Sri Chaitanya IIT Academy.

, India
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant
ICON CENTRAL OFFICE, MADHAPUR - HYD
Sec: Sri Chaitanya-Jr.Chaina-I CTA-17 Date: 02-12-19
Time: 09:00 AM to 12:00 Noon 2012_P1 Max.Marks:210
KEY SHEET

PHYSICS
1 B 2 D 3 A 4 D 5 D

6 B 7 A 8 A 9 A 10 D

11 BD 12 AD 13 AC 14 ABC 15 AC

16 3 17 4 18 5 19 2 20 3

CHEMISTRY
21 D 22 B 23 D 24 A 25 A
26 C 27 A 28 B 29 A 30 D
31 ABCD 32 BD 33 ABC 34 ABCD 35 ABCD
36 8 37 4 38 9 39 4 40 8

MATHS
41 A 42 B 43 B 44 A 45 B

46 B 47 D 48 C 49 C 50 D

51 AB 52 AD 53 CD 54 ABCD 55 ABC

56 3 57 5 58 9 59 0 60 9
Sri Chaitanya IIT Academy 02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv(2012_P1)_CTA-17_Key & Sol's
SOLUTIONS
PHYSICS
Singles:
1. Frequency of collision for unit area is constant so v / 2l 3 is constant. So temperature is
directly proportional to square of the volume.
2. Conceptual
3. Conceptual
4.

T T 1
 
sin  sin  sin 
   
5. Conceptual
6. Weight of sphere + Chain =  m  h g
 h 
Buoyant force =  3m   g
 7
For equilibrium, weight = Buoyant force
h
Or, m  h  3m 
7
7m
Or, h 
3
7. Initially force on particle P due to sphere is
GM GMm
F1  m. 
 2R 4R 2
2

After capacity is created by removing mass

3
M 4  R M
mcavity  3
.   
4 R 3  2  8
3
The force particle P is
F2  F1  FCavity


GMm  
G M8
2 m
4R  
3R
2
GMm  1 1 
 
R  4 18 
2

7 GMm

36 R 2
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F1 9
 
F2 7
8. As hinges are smooth the disc continue to rotate at  so by work energy theorem we
11 2 1
2
use  m  2 R     m 2 R
23  2
2
 
1
  mg  2 R  mgR 
2
2 2
2 2 2R  3gR
 2R   
3 2
2
8R 3g
 
3 2
9g

16 R
9. For block describing circle on the table,
2
T  m1 l1 .............1
For block describing conical pendulum,
T cos   mg
2
T sin   m 2  l2 sin  
2
 T  m 2l2 ............. 2
2 2
From (1) & (2), 1 l1   2l2
2
l1  2

l2 12
10.

2 2 2 2
F  M g   M  m g

F   M   M  m  g
2 2
 

Multiples:

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Sri Chaitanya IIT Academy 02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv(2012_P1)_CTA-17_Key & Sol's
11. A body cannot go back in time so option A is wrong. In practice body cannot change its
velocity abruptly. So option C is wrong.
0 3 0
12. For elastic collision     90 and from figure we use sin     60 hence
2
0
  30 .

13. When cylinder comes down, at the point where string leaves contact with the cylinder is
point of instantaneous rest, thus string does zero work.
1  mR 2   v  2
1 2
 
K R 2 IC 2  2   R  1
  
KT 1 2 1 2 2
mv mv
2 2
14. v0  2 m/s
  0.4
mv0  ft  mv .......1
Where v is velocity acquired by ring when slipping stops.
v
0  fRt  I ...... 2
R
Dividing (1) by (2), we get
mv0  ft mv

fRt 2 v
mR  
 R
fRt  mv0 R  fRt
mgRt  mv0 R  mg  R  f  mg 
2gt  v0
v0 2
t   0.25s
2g 2  0.4  10
Thus, ring will start pure rolling after 0.25s.
From (1),
mv0  ft  mv
mv0  mgt  mv
v  v0  gt  2   0.410 0.25
v  1 m/s

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Sri Chaitanya IIT Academy 02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv(2012_P1)_CTA-17_Key & Sol's
When ring will start rolling, its velocity is 1 m/s.
From 0.25s to 0.5s, i.e. t  0.5  0.25  0.25s,
v'  v0  gt
v'  2  1  1m/s
15. To get the maximum range on the level at a depth h below the base of tank we use
1/ 2 1/ 2
Range x =  2  2h  y  /g  x  2 gy 
For maximum range we use dx/dy = 0 which gives y = h and xmax = 2h.
Integers:
16. Torque about hinge is zero.
17. Conceptual
18. The hole spreads symmetrically away from the centre and in this process the surface
energy lost by an infinitesimal circular strip disappeared is available as kinetic energy.
h
r  5.0 ms
4
   0 
19. h0  1  2.0m
 1   
20. 3 cm towards the left.
CHEMISTRY
21. Conceptual
22. Conceptual
23. Conceptual
24. Heat evolved in combustion = 100×1×10 = 1000 cal = 1 k.cal
Of 0.2g of butanol
Heat evolved per mole = 74/0.2 = 370 k.cal
Heat of combustion = -370 k.cal
25. 222g Mg2P2O7 contain 62 g P
0.222 g Mg2P2O7 contain 62×10-3 gP
%P is compound = 6.2
M.W = (31×100)/6.2 = 500
H º 1 S º
26. log Kp    
2.3 R 2.3R
Since slope is negative, H º =+ve (endothermic)
H º
 3
2.3  2
H º  1.732  2  2.3
 8cal
27. Conceptual
28. 1.6  10 19 J  1.eV
4.9  1020 J  3.06 eV
The energy difference between n&n-1 shells is 3.06 eV. In H atom energy of 1st orbit
is  13.6  1.60  019  217.6  1019 J
The 4th orbit energy = 217.6  1020 / 16  13.56  1020 J
The 5th orbit energy = 217.6  10 20 / 25  8.68  1020 J
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-20
The difference = 4.9×10 J
So the element should be Sn
29. A) Both BeO and Al2O3 are amphoteric since the electronegativities of Be(1.5) and
Al(1.5) are same and also due to the polarizing of Be2+ and Al3+ are nearly same BeO
and Al2O3 should have equal amphoteric character, but due to more charge density on
Al3+ it has little more acidic character than Be2+ pKa values of Be2+ and Al3+ are 6.2 and
5.0 respectively.
B) As the electropositive character of the element decrease. The acidic character of their
hydroxides increase.
C) Na2 B4O7 .10 H 2O  2 NaBO2  B2O3  10 H 2O

glass bead

D) NaHCO3 is more soluble than CaCO3 but less than KHCO3

30. The reaction is endothermic. In this reaction carbon is oxidized and hydrogen is reduced.
The mixture of gas is also called synthesis gas or syn gas
31. Conceptual
32. Conceptual
33. Conceptual
34. Electron deficiency refers to the lack of sufficient electrons to account for the
connections between atoms as normal covalent bonds, Molecules which do not have
octet but have sufficient electrons to form normal covalent bonds between all atoms Ex.
B2H6 is electron – deficient and its structure is commonly described in terms of 2c-2e
and 3c-2e bonds. Molecules like AlCl3 exist as dimer which also contain 3c-4e bonds
and get octet.
35. Borax is a salt of tetra metaboric acid H2B4O7 which is obtained by heating orthoboric
acid
100º 160º C
4 H 3 BO3 
4 H O
2
 4 HBO2 
H O
 H 2 B4O7 .
2

Borax is a salt of tetra metaboric acid.

And consists of two six membered hetero cycling rings.

The 4 OH groups are in bond with 4 boron atoms. Its aqueous solution act as buffer
solution as it forms equimolar mixture of salt of strong base with weak acid and weak
acid
Na2 B4O7  3H 2O  2 NaBO2  2 H 3 BO3
As the pH of solution is more than 10 it act as basic buffer.
36. Conceptual
37. Conceptual
2
38. 7  2.3   300log ka
1000
7  0.23  2  3log ka

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- 7  1.38 logka
Ka  10 5
pKa  5
1
pH  7  5  log101 
2
=9
39. C2 H 4  3O2  2CO2  2 H 2O
x 2x
C3 H 8  5O2  3CO2  4 H 2O
10  x 310  x 

2 x  3 10  x  24
x  6  C2 H 4
C3 H 8  10  6  4
40. Ref. NCERT page no.321
MATHEMATICS
41. (A)
3
slope of 3 x  2 y  1 is
2
 1  3
 f 1   
2 2
x  x  1 0 1 1
p  lim 2 x 2 x    
x  e  e 0 1 1 3
f  f   f 1  f 1 
 2   2   2 2

1 1 13 13 1
  p r   2  ..... =  
r 1 3 3 1  1 3 2 3 2
42. (B)
solving

 3 3k 
C1 & C1  A  , 2

  a,ka  a,a  3
2
  
 1 k 1 k 
tangent 1 to C 2 at A is y  a 2  3  2kx      (1)
 B  1, 2  A  1
from expression (1) 2  a 2  3  2a 1  3  a2 .
 a = 3, a = - 2, a = 1
a=3

43. (B)
    
Let P1  t1, t13 , P2  t2 , t23 , P3  t3 , t33 …….. 
Solving tangent equation at P1 with the curve again we get t2  2t1 . Repeating the
process we have t3  4t1 t4  8t1 ………..
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t1 t13 1 t2 t23 1
P1P2 P3 1
  t2 t23 1  t3 t33 1 
P2 P3 P4 16
t3 t33 1 t4 t43 1

44. (A)
dt 1
t  cos 1 x 

dx 1  x2
dy dy dt 1 dy dy dy
     1  x2 
dx dx dx 1  x 2 dt dx dt
d2y dy d 2 y

 1  x2  dx 2
 x 
dx dt 2

45. (B) 

Image of orthocenter of ABC w.r.t. BC lies on the circle.
46. (B)
   2  2
sin 1  sin     2  2       3    2  2
 3
   1  x   1  x
 x 1
47. (D)
Let mth term of first A.P. be equal to the nth term of the second A.P. then
2 , 5 , 8 ,….50 terms series 1
3 , 5 ,7 , …., 60 terms series 2
Common series 5 , 11, 17 , ….., 119
40th term of series 1   59th term of series 2 = 119 = last term of common series
 an  5  (n  1)d  119  1  6n  n  20.
 Number of common terms is 20.
48. (C)
We must have
2
 x 2
 219  3 
2 x 1
9 x  27 3 0
x 2 2 x  2 
3  3  219  3 2 x 2
0
2x 2x

 3   381  219  39
2x
0

 1 1  2x
1    3  219
 81 9 
73 2 x
 3  219
81
32 x  3  81  35
2x  5
5
x
2

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5 
 Domain is  ,   .
2 
49. (C)
 x x
sin 2   
 2   2n  1 
x
the graph of sin 2   will be above the x–axis and will be meeting the x-axis at 0, 2  ,
 2
4  , . . . etc. It will attain maximum values at odd multiples of  lie.  , 3  , . . . (2n + 1)
x
 . The last point after which graph of y  will stop cutting will be  2n  1  .
 2n  1 
Total intersection = 2  n  1
50. (D)
Use “f(x) = x has non real roots  f(f(x)) = x also has non-real roots”

Multiple Correct Answer Type

51. (A,B)
(C) and (D) don’t intersect. The system of equations has no real solution so only (A)
and (B) are correct.
52. (A,D)
x3
f x     x 2 sin1.5a  x sin a.sin 2a  5sin 1  a 2  8a  17 
3
f(x) is defined when 1  a 2  8a  17  1
2
1   a  4   1  1  a4
x3 5
 f x    x 2 sin 6  x sin 4sin 8 
3 2
 f '  x   x 2  2xsin 6  sin 4sin8
f '  sin 8    sin 2 8  2sin 8sin 6  sin 4sin 8  sin 8  2sin 6  sin 8  sin 4  
= sin 8 [2 sin 6 – 2 sin 6 cos 2] = 2 sin 6 sin 8 (1 – cos 2)
Sin 6 < 0, sin 8 > 0, 1 – cos 2 > 0
 f '  sin8  0
53. (C,D)
The joined equation of straight line y = x – 1 and y = –x + 1 is
 x  y  1 x  y  1  0
 x 2  y 2  2 x  1  0 (1)
Let equation of line passes through (2, 0) is
y  m  x  2 (2)
By homogenizing equation (1) with help of line (2) is
2
2 2 mx  y   mx  y 
x  y  2x    0
 2m   2m 
1
 coefficient of x 2 + coefficient of y 2  0  m  
3
54. (A,B,C,D)

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  sum of roots  b  a
   product of root  ab
Because a  b so a is negative and b is positive.
Now,   b 1  a  b  b  1  a  1.
Because a is negative so magnitude of ' a ' is greater than one and magnitude of b is
greater than 1   or say greater than 2.
2 2
x x
Now, log a    1  0     a
b b
 x  b a
Magnitude of x is greater than ' a ' as well as greater than ' b '
 one root lies in   , a  and other root lies in  b,   .
55. (A,B,C)
If roots of the equation be  ,  ,  then
2
 2   2   2         2        a 2  2b
2
 2  2   2 2   2 2         2      
 b 2  2a
 2  2 2  1.
So, the equation whose roots are  2 ,  2 ,  2 is
x 3   a 2  2b  x 2   b 2  2a  x  1  0
It is identical to x 3  ax 2  bx  1  0
 a 2  2b  a and b2  2a  b, eliminating b, we get
2
a 2
 a
 2a 
a2  a
4 2
  2
a a  a  1  8  2  a  1  0
 a  a 3  2a 2  a  6   0
or a  a  3  a 2  a  2   0
 a  0 or a  3 or a 2  a  2  0
Which give b  0 or b  3 or b2  b  2  0
So, a  b  0 or a  b  3
Or a, b are roots of x 2  x  2  0

Integer Answer Type

56. (3) Equation of normal is y  mx  2am  am3 to the curve y2  4ax .
1
a
4
m m3  m2 1 
 y  mx   passes through (c, 0) then m    c   0
2 4  4 2 
 Remaining normals are perpendicular.

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m2 1
 Product of the roots of equation   c  0 will be 1 .
4 2
1
c
1 1 3
 2  1  c    so 4c = 3
1 2 4 4
4
57. (5) f ''  x   g ''  x   f '  x   g '  x   c1
 f  x   g  x   c1x  c2
f ' 1  g ' 1  c1 and f  2   g  2   2c1  c2
 f  4   g  4   4c1  c2
C1  f ' 1  g ' 1  2  4  2
C2  f '  2   g  2   2c1  2
 f  4   g  4   10
58. (9)
Tr  r  n  r  1 Tr  nr  r 2  r
n n n
n  n  n  1 n  n  1 2n  1 n  n  1
Sn   Tr  n  r   r 2   r   
r 1 r 1 r 1 2 6 2
n  n  1   2n  1  n  n  1  3n  2n  1  3  n  n  1 n  2 
 n   1    
2  3  2 3 6
n  n  1 n  2  25  26  27
Sn  ,S25   25  13  9
6 6
S25  325    9
59. (0)
From the given equation, we have x2   x  f   4 x  3  0 , where f = F. P. F. such that
0  f 1
  x 2  3x  3  f  0  f  x 2  3x  3 .
But 0  f 1 . Therefore 0  x2  3x  3  1 …(1)
3  9  12
Now, solving x 2  3x  3  0 , we get x = imaginary
2
 x 2  3 x  3  0 for all x  R .
Again from x 2  3x  3  1 , we get x2  3x  2  0   x  2  x  1  0
 1 x  2 .
Thus the inequality (1) is satisfied if 1 < x < 2  [x] = 1.
Putting {x} = 1 in the given equation, we get
2
x2  1  4 x  3  0  x 2  4 x  4  0   x  2   0  x  2 .
But x = 2 does not satisfy the inequality 1 < x < 2.
Hence no x is available to satisfy the equation. That is, the given equation has no
solution.

a b 3
60. (9)Given  2; 
R R 2

Sec: Sr. Chaina-I Page 11

Sri Chaitanya IIT Academy 02-12-19_Sri Chaitanya-Jr.Chaina-I_Jee-Adv(2012_P1)_CTA-17_Key & Sol's
a b
 R
2 3/ 2
2ac B
cos
BF a  c 2

CF 2 ab c
cos
ab 2
B
cos
ab 2  c ...............(1)
 
a  c cos C b
2
 a  2 R use here
7R
a 2  b2  c2  c 
2
3 7
sin B  ; sin 
4 4
B 4 7
cos 2  ;
2 2
B 4 7 c 7
cos 2  ;cos 2 
2 2 2 8
Now from ------------------------------(1)
BE 7 7  1

 
CF 9 2
A

F E

B C

Sec: Sr. Chaina-I Page 12