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AITS 1819 FT X ADV PAPER 1 Sol
AITS 1819 FT X ADV PAPER 1 Sol
AITS 1819 FT X ADV PAPER 1 Sol
JEE (Advanced)-2019
PAPER – 1
SECTION – A
1. B, D
Sol.
A B C A C B 0
C.B A CA B B.C A B.A 0
B.A C CA B 0
A BC 0
2. A, D
Sol. Uy V0 sin
Ux V0 V0 cos
Uy
tan
Ux 2
When throwing point and two stones are collinear
y1 y 2 2V0
t tan (where top point of pole is origin and x1, x2, y1, y2 are measured
x1 x 2 g 2
from there)
1
and h gt2
2
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 2
3. A, C
Sol. kx R kR2
I kR2
MR2
mR2 kR2
2
M
m
T 2 2
k
4. A, D
Sol. Basic concept of charging and discharging.
5. B
Sol. Shape of conductor does not make any difference.
6. A, B, D
Sol. Theory of wave optics
7. B
8. B
Sol. for (7-8)
660
v m/s
31
If duration of beep is t
then
330t 100
v 330 v
9. B
10. D
Sol. for (9 – 10)
Total charge in an element = Rd 0 sin
Rd 0 sin
On revolving this ring we get a sphere of charge density = which is a constant.
2R sin Rd
Basic concept of potential
VA VB E.R
SECTION – D
11. 00060.00
Sol. a2 a2 2a2 cos 180 a
= 60
12. 00012.50
Sol. For equilibrium centre of mass should be on the wire.
13. 00025.02
dh 2g h 76
Sol.
dt n2 1
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3 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
0.76 5
dh 2g dt
0.96
h 76
0 n2 1
14. 00015.00
Sol. Calculate by potential method.
15. 00004.00
Sol. fBeat f1 f2
c c
f f
c v c v
2fv
fbeat
c
16. 00017.50
Sol. Object must be at 2f distance of combination
1 2 1
fnet fL fM
17. 00001.00
edV eV r
Sol. F 00
dr r
mv 2 eV0r0
r r
v = constant
nh
mvr =
2
rn
evr
M Mn
2
18. 00001.50
Sol. Constraint at contract point
/2
cos30 v v
2
energy conservation 30
1 1
mg mv 2 I2
4 2 2
g
v g
26
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 4
Chemistry PART – II
SECTION – A
19. C, D
Sol. As per Usanovich concept, in the first reaction As2S3 will behave as a acid and (NH4)2S will
behave as a base. Similarly in second reaction Fe(CN)2 is acid and KCN is base.
20. B
Sol.
H
Aromatic
21. A
Sol.
Cl Cl
xy plane
yz plane
Cl Cl zx plane
22. C
Sol. Equilibrium constant for the formation of a hydrate electron deficient nature of the carbon of
carbonyl group (C = O). In the fourth compound the carbon of carbonyl group will be more
electron deficient.
23. A, B, C, D
Sol. Properties of orthoboric acid.
H3BO3 B2 O3
24. A, C
Sol. O O
HO P P OH Hypophosphoric acid
OH OH
It is tetrabasic
No P–O–P linkage
P atoms show maximum covalency
O. S. of P is 4
25. C
26. A
Sol. FeCl3 Yellow solution and does not react with dil H2SO4
2Fe3 H2S
H
2Fe2 S
U
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5 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
Fe3 3NaOH Fe OH3 3Na
(excess)
Brown ppt ( V )
27. B
28. D
Sol. N N CH3 N N CH3
H3C H3C
2+ 2+
Pt Pt
N N CH3 N N CH3
H3C H3C
Optically inactive Optically active
N N CH3 N N CH3
H3C H3C
2+ 2+
Pt Pt
N N CH3 N N CH3
H3C H3C
Optically inactive Optically active
N N CH3
H3C
2+
Pt
N N CH3
H3C
Optically inactive
SECTION – D
29. 00002.22
Sol.
N2
2N
2.8
0
28
2.8 50 2.8 50
2
28 100 28 100
3
Total moles =
20
PV = nRT
3
P 10 0.082 1805
20
P = 2.22
30. 00036.36
Sol. Fe + Fe2(SO4)3 3FeSO4
1.25 gm ferric alum produces 0.5913 gm FeSO4
Meq of FeSO4 = Meq of KMnO4
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 6
0.5913
1000 0.107 V
152
V = 36.36 ml
31. 00001.25
Sol. There are four co-ordination isomers are possible for the given complex. These are
Cu NH3 4 PtCl4 , Cu NH3 3 Cl PtCl3NH3 ,
Cu NH3 Cl3 Pt NH3 3 Cl , CuCl4 Pt NH3 4
32. 00009.50
Sol.
HA
H A
H CK a
Ka 108
BOH
B OH
OH CK b K a K b
= 10 9
1014
H 9
10 2
= pH = 9.50
33. 00001.25
Sol. As we know,
t1/2 a10 n
1 n
t1/2 c. a0 c constant
log t 1/2 log c 1 n log a0
1 n tan 45o 1 n 1 n 0
Now, for K,
As we know for zero order reaction,
a0
t1/2
2K
a 1
log t1/2 log 0 loga0 log … (1)
2K 2K
From graph,
1
log 2
2K
1
K moll1 sec 1
200
1
250 K 250 1.25 mol / l / sec
200
34. 00155.88
a 3
Sol. 2r
4
2r = 155.88 pm
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7 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
35. 00003.63
Sol. For a polyprotic process:
x
PV = K [x 1, ]
R
C = CV,m +
1 x
3 R
C R
2 3
11R 11 1.98
3.63
6 6
36. 00001.60
Sol. P is:
Ph
D
HO Ph
Me
OH
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 8
SECTION – A
37. C, D
x x2 x 2 x3
x a 1 ..... b x ..... 5
ae bln 1 x 5
Sol. L lim 2
L lim 1! 2!
2
2 3
x 0 x x 0 x
a = –5, b = 5, L = –5
38. A, B, C
3
n
n
Sol. Let lim 1 tan4 k L L lim cos cos k
n
k 3 2 n 4 k 3 2
sin x x sin x x
As cos k cos k
x k 1 2 x x k 3 2
x cos cos
2 4
3
sin x
x
x 2 2 1 3
lim lim cos k cos 2k L
x x x x
k 3 2 k 3 22 2 32
x cos cos
2 4
39. A, B
Sol. Let a1 = a and b2 – a1 = d (a + 4d)2 = (a + 2d)(a + 7d) a = 2d
9
Also, a9 = 40 a + 8d = 40 a = 8, b = 4 ai2 6144
i 1
b2 3 1 1
Also, b1 = 54,
b1 2
b
18
i 1 i
40. B, D
m m
Sol. A = Coefficient of xm – 2 in 1 x x 1 m C0 m C2 A 2m
Cm 2 m C2
41. A, B, C, D
Sol. Exponent of ‘2’ is same in 15!, 14!·1!, 13!·2!, .....
Number of values of ‘r’ = 16 k = 16
42. A, C, D
z z1
Sol. Arg 0 or
z2 z3
43. D
x x
20
a0 a1x a2 x ..... a125 x dx x x 2x 3x 1
2 125 3 5 6 4
Sol. dx
0 0
21
x2 x3 x4 x126 2x6 3x 4 1 1
a0 x a1 a2 a3 ..... a125
2 3 4 126 252
2x 6 3x 4 121 1
In the expansion of , we have only even powers of ‘x’
252
a0 = a2 = a4 = ..... = a124 = 0
44. D
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9 AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19
n 2k 2 2 2k 12
P 2 2
k 1 2k 2k 1
02 12 22 32 42 52 2n 2 2 2n 12
P .....
22 32 42 52 62 72 2n 2 2n 12
1 1
P 2
2 k1 = 8, k2 = 4, k3 = 1
2 8n 4n 1
4n 2n 1
k1 + k3 – k2 = 5
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AITS-FT-X (Paper-1)-PCM(Sol.)-JEE(Advanced)/19 10
49. 00001.00
iy x
Sol. 56x 33y i 2 2
, 33x 56y (z = x + iy)
x y x y2
2
x iy
56iz 33z
x2 y2
1 1 1 7 4i
56iz 33z z2 z
z 33 56i 7 4i 65
11 p
x y 6p – q = 66 – 65 = 1
65 q
50. 00041.00
1 1 1
Sol. x2 2 b a x 0 x t
x x x
t2 + at + b – 2 = 0 at + b + t2 – 2 = 0, t2 [4, )
This represents equation of line in a-b plane and a2 + b2 represent square of distance of a point
on this line from O (origin)
t2 2 2
d t2 [4, ), dmin at t2 = 4
2 5
1 t
2 4 p 2 2
dmin p + q = 41
5 q
51. 00010.00
n n 1 1 31
Sol. P(tail) = 1 n = 10
2n 1 2n 1 2 42
52. 00008.00
Sol. Let a a1ˆi a2 ˆj a3kˆ
b b1ˆi b2 ˆj b3kˆ
c c1ˆi c 2 ˆj c 3kˆ
a b D1ˆi D2 ˆj D3kˆ
a b D12 D22 D32 4
c c12 c 22 c 32 2
Maximum value of a b c a b c 4 2 8
53. 00001.00
Sol. x
2
4
1
2x 2 1 3 1 dx
0
3
x 1 2 1dx 1
1 1
2 1 0 3
x 2x 2 1 dx
4 3 x 1 2 1dx 1 2 1 I 2
1 1
54. 00004.00
Sol. Put ex = t ex dx = dt
2e5x e4 x 4e3x 4e2x 2ex 1 e
x
1
dx tan c
e2x 4 e2x 12 2 2 e2x 1
a+b=4
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