Previous year Questions jee and neet

Ques 1. Liquids A and B form an ideal solution in the entire composition range. At
350 K, the vapour pressures of pure A and pure B are 7 × 103 Pa and 12 × 103 Pa,
respectively. The composition of the vapour in equilibrium with a solution
containing 40 mole percent of A at this temperature is
(a) xA = 0.4; xB = 0.6 
(b) xA = 0.28 ; xB = 0.72 
(c) xA = 0.37 ; xB = 0.63 
(d) xA = 0.76 ; xB = 0.24

 Ques 2. A solution containing 62 g ethylene glycol in 250 g water is cooled to –

10°C. If Kf for water is 1.86 K kg mol–1, the amount of water (in g) separated as ice
is 
(a) 64  
(b) 32
(c) 16
(d) 48

Ques 3. Freezing point of a 4% aqueous solution of X is equal to freezing point of

12% aqueous solution of Y. If molecular weight of X is A,then molecular weight
of Y is
(a) 2A 
(b) 3A 
(c) A 
(d) 4A

Ques 4. Elevation in the boiling point for 1 molal solution of glucose is 2 K. The
depression in the freezing point for 2 molal solution of glucose in the same solvent
is 2 K. The relation between Kb and Kf is
(a) Kb = 1.5 Kf 
(b) Kb = 0.5 Kf 
(c) Kb = 2Kf 
(d) Kb = Kf
Ques 5. K2HgI4 is 40% ionised in aqueous solution. The value of its van’t Hoff
factor (i) is 
(a) 1.8
(b) 2.2
(c) 1.6
(d) 2.0

Ques 6. The mixture that forms maximum boiling azeotrope is :

(1) Water + Nitric acid
(2) Ethanol + Water
(3) Acetone + Carbon disulphide
(4) Heptane + Octane
Ques 7. The freezing point of a diluted milk sample is found to be –0.2°C, while it
should have been –0.5°C for pure milk. How much water has been added to pure
milk to make the diluted sample?
(a) 1 cup of water to 3 cups of pure milk 
(b) 2 cups of water to 3 cups of pure milk 
(c) 1 cup of water to 2 cups of pure milk 
(d) 3 cups of water to 2 cups of pure milk

Ques 8. Molecules of benzoic acid (C6H5COOH) dimerise in benzene. ‘w’ g of the

acid dissolved in 30 g of benzene shows a depression in freezing point equal to 2
K. If the percentage association of the acid to form dimer in the solution is 80, then
w is (Given that
–1 –1
Kf = 5 K kg mol , Molar mass of benzoic acid = 122 g mol ) 
(a) 2.4 g
(b) 1.8 g 
(c) 1.0 g 
(d) 1.5 g