KIM3002 ‘SULIT enrol rrs Es UNIVERSITI MALAYSIA TERENGGANU PEPERIKSAAN AKHIR FINAL EXAMINATION SEMESTER I SESI 2018/2019 (SARJANA MUDA) SEMESTER I 2018/2019 SESSION (DEGREE PROGRAMME) NAMA KURSUS PENGURUSAN DAN KESELAMATAN BAHAN COURSE KIMIA ‘CHEMICAL MANAGEMENT AND SAFETY KIM3002 KOD KURSUS COURSE CODE TARIKH 1 9 JANUARI 2019 (RABU) DATE 9 JANUARY 2019 (WEDNESDAY) TEMPAT : DEWAN SULTAN MIZAN (DSM) VENUE MASA : 3,00 — 5.00 PETANG (2 JAM) TIME 3.00 — 5.00 PM (2 HOURS) NO. MATRIK STUDENT NO. NAMA PROGRAM PROGRAMME NO. MEJA SEAT NO. ARAHAN KEPADA CALON INSTRUCTIONS TO CANDIDATES i. Sila jawab semua soalan Answer all questions ii, Semua jawapan hendaklah ditulis dalam buku jawapan yang disediakan All answers must be written in provided answer booklet JANGAN BUKA BUKU SOALAN INI SEHINGGA DIBERITAHU DO NOT OPEN THE QUESTION PAPER UNTIL INSTRUCTED KERTAS SOALAN INI MENGANDUNGI 10 MUKASURAT BERCETAK THIS QUESTION PAPER CONSISTS OF (10) PRINTED PAGESKIM3002 SULIT PART B [70 MARKS] QUESTION 1 [20 MARKS] ‘Arman was using thermometer to check the temperature of chemical reaction for his experiment. Suddenly, the thermometer slip from his hand and broke causing mercury spill incident. During this incident happened, the oxygen levels in the laboratory is less than 19.5%. Note: MSDS of Mercury is provided at the end of this questions. (Arman menggunakan termometer untuk memeriksa suhu tindak balas kimia bagi eksperimennya. Tiba-tiba, termometer tergelincir darl tangannya dan pecah menyebabkan kejadian tumpahan merkuri. Semasa kejadian ini berlaku, paras oksigen dalam makmal kurang dari 19.5%. Nota: MSDS bagi Mercuri disediakan pada akhir soaan ini) a) Briefly, explain spill clean-up procedures for mercury. (Secara ringkas, jelaskan prosedur pembersihan tumpahan untuk merkuri) (S marks) b) Due to the incident of mercury spill, accident and incident investigation must be took place. The investigation steps has divided into seven major parts. Explain briefly THREE(3) major parts involved in the accident and incident investigation. (01 sebabkan kejadian tumpahan merkuri, kemalangan dan penyiasatan insiden ‘mest’ dilakukan. Langkah penyiasatan telah dibahagikan kepada tujuh bahagian utama. Jelaskan secara ringkas TIGA(3) bahagian utama yang terlibat dalam penyiasatan kemalangan dan insiden.) (6 marks) ©) Based on the Globally Harmonized System (GHS) pictograms (given from MSDS of Mercury) state the hazards caused by mercury. (Berdasarkan pictograms Sistem Harmonized Global (GHS) (diberikan dari MSDS Merkuri) nyatakan bahaya yang disebabkan oleh merkuri.) (4 marks) d) In the event of mercury release under 1 pound happened, the minimum ‘level C’ Personal Protective Equipment (PPE) is required. List the ‘level C’ PPE which is needed for this circumstance. (Sekiranya pelepasan merkuri di bawah 1 paun berlaku, Peralatan Perlindungan Peribadi (PPE) minimum Yahap C' diperlukan. Senaraikan PPE minimum ‘tahap C’ yang diperlukan untuk keadaan ini,) (4 marks) €) In the event of a mercury spill over 1 pound or when concentration of oxygen in atmosphere is less than 19.5%, state the level of Personal Protective Equipment needed. (Sekiranya beriaku tumpanan merkuri lebih 1 paun atau apabila kepekatan oksigen di atmosfera adalah kurang dari 19.5%, nyatakan tahap Peralatan Perlindungan Peribadi yang dipertukan.) (1 mark) 6/10KIM3002 SULIT MERCURY Sofaty Data Shoot SS Te TT ‘eoverem Aptis Cony Prone samen CHU) cron ee Perpainte encore wae rats rah eins HN 7/10KIM3002 ‘SULIT QUESTION 2 [20 MARKS] Chemical management is not only about the purchasing of the chemicals, but it also involves storage, usage and disposal. (Pengurusan bahan kimia bukan sahaja mengenai pembelian bahan kimia, tetapi juga ‘meliputi penyimpanan, penggunaan dan pelupusan.) a) List THREE(3) best practices for ordering and stocking the chemicals. (Senaraikan TIGA(3) amalan terbaik untuk membuat pesanan dan stok bahan kimia.) (3 marks) b) Chemicals inventory is very important in order to track all the purchased chemicals. State THREE(3) requirements of inventory queries for chemicals. (inventor! bahan kimia adalah sangat penting untuk mengesan semua bahan kimia yang dibell. Nyatakan TIGA(3) keperluan untuk pertanyaan inventori bagi bahan kimia.) (3 marks) )_ Cryogens are the production and behaviour of materials at very low temperatures. An example of cryogens is dry ice. (Kriogen adalah pengeluaran dan sifat bahan pada suhu yang sangat rendah. Contoh kriogen adalah ais Kering) i. Define dry ice. (Takritkan ais kering) (1 mark) ii. List THREE(3) applications of dry ice. (Senaraikan TIGA(3) Kegunaan ais ering.) (3 marks) Explain the chemical storage system for cryogenics. (Terangkan sistem penyimpanan kimia untuk kriogen.) (3 marks) 4) Alin was doing lab cleaning until she found a chemical bottie labelled with “orphan” waste. Define “orphan” waste, State THREE(3) characterizations to clarify “orphan” waste. (Alin melakukan pembersinan makmal sehinggalah dia menemui botol kimia yang dilabel dengan sisa "orphan". Takrifkan sisa “orphan”. Nyatakan TEGA(3) ciri untuk menjelaskan sisa "orphan",) (4 mark) 8/10KIM3002 SULIT e) Recycling is a part of chemical waste management. List THREE(3) things in chemical waste management that should be recycled or redistributed. (Kitar semula adalah sebahagian daripada pengurusan sisa kimia. Senaraikan TIGA(3) perkara didalam pengurusan sisa kimia yang perlu dikitar semula atau diedarkan semula.) (3 marks) QUESTION 3 [15 MARKS] a) Thousands workers are blinded each year from work-related eye injuries. Eye protection shields divided by two main categories; primary and secondary protection. Explain both kinds of these protections. (Setiap tahun ribuan pekerja mengalami kecacatan buta dari kecederaan mata yang berkaitan dengan kerja. Perisai perlindungan mata dibahagikan kepada dua Kategori utama; perlindungan primer dan sekunder. Terangkan kedua-dua Jenis perlindungan tersebut.) (5 marks) b) Fire protection and prevention in chemical laboratories are crucial. (Perlindungan dan pencegahan kebakaran di makmal kimia adalah penting.) i. A fire must have four elements to ignite and maintain combustion. Briefly, explain these four elements. (Api mesti mempunyai empat elemen untuk menyala dan mengekalkan pembakaran. Secara ringkas, jelaskan empat elemen ini.) (4 marks) ji, Fire can be classified into several codes (Code A - Code F). State the type of fire for Code A and Code D and give ONE(1) example for each Code. (Kebakaran boleh dikelaskan kepada beberapa kod (Kod A - Kod F). Nyatakan Jenis api untuk Kod A dan Kod D den berikan SATU(1) contoh untuk setiap Kod.) (4 marks) ili, Based on Question 3b (ii), state the methods of fire extinguishing for Code A and Code D type of fire. (Berdasarkan Soalan 3b (ii), nyatakan kaedah pemadam kebakaran untuk Jenis api Kod A dan Kod D.) (2 Marks) 9/10KIM3002 SULIT QUESTION 4 [15 MARKS] a) Alab manager was monitored for exposure to toluene solvent during his working hour from 8 am until 4 pm. The monitored data is: (Seorang pengurus makmal dipantau untuk pendedahannya terhadap pelarut toluena sepanjang waktu bekerja beliau dari jam 8 pagi sehingga 4 petang. Data pemantauan tersebut adalah:) Time Period Concentration Number! m 1 80 2 110 3 55 i. Calculate the Threshold Limit Values-8 hours Time Weighed Average (TLV- TWaA8). (Kirakan “Threshold Limit Values-8 hours Time Weighed Average” (TLV- TWAs,) (4 Marks) ji, Will he be over exposed if the TLV-TWas for toluene is 185 ppm? (Adakah beliau terdedah secara berlebihan sekiranya TLV-TWAg untuk toluena alah 185 ppm?) (1 Marks) iii, Calculate a new concentration of toluene (in ppm) if the lab manager want to work safely for 12 hours/day. (Kira kepekatan baru bagi toluena (dalam ppm) jika pengurus makmal tersebut mahu bekerja dengan selamat selama 12 jam/hari,) (2 marks) b) Explain CIMAH regulation 1996, State THREE(3) activities which do not comply with this regulation, (Terangkan regulasi CIMAH 1996. Nyatakan TIGA(3) aktiviti yang tidak mematuhi peraturan ini.) (5 marks) c) List THREE(3) other regulations except CIMAH 1996 under occupational safety and health act 1994 (Act 514) in Malaysia. (Senaraikan TEGA(3) peraturan-peraturan lain kecuali CIMAH 1996 di bawah akta keselamatan dan kesihatan pekerjaan 1994 (Akta 514) di Malaysia.) (3 marks) -Kertas Soalan Tamat — -End of Questions— 10/10