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OTC 16048

Newbuild FPSO Corrosion Protection - A Design and Operation Planning Guideline


Adrian MacMillan, Karl Petter Fischer, Henning Carlsen, Øystein Goksøyr; Det Norske Veritas

Copyright 2004, Offshore Technology Conference


economic consequences. Therefore, it is very important to
This paper was prepared for presentation at the Offshore Technology Conference held in design, implement and manage a proper corrosion protection
Houston, Texas, U.S.A., 3–6 May 2004.
design.
This paper was selected for presentation by an OTC Program Committee following review of
information contained in an abstract submitted by the author(s). Contents of the paper, as
This paper provides some background and guidelines to
presented, have not been reviewed by the Offshore Technology Conference and are subject to facilitate the cost effective corrosion control design for
correction by the author(s). The material, as presented, does not necessarily reflect any
position of the Offshore Technology Conference or its officers. Electronic reproduction, newbuilding FPSO hulls. Specifically the focus is on:
distribution, or storage of any part of this paper for commercial purposes without the written
consent of the Offshore Technology Conference is prohibited. Permission to reproduce in print Identifying and quantifying the dominating factors related
is restricted to an abstract of not more than 300 words; illustrations may not be copied. The to corrosion control,
abstract must contain conspicuous acknowledgment of where and by whom the paper was
presented. How to select a cost effective corrosion protection system
based on a combination of corrosion margins, coating
Abstract systems and cathodic protection,
Corrosion control design and management for a newbuild Fabrication inspection related to the desired corrosion
Floating Production Storage and Offloading installation protection system,
(FPSO) operating in certain benign regions, such as West Providing an operation inspection, maintenance and repair
Africa, China and Brazil, can provide significantly increased strategies for selected corrosion protection system,
challenges compared to their North Sea counter parts. This is Introducing a new RBI tool for IMR control of coated
primarily driven by a number different environmental factors, areas.
such as relatively high ambient temperatures, humidity and Corrosion problems for converted vessels operating in the
cargo temperatures. Therefore, it is difficult to select a cost same regions, e.g. Brazil and West Aftrica, are well
effective corrosion control design that addresses both the documented and selecting a cost-effective corrosion protection
fabrication and operational aspects. This paper provides system can be equally difficult. Although this paper does not
guidance on how to address the key corrosion protection address converstions specifically, many of the basic concepts
design and fabrication issues and their corresponding impact are still applicable.
on inspection, maintenance and repair during operation.
Basic aspects of FPSO corrosion control
Introduction For carbon and low alloy steel FPSO hulls there are three
Eventhough there are over 100 FPSOs operating worldwide, principal types of corrosion to be considered/2/:
designing and implementing a cost optimal Inspection, General corrosion,
Maintenance and Repair (IMR) system for a 20 year service Pitting corrosion, including “in-line pitting attack” and
still remains a major challenge. Primarily this is due to the fact “grooving corrosion”, and
that there is limited information available to facilitate the
Galvanic corrosion (e.g. at welds).
corrosion control design for a 20 year continuous service.
If the ratio of corrosion attack depth to its width is much
Newbuilding FPSOs have traditionally been purpose built
less than 1 then this termed general corrosion. Should the
for harsh environments, such as the North Sea, with converted
depth of the corrosion exceed the width then this is defined as
FPSOs dominating the benign regions, such as Asia, Australia,
localised corrosion.
Brazil and West Africa. As a result previous newbuildings
When the ratio gets much greater than 1 then this is
have been designed with a major focus on fatigue and ultimate
defined as pitting corrosion. This typically occurs on
strength. However, it is forecast that 90% of future FPSOs will
horizontal surfaces, such as bottom plating. Pitting corrosion
be installed in benign regions, with 60% of these being
can also occur at structural intersections where water collects
newbuildings/1/. Although these regions may be benign from a
or flows and may also be termed as “in-line pitting attack” or
wave climate perspective they can impose significant
“grooving corrosion”.
corrosion control challenges relative to their North Sea
Galvanic corrosion is generated through preferential
counterparts. This is primarily a function of increased ambient
corrosion of the weld deposit due to galvanic action, e.g.
temperatures and humidity.
between a weld and the base metal.
Many of the current newbuilding ‘mega’ FPSOs will have
production capacities in excess of 200,000 bopd and, Corrosion consequences
There are a number of different consequences for each type of
therefore, any lost production time can have very significant
corrosion.
2 OTC 16048

General corrosion can result in fatigue, buckling and design parameters for the coated surface and the environment.
leakage at a local or global level. However, the frequency of The inspection outcome and the associated uncertainty are
such failures is low to medium as it is easier to observe during included in the prediction of the future coating degradation.
regular inspection intervals. During operation, qualified Cost models with regard to patch repair, re-coating or
surveyors and inspectors are able to easily identify whether replacement of steel may be entered into the tool in order to
general corrosion has exceeded the acceptance criteria and if establish a cost-optimised IMR plan along the service life of
repair is necessary. the vessel.
Localised corrosion (pitting and groove) can result in Figure 2 shows an example from CoatInsp on how
leakage of tank contents, which can lead to pollution and / or degradation models are updated and applied after two
explosion. Since pitting corrosion rates can be rapid the sequential inspections. After the first inspection, recoating is
frequency of occurrence is increased compared to general conducted while local repair is carried out following the
corrosion. Due to the small surface extension of pits, they can second inspection.
be more difficult to identify compared to general corrosion. Figure 3 shows an example event tree used for prediction
Structural integrity and corrosion control of future inspection condition based on the repair actions
The structural integrity of the FPSO hull, in relation to taken.
corrosion, can be achieved through the following: Corrosion influences and rates
Corrosion allowance (for given structural members) The corrosion impact on an FPSO is governed by the external
Corrosion protective coatings environmental and the operational conditions. The importance
Cathodic protection (for seawater tanks and for the of the site specific environmental conditions should not be
external hull) underrated. Basic knowledge on the climatic conditions,
A optimal FPSO structural integrity design can be diurnal and seasonal variations are important as a basis for the
achieved through a combination of these three measures. specification of the protection systems. In certain
Relationship between corrosion and time environments, the required corrosion protection measures may
The deterioration of the FPSO hull will mainly be determined have to exceed the corrosion protection measure requirements
by corrosion due to seawater and the conditions in the cargo given in present standards. Such variables may be entered into
spaces through changes in the corrosion protection system CoatInsp to assist with determining the cost-effective coating
over time. Consequently, the corrosion rate will change with system.
time. Typically three different corrosion-time equations can be Table 1 provides some basic corrosion ranges for cargo
used: and ballast tanks. Specific corrosion margins for different
member types are provided later. For simplicity the corrosion
Model A: Corrosion wastage rate decreases with time.
impact can be divided into three zones (see Figure 4):
Model B: Corrosion wastage rate increases linearly with
Upper zone (including deck and 2-3m down into the
time.
tanks/hold).
Model C: Corrosion wastage rate increases non-linearly
Middle zone (zone between the upper zone and the lower
with time.
zone).
Each of these corrosion wastage models are schematically
shown in Figure 1. Lower zone (including 2-3 m up from the bottom).
Semi-empirical or analytical equations for quantitative Table 2 summarises some of the key operational factors
assessments of the corrosion rates can be established. that tend to significantly influence the corrosion wastage for
However, it is important to be aware that the algorithms for an FPSO. These factors cover aspects such as temperature
determining the corrosion rate are very complex and all the increases, oxygen in seawater, chlorinity, humidity,
required input data may not be available. It has, therefore, temperature gradients, types of cargo oil, etc. For example, a
become common practice to utilise mathematical probabilistic temperature increase of 10ºC can double the corrosion rate if
modelling to predict corrosion wastage. all other conditions are kept constant.
DNV has recently developed an innovative tool (CoatInsp) In order to illustrate how to use this information it is
for IMR planning and follow-up of coated areas over the life- worthwhile considering a ballast tank in a double-bottom or
cycle of an FPSO/FSO. CoatInsp is a Risk Based Inspection side for an FPSO located in China where the viscous oil needs
(RBI) tool to ensure that consistent inspection plans are to be maintained at elevated temperatures (up to 80°C). As
developed based on all relevant design parameters of a coated presented in Table 1 there is the potential for a high corrosion
surface. rate in a basic seawater ballast tanks. However, with the
CoatInsp is divided into six main modules: ballast tanks being adjacent to a heated cargo tank the
corrosivity impact for the internal hull will be intensified. The
Input to coating specification,
high temperature of the oil tends to create a temperature
Inspection history,
increase in the ballast tanks, particularly in the bulkheads to
Probabilistic analysis of coating degradation, the oil storage tanks. This is commonly referred to as the
Cost optimised inspection planning, “thermos bottle effect”.
Time to next inspection, and To further compound the matter, the increase in the
Parametric studies. temperature of the ballast tanks can also lead to an increased
A probabilistic approach is taken where the expected bacterial corrosion. In this context it can also be mentioned
degradation rates are expressed mathematically based on the that bacterial corrosion can be exacerbated by the organic
OTC 16048 3

material. In this context it is important to remember that the As indicated above the optimal approach to FPSO
organic material could also be the protective coating. maintenance is to ensure adequate corrosion protection and,
Consequently only coating products which have been pre- thereby, avoid corrosion wastage. With this approach a
qualified should be utilised. corrosion allowance is not needed. However, a corrosion
FPSO hull arrangement and ‘corrosion zones’ allowance based on a 10-year service or any arbitrary selected
An FPSO typically consists of a number of tanks and void value may be used as a safety factor in the design (e.g. 2mm
spaces. The tanks may contain ballast water, stabilised oil, for a one sided exposure). These may be used as a safety
unstabilised oil, slop tanks, methanol tanks and / or factor for critical structural members and/or for structural
combination tanks. As a result there are a number of variables members exposed under such corrosive exposure conditions as
that need to be taken into consideration for each space. The indicated in Table 2.
division into the three corrosion zones (upper, middle and As guidance, annual corrosion rates for different zones,
lower, Figure 4) as mentioned above represents a first orientations and structural types are provided in Table 4.
categorisation of the corrosion impact. These rates can be multiplied by the corresponding time as
Each of these zones is further sub-categorised into deemed appropriate for the project, e.g. 10 years for an FPSO
horizontal and vertical surfaces and plating and stiffening to be maintained on station for 20 years.
members. Some recommended base corrosion margins are Selection of an average or a maximum corrosion rate
provided in Table 4. should correspond with the corrosion model, as discussed
above. For example the average corrosion rates given in Table
Recommended Corrosion Control System – Design 4 are appropriate for models A and B while the maximum
and Fabrication corrosion rates may be used for model C.
Corrosion management for an FPSO will involve decisions For evaluating other tanks, e.g. chemicals, sludge and in
taken at various stages throughout the design and operational void spaces, the factors mentioned in Table 2 along with the
phases. In this section, corrosion margins, coating systems and properties for the given chemical or cargo need to be
cathodic protection systems are recommended along with the considered.
corresponding decisions related to design and fabrication. Coating systems
Issues related to operation are covered later. Quality of the coating applied at the new building stage will be
An overview of the commercial and operational impact, the deciding factor for the subsequent maintenance during
from different corrosion protection measures, is provided in operation.
Table 3. A high performance coating will provide a long service life
Selecting a corrosion model and result in the minimum maintenance (Table 3). The high
Typically corrosion model B will be used as a basis, i.e. linear performance coating will imply high initial costs. However,
increase in corrosion wastage over time. However, based on the benefit will be the optimal life cycle cost for the operation
the various operational influences provided in Table 2, it may of the FPSO. The implication of this is that coating
be prudent to adjust the corrosion model and select the maintenance requires close attention to planning logistics to
expected corrosion rate based on Table 1. Consequently there ensure adequate coating quality. The repercussions for
is a need to evaluate the total impact of the environmental inadequate coating maintenance work can be an exceedingly
conditions and the operational factors when establishing the short service life of the corrosion protection performance
desired corrosion margin. and/or rapidly increasing maintenance/repair costs.
Design corrosion margins For example, a high performance corrosion protection
Corrosion allowances for traditional ship designs are based on system costs can be around US$4 to 8 million for a VLCC-
10-year service and are provided in various Classification sized newbuilding FPSO compared to US$ 1 to 2 million for a
Society standards, e.g. DNV Rules for Ships/3/. low quality coating system (based on surface area of 200,000
Utilising the corrosion rates given in Table 1, the general m2). The costs for re-coating only one tank (2000m2 at 3 times
ballast tank corrosion allowance will be in the range from the cost of work at a dockyard) during operation can be around
1mm to 3.5mm for one sided corrosion exposures. For US$100,000 to US$200,000. If you also consider the impact
members with two sided corrosion exposure the corrosion from lost production, then could easily imply $5,000,000
allowance will be in the range of 2mm to 7mm. delayed revenue (10% of 200,000 bopd at $25/bbl for 10
To apply these corrosion rates to account for corrosion days).
over a 20 year service would result in twice the values for the Some typical coating systems used by the marine industry
10-year service, which is typically an unrealistic approach. are listed in Table 5. In the case of the Coating I (200 µm, one
An analytical approach to corrosion control could be as coat system), this is only expected to have a service life
follows: between 2 and 8 years. Consequently the need for
Utilise corrosion allowance as a safety factor for critical maintenance coating will be manifested by coating breakdown
items, early in the service life of the FPSO and for the Coating
Plan and implement a corrosion protection system to System I it can be expected to result in extensive maintenance
avoid corrosion wastage, and needs over a 20+ year service life.
Develop an appropriate IMR plan to ensure correct and It is important to be aware that coating of an FPSO is a
consistent coating maintenance and anode retrofitting. very complex process which represents a considerable
workload and logistics task in the yard. A successful coating
application work will require extensive planning before
4 OTC 16048

contracting and follow up/inspection during coating work. A high performance coating will reduce the depletion of
Normally this is not part of the Classification Society’s scope the anode by a factor of between 10 and 20, which can provide
of work, unless specifically requested as a part of the contract significant weight and inspection savings. A low performance
or additional class notation, e.g. DNV COAT III/4/. coating system will only achieve a factor of approximately 3
Quality control of the surface preparation and application to 5.
is essential to ensure that the applied coating system will The tank bottom of a ballast tank is a critical area for
provide the expected performance. A high performance pitting type corrosion. It is important to ensure that anodes are
coating can best be ensured by using an experienced third retrofitted in the tank bottoms to ensure full protection during
party coating inspector during the FPSO fabrication period. the service of the FPSO.
It is important be aware that a high quality coating can be
best achieved at a yard as compared to the quality which can Inspection, Maintenance and Repair Strategies
be expected for maintenance on the FPSO in service. This is A corrosion protection design can only be cost effective if a
related to the possible complexities for the working conditions corresponding IMR program is prepared and implemented. An
and ability to achieve desirable climatic conditions when overview of the IMR program corresponding to the corrosion
executing maintenance on an FPSO in service. design is presented in Table 3.
Cathodic protection Specific aspects related to dealing with corrosion margins,
Sacrificial anodes provide cathodic protection (CP) in the part coating protection and cathodic protection are described
of the ballast tanks which are submerged .The design of the below.
CP system is done based on providing protection for a given Corrosion margins
service life. Sacrificial can here be retrofitted during the With a good corrosion protection design the FPSO global
service life. Optimal corrosion protection can be achieved by strength may be based on a gross thickness approach. A net
combining CP with a coating system. thickness (gross minus corrosion margin) approach may be
For the external hull, the protection will be a combination considered for local strength calculations (see /5/ for further
of coating and sacrificial anodes, which is necessary to details).
achieve a 20 year service life. For the external hull there are As described above, it was recommended to use corrosion
two alternatives: margins as an additional level of safety should there be a
Sacrificial anodes, or breakdown in either the coating or cathodic protection
Impressed current protection. systems.
The industry practice varies; some operators prefer Generally there is a poor link between what corrosion
impressed current anodes while others prefer sacrificial margins were used during design and what thickness loss may
anodes. Although advantages and disadvantages exist for both be accepted during operation. If pitting intensity is less than
systems, the critical issue is to plan for a needed refurbishment 20% then a localized 40% loss in thickness may be accepted.
of the anode system at the end of the FPSO service life. If the pitting intensity is greater than 20% then only localized
Cathodic protection: External hull 20% loss in thickness is acceptable. For main deck and bottom
The external hull can be protected by either sacrificial or plating with 0.4L a thickness of 20% is acceptable provided
impressed current anodes. adequate buckling strength remains.
The service life of the FPSO will imply that the external The current large newbuilding FPSO designs have
coating on the hull may show significant breakdown. This will extremely large stillwater bending moments that dominate the
imply that the cathodic protection current demand will be global strength design/6/ and so the buckling criteria can easily
highest at the end of the service life. govern. Therefore, it is important to develop, during the
It needs to be established how the sacrificial anodes and/or design phase, a summary of the corrosion margins used as this
the impressed current anodes shall be maintained or retrofitted is an important reference document for IMR program. Such
to ensure adequate cathodic protection also at the end of the information can then be loaded into a 3D graphical database,
service life of the FPSO. such as DNV’s Field Lifecycle Manager, to facilitate rapid
For the external hull, retrofitting anodes can be expected decision making when thickness measurements are made.
towards the final 5 to 10 years of the service life. Independent Coating protection
of the original installed cathodic protection system, sacrificial Maintenance coating for an FPSO requires close attention to
or impressed current systems can be applied. The choice will planning logistics to ensure adequate coating quality. The
depend on selecting the optimal solution. repercussions for inadequate coating maintenance work can be
Cathodic protection: Internal hull an exceedingly short service life of the corrosion protection
The ballast tanks of an FPSO will be protected by coatings and performance.
cathodic protection in the areas submerged in seawater. The maintenance strategies focus on the coating
For ballast tanks the benefit for replacement of zinc maintenance and the basic philosophy is that corrosion
sacrificial anodes needs to be considered at every scheduled wastage (general corrosion) is not considered a problem when
point in the maintenance planning. the coating breakdown is in the range 3-20% (see Figure 5 for
A combination of coating and cathodic protection can examples of degrees of rusting on painted steel surfaces).
ensure a 20 year corrosion protection service life. However, to ensure that corrosion wastage does not become a
Only sacrificial anodes are allowed in tanks with zinc concern, it is then necessary to plan that the coating
anodes primarily being in ballast tanks. maintenance be carried out prior to a 20% coating breakdown
situation.
OTC 16048 5

Since there are many variables that can impact the anode mass is reduced by about 80% the anode needs to be
performance of the coating system it is difficult to reliably replaced.
develop accurate performance prediction models, such as For the external hull the need for maintenance of the
CoatInsp. However, a coating breakdown of less than 3% anodes/impressed current system requires planning at the
within the first 2 to 3 years of operation typically indicates that design stage. This is necessary to ensure that anode retrofitting
the coating will function adequately for an extended service can be achieved in a cost effective manner as needed during
life. the service life of the system
As a part of the cost optimization of the corrosion
protection system, it is also important to understand the Conclusions
relationship between coating condition and corresponding Corrosion design, implementation and management during
Class survey action, as shown in Table 6. If the general operation for a newbuilding FPSO intended for a 20 year
corrosion breakdown exceeds 20% then annual inspection is service life remains a major challenge. However, the key
required, which requires that tank to be taken off line, cleaned, parameters and gudinelines for achieving a cost effective
gas freed and made available for inspection. This can be an corrosion protection system has been established in this paper.
expensive process, particularly when you consider the impact The key points are as follows:
from lost production. There are many different environmental factors that
The selected maintenance coating product needs to be influence corrosion and these need to be understood in
qualified or to have documented performance. In this context order to select an appropriate corrosion control system.
the service life of the maintenance system needs to be A combination of coating, cathodic protection and
considered. The alternative systems for coating maintenance corrosion allowance is recommended for newbuilding
for ballast tanks and cargo tanks are given in Table 7 and FPSOs.
Table 8, respectively. High performance coating systems (COAT III) are
For maintenance coating the following characteristics recommended as a cost effective solution due to their life
should be documented: cycle cost advantages.
Adequate corrosion protection Quality control of the coating application during
Need for qualification* (e.g. base system type as given in fabrication and maintenance is critical to ensuring that it
Table 7 and Table 8) functions as planned.
Establish compatibility with existing coating A coating breakdown of less than 3% within the first 5
Requirement for surface preparation (e.g. can be applied years generally indicates that the coating system will
on humid surface?) function adequately for an extended service life.
Application conditions (e.g. minimum application Corrosion allowances are primarily required as an
temperature). additional safety factor if a good quality painting system
Curing period and curing period between coats is applied and maintained. In this case a corrosion
Number of coats to provide full coating thickness. allowance based on a 10-year service is considered
* sufficient.
DNV has established a qualification testing for ballast
coatings, ref. /4/. New probabilistic methods and tools (CoatInsp) have
The requirement for surface preparation (e.g. use of water been developed that facilitate the development of a cost-
jetting or alternatives to dry blast cleaning) can represent optimal coating protection system.
considerable cost savings for the execution of the maintenance
coating. Acknowledgement
The maintenance coating systems can be hard The authors thank Kari Lønvik and Gudfinnur Sigurdsson for
coatings/paints (e.g. epoxy mastic, epoxy tar, polyurethane) or their assistance and technical support related to materials,
semi-hard coatings (e.g. variable chemistry). The hard probabilistic modelling and RBI.
coatings will have a possible service life in the range from 5 to
20 years. Semi hard coatings may have a lower surface life
than a traditional paint. This will depend mainly on the coating
formulation and surface treatment type. However the "semi-
hard" coatings will generally require less rigorous surface
preparation.
Cathodic protection maintenance
Replacement of anodes needs to be considered as the
initial anodes approach the end of their service life. This can
be determined by measuring the potential as described in
Table 9. Colour coding for the measured potential may be
used to highlight the critical areas in a 3D graphical database,
such as DNV’s Field Lifecycle Manager.
For ballast tanks the maintenance may also be based on a
visual inspection of the empty tank. At a point where the
6 OTC 16048

References
/1/ Westwood, John.; “The Prospects for the World
Deepwater Market”, DOT 2002
/2/ Paik, J. K., Lee J. M., Hwang, J. S.; “A Time-
Dependent Corrosion Wastage Model for the Structures
of Single and Double Hulled Tankers and FSOs and
FPSOs”, Marine Technology, Vol. 40, No.3, July 2003,
pp. 201-217
/3/ DNV Rules for Ships, “Part 3 Chapter 1 Section 2 Table
D1”, January 2003.
/4/ DNV Classification Notes 33.1, “Corrosion Prevention
Of Tanks And Holds”, July 1999.
/5/ MacMillan, A., “Effective FPSO/FSO Hull Structural
Design”, OTC 13212, Houston, TX, USA, 30 April – 3
May, 2001.
/6/ Terpstra, T. and MacMillan, A., “FPSO Design and
Conversion: A Designer’s Approach”, OTC 13210,
Houston, TX, USA, 30 April – 3 May, 2001.
/7/ DNV Technical report BGN-R3600197 , 29 May 2000
OTC 16048 7

Coating Degradation Models Including Inspection findings (Best Estimats)


100 %

Q =1 - Coating brakedown (%)


98 %

96 %

94 % Initial Model
Updated Model Coating Quality
92 % Updated Model Coating Quality
'Measured Model'
Model for repaired area
90 % Updated Model for intact area
Measured Coating Quality
88 %
0 2 4 6 8 10 12 14
Years from Installation

Figure 1 A simplistic model of corrosion wastage as a function of


Figure 2 Coating Degradation Models
time

Target PoF = 1.0E-01 T_3 | N1_N2


(failure = Re-Coating)
T_2 | N1 T_3 | N1_R2
2011
T_3 | N1_C2

T_3 | R1_N2

Coating Year Planning Year T_1 T_2 | R1 T_3 | R1_R2


2000 2000 2009 2013
T_3 | R1_C2

T_3 | C1_N2

T_2 | C1 T_3 | C1_R2


2014
T_3 | C1_C2

Figure 3 Event Tree used for prediction of condition based inspection intervals. Alternatives are dictated by inspection result leading to
alternative N (no action), R (Repair) or C (reCoat).

Upper
Zone

Middle
Ballast Cargo Cargo Cargo Ballast Zone
Tank Tank Tank Tank Tank

Lower
Zone

Figure 4 Corrosion zones for a typical double side / single bottom FPSO cargo region
8 OTC 16048

Figure 5 Evaluating the degree of rusting on painted steel surfaces (ASTM D 610-85)
OTC 16048 9

Table 1 General reference corrosion rate ranges for ballast and cargo tanks
Types of corrosion Effect on the general corrosion rate of low alloy steel
Average range in seawater ballast tanks (upper to lower zone): 0.08 to 0.35 m/year
General corrosion rates
Average range in cargo tanks (upper to lower zone): 0.04 to 0.12 mm/year
Average pitting rates can be from 0.5 to more than 1.0 mm/year in ballast tanks
Pitting corrosion rates often in conjunction with bacterial corrosion. (typically in the lower zone)
Pitting rates can be between 0.1 and 0.5 mm/year in cargo tanks.

Table 2 Operational factors and their influence on general corrosion rates


Operational Effect on the general corrosion rate of low alloy steel
Influence Factor
A temperature increase of 10°C will double the corrosion rate if other conditions are constant (e.g. based on an ambient
Temperature
temperature of 20ºC)
The corrosion rate will increase linearly with the oxygen content. However the oxygen solubility in seawater decreases with
Oxygen in the seawater
increasing temperature.
7.9 to 3.9 ml/l
Corrosion rate (µm/year) = 21.3 + 25.4 (O2 ,ml/l) + 0.356 (temp. °C)
Salinity of the seawater Marginal or no effect on corrosion. (Oxygen solubility in seawater is reduced slightly with increasing salinity. While
0
32 to 36 /00 increasing salinity will reduce seawater resistivity).
0 Chlorinity is related to the salinity by:
Chlorinity, /00
Salinity = 0.03 + 1.805 * chlorinity
Increasing flow rate will increase the corrosion rate. For a constant flow velocity V, m/s the corrosion rate will have a
Flow effect relationship:
0.6
Corr. Rate (µm/year)= constant + constant * V
Tank sloshing or wave Increased corrosion rate. The increase will depend on the tenacious/protective effect of the rust deposit on the steel
action surface.
Sulfides in small amounts (ppm –level) can cause dramatic increase in the general corrosion effects. The presence of
Sulfide pollution in the in
sulfides may also indicate microbiological corrosion (Sulphate Reducing Bacteria)
the seawater
NOTE : Sulfides may also initiate more insidious corrosion forms e.g. sulfide cracking corrosion mechanisms
Residual chlorine in The presence of residual chlorine (0.5 to 1 ppm) in the ballast water will increase the general corrosion by about 100%.
ballast water
In a tank with no free water the corrosion of steel will be negligible at humidity values below 60%.
Humidity The amount of water in the atmosphere increases with increasing temperature. For high temperatures, e.g. 30°C and
0 to 100% above, the humidity will lead to condensation in diurnal cycles in tropical and sub-tropical climates as the humidity will
become higher than 100% at least during the night.
Rust deposits Rust can effect the progressive corrosion in basically the three ways: Models A, B and C (Figure 1).
Coating will mitigate the corrosion in the areas were it acts as a barrier to water. The corrosion rate in an area with coating
Coating damage damage exposing bare steel will be as for the corrosion rate on any bare steel. Consequently exacerbated corrosion at
coating damaged areas may occur, but is not the common effect.
A temperature increase of 10°C will double the corrosion rate, if other conditions are constant. This can result in corrosion
Temperature gradients
rates of around 0.4 mm/year.
(e.g. due to hot
Corrosion mitigation require adequate coating, which implies a coating system which is qualified for such high temperature
bulkheads)
service (cyclic temperatures up to about 60°C).
Properties of the oil in the The oil may contain a separate water phase. This water phase may be acidic. An acidity in the water phase (pH < 5) needs
storage tanks: water cut to be considered as this will cause serious corrosion of bare steel.
“Sour oil” contains sulphides that may initiate localized corrosion forms, particularly in the tank bottom. Sulphides can also
Oil: “Sour”
lead to the insidious corrosion forms which leads to cracking (e.g. hydrogen induced cracking)
Oil: “Sweet” “Sweet” oil contains CO2 which results to increased acidity in the water phase.
The practice and procedures for cargo washing should be considered also in relation to the possible effect on the corrosion
Cargo washing
and corrosion protection measures status of the tank.
Sludge tanks The accumulation of sludge/deposits in tanks can be expected to exacerbate bacterial corrosion in the tank bottom

Table 3 Basic consideration for corrosion protection design and management for an FPSO hull
Corrosion protection design IMR approach Commercial implications
Low inspection volume for 20 years.
Predictable and reliable behaviour. Imply higher initial costs.
High performance
Low maintenance Low costs of inspection and maintenance
No steel repair
High inspection volume for 20 years.
Increasing inspection frequency with time
Standard performance Predictable behaviour.
High maintenance costs after about 10 years
Extensive maintenance after 10 years
10 OTC 16048

Table 4 Corrosion rates: General experience values for structural members


Structural member Ballast tanks Cargo holds
(Vertical r= v) Avg. rate Max. rate Avg. rate Max. rate
(horizontal= h) (mm/year) (mm/year) (mm/year) (mm/year)
Longitudinal elements
Deck plating (h) 0.30 0.40 0.08 0.28
Deck ,longitudinal web (v) 0.20 0.30 0.12 0.30
Side shell, upper 2m (v) 0.35 0.40 - -
Side shell , middle zone (v) 0.30 0.35 0.03 0.18
Side shell lower 2m (v) 0.20 0.25 - -
Stringer /side long. web (h) 0.35 0.40 0.04 0.18
Longitudinal bhd, upper 2m(v) 0.25 0.35 -
Longitudinal bhd ,middle zone (v) 0.20 0.25 0.05 0.22
Longitudinal bhd ,lower 2m (v) 0.20 0.25 - -
Longitudinal bhd, web (h) 0.35 0.40 0.04 0.21
Bottom plating (h) 0.20 0.25 0.08 0.53
Bottom long. web (h) 0.30 0.35 0.04 0.11
Transverse bulkheads
Transverse bhd plating (v) upper 2m 0.4 0.45 0.10
Transverse bhd vertical stiffener web 0.4 0.45 0.05
(v),middle zone
Transverse bhd horizontal stringer web 0.3 0.35 0.1
(h),lower 2m

Table 5 Typical coating system for marine service


Coating No. Typical coating system Coating thickness Expected service life
Nominal Dry Film Thickness
(number of coats)
I Epoxy based 200 microns (1) 5 ± 3 years
II Epoxy based 300 microns (2) 10 ± 3 years
III Epoxy based * 300 – 400 microns (2-3) ≥ 15 ± 3 years
* Require a surface with a measure salt content of less than 50mg/m2 on the substrate before coating

Table 6 Impact of coating condition on Class surveys


Coating breakdown Rating Class inspection consequence
Minor spot rusting Good Intermediate/renewal survey
Light rusting over > 20% Fair Intermediate/renewal survey
General breakdown > 20% and hard scale > 10% Poor Annual survey required
OTC 16048 11

Table 7 Maintenance coating and service life for ballast tanks (ref. /7/)
Service life Pre-treatment Coating system Comments
(years) Alternatives
Removal of mud, oil and grease.
Apply as:
Fresh water hosing - Epoxy mastic (surface tolerant)
1x stripe coat
5±3 High pressure hydro-jetting - Epoxy tar
2 x coats
Drying - Semi hard coating
= 300 µm DFT
Surface treatment to Sa 2
Removal of mud, oil and grease.
Fresh water hosing - Epoxy high build Apply as:
Removal of water - Epoxy mastic 1x stripe coat
Drying by means of dehumidifiers (surface tolerant) 1 coat
10 ± 3
Climatic control -Epoxy tar 1x stripe coat
Blast cleaning to Sa 2 ½ -Poly urethane tar 1x coat
The chloride content on surface to be coated shall be within the = 300 µm DFT
limits set by the coating manufacturer.
Removal of mud, oil and grease. Apply as:
Fresh water hosing -Epoxy high build 1x stripe coat
Removal of water -Epoxy mastic 1 coat
Drying by means of dehumidifiers (surface tolerant) 1x stripe coat
15 ± 3
Climatic control -Epoxy tar 1x coat
Blast cleaning to Sa 2 ½ -Poly urethane tar 1x stripe coat
The chloride content on surface to be coated shall be less than 50 1x coat
mg/m2 according to the Bresle method. = 450 µm DFT
Apply as:
-Epoxy high build 1x stripe coat
-Epoxy mastic 1 coat
As for 15 ± 3 years ,but pre-treatment and environmental control
(surface tolerant) 1x stripe coat
> 15 should by optimal and in full compliance with the requirement to
-Epoxy tar 1x coat
Sa 2 ½ for a surface with minimal pitted areas
-Poly urethane tar 1x stripe coat
1x coat
= 450 µm DFT

Table 8 Maintenance coating and service life for cargo holds (ref. /7/)
Service life Pre-treatment Coating system Comments
(years) Alternatives*
-Vinyl Epoxy’s applied:
Removal of mud, oil and grease.
-Chlorinated rubber 1x stripe coat
Fresh water hosing
-Epoxy mastic 1x coat
5±3 High pressure hydro-jetting
(surface tolerant) 1x stripe coat
Drying
-Polyurethane 1 x coat
Brushing to St 3 or blast cleaning to Sa 2 ½
-Epoxy HB = 300 µm DFT
Epoxy’s applied:
-Vinyl 1x stripe coat
Removal of mud, oil and grease.
-Chlorinated rubber 1x coat
Fresh water hosing
-Epoxy mastic 1x stripe coat
10 ± 3 High pressure hydro-jetting
(surface tolerant) 1x coat
Drying
-Polyurethane 1x stripe coat
Blast cleaning to Sa 2 ½
-Epoxy HB 1 x coat
= 450 µm DFT
Glass flake
Removal of mud, oil and grease. As for 10 ±3 years or:
applied:
Fresh water hosing -Epoxy glass flake
1x coat
> 10 High pressure hydro-jetting -Polyester glass flake
1x stripe coat
Drying Zinc epoxy
1 x coat
Blast cleaning to Sa 2 ½ Zinc silicate
= 400 µm DFT
*
Coating selected to be appropriate for the given cargo to be carried

Table 9 Anode replacement decision table


Measured Potential (mV) Colour code Action
Ag/AgCl
More negative than-900 Green Leave
More positive than -900 Amber Monitor and plan for retrofit
more positive than -800 Red Replace immediately

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