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1108-Article Text-5052-1-10-20190319 PDF
1108-Article Text-5052-1-10-20190319 PDF
Southeast Asia and western Africa, it has soft wood; high, considered as a solid waste disposal technique, [14].
branching limbs; and a large area of bark. The milky liquid Furthermore charcoal production undergo a lot of processes
(latex) that oozes from any wound to the tree bark contains as is shown by [15].
about 30 percent rubber, Latex can also be concentrated for A good quality charcoal should have a moisture content of
producing dipped goods, such as surgical gloves. about 5-15% of the gross weight of charcoal, and an ash
Natural rubber is an indispensable material for many content of about 3%. According to the Ukra Biofuel news
industrial applications such as in tires and medical devices report, the surface area per gram of materials can range from
[7]. Although more than 2500 plants produce latex, currently 500 to 1400 square meters. The conventional process of
the Pará rubber tree (Hevea brasiliensis Muell.Arg.) is the producing charcoal, is through methods such as earth pits or
only main commercial source for rubber production [8]. Even brick kilns, in which the energy required to produce the
when compared with oetrochemically synthesized rubber, carbonization, is obtained from the combustion of a part of
natural rubber showed better advantage interns of its the wood, which leads to a considerable decrease in the net
spasticity, adhesion and durability. Rubber trees are production of carbon, [16].
susceptible to several fungal infections including South
American leaf blight (Microcyclus ulei) and different II. MATERIALS AND METHODS
cultivars show different sensitivity, [9].
The materials used for this research includes engine oil,
Inks are used for different purposes ranging from printing, ethanol, gum Arabic, seal containers, empty refillable
colouring, etc, to writing; Different inks are produced to suit marker, mango wood, Oil bean (Ugba) wood, rubber wood,
different purposes and conditions. The basic raw materials for gas burner, cylinder, incinerator, pH meter, redwood
ink production are pigments, binders, solvents and additives, viscosity equipment, pycnometer.
and these materials are either sourced for and purchased
locally or overseas by manufacturers.
Ink, also called masi, is a mixture of several chemical A. Pyrolysis
components, which has been used in India since at least the In order to achieve an end product called charcoal, woods
4th century BC. According to [10], the practice of writing of mango, Oil bean and rubber were pyrolized differently.
with ink and a sharp pointed needle was common in early This was required in order to trap the carbonated gas present
South India for Several Jain sutras (a religious hand written in the woods from polluting the environment.
compilation). The knowledge of the inks, their recipes and the
techniques for their production comes from archaeological
analysis or from written text itself. As referenced by [11]. B. Crushing
Since the 23rd century BC, Chinese inks can be traced with The pyrolyzed product of wood was firstly broken down to
the utilization of animal, natural plant (plant dyes), and smaller particles using a rod. The smaller particles were
mineral inks based on materials such as graphite that were subjected to a crusher which crushed the charcoals to fine
blended with water and applied with ink brushes. The earliest particles.
Chinese inks, similar to modern ink sticks, showed up around
256 BC in the end of the Warring States period and it was
obtained from soot and animal glue. Resin from the pine tree C. Sieving
presents the best inks for drawing or painting on paper or silk. The crushed materials were sieved differently using a
They must be between 50 and 100 years old. 7.5um sieve. This was done to enable the charcoal be in its
The traditional Chinese method of making ink was to grind finest state.
a mixture of hide glue, carbon black, lampblack, and bone
black pigment with a pestle and mortar, then pour the mixture D. Ink Production
into a ceramic dish where it could dry. To use the dry mixture,
The addition of pigment with ethanol in its required mass
a wet brush would be applied until it reliquaries, [12].
and volume were added together in order to dissolve the
In the mid 1990’s dry erase markers became popular and
pigment. The dissolved pigment with ethanol was added with
these markers are better than chalk in so many different ways
some amount of gum Arabic and required volume of used
especially that they are easy to erase, they can be applied to
lube oil. A mix ratio of 6ml of charcoal to 20ml of used lube
the board with less pressure and they are unaffected by water.
oil was mixed in a container and then 20ml of ethanol was
It is worthy of note to say that this type of markers is made
added to the solution and a pinch of gum Arabic was added
basically for non porous surfaces such as mirrors, metals, and
and then the solution was stirred until a homogenous solution
opaque glass materials. The ink is made from color pigments.
was obtained. The product was continuously stirred and
Chemical solvents and a polymer also called a release agent.
further sieved with a white handkerchief to further remove
According to [13], charcoal is the solid carbon residue
the residue that was present in the solution. Alternatively, in
following the pyrolysis (carbonization or destructive
place of engine oil, some quantity of distilled water was used
distillation) of carbonaceous raw materials. Principal raw
in order to checkmate the best production. It was discovered
materials are medium to dense hardwoods such as beech,
that production of ink using distilled water was not a better
birch, hard maple, hickory, and oak. Others are softwoods
one than engine oil because distilled water is not a binder and
(primarily long leafy and slash pine), nutshells, fruit pits,
as such, was not suitable for use.
coal, vegetable wastes, and paper mill residues. Charcoal is a
highly porous and brittle material used primarily as a fuel for
outdoor cooking. In some instances, its manufacture may be
𝐶 = 𝐾𝑇 𝑛 (1)
Fig. 1. Block diagram for local ink production 𝐿𝑜𝑔𝐶 = 𝐿𝑜𝑔 𝑘 + 𝑛 𝐿𝑜𝑔 𝑡 (2)
b. Exponential Model
E. H
P Test This research further utilized the exponential model to
develop an empirical or theoretical model, using an
pH test was conducted on the different products of ink for equation of the form
rubber, ugba and mango charcoal respectively, using a pH
meter and their values recorded. Comparing the result of the
𝑌 = 𝐾𝑒 𝑎𝑥 (3)
pH of the three charcoals to that of ink produced with
crystalline dye which has a pH value of 7.94, showed that
Writing the above equation in terms of concentration and
production of ink with Ugba (Oil bean) charcoal, rubber
time gives
charcoal and mango charcoal was better since the pH of the
three products is 7.0 by approximation which indicates that
𝐶 = 𝐾𝑒 𝑎𝑡 (4)
they are all neutral and not harmful to human health but that
of the crystalline dye ink is alkaline in nature.
Where the equation above can be rewritten using the
inverse exponential method as
F. Viscosity Test
In order to ascertain the viscosity of the products, redwood 𝐿𝑛 𝐶 = 𝐿𝑛 𝐾 + 𝑎𝑡 (5)
viscosity equipment was used to ascertain the volumetric
flow rate of the products. The values of the volumetric flow
were traced on a chart that has a relation of viscosity and III. RESULTS AND DISCUSSION
volumetric flow rate. The result of the various tests as well as the initial and final
concentration of the ink is as shown.
G. Density Test
Pycnometer was used to conduct density test of the A. Results Characterisation
different samples. The empty pycnometer was initially The result of the atomic absorptive spectrometer analysis
weighed to ascertain its weight. Thereafter, the samples were is depicted in Fig. 2 below as.
weighed accordingly to know the weight of the product by as
well subtracting the total weight of the product from the
weight of the empty pycnometer. The final density 0f the
different ink samples obtained for the three charcoal products
were obtained using the formula.
Fig. 3. Graph showing the Carbon Content of Oil Bean Charcoal, Mango
Tree Charcoal and Rubber Tree Charcoal.
TABLE I: COMPARISON OF MANGO WOOD CHARCOAL INK, RUBBER WOOD CHARCOAL INK AND UGBA (OIL BEAN) WOOD CHARCOAL TO
DOLLAR-DRY ERASE INK AND HI-SHINE INK
Substance Mango Rubber Ugba(Oil Dollar- Hi- Percentage (%)
Charcoal charcoal Bean) dry Ease Shine Deviation
Ink Ink Charcoal Ink Ink
Ink
Colour Black Black Black Black Black
Odor Almost Almost Almost Almost Almost
odorless odorless odorless odorless odorless
Hazardous
Reaction Non Non Non Non Non
TABLE II: COMPARISON OF MANGO TREE CHARCOAL INK, RUBBER TREE CHARCOAL INK AND UGBA (OIL BEAN) TREE CHARCOAL TO DOLLAR-DRY ERASE
INK AND HI-SHINE INK AT DIFFERENT TEMPERATURE AND DYNAMIC VISCOSITY
Dynamic Viscosity Of
Dynamic Viscosity of
Dynamic Viscosity of
Charcoal
DynamicViscosityof
Dynamic Viscosity
Temperature (oC)
Percentage(%)
Hi-Shine Ink
(Oil Bean)
of Ugba
Ink
20 8.675 7.578 5.567 5.623 5.751 0.01
25 8.234 7.564 4.826 5.241 4.875 -0.09
30 7.985 6.345 4.223 4.345 4.177 -0-03
35 6.457 5.634 3.912 3.836 3.615 0.02
40 5.569 4.341 3.323 3.243 3.156 0.02
Table II shows the effect of temperature on the dynamic C. Volumetric Flow Rate
viscosity of the locally produced inks as compared with two
TABLE III: Volumetric Flow Rate of various Ink Samples
foreign inks. The results show a decrease in dynamic
Volumetric Flow Volumetric Flow Volumetric Flow
viscosity of the inks as temperature increases. The dynamic
Rate of Ugba (Oil Rate of Rubber Rate of Mango
viscosity of Mango charcoal ink and Rubber charcoal ink had
Bean) Charcoal Charcoal Charcoal
a higher range when compared to that of Dollar-dry erase ink
(cm3/min) (cm3/min) (cm3/min)
and Hi-shine ink. The result while that of oil bean tree shows
12 12 11
a good match. From these result, it can be clearly stated that
8.5 10.5 7.5
ink of oil bean charcoal is of better standard when compared 8.3 14.5 8.0
with international standard. 7.5 8.75 7.25
7.8 7.9 7.4
B. Variation of Concentration of Ink with Time
From the plot of Fig. 5, it would be seen that concentration
increased with increasing time for the various species From Table III, it is seen that the volumetric flow rate of
sampled. Results reveal that the concentration of ink obtained the charcoals progressively decreased from the first two
from rubber wood charcoal was greater than that of oil bean values in all the three products but increased at a particular
and mango wood charcoals. However, the ink obtained from stage and later diminished again.
oil bean charcoal gave the best result as the required D. Space Time
concentration should not be too high. The variation also The result of the space time in Table IV shows that the space
observed here can be attributed to the variations in the time for oil bean increased without any fluctuation but that of
characteristic parameters of the various species sampled or rubber and mango experienced an fluctuation in their space
more. time.
equation of line for the oil bean charcoal ink while the value F. Comparison between Experimental and Theoretical
of the best fit is given by the square root of 𝑅2 = 1, 𝑦 = Concentration of ugba (oil bean) charcoal ink
19.86𝑒 0.155𝑥 , representing the equation of line for the
Rubber charcoal ink, with the best fit 𝑅2 = 1 and 𝑦 =
16.79𝑒 0.154𝑥 and , representing the equation of line for the
Mango charcoal ink, with the best fit 𝑅2 = 1. Result
revealed that the theoretical exponential model could be
used to predict the concentration of the various species of
inks. Although the different ink products followed the same
trend, there is a slight difference in their exponential
performance. This result showed that the Rubber charcoal
ink had the highest concentration but the Ugba (oil bean)
charcoal ink had the best concentration required for writing.
Fig. 6. Concentration of Ugba, Rubber and mango wood charcoal ink with
Time
Fig. 6 shows the graph of the empirical or theoretical
computation for the values of the concentration of the
different ink samples. The graph shows that the Rubber wood
charcoal ink gave the highest concentration, however the
Ugba (oil bean) charcoal ink gave the best concentration
suitable for writing on a white non porous board.
Fig. 8 demonstrates the relationship between the I. I. Empirical Concentration for ink obtained
concentration of Rubber wood Charcoal based ink and time. from Mango Wood Charcoal ink
Increase in concentration was observed with increase in time
as demonstrated using the Power Model equation. The
equation of line for power model, revealed that
y=1.512x+2.700 with the square root of the best fit R2=0.996.
The variation in the concentration of the Rubber wood ink can
be attributed to the variation in time.
H. Comparison between Experimental and Theoretical
Concentration of Rubber Charcoal ink using Power
Model.
Fig. 10 Concentration for ink obtained from Mango Wood Charcoal ink
of the best fit R2=0.977. the result revealed that the [9] Lieberei, R. (2007). South American leaf blight of the rubber tree
(Hevea spp.): new steps in plant domestication using physiological
experimental data is more reliable than the theoretical data, features and molecular markers. Ann Bot.;100(6):1125–42.
however the behavior of both the theoretical and the [10] Woods, M. & Woods, M. (2000). Ancient Communication: Form
experimental show a good match, because they followed the Grunts to Graffiti. pp 51-52. Minneapolis: Runestone Press; an imprint
same trend, although there is a slight difference in their of Lerner Publishing Group.
[11] Gottsegen, M. D. (2006). The Painter's Handbook: A Complete
percentage of performance. This result shows that the Reference Page 30, New York: Watson-Guptill Publications. ISBN 0-
experimental model can be used for monitoring, predicting 8230-3496-8.
and simulating the characteristics of ink flow with respect to [12] Bosworth, C. E. (2004). A Mediaeval Islamic Prototype of the Fountain
Pen? Journal of Semitic Christian Science Monitor ‘Think ink’
time. The theoretical expression used is given as Log C=Log September 21.
2.998+0.739 Log t. Whereas the experimental expression [13] Shreve, R. N. (1967). Chemical Process Industries, Third Edition,
used is Log C indicating C values as experimental data. McGraw-Hill, NY, 1967.
[14] Scott, A. C. & Damblon, F. (2010). Charcoal Taphonomy ans
Significancein Geology, Botany and Archeology. Palaeogeogr.
Palaeocl., 291, 1-10.
IV. CONCLUSION [15] Novak, M. & Wilensky, U. (2007). Net logo/connected chemistry/solid
combustion model..
The pyrolysis that was done on the different woods gave a [16] Ramos, G., & Perez-Marquez, D. (2014). Design of Semi- Static
better result since the end product called charcoal was derived Concentrator fpr Charcoal Production. Ernerg. Proc., 57, 2167-2175.
after the process. The result of the PH, Viscosity, Volumetric
flow rate and Density test that was conducted on the produced
oils showed a range of values for the ink produced.
Furthermore, a better match in oil bean charcoal ink was Kenneth Kekpugile DAGDE, a Nigerian and
holder of B Tech, M Tech, Ph.D in chemical
observed when compared to the ink of international standard engineering from Rivers State University, Nigeria.
but higher values in the case of Mango and Rubber charcoal An academician with over 19 years varied
ink was recorded. Finally, The comparison showed that the experience in Chemical Process modeling,
simulation and optimization with over fifty
ink of oil bean charcoal is a better product. research publications in both local and
The model developed showed that the final concentration international journals. A registered Engineer and a
of produced ink can be predicted theoretically in future member of Nigerian Society of Chemical
Engineers. Friendly disposition and multitask
ability.
Author’s formal
ACKNOWLEDGMENT photo
We wish to thank the Lord, God Almighty for his grace and
mercies He has shown from the beginning of this research to
the end. We are also grateful to the Head of Department,
Chemical/petrochemical Engineering, Rivers State
University, Prof. Ukpaka. C. P. for his understanding,
guidance, constructive criticisms, patience and
encouragement. Thanks also go to Chief Tony Nwosa, Prof.
Millionaire Abowei and to all the lecturers and staff of the
Department of Chemical/petrochemical Engineering for their
inputs from the beginning of the research to the end.
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