Villanueva Velázquez Pedro Isaac 2AM2 Metodos cuantitativos aplicados 20/03/2020

Curva de titulacion potenciometrica NaOH

∆𝑝𝐻=𝑝𝐻2−𝑝𝐻1

N V(gasto) Vtotal mol NaOH mol HCl mol H+ molOH- pH

1 0 25 0 0.0025 0.0025 - 1
2 10 35 0.001 0.0025 0.0015 - 1.36797679
3 20 45 0.002 0.0025 0.0005 - 1.95424251
4 24 49 0.0024 0.0025 0.0001 - 2.69019608
5 24.5 49.5 0.00245 0.0025 0.00005 - 2.99563519
6 25 50 0.0025 0.0025 0 0 7
7 25.5 50.5 0.00255 0.0025 - 0.00005 10.9956786
8 26 51 0.0026 0.0025 - 0.0001 11.2924298
9 30 55 0.003 0.0025 - 0.0005 11.9586073
10 40 65 0.004 0.0025 - 0.0015 12.3631779
11 50 75 0.005 0.0025 - 0.0025 12.5228787

Primera derivada Segu

9
20
8
Punto de 15
7 equivalencia
10
6

∆(∆pH/∆V)/∆V
5 5
∆𝑝𝐻/∆𝑉

4 0
5 10 15 20
3
-5
2
-10
1
0 -15
5 10 15 20 25 30 35 40 45 50 55
-20
V(gasto)
 𝑚=∆𝑝𝐻/∆𝑉
∆𝑝𝐻=𝑝𝐻2−𝑝𝐻1 ∆𝑉=𝑉2−𝑉1

∆pH ∆V(gasto) 1era deriv.∆(∆pH/∆V) ∆(∆pH/∆V)/∆V

1 0 0 0 0
0.36797679 10 0.03679768 0.03679768 0.0036797678529
0.58626572 10 0.05862657 0.02182889 0.0021828893885
0.73595357 4 0.18398839 0.12536182 0.0313404550582
0.30543911 0.5 0.61087823 0.42688984 0.8537796729816
4.00436481 0.5 8.00872961 7.39785138 14.795702763334
3.99567863 0.5 7.99135725 -0.01737236 -0.03474471674
0.2967512 0.5 0.5935024 -7.39785486 -14.79570971413
0.66617749 4 0.16654437 -0.42695802 -0.106739505659
0.40457059 10 0.04045706 -0.12608731 -0.012608731398
0.15970084 10 0.01597008 -0.02448697 -0.002448697447

Segunda derivada

Punto de
equivalencia

5 10 15 20 25 30 35 40 45 50 55

V(gasto)