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®
P22.1-18
PAPER-1 Academic Session: 2018-19 SET / CODE - 1
ALL INDIA OPEN TEST (AIOT)
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

(JEE ADVANCED PATTERN)
Target : JEE (Main+Advanced) 2019

Date: 03-05-2019 | Duration : 3 Hours | Max. Marks: 240
COURSE: VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)
Please read the last page of this booklet for the instructions.
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MATHEMATICS
PART : I MATHEMATICS
MATHEMATICS
SECTION – 1 : (Maximum Marks : 60)
 This section contains FIFTEEN questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.
1. Number of different words can be formed using all the letters of the word 'INTEGRATION'
1
(A) The probability that each word starts with E and ends in N is
55
18
(B) The probability that each word either starts with  or ends in N is
55
1
(C) The probability that order of vowels remains same is
125
1
(D) The probability that the vowels and consonants alternate in the words is
462
Space for Rough Work
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P101JPAIOT050519C1-1
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MATHEMATICS
3
2. All non-zero complex numbers satisfying z  z on the complex plane lie on the vertices of
MATHEMATICS
(A) a square (B) a rectangle
(C) an isosceles trapezium (D) a cyclic quadrilateral
2 
 1
  1

 2 cos1 x   1
 2 cos1 x  2
3. If the equation  a    a  0 has only one real solution then subsets of
   2  
   
values of 'a' are
(A) (–3, 1) (B) (–, –3]
(C) [1, ) (D) (2, )
4. f : R  R is one-one, onto and differentiable function and graph of y = f(x) is symmetric about the
point (4, 0) then :
(A) f–1(2010) + f–1(–2010) = 8

2018
(B)  f(x) dx = 0
–2010
(C) if f'(–100) > 0 then roots of x2 – f'(10)x – f'(10) = 0 may be non-real
(D) if f'(10) = 20, then f'(–2) = 20
MATHEMATICS
5. If c is an arbitrary constant then solution of differential equation x dy – y dx – xy (x – y)dy = 0 is 2 2 2
MATHEMATICS
2 2
xy y x  y y
(A) n   c (B) n   c
x  y 2 xy 2
2 2
y y

(C) ( x  y )e 2
 cxy (D) ( x  y )e 2
 cxy
6. A rod of length 2 units whose one end is (1, 0, –1) and other end touches the plane x – 2y + 2z + 4 = 0,
is rotated on this plane, then
(A) the rod sweeps a solid structure whose volume is  cubic units
(B) the area of the region which the rod traces on the plane is 2
(C) the length of projection of the rod on the plane is 3 units

 2 2 5 
(D) the centre of the region which the rod traces on the plane is  , , 
3 3 3 
7. Let [.] and { . } be greatest integer function and fractional part function respectively. If A 1, A2 are
area of closed regions formed by curves y = {| x |} – 1 , 5y = | 2x2 – 7x + 5|, x = –1 and x = 1,
where A1 is area of the region on left to y-axis and A2 is area of the region on right to y-axis then -
7 19
(A) A1 + A2 = (B) |A1 – A2| =
5 15
(C) [15 A1A2] = 1 (D) [15 A1A2] = 0
MATHEMATICS
8. Which of the following is/are CORRECT ? ([.] denotes greatest integer function)
MATHEMATICS
(A) If [sin–1x] > 0 then complete set of values of x is [a, b]. Then the value of [(cos –1b) + a] is 0
(B) If [sin–1x] > 0 then complete set of values of x is [a, b]. Then the value of [(cos –1b) + b] is 1
(C) Let A be a 2 × 3 matrix, B be a 3 × 2 matrix such that det(AB) = 4. Then the value of det (BA) is 0
(D) Let A be a 2 × 3 matrix, B be a 3 × 2 matrix such that det(AB) = 4. Then the value of det (BA) is 4
In a triangle ABC,   bc cos A 1   

2
9. ab   k cos A   cos A cos B  cos A cos B cos C
if k is equal to
(A) R (B) –R
(C) 2R (D) – 2R
10. Which of the following is/are CORRECT ?

(A) The coefficient of a8b4c9d9 in expansion of (abc + abd + acd + bcd)10 is 2520
10!
(B) The coefficient of a8b4c9d9 in expansion of (abc + abd + acd + bcd)10 is
8! 4! 9! 9!
(C) Suppose the probability for A to win a game against B is 0.4. If A has an option of playing
either a “best of 3 games “ or a “best of five games” match against B (No match in draw).
Then he should choose the option of best of 3 games so that the probability of his winning
the match is higher.
(D) Suppose the probability for A to win a game against B is 0.4. If A has an option of playing
either a “best of 3 games “ or a “best of five games” match against B (No match in draw).
Then he should choose the option of best of 5 games so that the probability of his winning
the match is higher.
MATHEMATICS
11. A circle touches both the circle x2 + y2 = 25 and (x – 2)2 + y2 = 1. Then locus of its centre is
MATHEMATICS
(A) Ellipse with focus (2, 0) and (0, 10)
(B) Ellipse with length of major axes 6
(C) Ellipse with eccentricity 1/4
(D) Ellipse with auxillary circle x2 + y2 – 2x – 8 = 0
n
(1  c o s x )  5 n x
12. Consider the function f(x) = lim n
, then
n 
2  (1  c o s x )
(A) f(x) is continuous at positive odd multiples of 
(B) f(x) is discontinuous at positive even multiples of 

(C) f(x) is discontinuous at positive odd multiples of
2

(D) f(x) is continuous at positive even multiples of
2
n n
Cr
13. Let  = lim  r
, then
n 
r0
n .( r  3 )
(A)  > 1/2 (B)  < 1 (C)  < 2 (D)  > 3/2
MATHEMATICS

ax
 xe ; x  0
14. Let f(x) =  where a is constant. In which of the following intervals f (x) is
MATHEMATICS
2 3
x  ax  x
 ; x  0
increasing
 a   2  a 
(A)  – ,  ,a<0 (B)  ,    , 
 3   a  3 
 2 a   2 
(C)  ,  ,a>0 (D) – , ,a<0
 a 3   a 
A B C
15. If ABC is a triangle and tan , tan , tan are in H.P., then
2 2 2
B
(A) the value of cot can be equal to 3
2
B
(B) the value of cot can be equal to 2
2
B
(C) the value of cot attains minimum if A = C
2
B
(D) the value of cot attains minimum if 2A = C
2
MATHEMATICS
MATHEMATICS
 This section contains FIVE questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+4 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases
16. The three distinct numbers a, b, c are in G.P. such that a + b + c = bx , then find the least positive
integral value of x.
17. The roots of the equation x5 – 40 x4 + Px3 + Qx2 + Rx + S = 0 are in G.P., if the sum of their
|s |
reciprocals is 10, then the value of can be equal to.
4
3 x 
18 While traveling at a speed of x km/hr a bus burns petrol    litres/km. If cost of petrol be
 x 300 
Rs 30/litre and other cost is also Rs30/h then speed for a journey of 75 km having minimum cost is
20  km/hr. Find the value of .
MATHEMATICS
a  a  x
2 2
a
The segment of the tangent to the curve y   a  x
2 2
MATHEMATICS
19. n contained between
a  a  x
2 2
2
y-axis and the point of tangency is a, then the numerical quantity  is equal to
20. As shown in the figure, three circles which have the same radius r have centers at (0,0), (1,1) and
(2,1). If they have a common tangent line, as shown, then the value of 10 5r is ___.
y
r
r C2
C1
r
x
O 1 2
C
PHYSICS
PART : II PHYSICS
PHYSICS
darkened.
21. Largest and smallest distance of a satellite from center of planet are given by R max and Rmin.
respectively. At these two positions speeds are given v min and vmax respectively. The time period of
revolution of the satellite is T. If 'a' and 'b' are semi major and semi minor axis then
R max  R min
(A) a 
2
(B) b  R max . R min
T
(C) a  v max v min
2
T
(D) b  v max v min
2

® Corp. / Reg. Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
PHYSICS
22. Two identical blocks are resting on supports as shown. Two identical bullets travelling with the
PHYSICS
same speed hit the blocks & get embedded in them in very short time. The blocks leave the
contact immediately after bullet strikes them. In case (i) bullet's velocity is toward centre of mass
and in case (ii) bullet's velocity is off centre. The kinetic energies after collision are K 1 & K2 and
maximum height reached by the centre of mass are h1 & h2 respectively. then :
Case (i) Case (ii)

(A) K1 < K2 (B) K1 = K2 (C) h1 < h2 (D) h1 = h2
23. An object of mass m = 2 kg is thrown vertically up. In the presence of heavy air resistance the time
of ascent (t1) is no longer equal to the time of descent (t 2), Similarly the initial speed (u) with which
the body is thrown is not equal to the final speed (v) with which the object returns. Assuming that
the air resistance F = 10 N is constant.
t2 v t2 u t2 3 t2 3
(A)  (B)  (C)  (D) 
t1 u t1 v t1 1 t1 1
24. A radioactive nucleus A can decay in P or Q with decay constant 2 and  respectively. Another
radioactive nucleus B decays in Q with decay constant 3. Initially number of active nuclei of A and
that of B are equal (N0). Select correct relation for any later moment t.
N0
(A) NA = NB = N0e–3t (B) NP = NQ = (1– e–3t)
3
N0 4N 0
(C) NP = 2NQ = (1– e–3t) (D) 2NP = NQ = (1– e–3t)
3 3
P101JPAIOT050519C1-10
PHYSICS
25. In the circuit shown in figure capacitor was initially uncharged switch is closed at t = 0. Select
PHYSICS
correct alternatives.
1.2 M
S
+ 600 k 2.5 F

48V –
(A) The initial battery current immediately after switch S is closed is 40 A

80
(B) The battery current, long time after switch S is closed is A
3
(C) The time after which current through capacitor becomes half is n4 sec.
80
(D) The current through the 600k as a function of time is (1 – e–t) A.
3
26. If one of the slit of a standard YDSE apparatus is covered by a thin glass slab so that it allows only
one half of the light intensity of the other then
(A) Resultant intensity at centre of screen will decrease
(B) Resultant intensity at dark fringe will increase
(C) The fringe width will remain unchanged
(D) The fringe pattern will shift toward the covered slit.
P101JPAIOT050519C1-11
PHYSICS
27. Consider following circuit and select correct alternative(s)
PHYSICS
4
A B
6 3
2V
4 2V
C D
6 3
4
E F
1
(A) Current through each cell is A
6
1
(B) Current through each 6 resistance is A
6
1
(C) Current through each 3 resistance is A
3
1
(D) Current through each 4 resistance is A
2
28. When an impedance, consisting of an inductance L and a resistance R in series, is connected

across a 12V, 50 Hz supply, a current of 0.05 A flows which differs in phase from that of the
applied potential difference by 60º. If a capacitor of capacitance C connected in series in the above
circuit has the effect of bringing the current into phase with the applied potential difference. Select
correct alternative :
(A) R = 120 (B) L  0.66 H (C) C  15.37 F (D) C  25.37 F
P101JPAIOT050519C1-12
PHYSICS
29. A horizontal disk of radius r = 0.2 m is fixed onto a horizontal frictionless table. One end of a
PHYSICS
massless string of length L = 0.8 m is fixed to the perimeter of the disk, while the other end is
attached to an object of mass m = 0.6 kg, which stands on the table as shown. The object is then
given a velocity of magnitude v = 0.4 m/s in a direction perpendicular to the string.
r
O
v
m
(A) Object will hit disc after t = 4s.
(B) Angular momentum about O will remain constant.
(C) Angular momentum about O will decrease till particle hits the disc.
(D) Kinetic energy of particle will remain constant.
P101JPAIOT050519C1-13
PHYSICS
30. A point object is kept at a distance of O P  u . The radius of curvature of spherical surface APB is
PHYSICS
C P  R . The refractive index of the media are n 1 and n 2 which are as shown in the diagram, then
(consider only paraxial rays)
(A) If n1  n 2 image is virtual for all values of u

(B) If n 2  2 n1 image is virtual when R u
(C) The image is real for all values of u, n1 and n2
(D) If n 2  n1 then image will be always real
31. Wavelength and intensity of monocromatic light falling on a photoelectric cell as a function of time
is given by  = 10000 e–t/10 Å and  = 1000 (1 – e–t/10). The threshold wave length of metal used in
cell is 3700 Å.
(A) Work function of metal plate is equal to 3.35 eV
(B) At t = 0 sec photo current is zero.
(C) At t = 5 sec photo current is zero.
(D) At t = 20 sec photo current is zero.
32. Which among the following forces is conservative?

 
F  2 xy î  x ˆj F  y î  xy ˆj
2 3 2
(A) (B)
 
F  y î  x ˆj F  2 xy î  x y ˆj
2 2 2
(C) (D)
P101JPAIOT050519C1-14
PHYSICS
33. The circuit shown in the figure consists of two resistances R 1 & R2 connected to two ideal
PHYSICS
voltmeters V1 & V2. A time varying magnetic field B(t) exists in a circular region of radius a and it is
directed into the plane of the figure B(t) = B0t where B0 is a positive constant of proper dimensions
and t is the time
b b
v1 R1 R v2
2
B (t )
(A)The emf induced in the circuit is  a B 0 :

2
 a B 0 R1
2
(B)The reading of V1 is :
R1  R 2
 a B 0 R1
2
(C) The reading of V2 is :

R1  R 2
(D) V1 = V2
P101JPAIOT050519C1-15
PHYSICS
34. Consider a uniformly charged non conducting, uniform spherical shell of radius R. Net charge on
PHYSICS
the shell is Q. There is a small hole in the shell at 'A' shown in the figure. A point charge –q is
released at a distance 2R from the centre as shown in the figure. The shell and point charge have
same mass m. After release the point charge will move toward shell, passes through the hole and
hit the shell at 'B'.
× × ×
× ×
× ×
× A –q
B
×
m
× ×
R
× × R
× ×
× ×
Choose the correct option(s) :
5R
(A) The distance travelled by point charge till it hit the shell at B is
2
kQ q
(B) Speed of the point charge when it hit the shell is
2m R
3
8m R
(C) Time taken by the point charge to travel from A to B is
kQ q
(D) The distance travelled by the shell with constant velocity is R
P101JPAIOT050519C1-16
PHYSICS
35. A cylinder of mass M and radius R lies on a plank of mass M as shown. The surface between
PHYSICS
plank and ground is smooth, and between cylinder and plank is rough. Assuming no slipping
between cylinder and plank, and velocity amplitude of oscillation of plank V.
(M, R)
K
M
M
(A) Time period of oscillation of the set up when displaced from equilibrium is 4
3K
V MK
(B) Friction between plank and cylinder when acceleration is maximum is
2 3
M
(C) Time period of oscillation of the set up when displaced from equilibrium is 2
3K
V MK
(D) Friction between plank and cylinder when acceleration is maximum is
4 3
P101JPAIOT050519C1-17
PHYSICS
PHYSICS
36. In given arrangement both blocks are of same mass 2 kg. Initially spring is compressed by
compression 10 cm. Spring constant is 200 N/m. Find the ratio of magnitude of relative
acceleration of the two blocks and acceleration of centre of two blocks.
Smooth
A
30º
P101JPAIOT050519C1-18
PHYSICS
37. Consider the system as shown in figure. The body of mass M = 3kg leans against wall P placed at
the bottom of an inclined plane of an angle  = 30º and a length s = 10 m. This body is connected
PHYSICS
by an inelastic string passed over an ideal pulley mounted at the top of the plane to another body
of mass m = 1 kg as shown. What should be horizontal velocity (in m/sec) of m so that the other
the body (M) may detach from the wall.
P M 
 V
m
N  0 I( 2  1)
38. In the given circuit ABCD is a square of side 'a'. If magnetic induction at point O is
2a
find the value of N. Dotted line represents that wire goes upto infinity.
I I
2I B
C
I 2I
O
D
I A 2I
Space for Rough Work 4I
P101JPAIOT050519C1-19
PHYSICS
39. A fork and a string of length 100 cm give 4 beats/s. The string is made shorter, without any change
PHYSICS
of tension, until it is in unison with the fork. Its new length is 99 cm. The frequency of the fork is
80P Hz. Find the value of P.
40. A heater is designed to operate with a power of 1000 W in a 100 V line. It is connected in
combination with a resistance of 10 and a resistance R to a 100V mains as shown in Fig. What
should be the value of R so that the heater operates with a power of 62.5 W ?
10 
P101JPAIOT050519C1-20
CHEMISTRY
PART : III CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]


darkened.
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P101JPAIOT050519C1-21
CHEMISTRY
41. Select correct statement(s):
(A) The dissolution of CaCl2.6H2O in a large volume of water is endothermic to the extent of
CHEMISTRY
3.5 kcal/mol. If H = –23.2 kcal for the reaction, CaCl2(s) + 6H2O(l)  CaCl2.6H2O(s) then heat
of solution of CaCl2 (anhydrous) in a large volume of water is –19.7 kcal/mol
(B) If the equilibrium constant for the reaction A2 2A at 500 K and 700 K are 10–10 and 10–5
respectively, then reaction is exothermic
207
(C) In the nuclear reaction 92 U 
235
82 Pb , the total number of  and  particles emitted would be
11
(D) An aqueous solution of an alcohol (B.P. = 64.7ºC) in water (B.P. = 100ºC) has vapour pressure
more than that of water
d
42. For a gas, plot between v/s p, where (d= density of gas in g/L and p = pressure in atm) at
p
300 K temperature was obtained as :
d
 
P
P
Which of the following statement(s) is/are incorrect about the gas?
(A) The gas shows non ideal behaviour
(B) The curve should have positive slope for an ideal gas
(C) The curve should be parallel to pressure axis for an ideal gas
d
(D) The plot of   v/s temperature for an ideal gas should have a positive slope
p
P101JPAIOT050519C1-22
CHEMISTRY
43. Choose the correct statement(s) amongs the following:
(A) Radial distribution function (4r22dr) gives probability at a particular distance along one
CHEMISTRY
chosen direction
(B) 2(r) give probability density at a particular distance
(C) For s orbitals (r, ) is independent of  and 
(D) 2p orbital with quantum numbers n =2  =1, m = 0 also shows angular dependence
44. 20 ml of 0.05 M solution of the conjugate acid of an -amino acid methionine (H2A+) is taken. The
pKa of –COOH group in methionine is 2.8 and pKb of basic group is 4.8. Pick out the correct
statement(s) amongs the following [Use log 2 = 0.3, log 5 = 0.7] :
(A) pH of original amino acid solution was ~2.05
(B) pH of solution was ~2.8 when 10 ml 0.05 M NaOH solution is added to original solution
(C) pH of solution was ~ 6 when 20 ml 0.05 M NaOH solution is added to original solution
(D) pH of solution was 3.8 when 20 ml 0.05 M NaOH solution is added to original solution
45. Which of the following is/are correct for a non-ideal solution of liquids A and B, showing negative
deviation?
(A) Vmix = –ve, as interaction between molecule A and B is low
(B) Vmix = –ve, as interaction between molecule A and B is high
(C) Gmix = –ve, as mixing is spontaneous
(D)Ssurrounding = +ve, as Hmix is negative
P101JPAIOT050519C1-23
CHEMISTRY
46. During the production of iron and steel:
(A) The oxide ore is primarily reduced to iron by solid coke according to the reaction :
CHEMISTRY
2Fe2O3 + 3C  4Fe + 3CO2
(B) The oxide ore is reduced by the carbon monoxide according to the reaction.:
Fe2O3 + 3CO  2Fe + 3CO2

(C) Major silica impurities are removed as calcium silicate slag by addition of a fluxing agent lime
stone
(D) The slag containing phosphorus is used as a fertilizer
47. When an inorganic compound (X) having 3c-2e as well as 2c-2e bonds reacts with ammonia gas
at a certain temperature, gives a compound (Y) iso-structural with benzene. Compound (X) with
ammonia at a high temperature, produces a hard substance (Z). Then:
(A) (X) is B2H6 (B) (Z) is known as inorganic graphite
(C) (Z) having structure similar to graphite (D) (Z) having structure similar to (X)
48. Which of the following species(s) is/are having only one corner shared per tetrahedron?
(A) Si2O76 (B) Cr2O72 (C) S 2O72 (D) Si3O96
49. Correct statement(s) for [Co(EDTA)]– ion is/ are (EDTA4– is ethylenediaminetetraacetate ion):
(A) Total number of stereoisomers which are optically active is 2
(B) Number of [N — Co — O] bond angle in complex is 8
(C) Cobalt have oxidation number = +3 and co-ordination number = 6
(D) EDTA4– is a chelating ligand and is hexadentate
P101JPAIOT050519C1-24
CHEMISTRY
CONH2
CHEMISTRY
50.
Which statement is correct :

(A) Reduced product of P and Q will be metamers to each other.
(B) By dry distillation of hydrolysed products of P with Ca(OH) 2, gives benzophenone.
(C) Hydrolysed product of Q, reacts with NaNO2 + HCl followed by reaction with phenol, gives
orange red dye.

(D) Electrophile involved in the formation of Q is dichlorocarbene.
OH H H OH OH H
51.
Br H Cl H Br H Cl H Br H Cl H
(I) (II) (III)
Choose the correct option/s according to given compounds.
(A) Compound (I)st & (III)rd are Identical
(B) Compound (I)st & (II)nd are diastereomers
(C) Compound (II)nd & (III)rd are positional Isomers
(D) Compound (I)st & (III)rd are enantiomers
P101JPAIOT050519C1-25
CHEMISTRY
52. Observed the following reaction sequence and identify the correct options ?
O
CHEMISTRY
CH2–C Zn –Hg HCl
O  (A)  (B)  (C)
  (D)
 (E)
AlCl
3 Zn –Hg
5 3 PCl AlCl
+ HCl
CH2–C Pd–C/
O
(F)
(A) F reacts with KMnO4/H+ gives phthalic acid which upon heating gives phthalic anhydride.
(B) E upon monochlorination (Cl2/h) gives total four products.
(C) F upon complete catalytic hydrogenation gives saturated compound which show geometrical
isomerism.
(D) Compound (A) gives positive test with NaHCO3.
53. Which statements are correct in the following ?

(A) Cyclopentadiene reacts with NaNH2 and releases NH3 gas however cyclopropene does not.
(B) Cyclopropenone has a greater dipole moment than acetone
(C) Cyclobutadiene does not exist at room temperature but cyclobutene exists at room
temperature
(D) Cycloheptatrienyl bromide ionizes faster however cyclopentadienyl bromide does not
54. Optically active amines having molecular formula C5H13N on reaction with NaNO2 + HCl produces
tertiary optically inactive alcohol. Find out structures of amines.
NH2
NH2 N NH2
(A) (B) (C) (D)
P101JPAIOT050519C1-26
CHEMISTRY
55. Consider the structure of raffinose, a trisaccharide found in sugar beets and a number of higher
plants.
CHEMISTRY
HO
CH2OH O
H
HO OH
O
CH2 O
HO
H
HO OH
O
HOCH2
O
HO
CH2OH
OH
RAFFINOSE
Which is correct for raffinose :

(A) Raffinose is a non reducing sugar
(B) The glycoside linkages in raffinose are  (1, 6) glycoside linkage and  (1, 2) glycoside
linkage
(C) Raffinose is hydrolyzed into equal amounts of D-galactose, D-glucose and D-fructose
(D) Raffinose will show mutarotation
P101JPAIOT050519C1-27
CHEMISTRY
CHEMISTRY

56. Let z is the atomic number of the element with the maximum number of unpaired 4p electrons and
having spin multiplicity S. Let 'n' and 'p' are the group number and period number respectively in
zpSn
the modern periodic table for this element. Find .
8
57. The density of a pure substance 'A' whose atoms pack in cubic close pack arrangement is 1 g/cc.
If B atoms can occupy tetrahedral void and if all the tetrahedral voids are occupied by 'B' atoms.
What is the density of resulting solid in g/cc? [Atomic mass (A) = 20 g/mol & atomic mass
(B) = 40 g/mol]
P101JPAIOT050519C1-28
CHEMISTRY
58. How many of the following can liberate H2 gas when dissolved in water or heated with water?
CHEMISTRY
B2H6, C2H6, SiH4, CaH2,
B3N3H6, PH3, sodium amalgam, KO2,
XeF2, H2S, Cl2, SrC2,
59. Observe the following compounds.
OH NH2
.. ..
N
N
H N H N
(a) (d) (e) (f)
Write the number of those compound which is more basic than pyridine .
N
P101JPAIOT050519C1-29
CHEMISTRY
60. Consider the figure
CHEMISTRY
mixture separation
of amino of amino
acids acids
filter paper
Buffer solution
Buffer solution (pH = 5.0)
(pH = 5.0)
(Electrophoresis) (After Electrophoresis)
pKa Values
S.No. Amino acids
side chain
1. Arginine 2.17 9.04 12.48
2. Alanine 2.34 9.69 ------
3. Aspartic acid 2.09 9.82 3.86
4. Lysine 2.18 8.95 10.79
5 Glutamic acid 2.19 9.67 4.25
6. Valine 2.32 9.62 ------
Calculate :
Number of non essential amino acids move towards cathod = x
Number of essential amino acids move towards anode = y
Number of amino acids move towards cathod = z
FIND x + y + z = ?
P101JPAIOT050519C1-30
P22.1-18
ALL INDIA OPEN TEST (AIOT) (JEE ADVANCED PATTERN)
PA PER - 1 COURSE : VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)

DATE : 03-05-2019
SET / CODE - 1
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the
back cover of this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.

6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :
7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has two sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum

Number of
Section Question Type Negative Marks
Questions Full Marks Partial Marks Zero Marks
Marks of the Section
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of the
1 15 corresponding to all the corresponding to each correct In all other 60
Correct Option(s) bubbles is
correct option(s) is(are) option, provided NO incorrect cases
darkened
darkened option is darkened
+4 0
–1
Single digit Integer If only the bubbles If none of the
2 5 – In all other 20
(0-9) corresponding to the correct bubbles is
cases
answer is darkened darkened
OPTICAL RESPONSE SHEET :

9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :

13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.
NAME OF THE CANDIDATE : ………………………………………………………………..………………………
ROLL NO. : ………………………..………………………
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

®
P22.1-18
PAPER-2 Academic Session: 2018-19 SET / CODE - 1
ALL INDIA OPEN TEST (AIOT)

(JEE ADVANCED PATTERN)
Target : JEE (Main+Advanced) 2019

Date: 03-05-2019 | Duration : 3 Hours | Max. Marks: 240
COURSE : VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)
Please read the last page of this booklet for the instructions.
MATHEMATICS
PART : I MATHEMATICS
MATHEMATICS
 This section contains FOUR questions
darkened.
1. If composite function f1 ( f 2 ( f 3 ( . . . . . . . . . . . . ( f n ( x ) ) ) ) ) , is an increasing function and if r of fi’s are

n t im e s
decreasing function while rest are increasing, then maximum value of r(n – r) is
2 2
n 1 n
(A) when n is an even number (B) when n is an odd number
4 4
2 2
n 1 n
(C) when n is an odd number (D) when n is even number
4 4
MATHEMATICS
2. If f(x) ( 0) is a real function whose derivatives upto third order exist and for some pair a, b  R (a < b) ,
MATHEMATICS
 f ( a )  f  ( a )  f  ( a )  f  ( c )
n   = a – b, then for some c (a, b), can not be equal to
 f ( b )  f  ( b )  f  ( b )  f (c )
(A) 0 (B) 1 (C) –1 (D) 2
3. Let ABC be a right triangle with right angle at C. Let D and E be points on AB with D between A
DE 8 m p
and E such that CD and CE trisect C. f = , then tan B can be written as , where m
BE 15 n
and n are relatively prime positive integers and p is a positive integer not divisible by the square of
any prime. which is/are correct
(A) m2 + p2 = (n – 2p)2
(B) n + n + p = 18
m
(C) The probability of a prime number chosen from set {0, 1, 2, ........ 10} is
n
p
(D) The probability of a prime number chosen from set {0, 1, 2, ........ 10} is
n
4. Let C : x2 + y2 = 1 and H : x2 – y2 = 2 be two curves.

(A) Equation of common tangents to the curves C and H are y   3x  2
8
(B) Area of the region bounded by these common tangents is .
3
(C) Equation of the ellipse passing through the points of intersection of these common tangents is
2 2
3x  y  4 .
(D) If common tangent to these curves which intersects the positive coordinate axis is
considered as tangent at vertex and origin is considered as focus then latus rectum of the
parabola is 4.
MATHEMATICS
MATHEMATICS
 This section contains THREE paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct 
+4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened
Paragraph for Question Nos. 5 to 6

Consider f, g be two real valued differentiable functions defined on R.
Let g(x) = x3 + g''(1) x2 + (3g'(1) – g''(1) – 1) x + 3g'(1), f(x) = x g (x) – 12x + 1
5. N The function y = f(x) has
(A) Exactly one local minima and no local maxima
(B) Exactly one local maxima and no local minima
(C) Exactly one local maxima and two local minima
(D) Exactly two local maxima and one local minima
6. Which of the following is/are true for the function y = g(x)?

 1   1 
(A) g(x) monotonically decreases in   ,2    2 , 
 3   3 
 1 1 
(B) g(x) monotonically increases in 2 ,2  
 3 3 
(C) There exists exactly one tangent to y = g(x) which is parallel to the chord joining the points
(1, g(1)) and (3, g(3))
(D) There exists exactly two distinct Lagrange's mean value in (0, 4) for the function y = g(x).
MATHEMATICS
MATHEMATICS
Consecutive two digit numbers starting from any number upto 99 are written in the increasing
order to form a number N.
e.g. If N is divisible by 9, then
N may be equal to 10111213 .... 9899
In the given number N = 10111213 ..... 9899 there are
19 1’s
19 2’s
19 3’s
.
.
19 9’s
9  10
 Sum of digits = 19 × = 9 × 95
2
 N is divisible by 9
like wise N may be equal to 181920 ..... 99 (also divisible by 9) etc.
7. Two digit numbers from which one should start so that N is divisible by 3 are
(A) 13, 16, 19, 20 (B) 13, 16, 18, 20
(C) 13, 15, 16, 19, 20 (D) 12, 13, 15, 16, 18, 19, 21
8. Two digit numbers from which one should start so that N is divisible by 9 are
(A) 10, 18, 19, 27, 28, 36, 37, ...... (B) 10, 18, 19, 20, 21, ....
(C) 10, 18, 20, 22, 24, ..... (D) 10, 18, 20, 27, .....
MATHEMATICS
MATHEMATICS
The curve which is touched by each member of a series of lines, which are all drawn to satisfy
some given condition is called the envelope of these lines.
The envelope of the straight line x + my + 1 = 0 where the quantities  and m are connected by
the relation a2 + bm2 + 2gm + 2f+ 2hm+ c = 0 can be obtained by removing m or from the
condition with the help of the line x + my + 1 = 0. This gives us a quadratic in one of the
parameters or m. Further make discriminant of that quadratic equal to zero to get required
envelope.
9. If 2m + 2 – 3m2 + 1 = 0, then the variable line x + my – 1 = 0 always touches a fixed
(A) circle (B) parabola
(C) ellipse (D) hyperbola
10. The locus of the points from which two perpendicular tangents can be drawn to the curve obtained
in the above question is
(A) x2 + y2 = 8 (B) x = 1
(C) x2 + y2 = 2 (D) x = 0
MATHEMATICS
MATHEMATICS
 This section contains TEN questions.
 The answer to each question is DOUBLE DIGIT INTEGER ranging from 00 to 99 with Positive /
Negative.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
 If your answer is 55 then the correct response in ORS is 55.
 If your answer is –55 mark correct response in ORS is –55.
+4 If the bubble corresponding to only correct answer is darkened
 
11 If the sum of all the values of x in the interval 0,  satisfying the equation
 2 
3 – cos 6 x k
sin4x + cos4x = is , then find the value of k.
4 10
3 x 2  ( x  2 )2 5x
2
2x 
   
12. Let A =  1  , B = [a b c] and C = 5x2 2x
2
(x  2)  be three given matrices, where
 6x   2 2

   2x (x  2) 5x 
a,b,c, x  R. Given that trace(AB) = trace(C)  x R. If f(x) = ax2 + bx + c, then f(1) is, where
trace is sum of diagonal elements.
MATHEMATICS
13. = lim ( n
2
 n 1 – [ n
2
 n  1 ]) , where n and [.] denotes greatest integer function. Find the
MATHEMATICS
n 
value of 18 .
s in 2 x a  b cos x
14. If  3
dx  d
 e where a, b, c, d are positive integers and e is arbitrary
(3  4 cos x ) c (3  4 co s x )
constant then minimum value of (a + b + c + d – 20) equal to
15. If f(x) be a twice differentiable function from R  R such that t2f(x) – 2t f '(x) + f "(x) = 0 has two
 f(x) – 1 t 
equal values of t for all x and f(0) = 1, f '(0) = 2, then lim  –  is
x 0 x 2 
16. Let f(x) be a continuous function satisfying 9f(3)   ( x 2 2

f '( x )  ( f ( x )) ) dx + k. Find least possible
0
value of k.
MATHEMATICS
17. Let a  î  ˆj  kˆ and Let r be a variable vector such that r . î , r . ˆj and r . kˆ are positive
MATHEMATICS
integers. If r . a  12, and the number of values of r is  then the value of will be-
18. The first twelve alphabet are written along a line, at random. Let probability that there are exactly
p
4 letters between A and B is (p and q are relatively prime). If q is divided by p then remainder is
q
19. Number of integral values of ‘k’ for which the chord of the circle x2 + y2 = 125 passing through
P(8, k) gets bisected at P(8, k) and has integral slope is
0 , if r  s
20. If A1,A 2, A 3 and B 1 ,B 2 , B 3 are two sets of non-coplanar vectors such that Ar Bs = 
5 , if r  s
1
for r = 1,2,3 and s = 1,2,3 then the value of [A1 A 2
A 3
] [B1 B 2 B 3 ] equals.
25
PHYSICS
PART : II PHYSICS
PHYSICS
darkened.
PHYSICS
21. Four point sources each of frequency (f) are fixed at their position as shown in the figure. An
PHYSICS

observer moving with constant velocity V is crossing origin. 'N' is number of different frequencies
observed by the observer at the moment when it is crossing origin.
S2 (0, 2, 0)
S3 S1
(–2,0,0) (2,0,0) x
S4 (0, –2, 0)

(A) If v = 5 î then N = 3

(B) If v = 5 ( î  ˆj ) then N = 4

(C) If v = 5 kˆ then N = 1

(D) If v = ( î  ˆj  kˆ ) then N = 2
P201JPAIOT050519C1-10
PHYSICS
22. For the circuit shown in figure, R1 = 3R, R2 = R, C1 = C2 = C, and L1 = L2 = L. The electromotive
PHYSICS
force of the battery is E. Initially the switch is closed and the system is operating in steady state.
The voltmeter is ideal and it measures VA – VB. The switch is opened at t = 0
A B
V
R1 R2
c1
L2
L1 C2
The reading of voltmeter -
(A) Just before the opening switch is E
(B) Just after the opening of switch is –2 E
(C) Long time after opening the switch is E
(D) Is zero at any moment
P201JPAIOT050519C1-11
PHYSICS
23. A rod of mass m and length  is acted upon by two forces each of magnitude F as shown in the
PHYSICS
figure. The length of the rod is , area of cross section is A, the young’s modulus of the material is
Y. Select correct alternative
F F
Smooth
F
(A) The stress in rod at mid point of the rod is .
A
F
(B) The stress in rod at a distance from one end is .
4 2A
F
(C) Net change in length of the rod is .
AY
(D) Total elastic potential energy stored in the rod is zero.
24. In a certain gravity free space, the piston of an injection is being pushed so that the water jet
comes out with a constant speed v. The area of the piston is much greater than the orifice of the
injection.
(A) The force required to be applied on the piston is proportional to v2.
(B) The power developed by the force pushing the piston is proportional to v3.
(C) The time for emptying the injection is proportional to v1.
(D) The total work done in emptying the injection is proportional to v2.
P201JPAIOT050519C1-12
PHYSICS
PHYSICS
correct 


At t = 0 a charged particle of mass m, charge q moving with velocity V  V î is at origin. Either
 
electric field E  E 0 ˆj
or magnetic field B   B 0 kˆ is present in the region. For t > 0, E and B are
switched on in following manner.
E B Time

0 B 0  t  t0

E
0 t0  t  2t0
m
Where t0 
2qB 0
and numerically
VB0 = E0
y
x
q, m v
25. The speed of particle at t = 2t0 will be : for Rough Work
Space
V 3V
(A) 2V (B) (C) V (D)
2 2
mV
26. The coordinate of the particle at t = 2t0 will be, if R =
qB
 5   5 
(A) x = R ; y = R 1   (B) x = – R ; y = R 1  
 8   4 
 5   5 
(C) x = 2R ; y = R 1   (D) x = R 2 ;y= R 2 1  
 4   8 
P201JPAIOT050519C1-13
PHYSICS
PHYSICS
Consider two metallic plates of area A placed very close to each other. The charges on two plates
are +Q and –Q respectively. Space between two plates is filled by a non-conducting medium of
charge per unit volume . Assume that dimensions of plates are very large in comparison to
distance between plates. Maximum electric field between plates is two times of minimum electric
field in between the plates for condition (2Q > Ad).
+Q –Q
d
27. The separation between plates is
Q Q 2Q Q
(A) (B) (C) (D)
A 3A 3A 3A
28. Suppose we assume positive plate at zero potential. As we move along x-axis potential changes
according to curve –
v v
(A) (B)
x x
v v
(C) (D)
x x
P201JPAIOT050519C1-14
PHYSICS
PHYSICS
A piston encloses some air in the cylindrical vessel with horizontal longitudinal axis as shown in
the drawing. Initial pressure of the air is equal to the external atmospheric pressure of 10 5 Pa. The
cross-sectional area of the piston is 300 cm 2. An originally upstretched spring with spring constant
2000 N/m is attached the piston. The walls of the vessel and the piston are perfectly insulated. The
initial volume of the enclosed air is 0.024 m 3. Its initial temperature is 300 K. The air is heated to
360 K with a heating filament built into the vessel.
29. Find the displacement of the piston caused by the heating.
(A) 0.1 m (B) 0.2 m (C) 0.3 m (D) 0.4 m
30. Change in internal energy of the gas is
(A) 800 J (B) 1200 J (C) 2000 J (D) 200 J

P201JPAIOT050519C1-15
PHYSICS
PHYSICS
Negative.
31. A large tank is filled with water at the rate of 70 cm 3/s. A hole of cross-section 0.25 cm 2 is punched
at the bottom of the tank. Find the maximum height to which the tank can be filled (in cm).
(Take g = 9.8 m/s2)
32. A uniform disc of mass m and Radius R is to be kept in equilibrium such that its one surface is
touched at a horizontal wall, by irradiating a parallel beam of electromagnetic radiation of intensity
, at an angle  with the vertical. Whole arrangement is shown in figure. Disc is perfectly absorbing.
If the minimum coefficient of friction required between disc and horizontal wall for this propose is
2
 R  
  2
. Find minimum value of  +  +   use    .
 R  m g C  4 
 
g
P201JPAIOT050519C1-16
PHYSICS
33. Two masses m1 = 1 kg & m2 = 2kg, are connected by a fine inelastic taut string shown. Then m 1 is
PHYSICS
raised vertically by height 'h =20m' and let fall. Find the the interval (in second) between m 2 leaving
the table and returning to it again ?
m2 m1
2m 1 2h / g
t 
m 2  m1
P201JPAIOT050519C1-17
PHYSICS
34. In the system shown, M = 10 kg. The coefficient of friction between block and ground is 0.4 and
PHYSICS
that between two blocks is 0.1. The maximum value of m (in kg) so that the arrangement shown in
the figure is in equilibrium is given by P/4. Find the value of P.
 = 0.1
M m
 = 0.4
35. For short wave (ripples) speed of water waves depends on surface tension S, density of water ,
wave length  according to equation.
V = kSx y z.
hare k is a unit less term.
Find the value of 12 (x – y + z)
P201JPAIOT050519C1-18
PHYSICS
36. A cardboard strip, bent in the shape of the letter C, is put on a rough inclined plane, as shown in
the figure. If  is maximum angle for which block does not topple then find the value of 9 tan 2?
PHYSICS
(Assume that it does not slide).
  

37. A tunnel is dug inside the earth across one of its diameters. Radius of earth is R and its mass is M.
2G M
A particle is projected inside the tunnel with velocity from one of its ends then maximum
R
nG M
velocity attained by the particle in the subsequent motion is (assuming tunnel to be
R
frictionless). Find n.
38. In a hypothetical atom, negatively charged particle having a charge of magnitude 3e and mass 3m
revolves around a proton. Here, e is the magnitude of electronic charge and m is the electronic
mass. Mass of proton may be assumed to be much larger than that of the negatively charged
particle, thus the proton is at rest. This "atom" obeys Bohr's postulate of quantization of angular
 h 
momentum, that is m vr  n   . It is given that for the first Bohr orbit of hydrogen atom total
 2 
energy is – E0. The momentum of an emitted photon when it makes a transition from the second
NE0
excited state to ground state is. Find the value of N
c
P201JPAIOT050519C1-19
PHYSICS
39. A conductor carrying current 60A is in the form of a semicircle AB of radius R and lying in xy-plane
 
PHYSICS
with its centre 'O' at origin as shown in the figure. The magnitude of
 B .d  for the circle
x2 + z2 = 3R2 in xz-plane due to current in curve AB is 10n0. Find the value of n (n is an integer)
Y
B


O X
Z A
40. A 3-4-5 inclined plane is fixed to a rotating turntable. A block rests on the inclined plane and the
coefficient of static friction between the inclined plane and the block is s = ¼. The block is to
remain at a position 40 cm from the center of rotation of the turntable (figure). Find the minimum
angular velocity  (in rad/sec) to keep the block from sliding down the plane (toward the center)
(Round off to the nearest integer).
3
5
4


P201JPAIOT050519C1-20
CHEMISTRY
PART : III CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
CHEMISTRY
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

darkened.
41. Which statement(s) comparing the soap (sodium stearate) and the detergent (sodium lauryl
sulfate) is/are true?
(A) Both form micelles when dispersed in water
(B) The soap starts to precipitate out at mildly acidic pH, but the detergent does not
(C) The soap is less alkaline (basic) than the detergent
(D) Calcium salts of the soap are relatively insoluble in water
P201JPAIOT050519C1-21
CHEMISTRY
42. Consider the following two carbonyl compounds:
(i) [Tc(CO)6]+ and (ii) [Nb(CO)6]–1 [Atomic number Tc = 43, Nb = 41]
CHEMISTRY
Select incorrect statement(s) for given carbonyl compounds:
(A) [Tc(CO)6]+ acts as a reducing agent and [Nb(CO)6]–1 acts as oxidizing agent
(B) Bond order of C–O bond in both [Tc(CO)6]+ and [Nb(CO)6]–1 is 3
(C) Nb–C bond order in [Nb(CO)6]–1 is greater than Tc–C bond order in [Tc(CO)6]+1
(D) C–O bond order is greater in [Nb(CO)6]–1 than in [Tc(CO)6]+1
43. In which of the following reaction (s), reactant and products are correctly matched ?
(A)
(2 mole)
(B)
(C)
(D)
P201JPAIOT050519C1-22
CHEMISTRY
H2/Pt
Compound (Q) C8H18
CHEMISTRY
(Optically inactive)
Compound (P) C8H12
44. H2 + Pd + BaSO4
(Optically active enyne)
Compound (R) C8H14
Lindlar's catalyst
(Optically active)
Na / liq. NH3
Compound (S) C8H14
(Optically inactive)
Which amongs the following is/are correct for above sequence of reactions ?
(A) Oxidative ozonolysis product of P, R & S will be achiral
(B) R & S are diastereomers
(C) Product Q & R are formed by syn addition & S is formed by anti addition
(D) P must have cis configuration
P201JPAIOT050519C1-23
CHEMISTRY
CHEMISTRY
correct 
A fuel cell is the device to convert the energy of a fuel into electrical energy without the use of heat
engine, where the fuel is burnt directly. Such conversions are possible because the overall
reaction are highly exothermic. Electrical energy can be obtained indefinitely from a fuel cell as
long as the outside supply of fuel is maintained. In hydrogen -oxygen fuel cell, the following
reaction take place.
Anode reaction: 2H2(g) + 4OH–(aq)  4H2O(l) +4e–
Cathode reaction: O2(g) + 2H2O(l) +4e–  4OH–(aq)
Overall reaction: 2H2(g) + O2(g)  2H2O (l)
Hºf [H2O(l)] = –285.8 kJ mol–1 and G ºf [H2O(l)] = –237.39 kJ mol–1 at 25ºC
P201JPAIOT050519C1-24
CHEMISTRY
45. What is the standard EMF of the given fuel cell ?
(A) 1.21 V (B) 1.23 V (C) 1.25 V (D) 1.27 V
CHEMISTRY
46. How many litres of gaseous H2, when combined with excess O2 in the fuel cell at 25ºC and 1.00
bar, are needed to produce 23.739 kJ of useful work under standard conditions (R = 0.083 bar
L/mol K)?
(A) 2.47 L (B) 4.84 L (C) 1.23 L (D) 2.26 L
K2CrO4  Gas(H) H2O

 A B C FeSO4+dil H2SO4
very low D E
Yellow ppt Give blue colour Brown temp. Blue Complex compound
to the flame gas colour
H2S
dil. HNO3
F G + H

Black ppt Neutral oxide Gas
47. Compound (D) +I– + H+  Gas

Evolved gas is similar to:
(A) Gas–B (B) Gas–G (C) Gas–H (D) None of these
P201JPAIOT050519C1-25
CHEMISTRY
48. Which of the following statements are correct?
(I) Yellow ppt. of compound () is insoluble in CH3COOH
CHEMISTRY
(II) Type of hybridization of complex E is sp3d2.
(III) Compound C is N2O4.
(IV) Type of hybridization of central atom of gas (B) is sp2.
(A) I, II (B) III, IV (C) I, II, IV (D) I, II, III
On the bases of following information answer the given two questions.

dil.H2SO4
C5H10O Q + R R reduces Tollens reagent
(P) (1) I2+NaOH (1) I2+NaOH
(2) H3O (2) H3O
CHI3 + S CHI3 + T
49. P will be –
(A) CH2=C–O–CH2–CH3 (B) CH2=CH–O–CH2–CH2–CH3
CH3
(C) CH2=CH–O–CH–CH3 (D) CH2=CH–CH2–O–CH2–CH3
CH3
50. Which amongs the following is incorrect statement –

(A) [Q] is also formed when propene is reacted with dil.H 2SO4.
(B) [Q] will also give coloured complex with neutral FeCl3.
(C) The product formed by dry distillation of calcium salt of [S] will give acetone.
(D) [T] will also give silver mirror with ammonical solution of AgNO 3.
P201JPAIOT050519C1-26
CHEMISTRY
CHEMISTRY
Negative.
51. The degree of irreversibility of a process may be given as q irr/qrev. The entropy change for an
isothermal expansion of an ideal gas at 300 K from a particular state 'A' to another state 'B' is
50 J/K. When irreversible isothermal expansion was performed, the work done by the system was
6 kJ. Calculate the degree of irreversibility. [Fill your answer by multiplying it with 100]
P201JPAIOT050519C1-27
CHEMISTRY
52. Estimate Hºf {pyridine ()] in KJ/mole from the given data.
CHEMISTRY
Hºf 298K
Compound
in kJ/mole
CH2=N–CH3(g) +44 Resonance energy N = –125kJ/mol

Pyridine
CH3–NH–CH3(g) –18
(g) –37 Hvap.298K N = +40 kJ/mol

Pyridine
(g) –156
N–H(g) –50
P201JPAIOT050519C1-28
CHEMISTRY
53. Kinetic data for hydrolysis of a 0.3 M solution of ethyl acetate in presence of HCl as catalyst is
given in the following table. A constant volume of reaction mixture is taken at different time and
CHEMISTRY
titrated against standard alkali solution at different time.
Time / min 0 10 
Vol. of Alkali / ml 25.00 28.00 40.00
If the rate law is given by rate = k[Ester]1 [H+]1, where H+ is a catalyst, find the rate (in M/min) of
ester hydrolysis in a solution which is 0.1 M each in ester and acid HCl.
5
Use: ln   = 0.225. Report your answer by multiplying actual answer by 105.
4
54. When 1 mol of A(g) is introduced in a closed rigid 1 litre vessel maintained at constant temperature
the following equlibria are established:
A(g) B(g) + C(g) : K C1
C(g) D(g) + B(g) : K C2
K C2 Ceq 1
The pressure at equilibrium is twice the initial pressure. Calculate the value of if 
K C1 Beq 5
55. The first, second and third ionization energies of an element 'X' are 7 eV, 12 eV and 42.5 eV
respectively. The energy required in eV/atom to transform X(g) into its gaseous ion having most
stable oxidation state is :
P201JPAIOT050519C1-29
CHEMISTRY
56. Two inter halogen compounds are XYn1 and XYn2 where Y is more electronegative atom than X.
CHEMISTRY
If XYn1 is a non–polar, non planar inter halogen compound and XYn2 is a T–shaped inter halogen
compound then find n1 × n2.
57. How many statement(s) is/are correct.

(a) In some cases, constitutional isomers are chiral.
(b) In every case, a pair of enantiomers have a mirror-image relationship.
(c) Mirror-image molecules are in all cases enantiomers.
(d) If a compound has an enantiomer it must be chiral.
(e) Every chiral compound has a diastereomer.
(f) If a compound has a diastereomer it must be chiral.
(g) Every molecule containing one or more asymmetric carbons is chiral.
(h) Any molecule containing a stereocenter must be chiral.
(i) Any molecule with a stereocenter must have a stereoisomer.
(j) Some diastereomers have a mirror-image relationship.
(k) Any chiral compound with a single asymmetric carbon must have a positive optical rotation if
the compound has the R configuration.
(l) If a structure has no plane of symmetry it is chiral.
(m) All chiral molecules have no plane of symmetry.
(n) All asymmetric carbons are stereocenters.
(o) Gauche form of n-butane is chiral however, anti form is achiral along C2–C3 bond.
P201JPAIOT050519C1-30
CHEMISTRY
58. When p-aminophenol reacts with one molar equivalent of acetic anhydride, a compound A
(C8H9NO2) is formed that dissolves in dilute NaOH. When A is treated with one equivalent of NaOH
CHEMISTRY
followed by ethyl iodide, an ethyl ether B is formed.
Calculate the total number of delocalised in compound B.
59. Observe the following reaction and mention the number which show slowest and rate determine
step.
(1)
(2)
(3)
(4)
60. A six membered cyclic compound A (C7H14O) gives instant turbidity with lucas reagent and forms a
compound B. B on reaction with alcoholic KOH gives major product C. C on reductive ozonolysis
gives D. D in aq. alkali medium forms an  unsaturated carbonyl compound E. Find the sum of
ring size (if any) and degree of unsaturation (hydrogen deficency index) of E.
P201JPAIOT050519C1-31
ALL INDIA OPEN TEST (AIOT) (JEE ADVANCED PATTERN)
P22.1-18 PAPER-2
COURSE : VIJETA(JP),VISHWAAS(JF),VIJAY(JR),VIVEK(JCC)
DATE : 03-05-2019
SET / CODE - 1
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet .
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.

6. After the open booklet, verify that the booklet contains all the 60 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Negative Marks of the
Questions Full Marks Partial Marks Zero Marks
Marks Section
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of the
1 4 corresponding to all the corresponding to each correct In all other 16
Correct Option(s) bubbles is
correct option(s) is(are) option, provided NO incorrect cases
darkened
darkened option is darkened
+4 0
Comprehension –1
If only the bubble If none of the
2 (Single Correct 6 – In all other 24
corresponding to the correct bubbles is
Option) cases
option is darkened darkened
Double digit with +4 0
If only the bubble If none of the No negative
3 positive/negative/Z 10 – 40
corresponding to the correct bubbles is marks
ero option is darkened darkened
OPTICAL RESPONSE SHEET :

9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.
DARKENING THE BUBBLES ON THE ORS :
13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.
NAME OF THE CANDIDATE : ………………………………………………………………..………………………
ROLL NO. : ………………………..………………………

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator


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®

ALL INDIA OPEN TEST (AIOT)

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

Target : JEE (Main+Advanced) 2019

Space for Rough Work

(C) an isosceles trapezium (D) a cyclic quadrilateral

values of 'a' are

(A) (–3, 1) (B) (–, –3]

(C) [1, ) (D) (2, )

point (4, 0) then :

(A) f–1(2010) + f–1(–2010) = 8

(C) if f'(–100) > 0 then roots of x2 – f'(10)x – f'(10) = 0 may be non-real

(D) if f'(10) = 20, then f'(–2) = 20

Space for Rough Work

5. If c is an arbitrary constant then solution of differential equation x dy – y dx – xy (x – y)dy = 0 is 2 2 2

(C) the length of projection of the rod on the plane is 3 units

area of closed regions formed by curves y = {| x |} – 1 , 5y = | 2x2 – 7x + 5|, x = –1 and x = 1,

(C) [15 A1A2] = 1 (D) [15 A1A2] = 0

Space for Rough Work

In a triangle ABC,   bc cos A 1   

10. Which of the following is/are CORRECT ?

Space for Rough Work

(B) Ellipse with length of major axes 6

(C) Ellipse with eccentricity 1/4

(D) Ellipse with auxillary circle x2 + y2 – 2x – 8 = 0

(A) f(x) is continuous at positive odd multiples of 

(B) f(x) is discontinuous at positive even multiples of 

Space for Rough Work

Space for Rough Work

SECTION – 2 : (Maximum Marks : 20)

20  km/hr. Find the value of .

Space for Rough Work

Space for Rough Work

(B) b  R max . R min

Space for Rough Work

Case (i) Case (ii)

Space for Rough Work

+ 600 k 2.5 F

(A) The initial battery current immediately after switch S is closed is 40 A

Space for Rough Work

28. When an impedance, consisting of an inductance L and a resistance R in series, is connected

Space for Rough Work

given a velocity of magnitude v = 0.4 m/s in a direction perpendicular to the string.

(A) Object will hit disc after t = 4s.

(B) Angular momentum about O will remain constant.

(D) Kinetic energy of particle will remain constant.

Space for Rough Work

(A) If n1  n 2 image is virtual for all values of u

(C) The image is real for all values of u, n1 and n2

(D) If n 2  n1 then image will be always real

32. Which among the following forces is conservative?

Space for Rough Work

and t is the time

(A)The emf induced in the circuit is  a B 0 :

(C) The reading of V2 is :

Space for Rough Work

(D) The distance travelled by the shell with constant velocity is R

Space for Rough Work

between cylinder and plank, and velocity amplitude of oscillation of plank V.

Space for Rough Work

Space for Rough Work

SECTION – 2 : (Maximum Marks : 20)

acceleration of the two blocks and acceleration of centre of two blocks.