UNIT-12

Type – Fill in the blanks

Remembering:

Q1 All aliphatic amines are __________hybridised .

Ans. Sp3

Q2. Amines behaves as lewis base due to the presence of ___________.

Ans. Lone pair of electron.

Q3. Aniline reacts with conc.H2SO4 to form Sulphanilic acid which behaves as
___________ion.

Ans. Zwitter.

Understanding :

Q4. Gabriel pthalimide synthesis is used for the preparation of ____________amines.

Ans. Primary

Q5. Lower aliphatic amines are soluble in water due to the presence of ___________
bonds.

Ans. Hydrogen

Q6. The chemical test used to distinguish primary, secondary and tertiary amines is
_______________.

Ans. Hinsberg test

Q7. p- Hydroxyazobenzene (orange dye) is formed when benzene diazomium chloride is

reacted with____________

Ans.phenol

Q8. The structural formula of the compound with IUPAC name 2- methylpropan-2-
amine is __________________

Ans.(CH3)3 - C-NH2

Q9. The conjugate base of (CH3)2NH2+ is ______________

Ans. (CH3)2NH

Q10. In nitration of aniline, along with ortho and para derivative, meta derivative is
also formed due to the formation of ______________ion.

Ans. Anilinium
Application :

Q11. The IUPAC name of the given compound CH3 – CH2 – CH2 – C – NH2 is
____________ O

Ans. Butanamide.

Q12. The reagent required for the conversion of ethanamide to methanamine

is/are_______________.

Ans. (Br2 + NaOH/KOH)

Q13. Reduction of nitrobenzene using Fe and HCl gives _________________ as product.

Ans. Aniline.

Q14. Acid anhydride on reaction with primary amines gives_____________.

Ans. Amide.

Q15. The IUPAC name of the compound when chloroethane is reacted with
methanamine is ___________.

Ans. N- methylethanamine.

Q16. The product responsible for white ppt formed on reaction of aniline with Br2
water is __________________

Ans. 2,4,6Tribromoaniline.

Q17. Hydrolysis of benzene diazonium chloride gives _________________as product.

Ans. Phenol.

Evaluation and analyzing:

Q18. The reactant (source of nitrogen) in Gabriel synthesis of amine is ____________

Ans. Potassium Pthalimide.

Q19. The gas evolved when methyl amine reacts with nitrous acid is _______________.

Ans. N2

Q20. The foul smell in carbyl amine reaction is due to the formation of
___________compound.

Ans. Isocyanide.

Q21. pKb value of aromatic Amine is quite high due to ________ effect.

Ans. Resonance.
Q22. In coupling reaction , the medium required for the reaction between benzene
diazonium chloride and aniline is ___________________.

Ans. Acidic.

Q23. Due to salt formation with AlCl3, aniline does not undergo ____________reaction.

Ans. Friedel Craft.

Q24. The type of structural isomerism exhibited by CH3 – CH2 – NH – CH2 – CH3 ,

CH3 – CH2 – CH2 – NH – CH3 is called ________________

Ans. Metamerism.

Q25.The basic strength of amines decreases due to the presence of _____________

group.

Ans. Electron withdrawing.