Langmuir Langmuir

p (kpa) q p/q 10
6 10.2 0.588235 9 R² = 0.994538649471207
27.2 18.6 1.462366 8
53.2 25.5 2.086275
7
92.67 31.5 2.941905
6
99.97 36.9 2.709214
5
244.8 41.6 5.884615
4
424 46.1 9.197397
3
slope 0.020596
qm 48.55293 2
1
0
0 50 100 150 200 250 300 350

Frendlich
p (kpa) q ln p ln q Frendlich
6 10.2 1.791759 2.322388
4.5
27.2 18.6 3.303217 2.923162
4
53.2 25.5 3.974058 3.238678 R² = 0.964458319435334
92.67 31.5 4.529045 3.449988 3.5

99.97 36.9 4.60487 3.608212 3

244.8 41.6 5.500442 3.7281 2.5
424 46.1 6.049733 3.830813 2
slope 0.354259
1.5
n 2.822794
1
0.5
0
1.5 2 2.5 3 3.5 4 4.5 5 5.5

ANSWER:
Langmuir has a higher R2 value and give a better fit. Hence it is a monolayer
adsorption
ngmuir

250 300 350 400 450

Frendlich

4 4.5 5 5.5 6 6.5