CEM-304 Continuous Stirred Tank Reactor - Run 3 Results

Sample Sample Elapsed Sodium Ethyl Flowrate Flowrate Measured Stirrer Reactor
Number Time Time Hydroxide Acetate of Sodium of Ethyl Conductivity Speed Temp.
Concentaion Concentraion Hydroxide Acetate
[mol/dm³] [mol/dm³] [cm³/min] [cm³/min] [mS] [rpm] [°C]
1 13:38:18 00:00:00 0.050 0.050 30.3 30.4 4.63 166 45.0
2 13:38:48 00:00:30 0.050 0.050 30.1 30.3 4.61 166 45.0
3 13:39:18 00:01:00 0.050 0.050 29.9 30.0 4.53 165 45.0
4 13:39:48 00:01:30 0.050 0.050 29.9 30.1 4.52 166 45.0
5 13:40:18 00:02:00 0.050 0.050 29.8 30.0 4.47 165 45.0
6 13:40:48 00:02:30 0.050 0.050 30.0 30.1 4.48 166 45.0
7 13:41:18 00:03:00 0.050 0.050 30.4 30.5 4.55 167 45.0
8 13:41:48 00:03:30 0.050 0.050 30.7 30.6 4.52 167 45.0
9 13:42:18 00:04:00 0.050 0.050 30.5 30.7 4.51 167 45.0
10 13:42:48 00:04:30 0.050 0.050 30.4 30.5 4.43 167 45.0
11 13:43:18 00:05:00 0.050 0.050 30.2 30.3 4.40 166 45.0
12 13:43:48 00:05:30 0.050 0.050 30.3 30.3 4.34 166 45.0
13 13:44:18 00:06:00 0.050 0.050 30.3 30.4 4.33 167 45.0
14 13:44:48 00:06:30 0.050 0.050 30.3 30.3 4.28 166 45.0
15 13:45:18 00:07:00 0.050 0.050 30.2 30.4 4.29 166 45.0
16 13:45:48 00:07:30 0.050 0.050 30.2 30.3 4.27 166 45.0
17 13:46:18 00:08:00 0.050 0.050 30.2 30.3 4.29 166 45.0
18 13:46:48 00:08:30 0.050 0.050 30.2 30.3 4.29 166 45.0
19 13:47:18 00:09:00 0.050 0.050 30.2 30.3 4.31 166 45.0
20 13:47:48 00:09:30 0.050 0.050 30.1 30.3 4.32 166 45.0
21 13:48:18 00:10:00 0.050 0.050 30.2 30.3 4.35 166 45.0
22 13:48:48 00:10:30 0.050 0.050 30.1 30.3 4.37 166 45.0
23 13:49:18 00:11:00 0.050 0.050 30.2 30.4 4.39 166 45.0
24 13:49:48 00:11:30 0.050 0.050 30.3 30.3 4.40 166 45.0
25 13:50:18 00:12:00 0.050 0.050 30.2 30.3 4.41 166 45.0
26 13:50:48 00:12:30 0.050 0.050 30.2 30.3 4.42 166 45.0
27 13:51:18 00:13:00 0.050 0.050 30.1 30.3 4.43 166 45.0
28 13:51:48 00:13:30 0.050 0.050 30.2 30.3 4.43 166 45.0
29 13:52:18 00:14:00 0.050 0.050 30.2 30.3 4.42 166 45.0
30 13:52:48 00:14:30 0.050 0.050 30.3 30.4 4.42 166 45.0
31 13:53:18 00:15:00 0.050 0.050 30.1 30.2 4.38 166 45.0

Page 1
 CEM-304 Continuous Stirred Tank Reactor - Run 3 Results

Reactor NaOH EtAC Initial Final Final

Volume Feed Feed Feed NaOH NaAC
Notes
Concentration Concentration Conductivity Concentration Concentration
[dm³] [mol/dm³] [mol/dm³] [mS] [mol/dm³] [mol/dm³]
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.03 0.02 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.03 0.03 7.0 0.00 0.03
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.03 0.02 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02
1.12 0.02 0.03 7.0 0.00 0.02

Page 2
CEM-304 Continuous Stirred Tank Reactor - Run 3 Results

Page 3
 CEM-304 Continuous Stirred Tank Reactor - Run 3 Results

Calculated Current Current Conversion Production Specific

Final NaOH NaAC of of Rate ln ((a - a1)/
Conductivity Concentration Concentration NaOH NaAC Constant (a - a0))
[mS] [mol/dm³] [mol/dm³] [%] [%] K
2.8 0.01 0.01 0.56 0.56 0.108 -0.830
2.8 0.01 0.01 0.57 0.57 0.109 -0.838
2.8 0.01 0.01 0.59 0.59 0.123 -0.883
2.8 0.01 0.01 0.59 0.59 0.125 -0.889
2.8 0.01 0.01 0.60 0.60 0.134 -0.915
2.8 0.01 0.01 0.60 0.60 0.134 -0.913
2.8 0.01 0.01 0.58 0.58 0.122 -0.874
2.8 0.01 0.01 0.59 0.59 0.131 -0.903
2.8 0.01 0.01 0.59 0.59 0.129 -0.894
2.8 0.01 0.02 0.61 0.61 0.146 -0.941
2.8 0.01 0.02 0.62 0.62 0.153 -0.961
2.8 0.01 0.02 0.64 0.64 0.173 -1.009
2.8 0.01 0.02 0.64 0.64 0.175 -1.012
2.8 0.01 0.02 0.65 0.65 0.190 -1.046
2.8 0.01 0.02 0.64 0.64 0.185 -1.034
2.8 0.01 0.02 0.65 0.65 0.191 -1.047
2.8 0.01 0.02 0.64 0.64 0.185 -1.036
2.8 0.01 0.02 0.65 0.65 0.186 -1.037
2.8 0.01 0.02 0.64 0.64 0.178 -1.021
2.8 0.01 0.02 0.64 0.64 0.175 -1.012
2.8 0.01 0.02 0.63 0.63 0.168 -0.999
2.8 0.01 0.02 0.63 0.63 0.161 -0.981
2.8 0.01 0.02 0.62 0.62 0.154 -0.965
2.8 0.01 0.02 0.62 0.62 0.155 -0.970
2.8 0.01 0.02 0.61 0.61 0.150 -0.954
2.8 0.01 0.02 0.61 0.61 0.148 -0.948
2.8 0.01 0.02 0.61 0.61 0.144 -0.939
2.8 0.01 0.02 0.61 0.61 0.145 -0.941
2.8 0.01 0.02 0.61 0.61 0.147 -0.947
2.8 0.01 0.02 0.61 0.61 0.147 -0.947
2.8 0.01 0.02 0.62 0.62 0.160 -0.980

Page 4
CEM-304 Continuous Stirred Tank Reactor - Run 3 Results

Page 5
 Sodium Flowrate Measure
Ethyl
Sample Sample Elapsed Hydroxid of Flowrate d Stirrer
Acetate
Number Time Time e Sodium of Ethyl Conducti Speed
Concentr
Concenta Hydroxid Acetate vity
aion
ion e [cm³/min] [rpm]
[mol/dm³]
[mol/dm³] [cm³/min] [mS]
1 13:38:18 00:00:00 0.050 0.050 30.3 30.4 4.63 166
2 13:38:48 00:00:30 0.050 0.050 30.1 30.3 4.61 166
3 13:39:18 00:01:00 0.050 0.050 29.9 30.0 4.53 165
4 13:39:48 00:01:30 0.050 0.050 29.9 30.1 4.52 166
5 13:40:18 00:02:00 0.050 0.050 29.8 30.0 4.47 165
6 13:40:48 00:02:30 0.050 0.050 30.0 30.1 4.48 166
7 13:41:18 00:03:00 0.050 0.050 30.4 30.5 4.55 167
8 13:41:48 00:03:30 0.050 0.050 30.7 30.6 4.52 167
9 13:42:18 00:04:00 0.050 0.050 30.5 30.7 4.51 167
10 13:42:48 00:04:30 0.050 0.050 30.4 30.5 4.43 167
11 13:43:18 00:05:00 0.050 0.050 30.2 30.3 4.40 166
12 13:43:48 00:05:30 0.050 0.050 30.3 30.3 4.34 166
13 13:44:18 00:06:00 0.050 0.050 30.3 30.4 4.33 167
14 13:44:48 00:06:30 0.050 0.050 30.3 30.3 4.28 166
15 13:45:18 00:07:00 0.050 0.050 30.2 30.4 4.29 166
16 13:45:48 00:07:30 0.050 0.050 30.2 30.3 4.27 166
17 13:46:18 00:08:00 0.050 0.050 30.2 30.3 4.29 166
18 13:46:48 00:08:30 0.050 0.050 30.2 30.3 4.29 166
19 13:47:18 00:09:00 0.050 0.050 30.2 30.3 4.31 166
20 13:47:48 00:09:30 0.050 0.050 30.1 30.3 4.32 166
21 13:48:18 00:10:00 0.050 0.050 30.2 30.3 4.35 166
22 13:48:48 00:10:30 0.050 0.050 30.1 30.3 4.37 166
23 13:49:18 00:11:00 0.050 0.050 30.2 30.4 4.39 166
24 13:49:48 00:11:30 0.050 0.050 30.3 30.3 4.40 166
25 13:50:18 00:12:00 0.050 0.050 30.2 30.3 4.41 166
26 13:50:48 00:12:30 0.050 0.050 30.2 30.3 4.42 166
27 13:51:18 00:13:00 0.050 0.050 30.1 30.3 4.43 166
28 13:51:48 00:13:30 0.050 0.050 30.2 30.3 4.43 166
29 13:52:18 00:14:00 0.050 0.050 30.2 30.3 4.42 166
30 13:52:48 00:14:30 0.050 0.050 30.3 30.4 4.42 166
31 13:53:18 00:15:00 0.050 0.050 30.1 30.2 4.38 166
 Calculate
NaOH EtAC Initial Final Final Current
Reactor Reactor d
Feed Feed Feed NaOH NaAC NaOH
Temp. Volume Final
Notes Concentr Concentr Conducti Concentr Concentr Concentr
Conducti
ation ation vity ation ation ation
[°C] [dm³] vity
[mol/dm³] [mol/dm³] [mS] [mol/dm³] [mol/dm³] [mol/dm³]
[mS]
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.03 0.02 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.03 0.03 7.0 0.00 0.03 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.03 0.02 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01
45.0 1.12 0.02 0.03 7.0 0.00 0.02 2.8 0.01

t vs 1/CA

120 2
1.8
f(x) = 0.010840846460711 x + 99.6463702896716
100 R² = 0.223584158718738 f(x) = 0.000270372753
1.6
R² = 0.2221413495374
1/CA

1.4
80
1.2

60 1
0.8
40 0.6
0.4
20
 R² = 0.2221413495374

1/CA
1.4
80
1.2

60 1
0.8
40 0.6
0.4
20
0.2

0 0
0 100 200 300 400 500 600 700 800 900 1000 0 100 200
t
 Current Conversi
Production Specific
NaAC on ln ((a -
of Rate
Concentr of a1)/ 1/CA XA/(1-XA) t lnK
NaAC Constant
ation NaOH (a - a0))
[%] K
[mol/dm³] [%]

0.01 0.56 0.56 0.108 -0.830 91.94967 1.29419 0 -4.528209

0.01 0.57 0.57 0.109 -0.838 92.7447 1.310925 30 -4.528209
0.01 0.59 0.59 0.123 -0.883 96.98737 1.418201 60 -4.528209
0.01 0.59 0.59 0.125 -0.889 97.53309 1.431816 90 -4.528209
0.01 0.60 0.60 0.134 -0.915 100.2418 1.497663 120 -4.528209
0.01 0.60 0.60 0.134 -0.913 99.88718 1.492195 150 -4.528209
0.01 0.58 0.58 0.122 -0.874 96.02154 1.395804 180 -4.528209
0.01 0.59 0.59 0.131 -0.903 98.16043 1.457219 210 -4.528209
0.01 0.59 0.59 0.129 -0.894 98.09273 1.445899 240 -4.528209
0.02 0.61 0.61 0.146 -0.941 102.7374 1.561686 270 -4.528209
0.02 0.62 0.62 0.153 -0.961 104.8704 1.614824 300 -4.528209
0.02 0.64 0.64 0.173 -1.009 109.7221 1.743053 330 -4.528209
0.02 0.64 0.64 0.175 -1.012 110.1564 1.750281 360 -4.528209
0.02 0.65 0.65 0.190 -1.046 113.9078 1.845813 390 -4.528209
0.02 0.64 0.64 0.185 -1.034 112.7485 1.811265 420 -4.528209
0.02 0.65 0.65 0.191 -1.047 114.2323 1.848252 450 -4.528209
0.02 0.64 0.64 0.185 -1.036 112.8867 1.816572 480 -4.528209
0.02 0.65 0.65 0.186 -1.037 113.0255 1.821899 510 -4.528209
0.02 0.64 0.64 0.178 -1.021 111.3013 1.775172 540 -4.528209
0.02 0.64 0.64 0.175 -1.012 110.4584 1.752322 570 -4.528209
0.02 0.63 0.63 0.168 -0.999 108.7742 1.715758 600 -4.528209
0.02 0.63 0.63 0.161 -0.981 107.0502 1.667386 630 -4.528209
0.02 0.62 0.62 0.154 -0.965 105.2272 1.623729 660 -4.528209
0.02 0.62 0.62 0.155 -0.970 105.1914 1.631521 690 -4.528209
0.02 0.61 0.61 0.150 -0.954 104.0837 1.596933 720 -4.528209
0.02 0.61 0.61 0.148 -0.948 103.4626 1.581429 750 -4.528209
0.02 0.61 0.61 0.144 -0.939 102.6192 1.55699 780 -4.528209
0.02 0.61 0.61 0.145 -0.941 102.7344 1.561566 810 -4.528209
0.02 0.61 0.61 0.147 -0.947 103.3463 1.576823 840 -4.528209
0.02 0.61 0.61 0.147 -0.947 103.3475 1.576872 870 -4.528209
0.02 0.62 0.62 0.160 -0.980 106.7653 1.665588 900 -4.528209

t vs Xa/(1-Xa)
2
1.8
1.6 f(x) = 0.000270372753698 x + 1.48606274370081
R² = 0.222141349537404
1.4
1.2
1
0.8
0.6
0.4
 R² = 0.222141349537404
1.4
1.2
1
0.8
0.6
0.4
0.2
0
0 100 200 300 400 500 600 700 800 900 1000
Column AA Linear (Column AA)
 energi
1/T
aktivasi

0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143
0.003143