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KENDRIYA VIDYALAYA SANGATHAN
CHANDIGARH REGION
SUBJECT:CHEMISTRY

TIME :3HRS M M:70

GENERAL INSTRUCTIONS:

I. All questions are compulsory.

II. Question no. 1 to 5 are very short answer type questions and carry 1 mark each.

III. Question no. 6 to 10 are short answer type questions and carry 2 marks each.

IV. Question no. 11 to 22 are also short answer type questions and carry 3 marks each.

V. Question no. 23 is value based question and it carries 4 marks.

VI. Question no. 24 to 26 are long answer type questions and carry 5 marks each .

VII. Use log table if necessary. Use of calculator is not allowed.

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Q1) What is the maximum number of electrons in a d-subshell with same spin?

Q2) What will be the minimum pressure required to compress 500dm3 of air at 1 bar to 200

dm3 at 30 o C?

Q3) Draw the Lewis structure of CO32-?

Q4) Find the oxidation number of Cr in Cr2O72- ?

Q5) How does H2O2 behave as bleaching agent?

Q6) Calculate the number of atoms in a)52 moles of He. b) 52u of He?

Q7) What do you understand by isoelectronic species? Name the species that will be

isoelectronic with a) F- b) Rb+.

Q8) Which out of NH3 and NF3 has higher dipole moment and why?

Q9) Write structural formulae of the following compounds-

a) 3,4,4,5-Tetramethylheptane.

b) 2,5- Dimethylhexane.

OR

a) o-Ethylanisole

b) 2,3-dibromo-1-phenylpentane

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Q10) How are classical smog and photochemical smog different?

Q11) State Heisenberg’s uncertainty principle? Calculate the uncertainty in position of a dust

particle with mass equal to 1 mg, if uncertainty in its velocity is 5.5 X10-20 ms-1.

Q12) Arrange the following in their increasing order

a) B, Al, Mg, K (metallic character)

b) B, C ,N, F, Si (Non-metallic character)
c) F, Cl , O, N (Chemical reactivity in terms of oxidizing property)

OR

Explain in brief for the following-

a) Anions are bigger in size than their parent atom.

b) Oxygen has lesser first ionization energy than nitrogen.
c) Fluorine has less negative electron gain enthalpy than chlorine.

Q13) Define the following-

a) Critical temperature

b) Avogadro’s Law

a) Charle’s Law

Q14) Enthalpies of formation of CO (g), CO2(g) , N2O(g) and N2O4(g) are -110, -393, 81, and

9.7 kJmol-1 respectively. Find the value of ΔrH for the reaction.

N2O4 (g) + 3CO (g) N2O (g) + 3CO2 (g)

Q15) Nitrogen and Hydrogen react to form Ammonia as per the reaction:-

N2(g) + 3H2(g) 2NH3(g) + Heat

When the mixture of these three gases are in equilibrium, predict whether the amount of

ammonia increases or decreases if :–

a) The pressure is increased.

b) The temperature is raised.
c) The concentration of Hydrogen is increased.

Q16) Balance the equation in basic medium by ion electron method-

P4(s) + OH- (aq) PH3(s) +H2PO2-(aq)

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Q17) Give reasons-

a) Potassium and caesium, rather than lithium are used in photoelectric cells.
b) Alkali metal dissolved in liquid ammonia gives blue colour, but its colour changes to bronze when
concentration is increased.
c) Be and Mg do not impart colour to the flame, whereas other alkaline earth metals do so.

Q18) Write the composition of cement? How it is manufactured and what is the purpose of

adding gypsum in cement?

Q19) Write balanced equations for-

a) BF3 +LiH
b) SiO2 + NaOH
c) B2H6 + H2O

Q20) When metal X is treated with sodium hydroxide, a white precipitate ( A ) is obtained,

which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble

in dilute HCl to form compound (C). The compound (A) when heated strongly gives (D),

which is used to extract metal. Identify X, A, B, C & D. Write suitable equation to

support their identities

Q21) Explain with example-

a) Wurtz reaction b ) Acidic dehydration c) Markownikov’s rule.

Q22) What do you mean by green chemistry? How will it help decrease environmental

pollution?

Q23) In the school laboratory, the chemistry teacher instructed the laboratory attendant to

store a liquid solution of a compound made up of hydrogen and oxygen elements in

brown bottles in dark room . He also told to add some urea to it and keep it free from

dust. The substance can act an oxidizing agent and reducing agent both in acidic and

alkaline media .

Answer the following questions:-

a) Name the liquid substance.

b) Give its structure.
c) What values does it carry in pollution control of domestic and industrial effluents.

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Q24) a) Define solubility product.

b) Write the application of solubility product, in predicting the precipitation of salt.

c) Calculate the solubility of A2X3 in pure water, assuming that neither kind of ions reacts with water. The
solubility product of A2X3 , Ksp= 1.1 X 10-23.

OR

a) Define pH of a solution.
b) Assuming complete dissociation, calculate pH of 0.03M HCl.
c) Calculate the pH of 0.3g of Ca(OH)2 dissolved in water to give 500ml of the solution.
d) What is the effect in pH on diluting an acid.

Q25) a) What are the hybridization state of each carbon atom in CH2=CHCN.

b) Explain the term inductive effect.Also explain the correct order of acidity of the
carboxylic acid in-

(i) Cl3 CCOOH, Cl2CHCOOH, ClCH2COOH.

(ii) CH3CH2COOH, (CH3)2CHCOOH, (CH3)3CCOOH.

c) On what principle chromatography technique is based?

OR

a) Draw the resonance structure of C6H5NH2.

b) Define electrophile and nucleophile. Give two examples of each.
c) In sulphur estimation, 0.157g of an organic compound gave 0.4813g of barium sulphate. What is the
percentage of sulphur in the compound,(M.M of Ba=137u, S=32u,O=16u)

Q26) a) Bring out the following conversions :-

i) Methane to ethane
ii) Ethane to Ethene

b) Propanal and pentan-3-one are the ozonolysis products of an alkene ? What is the

structural formula of the alkene?

(c) Why is benzene extra ordinarily stable though it contains three doule bonds?

OR

a) Write IUPAC name of the products obtained by ozonolysis of 3,4- Dimethylhept-3-ene.

b) Draw the cis and trans structure of hex-2-ene. Which isomer will have higher boiling pointing and Why?
c) How will you convert:- (i) Benzene to p-Nitrobromobenzene
(ii) Hexane to Benzene.

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MARKING SCHEME
CLASS=XI SUB- CHEMISTRY
Q No Answer Distribution
of marks
1 5 1
2 Formula P1V1=P2V2 (1/2+1/2)
P2= 2.5bar
3 Correct structure, 1
4 +6 1
5 Bleaching action of H2O2 is due to nascent oxygen liberated on its 1
decomposition,
H2O2H2O +[O]
6 a) 5.2x6.022x10-23 =3.1x10-22atom 1+1
b) 52/4= 13atom
7 Correct definition 1+1/2+1/2
Ne,Na+,Mg2+,Al3+(Any one)
Br-,Kr,Sr2+(Any one)
8 NH3 ½+1/2+1
Structure of NH3 and NF3
Correct explanation
9 Correct structures 1+1
10 Any two correct differences 2
11 Correct definition
Δx.m Δ v=h/4π
Δx= 9.6x -10
12 Correct order 1+1+1
13 Correct definitions 1+1+1
14 Correct formula 1+1+1
Steps
=-777.7kJmol-1
15 a. Increases 1+1+1
b. Decreases
c. Increases
(with accurate reasons)
16 Steps 2+1
P4(s) + 3OH-(aq)+3 H2O(l)  PH3(g) +3H2PO2-(aq)
17 a. K and Cs have much lower I.E than Li, as a result these metals
on exposure to light lose electrons much easier than Li. 1+1+1
b. Due to ammoniated electrons
c. Due to small size of Be and Mg, they have high I.E, need large
amount of energy for excitation of electrons to higher energy
level.
18 -Composition of cement= Limestone, clay and gypsum 1+1/2+1/2+1
CaO, SiO2, Al2O3, MgO, Fe2O3
-Formation of clinker
-Addition of gypsum
-Gypsum slows down the setting of cement
19 a. 2BF3 +6LiH  B2H6 +6LiF 1+1+1
b. Na2SiO3 + Water

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c. B2H6 +6H2O  2H3BO3 + 6H2

20 Reactions 2
X= Aluminium
A= Aluminium hydroxide
B= Sod.tetrahydroxoaluminate(III) 1
D= Aluminium oxide

21 Correct explanation 1+1+1

22 -A program of developing new chemistry products and chemical 2+1
processes or making improvement in the already existing compounds
and processes so as to make them less harmful to human health and
environment.
-Any two points to decrease pollution
23 -H2O2 1+1+2
-correct structure
-Any two values.
24 a. Correct definition 1+2+2
b. If calculated ionic products>Ksp , precipitation takes place. If
calculated ionic products<Ksp, No precipitation
c. Correct solution
OR a. Correct definition 1+1+2+1
b. [H+] =[HCl] = 3x10-3 M, pH=2.52
c. [Ca(OH)2]=0.3/74 X1000/500
[Ca(OH)2]= Ca2+ +2OH-
[OH-] =2[Ca(OH)2]= 2x 0.008M
=1.6 x 10-2 M
P[OH-] =1.79
pH =14- 1.79
=12.21
d. increases
25 a. SP2,SP2,SP 1+3+1
b. Correct definition with correct explanation
c. Differential partitioning of components of mixture between
stationary and mobile phase
OR a. Correct structure
b. Correct definition with example
c. Molecular mass of BaSO4= 233
233g of BaSO4contain 32g of S
0.4813g of BaSO4 contain= 32 x 0.4813/233
Percentage= 42.10 %
26 a. Conversions 2+2+1
b. Structure of A
c. Correct answer
OR a. CH3CH2CH2COCH3 and CH3CH2COCH3 2+1+2
b. Structures , Trans
c. Conversion

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