CHEMISTRY Max Marks: 100

(SINGLE CORRECT ANSWER TYPE)

This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. The correct statement about the compounds A, B and C
COOCH3 COOH COOH

H OH H OH H OH

H OH H OH HO H

COOH COOCH3 COOCH3

(A) (B) (C)

1) A and B are identical 2) A and B are diastereomers
3) A and C are enantiomers 4) A and B are enantiomers
52. Which compound will be most reactive for Perkin condensation with ethanoicanhydride?

O 2N CHO
1) 2) C 2 H5CHO

CH3O CHO CH3 CHO

3) 4)
53. Which of the following is most reactive towards Hoffmann bromamide reaction?
O O O
C NH2 C  NH 2 O C  NH 2
C  NH 2

CH3 OCH3 NO 2
1) 2) 3) 4)
54. The fibre obtained by the condensation of hexa methylene diamine and adipic acid is
1) Dacron 2) nylon 6,6 3) Rayon 4) Teflon
55. Match the following:
1) Morphine a) Antipyretic
2) Ibuprofen b) Narcotic analgesic
3) Paracetamol c) Tranquillizer
4) Luminal d) Non-narcotic analgesic
e) Antiseptic
1) 1  b, 2  d , 3  a, 4  c 2) 1  b, 2  c,3  e, 4  d
3) 1  d , 2  b, 3  a, 4  e 4) 1  a,2  e,3  b,4  d
56. In which of the following reaction H 2O 2 acts as a reducing agent?
(P) H 2O2  2H   2e  2H 2O
(Q) H 2O 2  2e  O 2  2H 
(R) H 2O2  2e  2OH 
(S) H 2O 2  2OH   2e   O 2  2H 2O
1) P, R 2) Q, S 3) P, Q 4)R, S
57. Which of the following is a pyrosilicate.
1) Sc 2Si2O7 2) Zn 2SiO 4 3) Ca 2Si3O9 4) Be3A 2Si6O18
58. Which of the following is a wrong statement?
1) The value of dissolved oxygen in polluted water is < 4 ppm
2) COD gives the measure of organic pollution of water
3) COD value determination is based on chemical oxidation of organic substances
4) If BOD of a river is high, it means the river is not polluted
59. In the reaction sequence:
CH3MgBr H 2 /Pd+BaSO 4
CO 2
CH3 – C  C – H A B C
+
H 2O H
, C will be
H 3C CH3 MgHCO3
H 3C
C C C C
H 3C CH3 H
1) 2) H

H H H COOH

C C C C
H 3C COOH H 3C H
3) 4)
60. The end product ‘E’ in the reaction sequence

P2 O5 4 H HNO2,Cold Cu,300º C
CH3CONH 2  B LiAlH 4
C D E
1) CH3CHO 2) CH3COOC 2 H5 3) CH3COCH3 4)  CH3CO 2 O

61. For any H like system, the ratio of velocities of I, II & III orbit i.e, V1 : V2 : V3 will be
1) 1 : 2: 3 2) 1 : 1/2 : 1/3 3) 3 : 2 : 1 4) 1 : 1: 1

62. The number of geometrical isomers of Co  NH3 3  NO 2 3  is

 
1) 0 2) 2 3) 3 4) 4
63. 
What is the molar solubility of Fe  OH 2 Ksp  8.0  1016 at pH  13.0? 
1) 8.0  1018 2) 8.0  1015 3) 8.0  1017 4) 8.0  1014
64. One mole of a solute A is dissolved in a given volume of a solvent. The association of
the solute take place as follows nA  A n If  is the degree of association of A , the
Van’t Hoff factor i is expressed as
α α
1) i  1  α 2) i  1  3) i  1  α  4) i  1
n n
65. Ammonium chloride crystallizes in a body centered cubic lattice with edge length of unit
cell equal to 387 pm . If the size of C  ion is 181 pm , the size of NH +4 ion would be
1) 116 pm 2) 154 pm 3) 174 pm 4) 206 pm
66. An aqueous solution of Na 2SO4 in water is electrolyzed using Pt electrodes.
The products at the cathode and anode respectively.
1) H 2 ,SO 2 2) O 2 ,NaOH 3) H 2 ,O 2 4) O 2 ,SO2
t
67. The value of 0.875 for nth order reaction  A 
 Product  is:
t0.50

(2n  2) (2n  2) 1 8n-1  1 4n-1  1

1) 2 2) 2 3) 4)
2n-1  1 2n-1  1
68. During the extraction of gold the following reactions takes place
O
Au  CN   H 2O 
2  X,X  Zn  Y  Au

Here, X and Y respectively are

3- 2- - 4-
1)  Au  CN 4  and  Zn  CN 4  2)  Au  CN 2  and  Zn  CN 6 

4 2  2
3)  Au  CN 4  and  Zn  CN 4  4)  Au  CN 2  and  Zn  CN 4 
69. Which of the following statement is incorrect?
1) SRP values of halogens X 2  g  / X   aq  ; F2  Cl2  Br2  I 2

2) Boiling points of I 2  Br2  Cl2  F2

3) Bond dissociation enthalpy of Cl2  F2  Br2  I 2

4) Reducing power of I  Br   C  F

70. A gas ‘ X ’ is passed through water to form a saturated solution. The aqueous solution on
treatment with silver nitrate gives a white precipitate. The saturated aqueous solution also
dissolves magnesium ribbon with evolution of a colourless gas ‘ Y ’ .Identify X and Y .
1) X  CO 2 , Y  C  2 2) X  C 2 ,Y  CO 2
3) X  C 2 , Y  H 2 4) X  H 2 , Y  C 2

(NUMERICAL VALUE TYPE)

This section contains 5 questions. Each question is numerical value type. For each question, enter the correct numerical value
(in decimal notation, truncated/rounded-off to second decimal place. (e.g. 6.25, 7.00, ‐0.33, ‐.30, 30.27, ‐127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
CH3

Baeyer's reagent OH 

 A  B  products
HIO 4

71.
The number of possible products (excluding stereoisomerism) is?
72. How many molecule of phenyl hydrazine is used to form osazone from glucose?
73. Equivalent weight of H3PO 2 when it disproportionate into PH3 and H 3PO3 is (nM). The
value of n is(M is molecular weight of H3PO 2 )
74. One mole of a substance is cooled at rate of 0.4 kJ min –1 during freezing. What would be
the entropy of fusion (in JK –1 mol –1 ) for this substance using data from the following graph?

800

400

Temp  K 

1 4
Time  in minute 

75. Out of following how many oxides are amphoteric in nature

MnO, Mn 2O, MnO 2 , Cr2O3 , Mn 2O 7 ,Mn 3O 4