MARKING SCHEME PAWT CHEMISTRY FORM 5

PAPER 1

1 C 11 B
2 D 12 B
3 C 13 A
4 B 14 A
5 C 15 D
6 A 16 C
7 Bonus 17 D
8 D 18 D
9 D 19 B
10 B 20 C

PAPER 2

NO ANSWER SUB TOTAL

MARK MARK
3 (a) (i) Electrolytic cell 1 1

(ii) Electrical energy to chemical energy 1 1

(b) To allow the movement of ions 1 1

(c) Zn → Zn2+ + 2e 1 1

(d) (i) The blue solution turns to pale blue in cell A 1

in cell B the blue solution remains unchanged. 1 2

(ii) 1. The concentration of Cu2+ ion decreases in Cell A 1

2. The concentration of Cu2+ ion in Cell B remain unchanged 1 2

(e) (i) Replace the Zn electrode with Mg electrode 1 1

(ii) The distance between Mg and Cu in electrochemical series is 1 1

further.

TOTAL 10

NO ANSWER SUB TOTAL

MARK MARK
4 (a) The increase/change in volume of hydrogen gas per unit time 1 1

(b) Zn + 2HNO3 → Zn(NO3)2 + H2

Correct formula of reactants and products 1

Balanced equations 1 2
(c) Experiment I:
22
1 1
Average Rate of reaction= 2×60 =0.183 cm3 s-1
 (d) 0.1×20
1
Number of moles of HNO3 = 1000 = 0.002 mol

2 mol of HNO3 produce 1 mol of H2 // 1

0.002 mol of HNO3 produce 0.001 mol of H2
1 3
Maximum volume of H2 = 0.001 x 24 000 // 24 cm3
(e) (i) Temperature 1 1
(ii) At normal body temperature,
The rate of metabolism is high// insufficient oxygen supply to 1
organs
At low temperature surgery,
The rate of metabolisme reduced/low// organs do not require 1 2
much oxygen supply
TOTAL 10

BAHAGIAN B

Question Mark Scheme Sub Total

No Mark Mark

7 (a) (i) Alcohol : Methanol 1

Carboxylic asid: Propanoic acid 1

C2H5COOH + CH3OH → C2H5COOCH3 + H2O 2 4

(ii) Mol ester = 1.32 = 0.15 1

88

Mass alcohol = 0.15 x 32 = 4.8 g 1 2

(b) Empirical formula

Unsur Carbon Hydrogen

Mass 85.71 14.29

No. of mol 85.71 = 7.14 14.29 = 14.29 1

12 1

Mol ratio 7.14 = 1 14.29 = 2

1
7.14 7.14

Empirical formula of P = CH2

1
[ CH2 ]n = 56
[ 14 ]n = 56
n=4
1
Molecular formula of P = C4H8
1 5

(ii) Name of compound P: butene 1

 Homologous series: alkene 1 2

(c) (i) Compound R :

Name: Pentene 1
Fuctional group: Double bond between carbon atoms 1

Compound S :
Name: Pentanoic acid 1
Fuctional group: Carboxyl group 1 4

(ii)
H H H H H
I I I I I
H–C=C–C–C–C–H
I I I
H H H
1

H H H H H
I I I I I
H–C–C=C–C–C–H
I I I I
H H H H
1

H H H
I I I
H–C=C–C–C–H
I I
H H
H–C–H
I
H 1

H H
I I
H–C–C=C–C–H
I I
H H
H–C–H
1
I
H

H H H H
I I I I
H–C=C–C–C–H
I
H
H–C–H
I 1
H
 Max
Any three 3 3

Total 20