http://www.extendoffice.com/documents/word/733-word-insert-frame.

html#a1

1. Right-click the Ribbon and choose Customize Quick Access Toolbar....

2. In the Word Option dialog, please check Commands Not in the Ribbon box
from the Choose commands from.

3. Select Insert Frame and click Add button. Finally click OK button to close
the dialog. See screenshot:

4. After adding Frame icon into the Quick Access Toolbar, you can directly
click on the icon to insert frame into the document.
 Insert frames into document in Word 2010/2013

1. In Word 2010 and 2013, please click File > Options > Customize Ribbon.

2. In Word Options dialog, check the Developer box in the right pane. See
screenshot:

3. Click OK, the Developer tab will show on the Ribbon (if don’t, reopen
Word)
4. You just need to click Developer > Legacy Forms > Insert Framebutton to
start the Frame inserting. See screenshot:

Easily insert frames into document with Kutools for Word

With Kutools for Word, users can easily insert frames into document without
adding Frame function to Word manually.

Kutools for Word, a handy add-in, includes groups of tools to ease your work
and enhance your ability of processing word document. Free Trial for 45 days!
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1. Please apply this utility by clicking Kutools > More > Frame > Frame. See
screenshot:
2. Now, you can start inserting Frame in the document.

For more information about Frame, please visit: Frame feature description.