Calculos para diagramas T vs X-Y y X vs Y ideales para Metanol (1)-Agua(2) @

Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.8041 8415 8.08097 1582.271 239.726 64.548
Agua (2) 18.015 0.999 17.9970 0.5619 9718 8.07131 1730.63 233.426 99.997

Ec. Antoine Raoult/Dalton

(°C) (mm Hg) (-) (mm Hg) (-) (cal °C/mol) Relación de Equilibrio
Ti P1 i
0
P2 i
0
X1 P y1 hl Hv K1 K1 K2 K2
64.548 760 183.3643 1.000000 760.00000 1.000000 1251 9666 1.00000 1 0.24127 0.28571
65.000 773.6269 187.1186 0.976766 760.00000 0.994280 1258 9682 1.01793 1.01793 0.24621 0.24621
66.000 804.4805 195.6521 0.926941 760.00000 0.981192 1273 9717 1.05853 1.058527 0.25744 0.25744
67.000 836.3513 204.5142 0.879160 760.00000 0.967482 1288 9753 1.10046 1.100462 0.26910 0.26910
68.000 869.2652 213.7147 0.833323 760.00000 0.953130 1302 9790 1.14377 1.14377 0.28120 0.28120
69.000 903.2485 223.2643 0.789336 760.00000 0.938113 1317 9827 1.18848 1.188485 0.29377 0.29377
70.000 938.3279 233.1733 0.747108 760.00000 0.922411 1332 9865 1.23464 1.234642 0.30681 0.30681
71.000 974.5307 243.4526 0.706556 760.00000 0.906000 1347 9905 1.28228 1.282277 0.32033 0.32033
72.000 1011.885 254.1134 0.667598 760.00000 0.888858 1362 9944 1.33143 1.331427 0.33436 0.33436
73.000 1050.417 265.1667 0.630160 760.00000 0.870961 1378 9985 1.38213 1.382128 0.34890 0.34890
74.000 1090.158 276.6242 0.594168 760.00000 0.852286 1393 10027 1.43442 1.434418 0.36398 0.36398
75.000 1131.135 288.4977 0.559556 760.00000 0.832806 1408 10069 1.48834 1.488335 0.37960 0.37960
76.000 1173.378 300.7990 0.526257 760.00000 0.812498 1423 10113 1.54392 1.543918 0.39579 0.39579
77.000 1216.916 313.5406 0.494212 760.00000 0.791336 1439 10157 1.60121 1.601206 0.41255 0.41255
78.000 1261.781 326.7347 0.463362 760.00000 0.769292 1454 10203 1.66024 1.660239 0.42991 0.42991
79.000 1308.003 340.3943 0.433652 760.00000 0.746340 1469 10249 1.72106 1.721057 0.44789 0.44789
80.000 1355.613 354.5323 0.405030 760.00000 0.722453 1485 10297 1.78370 1.783701 0.46649 0.46649
81.000 1404.642 369.1619 0.377446 760.00000 0.697601 1500 10345 1.84821 1.848214 0.48574 0.48574
82.000 1455.124 384.2966 0.350853 760.00000 0.671757 1516 10395 1.91464 1.914637 0.50565 0.50565
83.000 1507.09 399.9502 0.325207 760.00000 0.644890 1531 10446 1.98301 1.983013 0.52625 0.52625
84.000 1560.573 416.1368 0.300465 760.00000 0.616971 1547 10498 2.05339 2.053386 0.54755 0.54755
85.000 1615.607 432.8706 0.276587 760.00000 0.587968 1562 10551 2.12580 2.125799 0.56957 0.56957
86.000 1672.227 450.1661 0.253534 760.00000 0.557850 1578 10605 2.20030 2.200298 0.59232 0.59232
87.000 1730.465 468.0383 0.231270 760.00000 0.526586 1594 10661 2.27693 2.27693 0.61584 0.61584
88.000 1790.358 486.5021 0.209761 760.00000 0.494141 1609 10718 2.35573 2.355734 0.64013 0.64013
89.000 1851.94 505.5729 0.188973 760.00000 0.460483 1625 10777 2.43676 2.436763 0.66523 0.66523
90.000 1915.248 525.2664 0.168875 760.00000 0.425576 1641 10836 2.52006 2.520063 0.69114 0.69114
91.000 1980.317 545.5985 0.149438 760.00000 0.389388 1657 10898 2.60568 2.60568 0.71789 0.71789
92.000 2047.184 566.5854 0.130633 760.00000 0.351881 1672 10960 2.69366 2.693664 0.74551 0.74551
93.000 2115.887 588.2434 0.112432 760.00000 0.313019 1688 11024 2.78406 2.784062 0.77400 0.77400
94.000 2186.463 610.5894 0.094811 760.00000 0.272765 1704 11090 2.87693 2.876925 0.80341 0.80341
95.000 2258.95 633.6405 0.077745 760.00000 0.231081 1720 11157 2.97230 2.972303 0.83374 0.83374
96.000 2333.387 657.4138 0.061210 760.00000 0.187930 1736 11226 3.07025 3.070246 0.86502 0.86502
97.000 2409.813 681.9270 0.045184 760.00000 0.143270 1752 11296 3.17081 3.170806 0.89727 0.89727
98.000 2488.267 707.1980 0.029646 760.00000 0.097063 1768 11368 3.27403 3.274035 0.93052 0.93052
99.000 2568.788 733.2450 0.014576 760.00000 0.049267 1784 11442 3.37998 3.379985 0.96480 0.96480
99.997 2651.154 760.0000 0.000000 760.00000 0.000000 1800 11518 3.48836 #DIV/0! 1.00000 1.00000

0.00 0
1.00 1
etanol (1)-Agua(2) @ 760 mm de Hg 760.0 mmHg = 1.0 atm = 1.0132472 bar = 1.033

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1251.2062 9666.2062 y Titulos generales del proceso de cálculo
1799.6414 11517.641 y Variables calculadas

volatilidad f (x) Referencia

a 1/(y-x) p/graficar
4.14475 ### 0.999977 Diagrama T vs x-y (mezcla METANOL-AGUA) @ 760 mm
4.13442 57.099 0.978081 IDEAL
4.11179 18.433 0.928205 100
4.08945 11.322 0.880382
4.06741 8.347 0.834511
4.04565 0.790497 95
6.721
4.02417 5.704 0.748250 liquido Va
4.00296 5.014 0.707684 90
3.98202 4.520 0.668720
3.96135 4.153 0.631281
85
3.94093 3.874 0.595295
Temperatura, T (°C)

3.92078 3.660 0.560694

3.90087 3.494 0.527412 80
3.88121 3.366 0.495389
3.86179 3.269 0.464566
75
3.84261 3.198 0.434888
3.82367 3.150 0.406303
3.80495 3.123 0.378761 70
3.78646 3.116 0.352214
3.76819 3.128 0.326618
65
3.75014 3.160 0.301931
3.73231 3.211 0.278112
3.71469 3.286 0.255122 60
3.69727 3.386 0.232926 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
3.68006 3.516 0.211487 Fracción molar x, y
3.66305 3.683 0.190774
3.64624 3.896 0.170755
3.62962 4.168 0.151400
3.61320 4.520 0.132680
3.59696 4.985 0.114569 Diagrama x vs y (mezcla METANOL-AGUA) @ 760 mm
3.58091 5.619 0.097041 IDEAL
1.0
3.56503 6.522 0.080071
3.54934 7.891 0.063635
0.9
3.53383 10.195 0.047712
3.51849 14.833 0.032280
0.8
3.50332 28.826 0.017319

0.7
el vapor, y

0.6
 0.9

0.8

3.48836 #DIV/0!
0.7

Fracción molar del vapor, y

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar del líquido, x

 Kg/cm2

0 0
1 1

OL-AGUA) @ 760 mm de Hg

liquido Vapor

0.6 0.7 0.8 0.9 1.0

x, y

L-AGUA) @ 760 mm de Hg
 0.6 0.7 0.8 0.9 1.0

uido, x
 Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol (1)-Agua(2)
Pman (Hg) 175 Patm (Hg) 585 PTOT (Hg) 760

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.8041 8415 8.08097 1582.271 239.726 64.548
Agua (2) 18.015 0.999 17.9970 0.5619 9718 8.07131 1730.63 233.426 99.997

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv K1
64.548 760 183.3643 0.999999 1.00000 1.75400 759.99956 1.000000 1.000001 1251 9666 1.00000
65.000 773.6269 187.1186 0.969310 1.00038 1.71230 760.00002 0.969310 0.987062 1257 9691 1.01831
66.000 804.4805 195.6521 0.902648 1.00396 1.62564 760.00009 0.902648 0.959258 1270 9744 1.06272
67.000 836.3513 204.5142 0.837700 1.01150 1.54633 759.99464 0.837710 0.932464 1284 9795 1.11312
68.000 869.2652 213.7147 0.774640 1.02322 1.47414 759.99996 0.774640 0.906581 1297 9846 1.17033
69.000 903.2485 223.2643 0.713623 1.03932 1.40879 759.99986 0.713623 0.881481 1310 9896 1.23522
70.000 938.3279 233.1733 0.654899 1.05997 1.35006 760.00008 0.654899 0.857056 1323 9944 1.30868
71.000 974.5307 243.4526 0.598741 1.08524 1.29775 760.00004 0.598741 0.833193 1337 9992 1.39157
72.000 1011.885 254.1134 0.545438 1.11507 1.25159 759.99962 0.545438 0.809775 1350 10040 1.48463
73.000 1050.417 265.1667 0.495265 1.14926 1.21128 759.99966 0.495265 0.786689 1364 10086 1.58842
74.000 1090.158 276.6242 0.448444 1.18743 1.17646 759.99960 0.448444 0.763820 1378 10133 1.70327
75.000 1131.135 288.4977 0.405117 1.22905 1.14669 759.99968 0.405117 0.741057 1392 10179 1.82924
76.000 1173.378 300.7990 0.365326 1.27349 1.12146 760.00010 0.365326 0.718293 1406 10226 1.96617
77.000 1216.916 313.5406 0.329010 1.32007 1.10025 760.00008 0.329010 0.695429 1421 10272 2.11370
78.000 1261.781 326.7347 0.296022 1.36809 1.08253 760.00042 0.296022 0.672371 1436 10318 2.27135
79.000 1308.003 340.3943 0.266148 1.41693 1.06780 760.00008 0.266148 0.649034 1451 10365 2.43862
80.000 1355.613 354.5323 0.239137 1.46605 1.05557 759.99982 0.239137 0.625341 1466 10412 2.61499
81.000 1404.642 369.1619 0.214721 1.51499 1.04545 759.99942 0.214721 0.601223 1482 10460 2.80002
82.000 1455.124 384.2966 0.192635 1.56339 1.03707 760.00039 0.192635 0.576618 1498 10508 2.99332
83.000 1507.09 399.9502 0.172624 1.61098 1.03015 759.99985 0.172624 0.551465 1514 10557 3.19460
84.000 1560.573 416.1368 0.154457 1.65758 1.02443 760.00024 0.154457 0.525716 1530 10606 3.40364
85.000 1615.607 432.8706 0.137923 1.70302 1.01969 759.99989 0.137923 0.499320 1546 10656 3.62028
86.000 1672.227 450.1661 0.122836 1.74723 1.01578 759.99978 0.122836 0.472234 1562 10707 3.84443
87.000 1730.465 468.0383 0.109032 1.79014 1.01256 760.00074 0.109032 0.444417 1579 10758 4.07602
88.000 1790.358 486.5021 0.096366 1.83174 1.00990 760.00069 0.096366 0.415827 1595 10811 4.31508
89.000 1851.94 505.5729 0.084713 1.87200 1.00772 760.00105 0.084713 0.386429 1612 10864 4.56162
90.000 1915.248 525.2664 0.073963 1.91095 1.00593 760.00088 0.073963 0.356185 1629 10918 4.81571
91.000 1980.317 545.5985 0.064020 1.94860 1.00448 759.99888 0.064020 0.325058 1646 10973 5.07744
92.000 2047.184 566.5854 0.054802 1.98498 1.00330 759.99915 0.054802 0.293020 1663 11029 5.34688
93.000 2115.887 588.2434 0.046235 2.02012 1.00237 759.99883 0.046235 0.260033 1680 11086 5.62415
94.000 2186.463 610.5894 0.038256 2.05406 1.00163 760.00120 0.038256 0.226069 1697 11145 5.90937
95.000 2258.95 633.6405 0.030807 2.08684 1.00106 759.99993 0.030807 0.191087 1714 11204 6.20273
96.000 2333.387 657.4138 0.023840 2.11850 1.00064 760.00036 0.023840 0.155063 1731 11264 6.50432
97.000 2409.813 681.9270 0.017311 2.14908 1.00034 760.00166 0.017311 0.117963 1748 11326 6.81431
98.000 2488.267 707.1980 0.011180 2.17863 1.00014 759.99817 0.011180 0.079746 1765 11389 7.13294
99.000 2568.788 733.2450 0.005415 2.20718 1.00003 760.00079 0.005415 0.040397 1782 11453 7.46022
99.997 2651.154 760.0000 0.000500 2.23212 1.00000 762.57906 0.000000 0.003880 1800 11513 7.76009

0.00 0
1.00 1
Metanol (1)-Agua(2) @ 760 mm de Hg 760.0 mmHg = 1.0 atm = 1.0132472 bar =

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1251.206157 9666.2062 y Titulos generales del proceso de cálculo
1799.641445 11517.641 y Variables calculadas

volatilidad f (x) Referencia

K2 a 1/(y-x) p/graficar
0.423186 2.36303 634190.2211 0.999999
0.421583 2.41545 56.3330 0.969310
Diagrama T vs X-Y (mezcla METANOL-AGUA) @ 760 mm
NO IDEAL
0.418499 2.53935 17.6647 0.902648
100
0.416116 2.67503 10.5525 0.837700
0.414533 2.82324 7.5792 0.774640
0.413857 2.98465 5.9574 0.713623 95
0.414209 3.1594818 4.9466 0.654899 liquido Vap
0.415710 3.34746 4.2653 0.598741 90
0.418480 3.54768 3.7831 0.545438
0.422620 3.75850 3.4314 0.495265
0.428207 3.97767 3.1708 0.448444 85
Temperatura, T (°C)

0.435285 4.20240 2.9767 0.405117

0.443861 4.42970 2.8331 0.365326 80
0.453913 4.65662 2.7291 0.329010
0.465397 4.88047 2.6571 0.296022
0.478252 5.09903 2.6117 0.266148 75
0.492413 5.31057 2.5893 0.239137
0.507815 5.51385 2.5873 0.214721 70
0.524400 5.7080799 2.6043 0.192635
0.542117 5.89283 2.6396 0.172624
0.560922 6.06793 2.6935 0.154457 65
0.580783 6.23345 2.7670 0.137923
0.601673 6.38956 2.8621 0.122836 60
0.623572 6.53657 2.9816 0.109032 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.646471 6.67483 3.1303 0.096366 Fracción molar x, y
0.670359 6.80474 3.3144 0.084713
0.695237 6.92672 3.5433 0.073963
0.721107 7.04118 3.8309 0.064020
0.747971 7.14851 4.1978 0.054802
0.775838 7.24913 4.6773 0.046235 Diagrama X vs Y (mezcla METANOL-AGUA) @ 760 mm
0.804716 7.34342 5.3245 0.038256 NO IDEAL
0.834625 7.43176 6.2391 0.030807 1.0
Fracción molar del vapor, y

0.865572 7.51448 7.6206 0.023840

0.897575 7.59191 9.9353 0.017311 0.9
0.930659 7.66440 14.5844 0.011180
0.964827 7.73218 28.5860 0.005415 0.8

0.7

0.6
 Fracción molar del vapo
0.9

0.8
0.996618 7.78642 295.8540 0.000500
0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0

Fracción molar del líquido, x

 1.033 Kg/cm2

ETANOL-AGUA) @ 760 mm de Hg

liquido Vapor

.5 0.6 0.7 0.8 0.9 1.0

molar x, y

TANOL-AGUA) @ 760 mm de Hg
0.5 0.6 0.7 0.8 0.9 1.0

r del líquido, x
 Calculos para diagramas T vs X-Y y X vs Y ideales para Metanol (1)-Agua(2) @
Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.8041 8415 8.08097 1582.271 239.726 58.040
Agua (2) 18.015 0.999 17.9970 0.5619 9718 8.07131 1730.63 233.426 92.852

Ec. Antoine Raoult/Dalton

(°C) (mm Hg) (-) (mm Hg) (-) (cal °C/mol) Relación de Equilibrio
Ti P1 i
0
P2 i
0
X1 P y1 hl Hv K1 K1 K2 K2
58.040 585 136.0279 1.000000 585.00000 1.000000 1125 9540 1.00000 1 0.23253 0.00000
59.000 608.471 142.2751 0.949654 585.00000 0.987756 1140 9574 1.04012 1.040121 0.24321 0.24321
60.000 633.741 149.0384 0.899441 585.00000 0.974381 1155 9609 1.08332 1.083318 0.25477 0.25477
61.000 659.8818 156.0740 0.851368 585.00000 0.960346 1170 9646 1.12800 1.128003 0.26679 0.26679
62.000 686.9169 163.3906 0.805326 585.00000 0.945628 1185 9683 1.17422 1.174217 0.27930 0.27930
63.000 714.8699 170.9974 0.761213 585.00000 0.930202 1200 9721 1.22200 1.222 0.29230 0.29230
64.000 743.765 178.9036 0.718931 585.00000 0.914044 1216 9760 1.27139 1.271393 0.30582 0.30582
65.000 773.6269 187.1186 0.678390 585.00000 0.897130 1231 9800 1.32244 1.322439 0.31986 0.31986
66.000 804.4805 195.6521 0.639504 585.00000 0.879433 1246 9840 1.37518 1.37518 0.33445 0.33445
67.000 836.3513 204.5142 0.602190 585.00000 0.860927 1262 9882 1.42966 1.42966 0.34960 0.34960
68.000 869.2652 213.7147 0.566372 585.00000 0.841585 1277 9925 1.48592 1.485923 0.36532 0.36532
69.000 903.2485 223.2643 0.531977 585.00000 0.821380 1293 9968 1.54401 1.544014 0.38165 0.38165
70.000 938.3279 233.1733 0.498936 585.00000 0.800282 1308 10013 1.60398 1.603979 0.39859 0.39859
71.000 974.5307 243.4526 0.467183 585.00000 0.778264 1324 10058 1.66586 1.665865 0.41616 0.41616
72.000 1011.885 254.1134 0.436658 585.00000 0.755294 1339 10105 1.72972 1.729717 0.43438 0.43438
73.000 1050.417 265.1667 0.407301 585.00000 0.731343 1355 10153 1.79559 1.795585 0.45328 0.45328
74.000 1090.158 276.6242 0.379057 585.00000 0.706380 1371 10202 1.86352 1.863518 0.47286 0.47286
75.000 1131.135 288.4977 0.351874 585.00000 0.680371 1386 10252 1.93356 1.933564 0.49316 0.49316
76.000 1173.378 300.7990 0.325702 585.00000 0.653285 1402 10303 2.00577 2.005774 0.51419 0.51419
77.000 1216.916 313.5406 0.300494 585.00000 0.625088 1418 10356 2.08020 2.080199 0.53597 0.53597
78.000 1261.781 326.7347 0.276206 585.00000 0.595746 1434 10410 2.15689 2.156891 0.55852 0.55852
79.000 1308.003 340.3943 0.252794 585.00000 0.565223 1449 10465 2.23590 2.235903 0.58187 0.58187
80.000 1355.613 354.5323 0.230219 585.00000 0.533483 1465 10522 2.31729 2.317287 0.60604 0.60604
81.000 1404.642 369.1619 0.208442 585.00000 0.500491 1481 10580 2.40110 2.40110 0.63105 0.63105
82.000 1455.124 384.2966 0.187428 585.00000 0.466208 1497 10639 2.48739 2.487391 0.65692 0.65692
83.000 1507.09 399.9502 0.167142 585.00000 0.430595 1513 10700 2.57622 2.576222 0.68368 0.68368
84.000 1560.573 416.1368 0.147551 585.00000 0.393615 1529 10763 2.66765 2.667646 0.71134 0.71134
85.000 1615.607 432.8706 0.128625 585.00000 0.355226 1545 10827 2.76172 2.761722 0.73995 0.73995
86.000 1672.227 450.1661 0.110333 585.00000 0.315388 1561 10892 2.85851 2.858507 0.76951 0.76951
87.000 1730.465 468.0383 0.092648 585.00000 0.274059 1577 10960 2.95806 2.95806 0.80007 0.80007
88.000 1790.358 486.5021 0.075544 585.00000 0.231197 1593 11029 3.06044 3.060441 0.83163 0.83163
89.000 1851.94 505.5729 0.058994 585.00000 0.186757 1609 11099 3.16571 3.16571 0.86423 0.86423
90.000 1915.248 525.2664 0.042974 585.00000 0.140695 1625 11172 3.27393 3.273928 0.89789 0.89789
91.000 1980.317 545.5985 0.027463 585.00000 0.092966 1641 11246 3.38516 3.385157 0.93265 0.93265
92.000 2047.184 566.5854 0.012437 585.00000 0.043524 1657 11323 3.49946 3.49946 0.96852 0.96852
92.852 2105.618 585.0000 0.000000 585.00000 0.000000 1671 11389 3.59935 #DIV/0! 1.00000 1.00000
0.00 0
1.00 1
etanol (1)-Agua(2) @ 760 mm de Hg 585.0 mmHg = 0.8 atm = 0.7799337 bar = 0.7951

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1125.051 9540.051 y Titulos generales del proceso de cálculo
1671.0601 11389.06 y Variables calculadas

volatilidad f (x) Referencia

a 1/(y-x) p/graficar
4.30059 ### 0.999977 Diagrama T vs x-y (mezcla METANOL-AGUA) @ 585 mm d
4.27672 26.246 0.978081 IDEAL
4.25220 13.344 0.928205 95
4.22801 9.176 0.880382
4.20414 7.128 0.834511
90
4.18059 5.918 0.790497
4.15735 5.125 0.748250 liquido Vapo

4.13442 4.572 0.707684 85

4.11179 4.168 0.668720
4.08945 3.865 0.631281 80
4.06741 0.595295
Temperatura, T (°C)

3.634
4.04565 3.455 0.560694
4.02417 3.318 0.527412 75
4.00296 3.215 0.495389
3.98202 3.138 0.464566 70
3.96135 3.086 0.434888
3.94093 3.055 0.406303
3.92078 3.044 0.378761 65
3.90087 3.053 0.352214
3.88121 3.081 0.326618
60
3.86179 3.129 0.301931
3.84261 3.201 0.278112
3.82367 3.297 0.255122 55
3.80495 3.424 0.232926 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
3.78646 3.587 0.211487 Fracción molar x, y
3.76819 3.796 0.190774
3.75014 4.064 0.170755
3.73231 4.413 0.151400
3.71469 4.877 0.132680
3.69727 5.512 0.114569 Diagrama x vs y (mezcla METANOL-AGUA) @ 585 mm de
3.68006 6.425 0.097041 IDEAL
1.0
3.66305 7.827 0.080071
3.64624 10.233 0.063635
0.9
3.62962 15.266 0.047712
3.61320 32.168 0.032280
0.8
3.59935 #DIV/0! 0.017319

0.7
el vapor, y

0.6
 0.9

0.8

0.7

Fracción molar del vapor, y

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9

Fracción molar del líquido, x

 Kg/cm2

0 0
1 1

-AGUA) @ 585 mm de Hg

liquido Vapor

0.6 0.7 0.8 0.9 1.0

AGUA) @ 585 mm de Hg
.6 0.7 0.8 0.9 1.0

do, x
 Calculos para diagramas T vs X-Y y X vs Y no ideales para Metanol (1)-Agua(2)
Pman (Hg) 0 Patm (Hg) 585 PTOT (Hg) 585

(g/mol) (cal/g°C) (cal/mol°C) VanLaar (cal/mol) A B C (°C)

Compuesto PM Cp A12_21 l Ctes. de Antoine (mm Hg y °C) p.e.
Metanol (1) 32.04 0.605 19.3842 0.8041 8415 8.08097 1582.271 239.726 58.040
Agua (2) 18.015 0.999 17.9970 0.5619 9718 8.07131 1730.63 233.426 92.852

Ec. Antoine Ec. Van Laar Raoult m

(°C) (mm Hg) (-) (-) (-) (mm Hg) (-) (-) (cal °C/mol)
Ti P1 i
0
P2 i
0
X1_supuesta g1 g2 P X1_calculada y1 hl Hv K1
58.040 585 136.0279 0.999901 1.00000 1.75387 584.96571 1.000000 1.000059 1125 9540 1.00006
59.000 608.471 142.2751 0.934096 1.00178 1.66585 585.00007 0.934096 0.973299 1138 9591 1.04197
60.000 633.741 149.0384 0.867114 1.00755 1.58162 585.00010 0.867114 0.946454 1152 9643 1.09150
61.000 659.8818 156.0740 0.801937 1.01757 1.50481 585.00003 0.801937 0.920483 1166 9694 1.14782
62.000 686.9169 163.3906 0.738754 1.03208 1.43517 584.99987 0.738754 0.895281 1179 9744 1.21188
63.000 714.8699 170.9974 0.677809 1.05126 1.37248 584.99995 0.677809 0.870743 1193 9793 1.28464
64.000 743.765 178.9036 0.619390 1.07526 1.31654 584.99978 0.619390 0.846758 1207 9842 1.36708
65.000 773.6269 187.1186 0.563815 1.10408 1.26711 585.00017 0.563815 0.823214 1221 9889 1.46008
66.000 804.4805 195.6521 0.511393 1.13756 1.22390 584.99989 0.511393 0.799998 1235 9937 1.56435
67.000 836.3513 204.5142 0.462396 1.17536 1.18655 585.00008 0.462396 0.776994 1249 9984 1.68036
68.000 869.2652 213.7147 0.417011 1.21696 1.15462 584.99963 0.417011 0.754088 1263 10030 1.80832
69.000 903.2485 223.2643 0.375323 1.26172 1.12760 584.99957 0.375323 0.731171 1278 10077 1.94811
70.000 938.3279 233.1733 0.337300 1.30889 1.10494 584.99962 0.337300 0.708137 1293 10124 2.09943
71.000 974.5307 243.4526 0.302808 1.35773 1.08606 585.00016 0.302808 0.684889 1308 10171 2.26179
72.000 1011.885 254.1134 0.271632 1.40755 1.07041 585.00009 0.271632 0.661335 1323 10218 2.43467
73.000 1050.417 265.1667 0.243510 1.45775 1.05748 585.00005 0.243510 0.637392 1338 10266 2.61752
74.000 1090.158 276.6242 0.218156 1.50782 1.04682 584.99955 0.218156 0.612987 1354 10314 2.80986
75.000 1131.135 288.4977 0.195285 1.55736 1.03804 585.00029 0.195285 0.588052 1370 10363 3.01125
76.000 1173.378 300.7990 0.174621 1.60607 1.03081 585.00008 0.174621 0.562525 1386 10412 3.22140
77.000 1216.916 313.5406 0.155913 1.65372 1.02486 585.00057 0.155913 0.536349 1402 10462 3.44005
78.000 1261.781 326.7347 0.138932 1.70016 1.01997 585.00000 0.138932 0.509472 1419 10513 3.66706
79.000 1308.003 340.3943 0.123477 1.74530 1.01594 584.99952 0.123477 0.481846 1435 10565 3.90231
80.000 1355.613 354.5323 0.109371 1.78906 1.01263 584.99991 0.109371 0.453427 1452 10617 4.14577
81.000 1404.642 369.1619 0.096458 1.83143 1.00992 584.99948 0.096458 0.424168 1469 10671 4.39744
82.000 1455.124 384.2966 0.084604 1.87239 1.00770 584.99965 0.084604 0.394032 1485 10725 4.65737
83.000 1507.09 399.9502 0.073691 1.91196 1.00589 584.99885 0.073691 0.362976 1502 10781 4.92564
84.000 1560.573 416.1368 0.063619 1.95016 1.00442 585.00113 0.063619 0.330966 1519 10837 5.20232
85.000 1615.607 432.8706 0.054296 1.98702 1.00324 584.99895 0.054296 0.297955 1536 10895 5.48761
86.000 1672.227 450.1661 0.045648 2.02258 1.00231 584.99996 0.045648 0.263916 1553 10953 5.78156
87.000 1730.465 468.0383 0.037606 2.05688 1.00158 585.00074 0.037606 0.228808 1570 11013 6.08436
88.000 1790.358 486.5021 0.030110 2.08997 1.00102 584.99868 0.030110 0.192591 1587 11074 6.39623
89.000 1851.94 505.5729 0.023110 2.12188 1.00060 584.99964 0.023110 0.155236 1605 11137 6.71725
90.000 1915.248 525.2664 0.016559 2.15266 1.00031 585.00013 0.016559 0.116702 1622 11200 7.04767
91.000 1980.317 545.5985 0.010417 2.18237 1.00012 585.00183 0.010417 0.076957 1639 11265 7.38764
92.000 2047.184 566.5854 0.004647 2.21104 1.00002 585.00059 0.004647 0.035956 1656 11331 7.73743
92.852 2105.618 585.0000 0.000010 2.23463 1.00000 585.04120 0.000000 0.000080 1671 11389 8.04265
0.00 0
1.00 1
Metanol (1)-Agua(2) @ 760 mm de Hg 585.0 mmHg = 0.8 atm = 0.7799337 bar =

NOMENCLATURA DE COLOR

(cal /mol) Celdas dato (llenar)

hli Hvi y Constantes de los componentes de la mz
1125.051018 9540.051 y Titulos generales del proceso de cálculo
1671.060114 11389.06 y Variables calculadas

volatilidad f (x) Referencia

K2 a 1/(y-x) p/graficar
0.407844 2.45206 6344.2611 0.999901
0.405144 2.57185 25.5081 0.934096 Diagrama T vs X-Y (mezcla METANOL-AGUA) @ 585 mm
0.402944 2.70881 12.6040 0.867114 NO IDEAL
0.401472 2.85904 8.4355 0.801937 105
0.400843 3.02333 6.3887 0.738754
0.401182 3.20215 5.1831 0.677809 100

0.402623 3.3954392 4.3982 0.619390 liquido Vap

95
0.405300 3.60247 3.8551 0.563815
0.409332 3.82172 3.4649 0.511393
90
0.414815 4.05088 3.1787 0.462396
0.421812 4.28702 2.9667 0.417011
Temperatura, T (°C)

85
0.430348 4.52682 2.8102 0.375323
0.440414 4.76694 2.6966 0.337300
80
0.451972 5.00428 2.6172 0.302808
0.464965 5.23625 2.5661 0.271632
75
0.479329 5.46080 2.5388 0.243510
0.495001 5.67647 2.5327 0.218156
70
0.511918 5.88230 2.5460 0.195285
0.530030 6.0777785 2.5780 0.174621
65
0.549293 6.26270 2.6286 0.155913
0.569674 6.43712 2.6988 0.138932
60
0.591147 6.60126 2.7904 0.123477
0.613694 6.75543 2.9065 0.109371
55
0.637305 6.90006 3.0515 0.096458 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
0.661974 7.03558 3.2318 0.084604
Fracción molar x, y
0.687702 7.16247 3.4568 0.073691
0.714489 7.28117 3.7405 0.063619
0.742352 7.39219 4.1041 0.054296
0.771291 7.49594 4.5815 0.045648
0.801326 7.59287 5.2301 0.037606 Diagrama X vs Y (mezcla METANOL-AGUA) @ 585 mm
0.832475 7.68339 6.1546 0.030110 NO IDEAL
0.864749 7.76787 7.5685 0.023110 1.0
Fracción molar del vapor, y

0.898170 7.84669 9.9857 0.016559

0.932760 7.92019 15.0286 0.010417 0.9
0.968545 7.98872 31.9398 0.004647
0.999930 8.04322 14199.1969 0.000010 0.8

0.7

0.6
Fracción molar del vapo
0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

Fracción molar del líquido, x

 0.7951 Kg/cm2

ETANOL-AGUA) @ 585 mm de Hg

liquido Vapor

.5 0.6 0.7 0.8 0.9 1.0

molar x, y

TANOL-AGUA) @ 585 mm de Hg
0.5 0.6 0.7 0.8 0.9 1.0

r del líquido, x