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Developments in Thermal Desalination Processes PDF
Developments in Thermal Desalination Processes PDF
Abstract
Desalination provides a sustainable source of fresh water for countries with limited water resources. Progress in
the desalination technology made highly competitive to water transportation over long distances. Also, desalination
is less harmful to the environment than water dams, which results in severe environmental problems up and down
stream. At present the desalination industry is dominated by the reverse osmosis (RO) and the multistage flash
desalination (MSF) processes. Other thermal desalination processes, which include the multiple effect evaporation
(MED) and the mechanical vapor compression process (MVC) are found on a much limited scale. Features of the
three thermal desalination processes are discussed with focus on design, energy, and economic aspects. Design
features include performance ratio, specific heat transfer area, and system dimensions.
Keywords: Multistage flash desalination; Multiple effect evaporation; Mechanical vapor compression
1. Introduction
300,000 m3/d. In addition thermal desalination
Since inception of the desalination industry in processes, start of the RO process in the 1970s for
the 1950s, rapid progress has taken place. This is desalination of brackish and seawater proved to
reflected in the unit production capacity, which be highly beneficial to the advancement of indus-
increased from small values of 500 m3/d up to the trial desalination. This is achieved through rapid
massive scale MSF units with a capacity of progress and developments of membrane tech-
75,000 m3/d. Also, the capacity of the entire nology. Currently, RO membranes have highly
desalination plants is considerably increased from selective separation properties, have high recov-
approximately 5,000 m3/d to reach values close to ery ratio, and have better mechanical and
chemical properties. The progress in the desali-
*Corresponding author. nation technologies and the reliable record of the
0011-9164/07/$– See front matter © 2007 Elsevier B.V. All rights reserved.
doi:10.1016/j.desal.2006.08.020
228 M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240
Ms λs = MR Cp (Tbo!Tf 1) (1)
Fig. 1. Cumulative production capacity of MSF plants in (MR/Md) = ((Ms/Md) λs)/Cph (Tbo!Tf1) (2)
Kuwait.
In Eq. (2) the term (Md/Ms) gives the system per-
formance ratio (PR). Therefore, Eq. (2) is reduced
to the following form
Fig. 2. Variation in the cumulative capacity of MSF and Division of Eq. (4) by the production capacity
RO in Bahrain. (Md) gives
In Eq. (5) the conversion ratio (CR) is ob- The stage height is obtained from the following
tained through a simple material balance, which relation:
is given by
Hst = Hb + Hpb +Ltb
CR = (Xbn!Xf) /Xbn (7)
The following illustration shows the use of the
Demister length is obtained from definition of the above simple model for analysis of large MSF
vapor velocity across the flashing stage. This system. The following parameters are defined to
gives the following relation solve the model equations: Number of flashing
stages, n = 24, plant capacity, Md = 655 kg/s
Lp = (D Vv)/(vv wst) (8) (56,600 m3/d), heating steam temperature Ts =
120EC, top brine temperature Tbo = 110EC,
The stage length is obtained from temperature of brine recycle entering the brine
heater, Tf1 = 102EC, temperature of brine blow
Lst= Lp + Ltb (9) down, Tbn = 37EC, intake seawater temperature,
Tcw = 30EC, salinity of feed seawater, Xf =
The tube bundle length is obtained as a function 40,000 ppm, salinity of brine blow down, Xbn =
of number of tubes, tube diameter, and the tube 70,000 ppm, outer diameter of condenser tubes,
spacing. The tube bundle length is obtained from dr = dj = 0.0312 m, specific heat at constant pres-
sure, Cp = 4.2 kJ/kg K, vapor velocity in demister
Ltb = nt1/2 dt St (10) in first stage, vv1 = 2 m/s, vapor velocity in
demister in last stage, vv24 = 12 m/s, stage width,
The number of tubes is obtained as a function of wst = 20 m, liquid density, ρ = 1000 kg/m3, tube
the stream flow rate and velocity. These equa- velocity of brine recycle stream, vR = 2 m/s, tube
tions are given by velocity of intake seawater, vcw = 2 m/s, height of
brine pool, Hb = 0.2 m, distance between demister
ntr = 4 MR/(ρ VR dr2 π) (11) and brine pool, Hpb = 2 m, performance ratio,
PR = 9.5, latent heat of heating steam at 120EC,
ntj = 4 (Mcw+Mf) /(ρ Vcw dj2 π) (12) λs = 2202.6 kJ/kg.
M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240 231
Table 1
Illustration results
Table 2
Costing parameters of the MSF system
Results of the above illustration are shown in The costing calculations given in this study
Table 1. As is shown, the demister length in the are based on previous analysis presented by
first stage is smaller than that in the last stage. Ettouney et al. [12]. Tables 2 and 3 show the
This is because of the increase in the vapor costing parameters and the unit product cost for a
specific volume. Irrespective of this, other design 68,000 m3/d MSF unit, which is equivalent to
characteristics of the heat rejection and heat 15 MIGD. As is shown, the plant life is assumed
recovery stages are quiet similar. This includes equal to 20 years. However, recent reports from
the stage height and length. old desalination and power plants in the Gulf
232 M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240
model includes some modifications that have Similarly, the temperature drop in effects 2-n is
resulted in sequential solution rather than iterative obtained by
procedure. The main feature of the model is the
equality of the heat transfer area in each effect. ΔTi = ΔT1 U1/Ui (15)
The main modification in the model is made in
definition of the temperature drop across all Brine temperature in the first effect is obtained
effects is obtained from the following relation from the relation
Table 5
Profiles of the MED system
Effect 1 2 3 4 5 6
2
U (kW/m K) 2.6 2.522 2.44634 2.37295 2.301761 2.232708
ΔT (EC) 3.86 3.98 4.10 4.22 4.36 4.49
Tb (EC) 71.14 65.17 59.07 52.85 46.49 40
Tv (EC) 69.14 63.17 57.07 50.85 44.49 38
λv (kJ/kg) 2335.92 2350.60 2365.46 2380.51 2395.77 2411.28
D (kg/s) 39.28 39.03 38.79 38.54 38.30 38.05
A (m2) 9152.22 9152.22 9152.22 9152.22 9152.22 9152.22
B (kg/s) 74.99 74.52 74.05 73.58 73.12 72.65
F (kg/s) 114.27 113.56 112.84 112.13 111.41 110.70
Xb (ppm) 64,000 64,000 64,000 64,000 64,000 64,000
Table 6
Design results of MED system
Table 7
Costing parameters of the MED system
the MVC process remained limited; in 1994, only show that the MVC consumes about 10–14
200 MVC units with very small unit capacity are kWh/m3 [22–24]. Most of the MVC unit capacity
reported by Zimmerman [21]. The most attractive is limited to 500 m3/d; however, Kronenberg and
feature of the MVC system is it requires only Lokiec [25] reported on the performance of large
electric power for operation; however, need for of MVC units with a capacity of 3000 m3/d. The
diesel engine is necessary for startup. Field data report shows specific power consumption of
236 M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240
Mb = Mf Xf /Xb (27) M bC p ( Tb − To )
Abh = (33)
U bh ( LMTD )bh
The preheater energy equation balances the
sensible heat of the feed seawater against the
A single-effect mechanical vapor-compression
sensible heat of the distillate and brine streams.
system is to be designed at the following condi-
tions: the distillate flow rate, Md = 500 m3/d, the
Mf Cpf (Tf!Tcw) = Md Cpd (Td!To) + Mb Cpb (Tb!To)
intake seawater temperature, Tcw = 35°C, the
(28) saturation temperature of compressed vapor, Td =
M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240 237
Table 9
Design results of the MVC system
72EC, the evaporation temperature, Tb = 70EC, demister is 0.5 m, which will provide the required
the feed seawater salinity, Xf = 42,000 ppm, the vapor velocity and degree of separation of brine
salinity of the rejected brine, Xb = 60,000 ppm, droplets.
the compressor efficiency, η = 60%, the outer Tables 10 and 11 show the costing parameters
diameter of the evaporator tubes, de = 0.025 m, and the unit product cost for the MVC system. As
the length of evaporator tubes, Le = 10 m, the is shown, the plant life is assumed equal to
overall heat transfer coefficient, Ue = 3.375 kW/ 20 years. The specific power consumption for the
m2 K, and the vapor velocity in demister, vp = system is set at 7 kWh/m3 [29,30]. The man
6 m/s. The design results, which are obtained by power is set at 0.1 because of the small capacity
solution of the above model equations are given of the unit. In reality such unit might exist in a
in Table 9. As is shown, the system specific station or a location that several other units and
power consumption is equal to 11.8 kWh/m3. applications. It should be noted that unit cost is
Also, the shell diameter is equal to 1.67 m, which similar to the values calculated previously for the
is typical of small MVC units. The width of the MSF and MED systems. However, if the system
238 M. Al-Sahali, H. Ettouney / Desalination 214 (2007) 227–240
Table 10
Costing parameters of the MVC system
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