 saslaala i i i i
d a
d a d a
d saaslaala d a
d saasla
Alcl 3ala
d adsaaslaala d a
d saaslaa
.P30.
.P a aHow will you prepare.Paluminium aa hydroxide .P.P a a 30. How will you prepare .P.Pa aaluminium hydroxide.P.P aa
w ww
w from potash alum w ww.P
w w ww
w from potash w
alum www w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a i
aslalathe following questions a i
aslala 10×5=50 a i
aslala the followingaquestions a
aslala i aslaa
a
II.Answer sa a sa a sa
II.Answer sa 10×5=50 a sa
. adad about uses of i)alum
.P31.Write
P adaii)Alcl
.P.P d
3 iii) BF3
adad31.Write about uses.of
.P.P P.P dad
ai)alum ii)Alcl3 iii) BFw
adad
.P.P
w w
ww iv)B h www w www w ww w w ww 3w
ww 2 6
ww ww iv)B2h6 ww ww
32. Write abouteuses
N tet of i) boron ii) boricNacid etet 32. Write e
N tet uses of i) boron ii)Nboric
about etet acid
iii) borax
a sa
l
asal a
a sa
l
asal a
a sa
l
asal
iii) a
borax
a sa
l
asal a
a saaslaa
d
a ad d
a aofdpotash alum , d
a ad33.Explain about preparation d
a ad of potash alum , .P.P d
a ad
w .P33.Explain
w .P
about preparation
w .P.P
w w .P.P
w w .P.P
w w w
w
www borax , boric acid ,wwww
diborane , boron trifluoride wwww borax , boric w
www
acid , diborane , boron w
www
trifluoride
34.Explain about action heat on diborane 34.Explain about action heat on diborane
35.Explain iabout .N . eteaction
N t of alcohol on iboric .N . eteacid
N t & 35.Explaini .N . etabout
N et action of alcoholi.N on. etboric
N et acid &
a i a i a i a i
B2Ha
d 6 s
d a
l
asa l a
d a
d
l
saasa l a
d a
dBsa2a
H l
sa6
l a
d adsaasal l a
d a
d saaslaa
.P36.a aExplain about action .heat aa a a 36. Explain about action a aheat on boric acid , .P.P aa
w ww
w
.P w wwP.P on boric acid , ww
w ww.P.P
w www .P.P
w ww
w
ww potash alum , boraxww ww potash alum , w w
borax ww
37. .A hydride e oft boron (A) reacts with lithium etet 37. .A hydride etet of boron (A) reactsi.N withetelithium
i . N
i . N et. On reaction i . N
i . N i . N
i . N i . N t
hydrideagives
s laal a (B) of
s l
A
asa a l a
with water
s l
hydride
asa al a gives (B) . On reaction
s l
asa aof
l a A with water
saaslaa
gives d a
d a
(C) s which is acid ). d a
d
identify aA , B and C d a
d a
gives (C) which is acid d
). ad a
identify A , B and C d a
d
aa
.P.(A)
P aa
.P.P aa
.P.P P.P
.in aa aa
.P.P
w ww
w only non-metal in w w
w w
group 13 reacts with nitric w ww
w (A) only non-metal w www group 13 reacts withwnitric ww
w
ww ww ww ww ww
acid gives acid (B) . (B) on reacting with NaOH acid gives acid (B) . (B) on reacting with NaOH
gives (C) identify
i . N . etet A , B and C
N i . N . etet
N gives (C)
i . N . N
tet
eidentify A , B and C .N.N
i etet
aslaa i
laallotropes of sulfur ,sphosphorous a
aslala i a i
aslala are allotropes of a a i
asla,laphosphorous aslaa
38.What a sa are a a a s
38.What
a s
sulfur
a a sa
.PTin
. ada,dsilicon , germanium.P.P
P adad adadTin , silicon , germanium
.P.P .P.Padad adad
.P.P
w w
ww 39.What are general w w
w w www w w w
ww electronic configuration w w
wwand
ww ww electronic configuration w w
and 39.What are general ww ww
highest oxidationt state of elements from group highest oxidation tet state of elementsNfrom
i . N . N t
egroup
e i . N . etet
N i . N . etheir
N i . . etet group
N
a sa asalaithe reaction
13-18 andlatheir name
a saaslaalai a sa aslaalai the reaction asaaslaalai
13-18 and group name
a saaslaa
d
40.Complete
a ad d
a ad d
a ad40.Complete d
a ad d
a ad
w .Pi).P
w w .P.P
w → w .P.P
w w .P.P
w → w w.P.P
w
www wwww wwww i) w
www w
www
→ →
i .N . ete→
N t
i .N . etet
N i .N . etet →
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa → l a
d a
d
l
saasa l a
d a
d saasal l a
→ d adsaasal l a
d a
d saaslaa
.P.P aa aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w →w ww
w w ww
w w www → w ww
w
ww ww ww ww ww
5×1=5
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet5×1=5
N
i i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaa
.P.P aa aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w w ww
w w ww
w w www w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
.P.P adad adad
.P.P adad
.P.P .P.Padad adad
.P.P
www w www w www w ww w w www w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asala a i l
asala a i aslaa
.P.P a ad a ad
.P.P a ad
.P.P .P.Pa ad a ad
.P.P
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d a
d
l
saasa l a
d a
d saasal l a
d adsaasal l a
d a
d saaslaa
.P.P aa aa
.P.P aa
.P.P .P.Paa aa
.P.P
w ww
w w ww
w w ww
w w www w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s aslaalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
d
aa ad a d
aa ad a Padasalai
d
aa a
d a aa d ad a d
aa a
d
w
ww w w
ww w ww ww www w ww w w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d adsaaslaala
CHEMISTRY SOLID d adsaaslaala FIRST
STATE d a
d
aslaala
saCHEMISTRY SOLIDd ad
laala
saasSTATE FIRST d a
d saaslaa
.P.Paa .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w w
HALF ww
w TEST wwww w ww
w
HALF TEST w ww
w
ww ww ww ww ww
tet MARKS : 60
tet tet MARKS tet : 60
. N e
N . N e
N . N e
N . N e
N
a saaslaaliai. a a aslaaliai.
TIME :1hrs30min
s a s aaslaaliai. TIME
a sa
iai.
aslaal:1hrs30min a saaslaa
.P.Padad .P.Padad adad
.P.P adad
.P.P adad
.P.P
w w
ww I. Choose the best ww w w
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wbestw
w answers 10×1=w10 www w
ww ww ww w
1. The cationeleaves tet its normal position etet in 1. The cation etet leaves its normal position
e tet in
i . N . N
i moves to somealainterstitial i
alai. N . N i . N . N
alai and moves tossome i . N . N
a saaslaalaand
the crystal
a sa s a
the
s aaslacrystal
a aaslaalai interstitial a saaslaa
d
a ad d d
a acrystal d
a adposition, the defect d d crystal is known
ainathe d
a ad
w .Pposition,
w .P the defect in.P
w w
the
.P is known .P.P
ww w .P.P
w w .P.P
w
w
www as a) Schottky defect w
www b) F center c) Frenkel wwww as a) Schottky w w
wwdefect b) F center c)wFrenkel w
ww
defect d) non-stoichiometric
etet defect etet defect d)enon-stoichiometric
tet defectetet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
2. Schottky
d adsaasal l a defect in a crystal
d adsaasal
is l a
observed
d a
d
2.
saasa l l a
Schottky defect in
d
a
a
l
crystal
dsaasa l a is observed
d a
d saaslaa
a a a) unequal number
.Pwhen .P.Pa aof anions and a a when a) unequal .number
.P.P a a of anions and .P.P aa
w ww
w
.P w ww
w wwww w wwP.P
w w ww
w
ww anions are missing wwfrom the lattice ww anions are missing ww from the latticeww
b) equal number
i . N . etet of anions and anions
N i . N . eteare
N t b) equal enumber
i . N . N
tet of anions and anions
i . N . etet are
N
i i i i
missing
d adsaaslaafrom
la the lattice
d adsaaslaala d a
d saaslaala from the lattice
missing
d adsaaslaala d a
d saaslaa
.Pc)
.Pa aan ion leaves its normal .P.Pa a site and a a c) an ion leaves its
.P.P aa
.P.normal
P site and ww aa
.P.P
w ww
w w ww
w wwww w ww
w w w
ww occupies an interstitial ww site ww occupies anwinterstitial w site ww
d) no ion isNmissing
i . . etet
N from its lattice.
i . N . etet
N d) no ion
i . N . N
tetmissing from its lattice.
eis i . N . etet
N
a i
aslala due to Frenkel
3. Assertion: a i
aslala density
defect, a
lala i
3.saasAssertion: due to Frenkel a a i
aslaldefect, density asaaslaa
a sa a sa a a sa
.Pof
. adathe
P d crystalline solid.Pdecreases.
. adad
P adadof the crystalline .solid
.P.P adaddecreases.
P.P adad
.P.P
www w ww w w wwww ww w w www w
ww Reason: in Frenkel ww defect cation and anion ww Reason: in Frenkel ww defect cation and ww anion
leaves the .crystal. e t t e t t leaves.N t t
e crystal. et t
a iaN i.Ne a ia.Ni.Ne a iathe
i.Ne a ia.Ni.Ne
a) dBoth
a saas la l
assertion and reason d a sa a
are
sla l true and d a a la l
a)sasBoth assertion anddreason a saas la l are true and dasaaslaa
.Pa ad is the correct explanation
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.P.P .P.P ad
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.P.P
w w w w w w w ww w w w
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b) Both assertioni .N . etet and reason are itrue
N .N . etebut
N t b) Both i .N . etet
assertion
N and reasoni.are N . ettrue
N et but
a i a i a i a i
reason
d ad
l l a
saasisa not the correct explanation
d adsaasal l a of d a
dreason l l a
saasa is not the correct d ad
asal l a
saexplanation of d a
d saaslaa
aa
.Passertion.
.P .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w wwww assertion. w ww
w w ww
w
ww c) Assertion is true ww but reason is false. ww c) Assertionwiswtrue but reason is false. ww
d) Both assertioni . N . etet and reason are ifalse
N . N . etet
N d) Both i . N . etet
assertion
N and reasoni.are N . etfalse
N et
a i a i a i a i
4. dThe
ad
l l a
saascrystal
a with a metal d adsaasal l
deficiency
a
d a
d
l
4.saasThe l a
a crystal with a metal
d ad
l l a
saasadeficiency d a
d saaslaa
aa
.Pdefect
.P .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w is w ww
w wwww defect is w ww
w w ww
w
ww ww ww ww ww
a) NaCl b) FeO c) ZnO d) KCl a) NaCl b) FeO c) ZnO d) KCl
5. The yellow i . N . etecolour
N t in NaCl crystal
i . N . eteist due
N 5. The i . N . etet colour in NaCli.N
yellow
N etet is due
crystal
. N
a
aslala i a i
aslaFlacenters a
lala
asa) i a i
aslalain F centers aslaa
adsaexcitation
toadaa) of electrons
adada sain a
adad
s
to a excitation of a s
electrons
adad a a
adad
sa
w .Pb)
w . P reflection of lightwfrom .P.P
w Cl- ion on the ww.P.P b) reflection of w .P.P
w
light from Cl- ion on w
the.P.P
w
ww
ww ww
ww ww ww wwww ww ww
surface c) refraction of light from Na+ ion surface c) refraction of light from Na+ ion
d) all oflathe i . N . etet
N
above i . N . etet
N d) all i .
ofN . N
tet
ethe above i . N . etet
N
l a i l al a i l a
al a i l a
al a i aslaa
6.ada adsaasa and diamondadaare
Graphite adsaasa d a
a ad
s
6. aasGraphite and diamondd
a ad a saasare
d a
a ad
sa
w .Pa)
w .P Covalent and molecular w .P.P crystals b) ionicww
w .P.P w .P.P
w w .P.P
w
w
www w
www wwww a) Covalent w
and
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b)
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and covalent crystals and covalent crystals
c) both lcovalenti .N . etet crystals d) both imolecular
N .N . etet
N c) both i .N . etet
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covalent crystals d)laboth i .N . etmolecular
N et
a i a i a i i
d ad
crystalssaasa l a
d adsaasal l a
d a
d saasa l
crystals
l a
d adsaasa l a
d a
d saaslaa
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.P.P aa
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w ww
w w ww
w wwww w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a aa d a
d a Padasalaid
aa a
d a aad a
d a d
aa a
d
ww
ww 7.Solid CO is an w w
wwexample of wwww w w w ww w w
2 7.Solid CO2 iswan example of
a) Covalent i . N . etet b) metallic solid
solid
N i . N . etet
N a) Covalent
i . N . etet solid b) metallici.solid
N N . etet
N
i i i i
a saaslaala solid d) ionicdadsolid
c)admolecular
d saaslaala d a
dc)
laala
saasmolecular solid d) d a saaslaasolid
ionic
d
la
d a
d saaslaa
.Pa number of carbon
.P8.The aa
.P.P .P.Paa P.P aa
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w ww
w w ww
w atoms per unit cell wwww 8.The numberwof ww
w atoms per unit w wcell
w w
ww ww ww ww ww
of diamond is of diamond is
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N a)8 b) i .6N . ete1t d) 4
N
c) i . N . etet
N
al odd one out asaaslala
asthe a i a i
aslala the odd one outasaaslala a i aslaa
a
9.Find sa a sa
9.Find a sa
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. adad
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.P.P .P.Padad .P . adad
P .P.Padad
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ww c)glucose wwww a) naphthalene www
b)w anthracene c)glucose www w
ww ww ww ww ww
d) SiO2 d) SiO2
10. In Hexagonali . N . etet unit cell
N i . N . etet
N 10. In i . N etet
N
Hexagonal
. unit cell i . N . etet
N
l
asal a a i l
asala a i l
asal a a i l
asala a i aslaa
d a s
a)a=b=ca b) a≠b=c c) d
a=b≠c a sad) a≠b≠c d a sa
a)a=b=c b) a≠b=c c)d a sa
a=b≠c d) a≠b≠c d a sa
.P.Pa ad a ad
.P.P .P.Pa ad .P.P a ad .P.Pa ad
w w w w w w w ww w w w w w w
www www www www www
II.Answer thet following questions t II.Answert the following questions
6×2=12lalia.N . e et
N i .N . e et
N i .N . e et
N i .N . etet
N
i a i 6×2=12 a i a i
1. d a
d saasa unit cell.
Define d a
d
l
saasa l a
d a
d1.
l l
saasDefine
a a
unit cell. d a
d
l
saasa l a
d a
d saaslaa
.P.Paa aa
.P.P .P.Paa .P.P aa .P.Paa
w ww
w 2. Give any three w ww
w
characteristics of ionic wwww 2. Give any w ww
w
three characteristics of w ww
w
ionic
ww ww ww ww ww
crystals. crystals.
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
3. What are i point defects? i 3. What i are point defects? i
a saaslaala a saaslaala a saaslaala a saaslaala a saaslaa
4.
.P.P
d
aaWhat
d is meant by the aa
.P.P term
d d “coordination .P.P
d
aa d4. What is meant by
.P.P the
aad d term “coordination .P.P
d
aa d
w ww
w number”? w ww
w wwww number”? w ww
w w ww
w
ww ww ww ww ww
5.Define anisotropy etet and isotropy etet 5.Define anisotropy
etet and isotropy etet
a i . Ni . N a i . N
i . N a i . N
i . N a i . N
i . N
6.The adiffraction
a sa s lala of crystal
a
of
sa
barium
aslala with
a
6.The
saaslala diffraction of crystal
a saaslalaof barium with
a saaslaa
adad of wavelength .2.29
.PX-ray
. P adaẴ
P.P d gives a first .PP
. adadX-ray of wavelength .P.P ada2.29
d Ẵ gives a first.PP
. adad
w w
ww order deflectionwatw w
w30 w
w .What is the ww
0 wwww w w
wwat 30 .What is theww
0 www w
ww order deflection ww
distance between etet the diffracted planes? etet distance ebetween tet the diffracted eplanes? tet
i . N a i . N
i . N a i . N
i . N
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
a ad d
a adquestions d
a adIII.Answer the following d
a ad questions .P.P d
a ad
w .PIII.Answer
w .P the following
w .P.P
w ww.P.P w .P.P
w w w
w
www 6×3=18 wwww w
www 6×3=18 wwww wwww
1.Write aboutetecharacteristicst of solids etet 1.Write about etet characteristicsi.of tet
esolids
i . N a i . N
i . N a N
i . N
2.Two
d a
d
l l
saastypes a
a of unit cell asaasa
d d
l l a
d a
d
2.Two l l a
saasa types of unit cell d a
d
l
saasa l a
d a
d saaslaa
aa
.P3.What are seven primitive a a crystal systems .P.P
.P.P a a 3.What are seven.P aa .P.Paa
w ww
w
.P w ww
w wwww w wwprimitive
w
.P crystal systems
w ww
w
ww 4. Barium has a w w centered cubic unit
body ww 4. Barium has wwa body centered cubic wwunit
cell with a N
i . . etet of 508pm alongi.Nan
length
N . eteedge.
N t cell with
i . N . eatelength
N t of 508pm along
i . N . etetan edge.
N
aslaathe i i
laalaKg m i
aslaalais the density of abarium i
aslaala in Kg m-3
la density of barium saaslaa
-3
What a sais a saasin aWhat
sa sa a
d
aa d aa d d d d
a a 5.Write about impurity d d
a a defect d
aa d
ww.P5.Write
.P about impurity ww .P.defect
P ww.P.P ww.P.P ww.P.P
w w
ww 6.Write about non w w
wwstoichiometric defects wwww 6.Write about
w w
wwnon stoichiometric defects ww w w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
IV.Answer a i
aslala the following aquestions a
aslala i a
aslala
IV.Answer
i the following a la i
aslaquestions aslaa
a sa sa a sa a sa a sa
.P.Padad adad
.P.P 4×5= 20ww .P.Padad .P.P adad 4×5= .P20
. adad
P
www w www w ww www w wwww
ww 1.Sketch i.SC ii.BCC ww iii.FCC & its number ww 1.Sketch i.SC ww ii.BCC iii.FCC & itswnumber w
of atoms per N tet cell
eunit N etet of atoms N tet unit cell
eper N etet
2.Write
a sa
l l
asaabouta i.ionic solids a s l
asal a
ii.covalent
a a s l
2.Write
a
a
asal about i.ionic solids a sa
l l a
asaii.covalent a saaslaa
d
a ad iii,mettalic solids d
a ad d
a adsolids iii,mettalic.P d
a ad d
a ad
w .Psolids
w .P w .P.P
w ww.P.P w w .P
solids ww.P.P
w
www 3.Explain Schottky w
wwwand Frenkel defect w w
ww w
www and Frenkel defect w
wwwwith
with 3.Explain Schottky
neat diagram i .N . etet
N i .N . etet
N neat diagram
i .N . etet
N i .N . etet
N
a i a i a i i
4.Explain
d a
d
l l a
saasa molecular solids d a
d sand
a
l l a
asa its types
d a
d saasal
4.Explainl a moleculardsolids a
d
l a
saasaand its types dadsaaslaa
l a
.P.Paa aa
.P.P .P.P aa .P.P aa .P.Paa
w ww
w w ww
w wwww w ww
w wwww
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s aslaalia. i.N s as laalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
d
aa a
d a d
aa a
d a Padasalai d
aa a
d a aad a
d a d
aa ad
w
ww w www w w
ww w ww w w ww w w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d adsaaslaa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i a
aslala ; 70i a
aslala i a
aslala i aslaa
a sa a sa a s a a sa ; 70 a sa
.P.P adad .P.P adad .P.P adad .P.P adad .P.P adad
www w ww w w www w ww w w www w
ww ww ww ww ww
I .Choose the best answers 10×1=10 I .Choose the best answers 10×1=10
1.Roasting i . N
of. etsulphide
N et ore gives i . N
the . N
tet
egas 1.Roasting i . N . eteof
N t sulphide ore gives
i . N . etthe
N et gas
l a a i
asaisl a colourless gas.aAqueous l
asal a a i l a a i
asal is a colourlessagas. l al a
asaAqueousi aslaa
a
(A).(A)
d sa d sa d a s a
(A).(A) d sa d a sa
.Pa ad
.Psolution .P.P a ad .P.P a ad P.Pa ad
.acidic. .P.P a ad
w w w of (A) is w w w
acidic. The gas (A) is w w w solution of (A)w w
isw The gas (A) w w
is w
www www www www www
a)CO2 b)SO
tet 3 c)SO 2 d)H 2S
tet a)CO 2
tet b)SO 3 c)SO 2
tet 2S
d)H
N e N e N e N e
2. Which
s as a. i.N
laaliof the metal is extracted
s as
.N Hall-
laalia. iby s as laalia. i.Nof the metal issextracted
2. Which
aslaalia. i.N by Hall- saslaa
a
adada process?
Heroult a
adada a a
adadHeroult process? Padada a adaada
. P.
wwa) AlP .P .
ww c) CuP ww. P. P w . .P ww. P. P
ww
ww b) Ni
wwww d) Znww ww a) Al wb)ww
w Niw c) Cu d)wwww
Zn
3. Wolframitetore is separated from t t 3. Wolframite tet ore is separatedNfrom
i . N . e
N e t
i . N . e
N e i . N . e
N i . . etet
N
tinstone by ithe process of i tinstone i by the process of i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d adsaaslaa
a)
.P.P aa Smelting b) Calcination
.P.P aa .P.P aa a) Smelting b) Calcination
.P.P aa .P.P aa
w ww
w c) Roasting d) w ww
w
Electromagnetic separation w ww
w c) Roasting d)w ww
w
Electromagnetic w ww
w
separation
ww ww ww ww ww
4. Flux is a substance e tet which is used eto
tet 4. Flux ise a
tetsubstance which is used
e tet to
. N N . N N . N N . N N
convert
a saaslaaliai. a saaslaaliai. a aaslaaliai.
convert
s a saaslaaliai. a saaslaa
.Pa)
. adaMineral
P d into silicate .P.b)adaInfusible
P d .P.P adada) Mineral into silicate .P.P adadb) Infusible .P.P adad
w w
ww impurities to soluble w w
wwimpurities www w ww w w www w
ww ww ww impurities toww soluble impurities ww
c) Soluble impurities etet to infusible etet c) Soluble eteimpurities
t to infusible etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
impurities
a sa
l
asal a d) All of these
a sa
l
asal a
a s a
l
asal
impurities a d) All of these
a sa
l
asal a
a saaslaa
d d
a aWhich d
a ad ores is best .P.P d
a ad5. Which one of the d
ad
afollowing d
a ad
w .P5.
w .P one of the following
w w.P.P w w w .P.P
w
ores is best
w .P.P
w
w
www concentrated bywfroth w
ww – floatation method? w
www concentratedww w
bywfroth – floatation method? wwww
a) Magnetiteeb)
N tetHematite N etet a) Magnetite
N etet b) Hematite i.N.N etet
a i . i . N a i . i . N a i . i . N a i
c) Galena
d a
d
l
saasa l ad) Cassiterite
d a
d saasal l a
d a
d
c)
saasa l l
Galenaa d) Cassiterite
d a
d
l
saasa l a
d adsaaslaa
.P6.
.Pa aZinc is obtained from .P.P aZnO
a by .P.P a a 6. Zinc is obtained a a ZnO by
.P.from
P .P.P aa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww a) Carbon reduction ww b) Reduction usingww a) Carbon reduction ww b) Reduction using ww
i . N . etet
silver c) Electrochemical
N process N
i . . N
tet
d)eAcid silver c)
i . N . N
tet
eElectrochemical process
i . N . eted)
N t Acid
a i a i a i a i
leaching
d a
d
l
saasa l a
d a
d saasal l a
d a
d saasa l
leaching l a
d a
d
l
saasa l a
d adsaaslaa
.P7.
.Pa aExtraction of gold and .P.P a asilver involves .P.P a a 7. Extraction of gold .P.P a aand silver involves.P.P aa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww leaching with cyanide ww ion. silver is laterww leaching with wwcyanide ion. silver iswlater w
recovered .by
i N . etet
N i . N . etet
N recovered
i . N . eteby
N t
i . N . etet
N
a i
aslala b) Zone refining
a) Distillation a
aslala i a
lala i
a)saasDistillation b) Zonearefining a
aslala i aslaa
a sa a sa a sa a sa
.Pc)
. adaDisplacement
P d
with .P . adadd) liquation
P
zinc .P.P adadc) Displacement with .P.P adazinc
d
d) liquationww .P.P adad
www w ww w w www w ww w w ww
ww 8.In the electrolytic ww refining of copper,ww 8.In the electrolytic ww refining of copper, ww
which onei.N of tet following is usedNas
ethe etet whichi.N one eteoft the following is.Nused etet as
a i . N a i . i . N a i . N a i i . N
cathode?
a sa
l
asal a
a sa
l
asal a
a s l
asal
cathode?
a
a
a sa
l
asal a
a saaslaa
d d
a aPure d d
a acopper d
a ada) Pure copper b).P d
a ad copper d
a ad
w .Pa)
w .P copper b) w w.P.P
Impure w .P.P
w w w .P
Impure w .P.P
w
w
www c) Carbon rod d)wPlatinum w
ww w w w w wwww
electrode ww c) Carbon rod wwd) Platinum electrode
9.Chlorargyrite i .N . etetis otherwise called
N i .N . etet
as
N 9.Chlorargyrite
i .N . etet is otherwise icalled
N .N . etet as
N
a i a i a i a i
a) dRuby
a
d
l l a
saasasilver b) Hematite d a
d saasal l a
d a
d
l
a)saasRubyl a
a silver b) Hematite
d a
d
l
saasa l a
d adsaaslaa
.Pc)
.Paa .P.P aa .P.P aa P.P aa
.Tinstone .P.P aa
w ww
w Horn silver d) Tinstone w ww
w w ww
w c) Horn silverwd) ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s aslaalia. i.N s as laalia. i.N s aslaalia. i.N saaslaa
aad a
d a aa d ad a Padasalai
d
aa a
d a aad a
d a d
aa a
d
ww.P.P ww .P.P ww.P.P ww.P.P ww .P.P
ww
ww 10.Van-Arkel iswused w w
w for refining ww w w w w w w w w
10.Van-Arkelwis used for refining w
a) Al b)
N tet c) Cu
eNi d) N Zretet a) Al i.N eteb)
t Ni c) Cu .NN tetZr
ed)
i . i . N i. i . N i . N i i .
d a
d saaslaala d ad saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
aa
.PII.
.P aa
wwww Answer the following w ww
w 7×2=14 w ww
w II. Answer the w wfollowing
w w w ww
7×2=14
w
ww 1.Difference between wwmetal and ore ww 1.Difference between
ww metal and ore ww
2.Give two examples
i . N . etet for ores of iron i.N.N
N etet 2.Give .two
i N . etexamples
N et for ores of iron
i . N . etet
N
3.What a i
a meant by cementation
asdolalyou a
aslala i a i
aslalado you meant by cementation
3.What a
aslala i aslaa
. adad about method to .concentrate
.P4.Write
P adad gold and
P.P .P.Padad4.Write about method .P.toadaconcentrate
P d gold and .P.P adad
ww
ww oxide ores www w ww w w www w www w
ww ww ww oxide ores ww ww
5.Write down steps for extraction of crude tmetal 5.Write down steps for extraction of crude metal
i . N . etetore
N i .N . e et
N i . N . etet
N i . N . etet
N
s alai
from concentrated
aslaroasting s aslaalai s aslaalai roasting and calcination
from concentrated ore
s aslaalai s aslaa
d
a ada
6.Define a and calcination
d
a ad a a d a
a ad a
6.Define d
a ad a a d a
a ad a
ww.P7.
.P What is the role ofwLimestone w w.P.P in the w .P.P
w 7. What is the role w .PLimestone
w
of .P in the w w.P.P
w
www extraction of Iron w wwits oxide Fe2O3? wwww w
wwfrom its oxide Fe2O3?www w
from extraction of w Iron
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
III.aAnswer
d d
l l a
saasa the following d ad
l l a
saasa7×3=21 d a
d
III. l l a
saasaAnswer the following d a
d
l
saasa l a 7×3=21
d a
d saaslaa
a a about steps involved
.P1.Write
.P a in
.P.P a electrolytic .P.Pa a 1.Write about steps .involved P.Pa a in electrolytic .P.P aa
w ww
w w w
w w w w
w w w w
w w w w
w w
ww refining of crude metal ww ww refining of crude wwmetal ww
2.How do you concentrate tet ferromagnetic ores
tet and 2.How do you
tet concentrate ferromagnetic tet ores and
N e
N N e
N N e
N N e
N
write down
s laalia.itsi. principle .
awill
s s
.
aslaaliai.
writeladown
s
. i. its principle .
asaliawill s
.
aslaaliai. saaslaa
aad
3.How a
d a you concentrate aa d
ZnSad a d
aa a
d a
3.How you concentrate
aad a
d aZnS d
aa a
d
ww.P4.List
.P down ores of zinc ww,.P.P
tin , silver ww.P.P 4.List down oreswof ww P.P
.zinc , tin , silver ww .P.P
w w
ww 5.Write about aluminothermic ww w w ww w w w w w
process 5.Write aboutw w
aluminothermic process ww
6. Explain roasting
i . N . etet and calcination with
N i . N . etet
example
N 6. Explain
i . N . N
tet
eroasting and calcinationNwith
i . . etetexample
N
7. Predict a
aslalthe i
a conditions under which a
aslala i a i
lala the conditions under
7.sasPredict a la
aslawhich i aslaa
a sa a sa a a a sa a sa
. adaAluminium
.P(i)
P d adad to reduce
might be expected
.P.P .P.Padad(i) Aluminium might.Pbe . adexpected
P ad to reduce .P.P adad
w w
ww magnesia. (ii) Magnesium w w
ww could reduce alumina. ww w w www w www w
ww ww ww magnesia. (ii)w Magnesium
w could reduce alumina. ww
(B) Carbon monoxide is more effective reducing (B) Carbon monoxide is more effective reducing
agent thanacarbon i . N . etetbelow 983K but, above
N i . N . N
tet
ethis agentathani . N . N
tet below 983K but,Nabove
ecarbon i . . etet this
N
l a i
asal the reverse is truea–Explain. l a a i
asal (c) it is l
asal a i l a l a i
asa–Explain. aslaa
a sa
temperature,
d d sa d a sa
temperature, the reverse disa sa
true (c) it is d a sa
a ad to reduce Fe2O3 .by
.Ppossible
.P P.P ad at a temperature .P.P
acoke a adpossible to reduce Fe.P 2.O
a3aby
P d .P.Pa ad
w w w w w w w w w w w w coke at a temperature
w w w
www around 1200K www www around 1200Kww
w www
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a i a i a i a i
III.Answer
d a
d
l l a
saasa the followingdadsaas7×5=35 la l a
d a
d saasal l
III.Answer a the following
d a
d
l l a
saasa 7×5=35 d a
d saaslaa
aa
.P1.Explain
.P about reduction.Pof ametal
.P a oxide with its .P.P a a 1.Explain about reduction .P.P a a of metal oxide with .its P.Paa
w ww
w w w
w w w w
w w w w
w w w w
w w
ww different types ww ww different typesww ww
2.Explain about refining based on vapour phase 2.Explain about refining based on vapour phase
method laia.N . etet
N i . N . etet
N method i . N . etet
N i . N . etet
N
i i
aslaala on the i i
a
3.Explain
d d
l
saasaabout method which d aissabased
d d a
d saaslaala about method dwhich
3.Explain a
d
ala
saaslais based on the d a
d saaslaa
aa
.Psolubility
.P aa
.P.P .P.Pa a solubility of ore in suitable .P.P a a solvent .P.Paa
w ww
w of ore in suitablew ww
w solvent w ww
w w ww
w w ww
w
ww 4.What are the applications ww of Al , Zn ww 4.What are thewapplications
w of Al , Zn ww
5. What are theeapplications
N tet of Fe , Cu , Au
N etet 5. What are
N etethe
t applications of Fe.,NCu ete, tAu
a i . i . N a i . i . N a i . i . N i i . N
a aaslalathe role of the following
6. Describe
s a saaslainlathe process a
6.sa
a s lala the role of the following
Describe
a sa
a
aslala in the process asaaslaa
. adad
.Pmentioned.
P (i) Silica in the adad
.P.extraction
P of copper. .PP
. adadmentioned. (i) Silica.P inP
.
dadextraction of copper.Padad
athe . .P
w w
ww (ii) Cryolite in the w w w
w w
extraction of aluminium. w
(iii) w
w w (ii) Cryolite in w
thew
w w
extraction of aluminium. w ww
w
(iii)
ww w w w w w ww
Iodine in the refining of Zirconium. (iv) Sodium Iodine in the refining of Zirconium. (iv) Sodium
cyanide in froth i . N . etfloatation.
N et i . N . etet
N cyanide i . N
in. N
tet floatation.
efroth i . N . etet
N
l a l a i l a a i l a a i l a a i aslaa
d s
7.Explain
a aasaabout zone refiningdasaasal d a saasal about zone refining
7.Explain d a saasal
d a sa
.P.Pa ad a ad
.P.P .P.Pa ad .P.P a ad .P.Pa ad
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d saasal l a
d ad
l
saasa l a
d a
d saasal l a
d a
d
l
saasa l a
d a
d saaslaa
.P.Paa aa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s aslaalia. i.N s aslaalia. i.N s aslaalia. i.N saaslaa
aad ad a aad ad a Padasalai
d
aa ad a aad a
d a d
aa a
d
w
ww w www w ww w w w
ww w ww w w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d adsaaslaala d ad saaslaala d adsaaslaala d a
d saaslaala d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w www w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
lala
as90 i a
aslala i a
aslala90 i a
aslala i aslaa
Marks: a sa a sa a s
Marks:
a a sa a sa
adad
P.P
.Time: adad
.P.P adad
.P.P adad
.P.P adad
.P.P
www w 1 hr 30 min www w www w Time: 1 hr 30 w
min
ww w www w
ww ww ww ww ww
i.Answer athe i . N . etet
following
N questions i . N . etet
15×2=30
N i.Answer i . N . N
tet following questions
ethe i . N . etet15×2=30
N
l l a
asaashort i l a a i
asal properties l a a i
asal a short note on aanamolous l
asala a i aslaa
a
1. aWrite
d sa note on a s
anamolous
d a d a
1. sa
Write d sa properties d a sa
.of ad
P.Pthe a ad
.P.P a ad
.P.P .P a ad
.P a ad
.P.P
w w w first element of
w w w
p-block. w w w of the first element
w w wof p-block. w w w
www www www www www
2.Describe briefly allotropism in p- block 2.Describe briefly allotropism in p- block
tet
especific etet etet specific reference e tt
elements lwith a i .Ni . N referencelatoia.N i . N
carbon. elements a i .Ni . N
with a i .Ni . toecarbon.
N
3.Boron
d adsaasdoesl a
a not react directly
d ad
l
saaswith
a hydrogen. 3.Boron
d ad
l l a
saasa does not reactddirectly a
d
l l a
saasa with hydrogen. d a
d saaslaa
aa
P.P
.Suggest aa
P.P
.prepare aa
.P.P aa
.P.to
P aa
.P.P
w ww
w one method w ww
to
w diborane from
w ww
w Suggest one ww
method
w w prepare diborane w wfrom
w w
ww ww ww ww ww
BF3. BF 3.
4. Give the i . N
uses. eteof
N t
Borax. i . N . etet
N 4. Give i . N
the. eteuses
N t
of Borax. i . N . etet
N
alaala i i i i
daadsasa note on Fisher
5.PaWrite d ad saaslaasynthesis.
tropsch
la
d a
5.d a aslaala
sWrite a note on d
Fisher a
d
aslaala
satropsch synthesis. d a
d saaslaa
. .P aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w 6. Give the structure w w
w
ofw CO and CO . w ww
w 6. Give the w www
structure of CO and CO . w ww
w
ww ww 2 ww ww 2ww
7. Write a shorttnote on hydroboration 7. Write a short note on hydroboration
ila.N .Ne et i . N . etet
N i . N . etet
N i . N . etet
N
8. Writeaalanote
a i on metallic nature a
aslala of i p-block 8. Write a
aslala ia note on metallic i
aslala of p-block asaaslaa
nature
a
a sa s a sa a sa a sa
adad
.elements
P.P adad
.P.P adaelements
.P.P d adad
.P.P adad
.P.P
w w
ww 9. How will you identify w w
ww borate radical ww www w 9. How will you ww w w
identify borate radical www w
ww ww ww ww
10. How will you
i . N . etet convert boric acid
N i . N .
tot boron
e et
N
10. How will
i . N . etet you convert boric
N i . N
acid
. etet to boron
N
nitride? alaalai aslaalai aslaalai
nitride? aslaalai aslaa
d a sa s d a sa d a sa d a sa d a sa
.11.aCO
P.P ad is a reducing agent a a. djustify with an .P.P
.P.P d CO is a reducing
a a11. ad . justify with an
aagent
.P.P a ad
.P.P
www example www www example www www
12.What is inert etepair
t effect etet 12.What isetinert et pair effect i.N etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
13.What
d adsaasal
arel a the necessary
d ad
l
condition
saasa l a for
d
13.What
adsaasal l a are the necessary
d a
d saasa l l a
condition for
d a
d saaslaa
aa
.catenation
P.P aa
.P.P a acatenation
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w www w ww
w
ww 14.Give Uses of silicones ww ww 14.Give Useswof w silicones ww
15.Write abouteteasbestos t etet 15.Write about etet asbestos etet
i . N
i . N i . N
i . N i . N
i . N i . N
i . N
d adsaaslaala d ad saaslaala d adsaaslaala d a
d saaslaala d a
d saaslaa
aa
P.P
.ii.Answer the following aquestions
.P.P a 5×3=15w.P.P a aii.Answer the following a a questions 5×3=15
.P.P aa
.P.P
w ww
w w ww
w w w w w www w ww
w
ww 16.Write about zeolites ww ww 16.Write about wwzeolites ww
17.Explain about
i . N . etetfullerene and carbon
N i . N . etet
N
17.Explain
i . N . etabout
N et fullerene and N
i . . etet
carbon
N
nanotube a
aslala i a
aslala i a
aslala
nanotube i a
aslala i aslaa
adad
P.P
.18.Explain about ionisation adad
.P.P enthalpy and ww ada18.Explain
.P.P d adad enthalpy and.P.P
.P.P
aboutwionisation adad
w w
ww electronegativity w w w w w w
wwof P block elementsww www w
ww ofwPwblock elements www electronegativity ww
19.Give some N tet
eexamples of allotropes N tet given 19.Give N
efor someetet examples of allotropes N etet for given
p blocka sa s lal a
aelements – Boron , Carbon
a sa
l a
asal , Tin pablock
sa
l a
asal elements – Boron a sa
lal a
,asCarbon , Tin a saaslaa
dad
adouble
P.P d
a ad fourth period .P.P d d double salt which
a a20. d
ad
acontains d
a ad
w .20.
w salt whichwcontainsw.P.P w w w .P.P
w fourth period w .P.P
w
w
www alkali metal (A) on w w
wwheating w w w w w
ww (B).
at 500K givesww (B). alkali metal (A) wwon heating at 500K w gives
aqueous solution i .N . etetof (B) gives white
N i .N . etet
precipitate
N aqueous i .N . etet of (B) gives iwhite
solution
N .N . etetprecipitate
N
a i a i a i a i
withdBaCl
ad
l l a
saasa2 and gives a reddadsaasa l l a
d ad
l l
saasBaCl2
with a a and gives adared
dsaasa l l a
d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w www w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
aad ad a aad a
d a Padasalai
d
aa ad a aad a
d a d
aa a
d
ww
ww colour compoundwwith w w
w alizarin. Identify w w w w w
ww with alizarin. Identify w
ww A w
Aw colour compound
and B. i . N . etet
N i . N . etet
N and B. i.N . etet
N i . N . etet
N
i i i i
d adsaaslaala d a
d saaslaala d a
d saaslaa
aa
P.P
.iii.Answer .P.Paa aa
.P.P .P.P aa aa
.P.P
w ww
w the following w ww
w questions 9×5=45 w ww
w iii.Answer the w ww
following
w questions 9×5=45 w ww
w
ww ww ww ww ww
21.Explain about structure of diborane 21.Explain about structure of diborane
N tet of silicates Netet
etypes N etthe
et types of silicates N etet
22.Explain a ithe
. i . N a i . i . N 22.Explain a i . i . N a i . i . N
23.What a sa ala differences between
aslare a sa
la
asladiamond a sa aslala are differencesabetween
23.What saaslala diamond a saaslaa
adad
P.P
.and .P.Padad adad
.P.P .P.P adad adad
.P.P
www w graphite ww w w ww w w and graphite ww w w www w
ww ww ww ww ww
24.Write about Physical properties of group 24.Write about Physical properties of group
14 elements i . N . etet
N i . N . etet
N 14 elements
i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asal a a i l
asala a i aslaa
25.ad a
Writesa about Physical d a sa
properties of group d a
25.sa Write about Physical d a sa
properties of group d a sa
w w P.Pad
.13 w .P.P
w
a ad
w w
a ad
.P.P w .P.P
w
a ad
w w
a ad
.P.P
w
www elements w
www w
www 13 elements wwww wwww
26.Write about tuses i)boron ii)Boric acid tet ii) 26.Write about
tet uses i)boron ii)Boric tet acid ii)
N e e t N e N e N e
diborane lalia. i.N laalia. i.N diborane laalia. i.N laalia. i.N
d
27.Writeadsa as a
about uses of d
i)AlCl a
d saas
ii)Alum d adsa as
27.Write about uses of d a
d saa
i)AlCls ii)Alum d a
d saaslaa
.P.Paa .P.Paa 3 aa
.P.P .P.P aa 3 aa
.P.P
w ww
w iii)CO w ww
w w ww
w iii)CO w ww
w w ww
w
ww ww ww ww ww
28.Give uses ofti)CO ii) silicon 28.Give uses of i)CO ii) silicon
i . N . e et 2
N i . N . etet
N i . N . etet
N
2
i . N . etet
N
tetrachlorideaslaala i iii)allotropes of oxygen
aslaala i , tetrachloride
aslaala i iii)allotropes of i
oxygen
aslaala ,
d adsa d a
d sa d adsa d a
d sa d a
d saaslaa
antimony
.P.Paa , silicon .P.Paa aa
.P.P antimony , silicon .P.P aa aa
.P.P
w ww
w 29. Complete the w ww
w
following reactions w ww
w 29. Complete w
the wfollowing
w w reactions w ww
w
ww ww ww ww ww
i) B (OH)3 +NH ete3 t → etet i) B (OH) +NH
3 t t
ee 3 → etet
ii)Na2Bs4a0la7alia+ .Ni.H N a i . N
i . N a i . N
i . N a i . N
i . N
a a s 2 SO 4 + H 2 O
a s→
aaslala ii)Na
a sa asl2ala4 7
B 0 + H 2 SO 4 + H
a
2 alala
sO
a s
→
a saaslaa
ada2dH6 + 2NaOH + 2H.P2.O
.iii)B
P.P ada→d
P adaiii)B
.P.P d 2H6 + 2NaOH .+P2H
. ada2dO →
P adad
.P.P
w w
ww iv) B2H6 + CH3OH w→ w
w w ww w w w w w
w → www w
ww ww ww iv) B2H6 + CHw3w OH ww
v) BF3 +9H2O e→tet etet v) BF3 +9H et2eOt → etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
vi)HCOOHa sa
l a
asal + H2SO4 → asaasal l a vi)HCOOH
a sa
l
asal a + H2SO4 →asasal
a
l a
a saaslaa
d d 4 + NH3 → .PP
a aSiCl d d d d SiCl4 + NH3 →.PP d d d
a ad
w w w P.P
.vii)
w w w .a a w w w
a avii)
.P.P
w w w .a a w w .P.P
w
www viii) SiCl4 + C2H3wOH→ ww www viii) SiCl4 + C w2wHw3OH→ www
ix) B + NaOH e→tet etet ix) B + .NaOH etet → etet
a i .Ni . N a i .Ni . N a i N
i . N a i .Ni . N
Bsa4O
x) aHda2ad
l
asa
7 →
la𝑅𝐸𝐷 𝐻𝑂𝑇
d a
d
l
saasa l a
d a
x)d
l l a
saHas2aB4O7 → 𝑅𝐸𝐷 𝐻𝑂𝑇
d a
d
l
saasa l a
d a
d saaslaa
.P.P .P.Paa aa
.P.P .P.P aa aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d adsaaslaala d a
d saaslaala d a
d saaslaa
.P.Paa .P.Paa aa
.P.P .P.P aa aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
.P.Padad .P.Padad adad
.P.P .P.P adad adad
.P.P
www w ww w w ww w w ww w w www w
ww ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asal a a i l
asala a i aslaa
.P.Pa ad .P.Pa ad a ad
.P.P .P.P a ad a ad
.P.P
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d adsaasal l a
d a
d
l
saasa l a
d adsaasa l l a
d a
d
l
saasa l a
d a
d saaslaa
.P.Paa .P.Paa aa
.P.P .P.P aa aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s as laalia. i.N s aslaalia. i.N s aslaalia. i.N s as laalia. i.N saaslaa
aad a
d a aad a
d a Padasalai
d
aa a
d a aad a
d a aad a
d
ww.P.P ww.P.P ww .P.P ww.P.P ww.P.P
w
ww w www w www w wwww wwww
i . N . etet
N i. N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
.P.Paa .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w w www w ww
w wwww wwww
ww 12 P block (Bookwback
th w ,Types of silicate ,wStructure w ww
of Diborane , Introduction to P block elements ww )
Marks: 90
ila.N etet N etet N etet N etet
Time: a 1la a
hr i.Nmin
30 a
aslala i . i . N a
aslalai . i . N a
aslala i . i . N
aslaa
a sa s a sa a sa a sa a sa
. adad
.Pi.Answer
P .P.Padad adad
.P.P adad
.P.P adad
.P.P
www w the followingww w w
questions www w wwww wwww
15×2=30
ww ww ww ww ww
1. Write a short note on anamolous properties of the first element of p-block.
2.Describe ibriefly . N . etetallotropism in p- block
N i . N . N
tet
eelements . N
with specificireference. etet to carbon.
N i . N . etet
N
l a a i
al not react directlyawith
asdoes l a l a i
asahydrogen. l a a i
asal to prepare diborane l a a
al BF3.
asfrom i aslaa
3.Boron
d a sa d sa Suggest one
d a samethod
d a sa d a sa
.P4.
.P ad the uses of Borax..P.P
aGive a ad a ad
.P.P a ad
.P.P a ad
.P.P
w w w w w w w w w w ww w ww
www 5. Write a note on w ww tropsch synthesis. www
Fisher www www
6. Give the structure
i . N . etet of CO and CO2. i.N.N
N etet i .N . etet
N i .N . etet
N
7. Write alashort i a i a i a i
saaslaa
l a note on hydroboration l l a l l a l l a
d a
d
8.aWrite saasaanote on metallic nature d a
d saaof
sap-block elements dadsaasa d a
d saasa d a
d
.P9. a
.PHow P.Paa
.borate aa
.P.P aa
.P.P aa
.P.P
w ww
w will you identify w www radical w ww
w wwww wwww
ww 10. How will you convert ww boric acid to boronwnitride? w ww ww
11. CO is a .reducing
i N . etet agent . justify with
N i . N an
. eteexample
N t
i . N . etet
N i . N . etet
N
ala i i i i
12.What
d a
d saasla is inert pair effect
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
.Paa
.P13.What are the necessary aa
.P.condition
P for catenation .P.P aa aa
.P.P aa
.P.P
w ww
w w ww w w w
w w wwww wwww
ww 14.Give Uses of silicones ww ww ww ww
15.Write about asbestos
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
a
aslalthe a i a
aslala i a
aslala i a
aslala i aslaa
a
ii.Answersa following a
questions sa a sa a sa 5×3=15 a sa
. adad
.P16.Write
P .P.Padad adad
.P.P adad
.P.P adad
.P.P
www w about zeolites
ww w w www w wwww wwww
ww 17.Explain about fullerene ww and carbon nanotube ww ww ww
18.Explain about
i . N . eteionisation
N t enthalpy and
i . N . N
tet
eelectronegativity of P block
i . N . eteelements
N t
i . N . etet
N
19.Give l a a i
al examples of allotropes
assome l a a i
asalfor given p block elements l a a i
asal – Boron , Carbon , aTin l
asal a a i aslaa
d a
d sa d a
d sa d a sa
d on heating at 500K d sa d a sa
.Pa adouble
.P20. salt which contains .P.Pa afourth period alkali metal a a(A)
.P.P a ad (B). aqueous solution
.P.gives
P a ad
.P.P
www of (B) gives white w ww
precipitate with BaCl2 andw ww a red colour compound
gives w alizarin. Identify Awand
wwwith wwB.
tet
efollowing etet etet ete9×5=45
t
iii.Answer a i .N
thei . N questions ai.N i . N a i .Ni . N a i .Ni . N
a
21.Explain
d d
l l a
saasa about structure ofddiborane a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
d a
d saaslaa
.Paa
.P22.Explain .P.P
the types ofwsilicates
aa aa
.P.P aa
.P.P aa
.P.P
w ww
w w w w w ww
w wwww wwww
ww 23.What are differences ww between diamond andww graphite ww ww
24.Write aboutePhysical
N tet properties of group
N ete14
t elements N etet N etet
i . i . N i . i . N i . i . N i . i . N
25. Write
d a
d saaslaaabout
la Physical properties
d a
d
alagroup 13 elements salaala
saaslaof d a
d a s d a
d saaslaala d a
d saaslaa
aa
26.Write
.P27.Write
.P about uses i)boron
.P.Paa
ii)Boric acid ii) diborane aa
.P.P aa
.P.P aa
.P.P
w ww
w about uses w
ofww w
i)AlCl ii)Alum iii)CO w ww
w wwww wwww
ww ww 3 ww ww ww
28.Give uses of i)CO2 ii) silicon tetrachloride iii)allotropes of oxygen , antimony , silicon
29. Complete i . N . etefollowing
N
the t reactions i.N . etet
N i . N . etet
N i . N . etet
N
a i
a 3 →
asla3 l+NH a
aslala i a
aslala i a
aslala i aslaa
i) Bda s
(OH)
a a sa a sa a sa a sa
. a ad2B407 + H2SO4 + H2.O
.Pii)Na
P P.Pada→d adad
.P.P adad
.P.P adad
.P.P
w w
ww iii)B2H6 + 2NaOH w w w w
w2O → www w wwww wwww
ww +w 2H ww ww ww
iv) B2H6 + CH3eOH
N tet → N etet N etet N etet
v) BF3 +9H
a sa
l
asal a
2 O →
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
a ad + H2SO4 → Pa ad d d
a ad d
a ad d
a ad
w .Pvi)HCOOH
w .P w . .P
w w .P.P
w ww.P.P ww.P.P
w
www vii) SiCl 4 + NH 3 → w
www w
www w
www w
www
viii) SiCl4 + C2H3OH→
ix) B + NaOH i N
.𝑅𝐸𝐷 . e→tet
N i . N . etet
N i . N . etet
N i . N . etet
N
a i a i a i a i
x)adH a
d B
l l a
sa4asOa7 → 𝐻𝑂𝑇 d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasal l a
dadsaaslaa
.P.Pa 2
.P.Paa aa
.P.P aa
.P.P .P.Paa
w ww
w w www w ww
w wwww www
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s aslaalia. i.N s aslaalia. i.N s aslaalia. i.N s a slaalia. i.N saaslaa
d
aa a
d a aad a
d a Padasalai
d
aa ad a d
aa ad a aad a
d
w
ww w ww w w www w w
ww w www w
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaala d a
d saaslaala d adsaaslaala d adsaaslaala d a
d saaslaa
.P.Paa .P.Paa .P.Paa .P.Paa .P.Paa
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w w w
w w w w
w w w w
w w w w
w w
ww Name : ww ww ww Marks :90 ww
Subject : Chemistry etet etet etet Time:1hr 30min etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
i.Choose
a sa
a best answers saslala
aslalthe a a a saaslala a sa aslala 20×1=20 a saaslaa
.P1.
. ada.----------------block
P d
. adad
.Pelements
P which show.only P.Padadpositive oxidation.Pstate . adad
P .P.Padad
w w
ww a) s www w www w ww w w w
wf w w
ww ww b) p ww c) d ww ww
d)
2. Halo acidsehave
N tet no reaction with N etet N etet N etet
a) B sasal
a a
l a b)sCasal
a a
l a
a sa
c)l
asaZn l a
a sa
l
asal a d) Al
a saaslaa
d
a aIndthe manufacture.of d
ad glass,..is used.
aPyrex d
a ad d
a ad d
a ad
w .P3.
w .P w wP.P w .P.P
w w .P.P
w w .P.P
w
w
www a) boric acid www w b) boric oxidewww w c) sodium w w
ww
borate d) boric anhydride w
www
eteacid
t reacted with ethyl etealcohol
t eteconc.Sulphuric
t ittgives ….
. i.Net
4. When boric in presenceNof acidNe
a i .Ni . N a i .Ni . N a i . i.N a i
a) Borax
a
l
saasa l a b)
a
l
asa l a
satrialkylborate a
l l a
asaSodium borate ad)
sac) l l a
saasOctahedral
a borax asaaslaa
d d
a aDiborane reacts with d d
amethyl
a d
aa d d
aa d adad
w .P5.
w . P w .P.P
w alcohol to give w .P.P
w w .P.P
w w .P.P
w
ww
ww ww ww wwww ww
ww wwww
a) Borax b) trialkylborate c) trimethyl borate d) Octahedral borax
6. The mixture t
e eoft carbon monoxide tet nitrogen is called
eand t
e et
----------------- t
e et
a i .Ni . N a i .Ni . N a i .Ni . N i .Ni . N
a) water
d a
d
l l
saasagas a
db)
a
d
l
asa l
saproducer a gas
d adsac)l l a
asaboth a and b
d ad
l a
sad)asanone of these dadsaaslaa
l a
.P7.
.Pa aThe process in which .P.PaEthene
a is mixed with a a and Hydrogen gas
.P.CO
P a aproduce propanal . P.P
.P.to
P aa
w ww
w w ww
w w ww
w w ww
w w ww
w
ww a) McAfee process ww b) Oxo process ww c) Syn process ww d) Liquationwprocess w
8. The compound i . N . etet which act as a imolecular
N . N . etet
N sieve for thei.N . etet of permanenti.hardness
removal
N N . etet of
N
a
aslala i a
aslala i a
aslala i a
aslala i aslaa
water a sa a sa a sa a sa a sa
.Pa)
. adaInosilicates
P d .P.Padab)d Tecto silicates .P.P adad c) Amphiboles .P.P adadd) Zeolites .P.Padad
www w www w www w ww w w ww w w
ww 9. Boric acid is an ww acid because its molecule ww ww ww
a) contains i . N . etet
replaceable
N H+ ion i.N . etet
N b) gives i . N . eteat proton
up
N i . N . etet
N
l a a i
asal with proton toaform l a a i
asal water molecule d) l
asala a i l a
al a
asreleasingi aslaa
a s
c) dcombines
a d sa d a saaccepts OH -
from water
d a sa proton. d a sa
.Pa ad
.P10. .P.Pa ad .P.Pa ad .P.Pa ad .P.Pa ad
w w w In diborane, the
w wnumber
w of electrons w w
thatwaccounts for banana w wbonds
w is w w w
www www www www w w
a) six b) two c) four d) w
three
e t t e t t e t t e t t
11. Carbon alia.N Ne in fullerene with
i.atoms a ia.Ni.N e
formula C60 have ai.N i.Ne a ia.Ni.Ne
3sa sla
a)adspadahybridised d a
d sasa la l b) sp
d ad
a
sas la l
hybridised
a
d adsasa la l
d a
d saaslaa
.Pasp2 hybridised www
.Pc) .P.Paa .P.Paa .P.Paa 3 .P.Paa
w ww
w w w ww
w d) partially sp2 and
w ww
partially
w sp hybridised w ww
w
ww ww ww ww ww
12. The basic structural unit of silicates is
a) (SiO3l)a2-ia.N . etet
N b) (SiO i . N
) 2-etet
. N c)(SiO)i . N . e2-tet
N i . N . eted)(SiO
N t
4)
4-
i a i a i a i
a a a saaslaa
4
saasa l l l
saasina its hydrides l
saasa l saasa l l
13.d
aa a
Oxidation
d state of carbon
aad a
d d
aa ad d
aa ad aad a
d
ww.Pa)
.P +4 ww .P.P b) -4 ww.P.P c) +3 ww.P.P d) +2 ww.P.P
w
ww w ww w w www w w
ww w www w
14. The geometry at which carbon atom in diamond are bonded to each other is
a) Tetrahedral i . N . etet
N b) i
hexagonal. N . etet
N c) i . N .
Octahedral etet
N d) i . N
none . eteof
N t
these
a a
lala i a a
lala i a a
lala i a a
lala i aslaa
a sa s a sa s a sa s a sa s a sa
.P.Padad
15. Duralumin is an alloy
.P.Padad
of
.P.Padad .P.Padad .P.Padad
www w a) Cu,Mn www w b) Cu,Al,Mg www w c) Al,Mn ww w w d) Al,Cu,Mn,Mg ww w w
ww ww ww ww ww
16. The stability tet of +1 oxidation state teincreases in the sequence
i . N . e
N i . N . e
N t
i . N . etGa
N et < Al d) Ga<i.In N . e<teAl
N t
a) Al <alGa a
al a i
< In < Tl b) Tl < In
l
asala <a iGa < Al c) In <
l
asalaTl a i < l
asal a a i < Tl aslaa
d a sa s d a sa d a sa d a sa d a sa
.Pa ad empirical formula
.P17.The .P.P d the silicones .PP
a afor .a a
d .P.Pa ad .P.Pa ad
www a ) (R2SiO) www b) (RSiw2O) ww www
c) (RSiO) d)(R3SiO) www
18.Which onetist the example for three
i . N . ee
N i . N . etetdimensional silicates
N i .N . etet
N i .N . etet
N
a i a i a i a i
saaslaa
a)Quartz l l a b)Feldspar
l l a c)Talc
l l a l l d)Beryl
a
d a
d saasa d a
d saasa d adsaasa d adsaasa dad
a a critical temperature
.P19.The
.P .P.Pa a of CO2 .P.Paa .P.Paa .P.Paa
w ww
w 0 w w
w w 0 w w
w w 0 w w
w w 0 w w
ww
ww a)35 ww b) 36 ww c) 38 ww d) 31 ww
i . N . etet
N i . N . etet
N
aad a
d a d
aa a
d a Padasalai
aad a
d a d
aa a
d a d
aa a
d
ww.P.P ww .P.P ww .P.P ww .P.P ww.P.P
ww
ww 20.Which compound w w
ww on hydrolysis willwgives w
w w www w www w
boric acid and sodium hydroxide
a)Borane i.N . etet
N b)Aluminium i . N . etet silicate c)boron
N i . N . etet
N d)Borax
i . N . etet
N
i i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
aa
.Pii.Answer
.P aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w the following
w ww
w questions w ww
w w ww
w w ww
6×2=12
w
ww ww ww ww ww
21. A hydride of 2nd period alkali metal (A) on reaction with compound of Boron (B) to give
a reducing i . N etet (C). identify A i,.N
N
agent
. B . N
tet C.
eand i . N . etet
N i . N . etet
N
a i
aslalaa short note on hydroboration a
aslala i a
aslala i a
aslala i aslaa
22. a sa
Write a sa a sa a sa a sa
. adad
.P23.
P adad
.P.P adad
.P.P adad
.P.P adad
.P.P
www w What are w
necessary
ww w condition for w
catenation
ww w ww w w www w
ww ww ww ww ww
24. Write about producer gas
25.Whatlais i . N etet alum
N
burnt
. i . N . etet
N i . N . etet
N i . N . etet
N
asal a i l
asala a i l
asal a a i l
asala a i aslaa
d
26.Howa sa will you prepare d a sa
Boron trifluoride d a sa
industrially ? d a sa d a sa
.P.Pa ad a ad
.P.P a ad
.P.P a ad
.P.P a ad
.P.P
www www www www www
iii.Answer thet following questions t 6×3=18
i .N . et
edifferences
N i N . e et and diamondi.N.N
N
.graphite etet i .N . etet
N
27.Whatlaare i between a i a i a i
28. d a
d
Write
l a
saasa the Anomalousdproperties a
d
l
saasa l a
of the first d a
d
elements
l l a
saasa of p – block dadsaasa l l a
d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w 29.What are w
siliconesww
w .How will you w
prepare ww
w silicones w ww
w w ww
w
ww ww ww ww ww
30.How will you prepare perchloro siloxanes .What will you get after alcoholysis &
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
ammonialysis i on silicon tetrachloride i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
31.Write
.P.Paa about laboratory aa
.P.P preparation , reducing aa
.P.P behaviour , acidic behaviour
aa
.P.P & water gas aa
.P.P
w ww
w equilibrium of CO w w
w w w w
w w w w
w w w w
w w
ww ww2 ww ww ww
32.How will eyou tet prepare sodium borate
etet , borazole , lithium borohydride
etet etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
33.Give
a sa
uses
aslala of i) Boron
a
ii)Boric
saaslala acid iii)Alum
a sa aslala a saaslala a saaslaa
.P.Padad adad
.P.P adad
.P.P adad
.P.P adad
.P.P
w w
ww v)Answer the following www w ww w w ww w w www w
ww ww questions ww ww ww
6×5=30
34.Explain structure etet of diborane , Boric etet acid etet etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
35.What
a sa
l
asal a
are silicates and explain
a sa
l
asal a its types
a sa
l
asal a
a sa
l
asal a
a saaslaa
d d
a aDescribe d
a ad d
a ad with specific reference d
a ad to carbon & .P.P d
a ad
w .P36.
w .P briefly allotropism
w w.P.P in p- block elements
w w.P.P w w.P.P w w
w
www metallic nature of w w
wwp-block elements & uses w
wwwof silicones w
www w
www
th
37.A compound
i . N . etet (A) which is only
N i . N . etet
non-metal
N
in 13 groupetereacts
i . N . N t with fluorine toetgive
i . N . N et (B) .
i i i i
Compound
d a
d saaslaala (A) on reacting d a
d saaslaala
with oxidising acids to sgive
d a
d a aslaala(D) .(D) on heating
d a
d
laala soda ash
saaswith d a
d saaslaa
a a compound (E) .(E)
.Pgives
.P a aon heating gives borax
.P.P a abeads
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww 38. A compoundw(A) w is colourless andwpoisonous w gas reactingwwith w synthetic gas gives ww
compound N(B)
i . . etet. B on reaction with
N i . N .
tet
ecompound
N of boronN(C)
i . . etegives
N t Compound (D)
i . N . ete.Ct on
N
i
alared hot gives non-metal i i i
heating
d a
d saaslaat d a
d saaslaala (E) .(E) on reaction d a
d saaslaawith
la sodium hydroxide
d a
d saaslaalagives d a
d saaslaa
.Paa
.Pcompound (F) aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww
3100𝐾 ww
39.Complete the reaction i)CO + C2H6 + H2 → ii)CO2 ⇔
iii)SiCll4ali+a.N C. e2tH
N et5OH → iv) SiCli.4N . etet 3 → v)AlCl3 i+.N.3NH
N
+NH etet 4OH →
N i . N . etet
N
asa i a
aslala i a
aslala i a
aslala i aslaa
adad
40.How
.Piii)Diborane
. P
will you prepare adad
.P.P
i) meta aluminate adad
from
.P.P
AlCl 3 ii) BF 3 from adad
boron
.P.P
trioxide adad
.P.P
www w from www w
sodium boro hydride ww w w
iv)Boron trifluoride ww
from w w
boric acid www w
ww ww ww ww ww
v)Boron nitride from boric acid
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asal a a i l
asala a i aslaa
.P.Pa ad
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ACADEMY
.P.P 8098850809 a ad
.P.PPEELAMEDU a ad
COIMBATORE
.P.P ******* a ad
.P.P
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saasa l l a
d a
d
l
saasa l a
d a
d saaslaa
.P.Paa aa
.P.P aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w w ww
w w ww
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N
s aslaalia. i.N s aslaalia. i.N s as laalia. i.N s as laalia. i.N saaslaa
d
aa ad a aad a
d a Padasalaid
aa a
d a aa d a
d a d
aa a
d
ww .P.P ww .P.P ww.P.P ww .P.P ww.P.P
w
ww w www w ww w w w w w w ww
11.In bragg’swequation n represents w
i . N . etet
N i . N . etet
N a) number i . N . eteof
N t moles b) avagardo
i . N . etet number
N
i i i i
d adsaaslaala d a
d saaslaala d a
d saasalaaquantum
c) la number d a
dd)
laala
saasorder of reflection d a
d saaslaa
.P.Paa .P.Paa .P.P aa aa
.P.dimensional
P .P.P aa
w ww
w w www w ww
w 12.A regular three w ww
w wwww
ww ww ww ww ww
arrangement of identical points in space is
. N etet
N Marks . N ete; t75
N called . N etet
N . N etet
N
a
aslala i i . a i i
aslala3o min. a
lala
asunit i i . a ia
aslallattice i . aslaa
adada sa Time ;
adad 1hrs
a sa a
adad
s
a)a cell b)
adad a sa
space a
adad
sa
w w.P.P w w.P.P w .P.P
w c) primitive w w.P.d)
P crystallography ww.P.P
ww
ww wwww ww ww wwww ww ww
I. Choose the best answers 25×1=25 13. The smallest repeating unit in space
1. The ratio i . N . eteclose
N
of
t
packed atoms i . N . etet
N
to lattice i . N etet when repeatedi.N
N
which
. over
. etetand
N
l
asala a i l
asala a i l
asal a a i asall a a i aslaa
d a sa
tetrahedral hole in cubic d a sa
packing is d a sa
again results in crystal d a s
ofa the given d a sa
.Pa)
.Pa ad .P.Pa ad .P.P a ad .P.Pa ad .P.P a ad
w w w 1:1 b) 1:2 w w w
c) 2:1 d) 1:4 w w w substance is w w
calledw w ww
www www www www www
2. In calcium fluoride, tet having the flurite a) unit cell b) space lattice
i .N . ecoordination
N i .N . eteCa
N t 2+
i .N . etet
N i .N . etet
N
structure a the i number a i of c) primitive
a i d) crystallography
a i
iond ad
and
l l a
saasaF- Ion are d a
d saasal l a
d a
d14.The
l l a
saasa number of close d a
d
asa l l
saneighboursa
in a d a
d saaslaa
.P.Paa .P.Paa .P.P aa .P.Paa .P.P aa
w ww
w a) 4 and 2 b) 6 andw w
6ww c) 8 and 4 d) 4 and w
8 ww
w bcc is w ww
w wwww
ww ww ww ww ww
3. The numbert of carbon atoms per unit a) 6 b) 4 c) 12 d) 8
i . N . e et
N i . N . etet
N i . N . etet
N i . N . etet
N
laala i aslaala i 15.In
aslaal a i scc , each point on a
aslaala i
corner is
saaslaa
cell ofadiamond is
d adsa s d a
d sa d a
d sa d a
d sa d a
d
a)
.P.Paa 8 b) 6 c) aa
.+P.P1 d) 4 .P.P aa shared by a) one unit
.P.Paa cell b) two unit cell
.P.P aa
w ww
w 4.The ionic radii w
of ww
A w and B −
are 0.98 ×w ww
w c) 8 unit cell w
d) w4w
w unit cell wwww
ww ww ww ww ww
10-10 and 1.81 e ×
tet 10 -10
. the coordination e tet 16.The distance
e tet between crystals e tetwhen x
. N N
i. ion in AB is alaaliai. . N N . N
i. N . N N
iai. a first
aslaaofliaeach aliawavelength 0
number rayalaof 2.31 Aalaalgives aslaa
a sa a sa s a sa s a sa s a sa
Pada8d
.P.a) b) 2 c) adad d) 4
.P.6P .P.P adadorder reflection at.P90 . adad
P
0
.P.P adad
w w
ww 5. CsCl has bcc w ww w w www w ww w w wwww
ww w
arrangement, its unit cell ww a) 1.31 b)w4.31 w c) 5 d)ww 2.31
edge length is ete400pm,
t its inter atomic etet 17.In fccearrangement
tet , the corner etetatoms
i . N . N i . N . N i . N . N i . N . N
distance
a saaslaaislai a sa aslaalai a
are
saaslaAalatypei and those at face
a sa
ai
aslaalcenters are B
a saaslaa
d d
a a400pm d
ab)ad800pm d
a adtype .What is the .simplest d
a ad formula of the.P.P d
a ad
w w.Pa)
.P w w.P.P w .P.P
w w w P.P ww
w
www c) √3 ×100pm www d) √3/2 × 400wpm w w
ww compound www w www w
6. The vacant i . N . etspace
N et in bcc latticei.N unit
. etecell
N t a) AB eb)
i . N . N
tet A c) B
i .
d)eAB
N . N
tet 2
a i a i a i i
is dadsaasa l l a
d a
d saasal l a
d a
d
18.Thel l a
saasa number of unit d a
d
cell l a
saasain NaCl crystal dadsaaslaa
l a
.Pa)
.Paa .Pc)aa
.P .P.P a a when it is arranged .P.Painafcc arrangement .P.P aa
w ww
w 48% b) 23% ww ww 32% d) 26% ww ww w ww
w wwww
ww 7. The radius ofwanw atom is 300pm, if itww a) one unit cell ww b) two unit wwcell
crystallizes i . N in
. eteatface centered cubic
N i . N . N
tet
elattice, c) 8 unit
i . N . N
tet
ecell d) 4Nunit
i . . etet cell
N
i i i i
theda saaslaalaoif the edge ofdthe
length
d a
d saaunita
slalacell is d a
d saaslaalabcc the coordination
19.In
d a
d saaslaa la
number is
d a
d saaslaa
.Pa)
.Paa .P.Paa .P.P a a a) 8 b) 6 ww .P.Pac)a1 d) 4 .P.P aa
w ww
w 488.5pm w www b) 848.5pm ww ww w w wwww
ww ww ww 20. Diamond ww belongs to ………type wwof
c) 884.5pm d) 484.5pm
8. Potassium N tet a bcc structure with
ehas N etet crystal.NN etet N etet
a i . i . N a i . i . N a i i . i . i . N
a
nearest sa ala
aslneighbor distance a s
4.52a aslaAla0 . its a aaslalacubic closed packing
21.In
s a sa
a
asla,lapercentage of asaaslaa
. adad
.Patomic
P .P.Padad .P.P adadempty space .P.Padad .P.P adad
www w weight is 39.
ww w w
its density will be www w ww w w wwww
ww ww ww a) 50 w
b)w36 c) 24 d) 26ww
a) 915 kg m-3 b) 2142 kg m-3
N -3etet N emte-3t 22. Ai.face N etecentered
t cubic solid N eoftean
t
c) 452 kg a im. i . N d) 390 a i .
kgi . N a i . N i . i . N
9.ada
l l a
adsaasa with a metal deficiency
crystal a sa
l a
asal defect is a s l
element
a
a
asal (atomic mass a60) sa
l
ashas a
al a cube edge asaaslaa
a
d
a ad d
a adof 4A0 . Calculate.Pits d d
a adensity. adad
w .wPa)
. P NaCl b) FeO wc) .wP.P w . P. P w . P w . P. P
ww
ww wwww ZnO d) KCl ww www wwwww ww www
10.The crystalt which are good conductor 23.In triclinic primitive systems , relate
i .N . N et heat are
eand i .N . etet
N intercepts i .N . eteand
N t interfacial angles
i .N . etet
N
of electricitya i a i a i a i
d a
a)ionicd
l
saasa l a
d a
d
b)
l
asa l a
samolecular d a
d
l
24.Find l a
saasa the odd one out d a
d saasa l l a
d a
d saaslaa
.P.Paa .P.Paa .P.P aa .P aa
P .P.P aa
w ww
w c) mettalic w www d ) covalent w ww
w glucose, urea w ww
,CO
w 2. wwww
ww ww ww ww ww
i . N . etet
N i . N . etet
N
d
aa a
d a d
aa a
d a Padasalai
d
aa a
d a d
aa a
d a d
aa a
d
ww
ww 25. silicon carbide w w
wwis the type of ……… ww w w wwww wwww
crystal i.N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
i i i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
aa
.PII.
.P .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w Answer the following w ww
w questions w ww
w wwww wwww
ww ww ww ww ww
5×2=10
26. Distinguishi . N . etetbetween hexagonal
N i . N . N
tet
eclose i . N . etet
N i . N . etet
N
ala
aslaand i a
aslala i a
aslala i a
aslala i aslaa
a
packingsa cubic close a sa
packing. a sa a sa a sa
. adad
.P27.
P .P.Padad adad
.P.P adad
.P.P adad
.P.P
www w Distinguish w w
tetrahedral
ww and octahedral www w wwww wwww
ww ww ww ww ww
voids.
N tet
ethe N eteat fcc N etet N etet
28. Calculatea i . i . N number of atomsa i . i . N
in a i . i . N a i . i . N
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
unit
a adcell d
a ad d
a ad d
a ad d
a ad
w .P29.
w .P w .P.are
w P w .P.P
w ww.P.P ww.P.P
w
www Why ionic w
crystals
www hard and w
brittle?
www w
www w
www
30. Define unitt cell.
i .N . e et
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
III.Answer
l l a
saasa the followingdadquestions l
saasa l a
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saaslaa
.P.Paa .P.Paa aa
.P.P aa
.P.P aa
.P.P
w ww
w 5×3=15 w ww
w w ww
w wwww wwww
ww ww ww ww ww
31. Calculate the percentage efficiency of
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
packing in i
case of Simple cubic i
crystal. i i
d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaala d a
d saaslaa
32.Write
.P.Paa about impurity
.P.P defect
aa aa
.P.P aa
.P.P aa
.P.P
w ww
w 33.Calculate numberw ww
w of atoms in SC and w ww
w wwww wwww
ww ww ww ww ww
BCC etet etet etet etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
34.Write
a saaslalaabout characteristics
a sa
of
aslala ionic
a saaslala a saaslala a saaslaa
. adad
.Psolids
P .P.Padad adad
.P.P adad
.P.P adad
.P.P
w w
ww 35. Distinguish w www w www w wwww wwww
ww crystalline
w and amorphous ww ww ww
solids etet etet etet etet
a i . N
i . N a i . N
i . N a i . N
i . N a i . N
i . N
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a sa
l
asal a
a saaslaa
d
a ad d
a ad d
a ad d
a ad d
a ad
w .PIV.Answer
w .P the following
w .P.P
w
questions
w .P.P
w ww.P.P ww.P.P
w
www 5×5=25 w
www wwww w
www w
www
36.Classify the
i . N . etetcrystalline solidsi.N
N
and
. eteadd
N t
i . N . etet
N i . N . etet
N
a i a i a i a i
two main
d a
d
l l a
saasa points to each type d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saaslaa
a aCalculate the percentage
.P37.
.P .P.Pa a efficiency of .P.P aa aa
.P.P aa
.P.P
w ww
w w ww
w w ww
w wwww wwww
ww packing in case w ofwbody centered cubicww ww ww
crystal. Netet N etet N etet N etet
i . i . N i . i . N i . i . N i . i . N
d d saaslaala the percentage
38. aCalculate
d a
d
aslaala
saefficiency of
d a
d saaslaala d a
d saaslaala d a
d saaslaa
.Paa
.Ppacking in case of face Paa
.P.centered cubic ww aa
.P.P aa
.P.P aa
.P.P
w ww
w w ww
w w w wwww wwww
ww crystal. ww ww ww ww
39.Explain.Nabout
i . etet types of stoichiometric
N i . N . etet
N i . N . etet
N i . N . etet
N
defect a i
lala neat diagram saslala
aswith a i a
aslala i a
aslala i aslaa
a sa a a a sa a sa a sa
. adad
.P40.Explain
P about two .P. adad
P
dimensional closed ww adad
.P.P adad
.P.P adad
.P.P
www w www w ww wwww wwww
ww packing ww ww ww ww
i . N . etet
N i . N . etet
N i . N . etet
N i . N . etet
N
l
asala a i l
asala a i l
asala a i l
asala a i aslaa
.P.Pa ad .P.Pa ad a ad
.P.P a ad
.P.P a ad
.P.P
www www www www www
i .N . etet
N i .N . etet
N i .N . etet
N i .N . etet
N
a i a i a i a i
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d
l
saasa l a
d a
d saaslaa
.P.Paa .P.Paa aa
.P.P .P.Paa .P.Paa
w ww
w w ww
w w ww
w wwww www
w
ww ww ww ww ww
i . N . etet
N i . N . etet
N

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