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2270 - Acid Base For Student 1920
2270 - Acid Base For Student 1920
example :
Bronsted-
Lowry
theory
Advantages of Bronsted Lowry Acid Base theory :
1. The solvent must not water
2. The compound abilities to act as an acid or a base (It is called amphoteric or amphiprotic
substances)
Lewis
theory
QUESTIONS
S
1. Determine conjugate acid of :
a. H2O :
b. NH3 :
c. HCO3– :
d. SO42– :
e. CH3COOH :
5. Draw and use the Lewis theory to show that the following reactions are acid-base reactions :
a. BF3 + F– → BF4– b. NH2 – + H+ → NH3
B. pH SCALE
Strong acid
Solid form
ACIDS
Weak acid 1000 mass of solute
M= x
volume of solution Mr
[H+] = √𝐊 𝐚 𝐱 𝐌
Liquid form
[H+] = x M M=
10 x density x percentage
Mr
Strong base
Example :
We have a solution of 100 mL of ethanoic acid/ vinegar/ CH3COOH 0.2 M (Ka = 1.8 x 10–5). What is its pH value?
[H+] = √𝐊 𝐚 𝐱 𝐌
pH = 3.5 – log 6
Two grams of NaOH is dissolved into 500 mL of solution. Calculate the pH of solution! (Mr of NaOH = 40)
1000 2
M= x = 0.1
500 40
[OH–] = M x valence
= 0.1 x 1 = 10–1
pOH = 1 → pH = 14 -1 = 13
QUESTIONS
1. The concentration of H+ ion in the blood sample of a diabetic is 7.90 x 10– 8 M. What the concentration of OH–
ions in the sample? Is the blood of the diabetic acidic, basic or neutral?
2. What is the pH value of the following solutions of :
a. 0.001 M sulfuric acid (H2SO4) d. 0.02 M potassium hydroxide (KOH)
b. 0.1 M HF ( = 0.08) e. 0.1 M ammonia (NH3), Kb = 1.8 x 10– 5
c. 0.1 M formic acid HCOOH (Ka = 1.8 x 10– 4)
3. The ionization degree of HA 0.1 M solution is 25%. Calculate pH and acid equilibrium constant (Ka) for HA
solution!
4. When 0.1 M formic acid is dropped with indicator will provide the same color with HCl 2 x 10–3 M. What is the
value of acid equilibrium constant (Ka) of formic acid?
5. If pH solution of 0.15 M C6H5COOH is 3 – log 3, calculate pH solution of 0.06 M C6H5COOH!
6. 3.7 gram Ca(OH)2 Mr = 74 is dissolved into 5 liter water, calculate pH of solution !
7. 3.36 liter (STP) of NH3 gas flows into 1 liter water. Kb NH3 = 10–5, determine the pH!
8. Calculate the mass of NaOH (Mr = 40) needed to make 100 mL solution with pH 11 + log 2!
9. Calculate the mass of Ca(OH)2 (Mr = 74) needed to make 200 mL solution with pH 13 – log 2!
log 2 = 0.3, log 5= 0.7
10. A student wants to make base solution which has pH is 11 + log 5. He dissolves 29 mg of strong base which has
2 valences into water in Erlenmeyer flask. If the molecule relative mass of base is 58, determine the volume of
solution formed!