1.

Diketahui : T = 25oC =298 K

P = 1 atm = 101325 Pa
K = 1,380 x 10-23 J/K
D = 3,61 Å = 3,61 x 10-10 m

Ditanya : a.) Tumbukan Perdetik Permolekul

b.) Jumlah mol tumbukan perliter perdetik

Jawab :
a.) Tumbukan perdetik permolekul
ṽ = 0,921 vrms
3 RT
ṽ = 0,921
√ Mr O 2
3 x 8,314 x 298
ṽ = 0,921
√ 0,032kg /mol
ṽ = 0,921 √ 232272,375
ṽ = 443,87 m/s

b.) Jumlah mol tumbukan perliter perdetik

N
Z1 = πvd2 √2
V
p
Z1 = πvd2 √2
kT
 2
101325 N /m
Z1 = π(443,87 m/s) (3,61 x 10 -10
m)2
√2
1,380 x 10−23 J /K x 298 K
Z1 = π(1425,251 x 10-3 ) √ 2 /s
Z1 = 6332,22 /s

2. Diketahui: T = 700 K
K = 6,42 x 10-2 liter/mol detik
Ea = 167 kJ → 167000 J
σ H2 = 225 pm → 112,5 ppm
σ I2 = 559 pm → 279,5 ppm
m H2 = 2,01588 gr/mol
m I2 = 253,8039 gr/mol
KB = 1,380 x 10-23 J/K
R = 8,314472 J/K mol
22
π =
7
Ditanya:
a. Tetapan laju (k)?
b. Faktor koreksi (faktor sterik)

Jawaban
 1 −Ea
m + mB
k =σ 2
AB
{
8π kBT A
(
m A . mB )}
2
e RT

−167000 J
1 J
22 J 2,01588+ 253,8039
k =(112,5 +279,5)2 ppm 8 x
{ 7
x 1,380 x 10−23 x 700 K
K (
2,01588 x 253,8039 )} e
2
8,314472
K .mol
x 700 K

1
22 J 255,81978
k =(392) ppm 8 x2
7 {
x 1,380 x 10−23 x 700 K
K 511,638206 ( )}
2

−167000 J
1 J
k= 2
5820.1304
mol
153664 ppm x {2,4288 x 10−19 ( 0,500001323 ) } e

1
k = 153664 ppm x ( 1,21440321 x 10−19 Joule ) 2 x 3,45592803 x 10−13

k = 153664 ppm x 3,84028014 x 10−10 Joule x 3,45592803 x 10−13 mol

k = 590112,807 x 10−10 x 3,45592803 x 10−13 mol

k = 2,03938739 x 10−17