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Oilfield Review

Autumn 2012

Pressure and Sampling in Extreme Conditions


Thermal Properties of Reservoir Rocks
Plate Tectonics in Exploration
12-OR-0004
Frontier Hydrocarbon Exploration: The Importance of Tectonic Models

Advances in understanding the dynamics of modern tectonic precipitation in deep sags above oceanic crust during sea-
processes have transformed scientists’ interpretations of floor spreading, a characteristic once attributed to hyperex-
ancient tectonic environments and regional deformation tended continental crust. The existence of the Red Sea
regimes and have led to radical conceptual changes about central trough, Angola escarpment and São Paulo plateau
the tectonic evolution of basins in continental, marginal and are most easily accounted for by incorporating seafloor
oceanic environments. These new concepts are making a spreading in the early evolution of the margins. The flood-
significant impact on operators’ exploration strategies and gate models may preclude simple extrapolation of onshore
on the discovery of hydrocarbon plays in regions that were or shallow near-shore stratigraphy far beneath the deep salt.
previously unknown, poorly explored, difficult to access or However, the existence of deep offshore hydrocarbon plays
quickly dismissed. Tectonic insights suggest that there may in a still largely unexplored environment was proved in 2007
be significantly more hydrocarbon resources to be found in by the discovery of the presalt Lula—formerly Tupi—oil
places that were once deemed valueless (see “Basin to Basin: field in the Santos basin offshore Brazil and by the discover-
Plate Tectonics in Exploration,” page 38). ies in 2012 of the presalt Azul and Cameia oil accumulations
For example, high orogenic plateaus, while typically set in in the Kwanza basin offshore Angola.
the heart of mountainous regions, are now understood as The odds are that vast oil reserves exist on top of the
mosaics of internally drained basins rather than as coales- deep basaltic seafloor. Thick salt forming in a restricted
cent mountain ranges. Dynamic surface processes consisting anoxic environment resulting from tectonic activity is the
of erosion, sediment transport and deposition by large rivers key; the presence of prerift or synrift source rocks might
interacted with tectonically rising mountain rims to shape not be required. The North American and West African
the high, flat and smooth morphology of these plateaus. This margins of the central Atlantic also may harbor such plays,
creates “cold” basins of a novel type, best represented sealed deep beneath thick salt. Scientists will gain a better
within and to the north of the Tibet plateau. The basins understanding of these phenomena by developing tectonic
filled rapidly with great thicknesses of Tertiary clastic sedi- models with overlapping spreading centers that isolate
ments from internal drainage. The sediments likely host continental slivers rather than models that rely merely on
potential reservoirs and seals on top of source rocks in crustal hyperextension.
Mesozoic marine and Tertiary lacustrine limestones or shales, In understanding the tectonic evolution of basins, geo-
adding to new leads in the high plains south of the long-pro- scientists may change classic perspectives and develop
ducing basins in western China. new paradigms for oil and gas exploration. The most
On the Lebanese stretch of the Levant basin margin, recent important lessons from tectonic studies are that no envi-
seismic and bathymetric offshore surveys, coupled with ronment should be considered beyond the bounds of explo-
onshore tectonic studies, have also brought new insight. They ration and that current models should be revisited. It
show that this passive margin has experienced inverted fold- seems certain that coherent, dynamic tectonic models,
ing since about 13 Ma. To the west of Mount Lebanon, which based on the well-constrained kinematics of active analogs,
rises 4,800 m [15,700 ft] above the Levant basin floor, is a 150- will be essential to the future of hydrocarbon exploration.
km [93-mi] active thrust fault and an underwater fold-and-
thrust belt that deforms Tortonian carbonates, Messinian Paul Tapponnier
evaporites and Pliocene-Quaternary turbidites. This subma- Professor and Group Leader, Tectonics and Earthquakes Group
rine, thin-skinned, foreland-migrating thrust wedge is worthy Nanyang Technological University
Singapore
of modern exploration. Many structures are sealed by the
Messinian salt, which may trap large reservoirs, as it might do Paul Tapponnier is Professor and Group Leader of the Tectonics and
elsewhere in the Mediterranean region. Since 2009, discover- Earthquakes Group at the Earth Observatory of Singapore at the Nanyang
ies of large gas accumulations in subsalt Miocene strata off- Technological University in Singapore, where he has worked since 2009.
Previously, he worked at the Tectonique, Mécanique de la Lithosphère group
shore Israel and Cyprus have demonstrated the importance of at the Institut de Physique du Globe de Paris. His contributions to geology,
the Levant basin for significant natural gas resources. tectonics and geophysics span more than 40 years and his research inter-
In the early opening stages of both the Cretaceous South ests include continental dynamics and tectonics, particularly in Asia and the
Mediterranean region; active faulting and seismotectonics; earthquake hazard
Atlantic and the Miocene Red Sea, thick salt deposition was assessment; quantitative geomorphology; rates of active deformation processes;
controlled by a peculiar tectonic framework in which the and rock mechanics and rock deformation physics. He is a member of both the
marine environment was restricted between fissural “flood- French and US National Academy of Sciences and a Fellow of the American
Geophysical Union, Geological Society of America and Geological Society
gates” formed through volcanism and transform faulting.
of London. Paul holds an ingénieur des mines degree from Ecole Nationale
Much of the evaporitic deposition likely resulted from Supérieure des Mines de Paris and a doctorat d’etat degree from Université
Montpellier 2 Sciences et Techniques, France.

1
Schlumberger

Oilfield Review
www.slb.com/oilfieldreview

Executive Editor 1 Frontier Hydrocarbon Exploration: The Importance of Tectonic Models


Lisa Stewart
Editorial contributed by Paul Tapponnier, Professor and Group Leader,
Senior Editors
Matt Varhaug Tectonics and Earthquakes Group, Nanyang Technological University
Rick von Flatern

Editors
Richard Nolen-Hoeksema
Tony Smithson
4 Testing the Limits in Extreme Well Conditions
Contributing Editors
Ginger Oppenheimer High-temperature wells pose challenges for design engineers
Michael Oristaglio
Rana Rottenberg who develop pressure and sampling tools. In addition to
pressure and sampling tools, downhole pressure gauges used
Design/Production
Herring Design
in long duration tests must be designed to operate for
Mike Messinger extended periods with few options to protect sensitive elec-
tronics from heat. High-pressure wells present a different
Illustration 
Chris Lockwood but equally daunting set of challenges. Case studies from
Tom McNeff the North Sea, Thailand and India demonstrate how recent
Mike Messinger innovations are overcoming these challenges.
George Stewart

Printing
RR Donnelley—Wetmore Plant
Curtis Weeks

20 When Rocks Get Hot: Thermal Properties of


Reservoir Rocks
More than half of the oil produced worldwide by enhanced
recovery methods is a result of thermal stimulation.
Decisions on project economics may hinge on long-term
forecasts of the amount of additional oil that can be liberated
from the reservoir by injected heat. Although accurate fore-
casts usually require accurate knowledge of the thermal
properties of the reservoir fluids and rocks, these properties
of reservoir rocks are rarely measured. This article reviews
rock thermal property measurements and describes an effi-
cient new optical technique for obtaining them.

On the cover:

Seismic data, shown in the background, Oilfie


are crucial inputs to exploration work- AUTU
flows. Seismic techniques help identify HPHT
subsurface structures that may trap and ORAU
accumulate hydrocarbons. In this case,
interpretation of seismic data from off-
shore Angola reveals the presence of About Oilfield Review
walls of Aptian salt (purple and white), Oilfield Review, a Schlumberger journal, Oilfield Review is published quarterly and © 2012 Schlumberger. All rights reserved.
minibasins for sediment deposition and communicates technical advances in printed in the USA. Reproductions without permission are
overhangs that may serve as traps. The finding and producing hydrocarbons strictly prohibited.
Aptian salt is a regional seal for presalt to employees, clients and other oilfield Visit www.slb.com/oilfieldreview for
reservoirs. (Background data courtesy of professionals. Contributors to articles electronic copies of articles in English, For a comprehensive dictionary of oilfield
TGS and WesternGeco. Image courtesy include industry professionals and experts Spanish, Chinese and Russian. terms, see the Schlumberger Oilfield
of Sonangol EP and WesternGeco.) from around the world; those listed with Glossary at www.glossary.oilfield.slb.com.
only geographic location are employees
of Schlumberger or its affiliates.

2
Fig3_1 Autumn 2012
Volume 24
Number 3
ISSN 0923-1730

38 Basin to Basin: Plate Tectonics in Exploration Advisory Panel


Gretchen M. Gillis
Exploration companies have recently made several large Aramco Services Company
discoveries in rifted and transform margin systems. The Houston, Texas, USA
plays they proved on one continent have been applied Roland Hamp
across the Atlantic Ocean—from South America to Africa— Woodside Energy Ltd.
Perth, Australia
and back. This article explains how geoscientists are using
plate tectonics to uncover plays in rifted and transform Dilip M. Kale
ONGC Energy Centre
margin systems. Delhi, India
George King
Apache Corporation
Houston, Texas
Alexander Zazovsky
58 Contributors Fig3_2 Chevron
Houston, Texas
60 New Books and Coming in Oilfield Review

63 Defining Porosity:
How Porosity Is Measured
This is the seventh in a series of introductory articles describing basic concepts of the E&P industry.

Editorial correspondence Subscriptions Distribution inquiries


Oilfield Review Client subscriptions can be obtained Tony Smithson
5599 San Felipe through any Schlumberger sales office. Oilfield Review
Houston, Texas 77056 USA Paid subscriptions are available from 12149 Lakeview Manor Dr.
(1) 713-513-1194 Oilfield Review Services Northport, Alabama 35475 USA
Fax: (1) 713-513-2057 Pear Tree Cottage, Kelsall Road (1) 832-886-5217
E-mail: editorOilfieldReview@slb.com Ashton Hayes, Chester CH3 8BH UK Fax: (1) 281-285-0065
Fax: (44) 1829 759163 E-mail: DistributionOR@slb.com
E-mail: subscriptions@oilfieldreview.com

3
Chris Avant
Saifon Daungkaew Testing the Limits in Extreme
Bangkok, Thailand
Well Conditions
Bijaya K. Behera
Pandit Deendayal Petroleum University
Gandhinagar, Gujarat, India
High borehole temperatures and pressures pose design challenges for engineers
Supamittra Danpanich developing formation evaluation tools. Pressure and sampling tools that use motors
Waranon Laprabang
PTT Exploration and Production and pumps require high power to operate and often generate considerably more heat
Public Company Limited
Bangkok, Thailand than tools used for basic petrophysical measurements. Traditional solutions to
combat temperature and pressure are insufficient for these types of tools. Recent
Ilaria De Santo
Aberdeen, Scotland innovations make it possible to obtain downhole pressure measurements and

Greg Heath
samples and to perform extended well tests in extreme conditions.
Kamal Osman
Chevron Thailand Exploration and
Production Ltd
Many E&P companies are drilling wells in envi- that they remain downhole for hours, even days,
Bangkok, Thailand
ronments that push the limits of equipment and constantly exposed to extreme conditions. Many
Zuber A. Khan services as they search for new sources of oil and methods traditionally employed to withstand
Gujarat State Petroleum Corporation Ltd gas. Operators are looking in places where few high wellbore temperatures are ineffective in
Gandhinagar, Gujarat, India have ventured or that not so long ago were con- these instances.
sidered impractical. The depths they are now This article reviews two pressure and sam-
Jay Russell probing tend to be hotter and higher pressured pling tools that require high power to operate
Houston, Texas, USA than ever before and often exhibit extreme well and were engineered to withstand high-pressure,
conditions that test the limits of downhole tools high-temperature (HPHT) operating environ-
Paul Sims and equipment. ments. In addition, a recently introduced down-
Dar es Salaam, Tanzania
Service companies continue developing solu- hole pressure gauge has been proved to operate
tions to contend with extreme well conditions; for many hours at high temperature. Case studies
Miroslav Slapal
Moscow, Russia however, certain situations present particular from the North Sea, Thailand and India demon-
problems for downhole tool developers.1 For strate the application of these advances.
Chris Tevis instance, applications such as acquiring forma-
Sugar Land, Texas tion pressures and fluid samples and performing A Niche Market That Matters
extended downhole pressure tests require tools Hostile environments are typically character-
Oilfield Review Autumn 2012: 24, no. 3.
Copyright © 2012 Schlumberger.
that are designed to overcome more than heat ized as having HPHT conditions. HPHT wells
For help in preparation of this article, thanks to Renato and pressure, which is a difficult feat. These tools will generally cross thresholds of either tem-
Barbedo, Ravenna, Italy; Larry Bernard, Jean-Marc Follini, must also deal with time as it relates to internally perature or pressure, but few wells cross both.
David Harrison and Steve Young, Houston; Libby Covington,
Simmons & Company International, Houston; Alan Dick, generated heat and the challenges of long expo- However, the term HPHT is applied to any well
Simmons & Company International, Aberdeen; Eduardo sure to potentially destructive conditions. that is considered hot or high pressured. Various
Granados, Richmond, California, USA; Khedher Mellah,
Chevron, Houston; and Sophie Salvadori Velu, Clamart, Pressure and sampling tools utilize motors criteria are used within the oil and gas industry
France. that require high power; these motors generate to define “high,” although there is no widely
InSitu Density, MDT, MDT Forte, MDT Forte-HT,
PressureXpress, PressureXpress-HT, Quicksilver Probe,
heat that is trapped inside the tool. To acquire accepted industry standard. Whichever criteria
Signature, SRFT and Xtreme are marks of Schlumberger. pressure measurements and formation fluid sam- are used, the majority of wells drilled today are
INCONEL is a registered trademark of Special Metals ples, these tools may have to remain stationary for not extreme, being neither high pressure nor
Corporation.
Quartzdyne is a registered trademark of Dover Corporation.
long periods of exposure to heat and pressure. high temperature.
These tools have pressure gauges and sensors that Approximately 107,000 oil and gas wells
must remain stable at high operating tempera- will be drilled worldwide in 2012.2 A study
tures while retaining their measurement preci- conducted by engineers at Schlumberger esti-
sion. Other uses for pressure gauges may require mates approximately 1,600 of these wells will be

4 Oilfield Review
1. For solutions available in extreme operating conditions: “Oilfield Chemistry at Thermal Extremes,” Oilfield Review 2. “Special Focus: 2012 Forecast—International Drilling and
DeBruijn G, Skeates C, Greenaway R, Harrison D, 18, no. 3 (Autumn 2006): 4–17. Production. Global Drilling Remains Consistently Strong,”
Parris M, James S, Mueller F, Ray S, Riding M, Temple L Adamson K, Birch G, Gao E, Hand S, Macdonald C, World Oil 233, no. 2 (February 2012): 43–46.
and Wutherich K: “High-Pressure, High-Temperature Mack D and Quadri A: “High-Pressure, High-Temperature “Special Focus: 2012 Forecast—U.S. Drilling. Growth
Technologies,” Oilfield Review 20, no. 3 (Autumn 2008): Well Construction,” Oilfield Review 10, no. 2 Amidst Economic and Regulatory Turbulence,”
46–60. (Summer 1998): 36–49. World Oil 233, no. 2 (February 2012): 67–72.
Chan KS, Choudhary S, Mohsen AHA, Samuel M, Baird T, Fields T, Drummond R, Mathison D, Langseth B,
Delabroy L, Flores JC, Fraser G, Fu D, Gurmen MN, Martin A and Silipigno L: “High-Pressure, High-
Kandle JR, Madsen SM, Mueller F, Mullen KT, Temperature Well Logging, Perforating and Testing,”
Nasr-El-Din HA, O’Leary J, Xiao Z and Yamilov RR: Oilfield Review 10, no. 2 (Summer 1998): 50–67.

Autumn 2012 5
HPHT Wells Drilled 2007 to 2010 Worldwide classified as HPHT wells, representing about 1.5%
650 of the worldwide total. Most of the wells consid-
Well ered HPHT exceed established temperature
High temperature limits; only a few wells exhibit truly extreme
550 pressures (left). The study also indicated that the
High pressure
HPHT market is heavily dominated by two coun-
Reservoir temperature, °F

tries: the US (60%) and Thailand (20%) (below).


450 One caveat to consider in this analysis is that
geothermal wells are not included in the totals.
Because of their extremely high bottomhole tem-
350 peratures, geothermal wells present operational
complexities rarely encountered in oil and gas
exploration.3 Moreover, the number of geother-
250 mal wells is small compared with the number of
their oil and gas counterparts.
The HPHT market may currently be relatively
150 small, but there is an industry-recognized accel-
0 5,000 10,000 15,000 20,000 25,000 30,000 35,000
eration in the number of extreme wells being
Reservoir pressure, psi
drilled and planned. For example, according to
> Extreme temperature or pressure. Schlumberger engineers conducted an internal study of
one report covering extreme wells drilled off-
temperature and pressure data from wells worldwide. Over a four-year period, no wells exceeded
both high-temperature (350°F [177°C]) and high-pressure (20,000 psi [138 MPa]) limits, which are shore, during the 30-year period from 1982 to
commonly used for wireline logging tools. Many wells exhibiting extremely high pressure do not 2012, operators drilled 415 HPHT offshore wells
exhibit high temperature, and vice versa. In addition, more wells exceeded the 350°F temperature than
exceeded 20,000 psi.

Oilfield Review
AUTUMN 12
HPHT Fig. 1
ORAUT 12-HPHT 1

Significant high-temperature activity


Potential for high-temperature activity
Geothermal activity

> Drilling activity in high-temperature environments. Exploration and development drilling in high-temperature environments is regionally isolated. The
majority of extreme wells are located on land, although there is significant activity in the Gulf of Mexico, the North Sea and offshore India and Southeast
Asia. The number of geothermal wells, which represent the high end of extreme temperatures, is not statistically significant.

6 Oilfield Review
Offshore HPHT Wells

Norwegian North Sea


14
North Sea 118 16
13
23 3 Mediterranean Sea Caspian Sea

0
Gulf of Mexico 0 26
17
4 10
97
133 90

Southeast Asia
West Africa
0
18 0 16
52 10
Brazil

238

75 290
Australia
36
10 22
Wells
415 Drilled through 2011

433 Projected from 2012 through 2015

483 Projected from 2016 through 2020

> Offshore HPHT activity. HPHT drilling activity is projected to accelerate in the coming years, especially offshore. In the next four years, the number of
offshore HPHT wells (green) is expected to be more than double the total drilled in the preceding three decades (blue). By the year 2020 (pink), the well
count is projected to triple. (Adapted from Simmons & Company International Limited, reference 4. Used with permission.)

worldwide (above).4 The forecast for the four-year In an effort to resolve some of the confusion, If any one of these conditions is met, the well
period ending in 2016 anticipates that the total the API recently published recommendations for is considered an HPHT well. Although the report
will be doubled, with the region off the coast of equipment used in HPHT wells, which were establishes specific guidelines for defining HPHT
Brazil alone adding more than 238 deep wells by defined as those with pressure greater than and provides protocols for certifying equipment,
2016. By 2020, the total number of offshore HPHT 15,000 psi [103 MPa] and temperature above it does not specifically address downhole elec-
wells is projected to exceed 1,200—tripling the 350°F.5 The recommendations apply primarily to tronics or certification of downhole tools.
total number of extreme offshore wells in just engineering standards related to design speci­ In an attempt to define thresholds that
10 years. The analysis highlights the need in the fications of equipment, acceptable materials reflect physical and technological limitations,
coming decade for equipment to address these and testing of well control equipment and com- Schlumberger developed an HPHT classification
HPHT operating conditions. The problem with pletion hardware. system representing stability limits of common
such analyses, however, is that the results depend The report includes design verification and
Oilfield Review 3. A recent study estimates that approximately 4,000
on the user’s definition of HPHT. validation, material
AUTUMN selection
12 and manufacturing geothermal wells had been drilled through 2011.
Sanyal SK and Morrow JW: “Success and the Learning
HPHT Fig. 3 are intended to ensure
process controls, which
Curve Effect in Geothermal Well Drilling—A Worldwide
A Matter of Semantics that equipmentORAUT
used12-HPHT
in the oil 3and gas industry is Survey,” paper SGP-TR-194, presented at the 37th
Operators and service companies often use vary- fit for service in HPHT environments. The three Workshop on Geothermal Reservoir Engineering,
Stanford, California, USA, January 30–February 1, 2012.
ing criteria for classification of HPHT wells. criteria for HPHT classification are the following: 4. These findings were noted in the Simmons & Company
Operators contend with the effects of pressure • anticipated surface conditions that dictate International Limited 2012 analysis prepared for Quest
Energy. For the report, HPHT was defined as conditions
and temperature on drilling, well construction completion and well control equipment rated greater than 10,000 psi [69 MPa] and 300°F [150°C].
and surface equipment; service companies often above 15,000 psi The number of land-based HPHT wells drilled during
the period was much higher than that of those
focus on how those conditions affect their prod- • anticipated shut-in surface pressure in excess drilled offshore.
ucts, equipment and services. Although the dis- of 15,000 psi 5. API: “Protocol for Verification and Validation of HPHT
tinction may appear subtle, the engineering • flowing temperature at the surface in excess of Equipment,” Washington, DC: API, Technical Report
PER15K-1, 1st ed., 2012.
design approach often differs. 350°F.

Autumn 2012 7
600
HPHT-hc conductivity and thermal diffusivity to ensure
260°C
that the temperature inside the housing rises
500
Ultra-HPHT very slowly.
Static reservoir temperature, °F 205°C Flasks have become an integral component in
400
HPHT tools such as the Schlumberger suite of Xtreme
150°C tools, designed for HPHT environments.7 The
300
Xtreme platform includes common measure-
ments for petrophysical analysis. Unfortunately,
200
the solution for keeping electronics protected
from wellbore heat traps self-generated heat

138 MPa

241 MPa
100
69 MPa
inside the tool housings. This heat can push
0
internal temperatures well beyond a tool’s ther-
0 5,000 10,000 15,000 20,000 25,000 30,000 35,000 40,000 mal rating. Logging engineers monitor both time
Static reservoir pressure, psi
and temperature to avoid potentially catastrophic
> HPHT classification system. This classification system was proposed by tool failure related to temperature when using
Schlumberger engineers and is based on pressure and temperature flasks in HPHT environments.
boundaries that represent stability limits of common components used by
Tools that employ high-powered downhole
service companies. These include electronic devices and sealing
elements. The HPHT-hc classification defines environments that are motors and pumps, such as pressure and sam-
unlikely to be seen in oil and gas wells, although there are geothermal pling tools, are examples of tools that generate
wells that exceed 500°F. considerable heat—much greater than most
other evaluation tools. The thermal loads gener-
ated by these tools can quickly raise the tempera-
components such as elastomeric seals and elec- electronics are protected, barring a seal failure, ture inside a flask above the rating of the
tronics (above).6 Other service companies and which would be catastrophic should failure occur electronic components. Thus, flasking alone may
operators use their own definitions, which are (below left). not provide sufficient operating time to complete
similar to the Schlumberger guidelines. Protecting sensitive downhole electronics the required task when these high-power, high
from extreme temperatures, however, usually heat–generating tools are used.
A Niche in Design relies on sheltering sensitive components from Tools that do not generate excessive heat and
The well type—HP or HT—dictates the engi- the cumulative effects of exposure to heat. This is have low power consumption, such as downhole
neering design approach because techniques most often accomplished using thermal barriers pressure gauges, may be used to collect data for
used for contending with pressure differ from in the form of flasks—double-insulated metal many hours, even days, in extreme conditions.
those for temperature. For pressure, the solution housings—that protect electronic components
is often to design equipment with sealing ele- long enough for data acquisition and other
ments capable of withstanding extreme forces. operations to be performed (below right). Flasks
Exposed surfaces may be at risk, but internal are constructed to have extremely low thermal
Oilfield Review
AUTUMN 12
HPHT Fig. 4
ORAUT 12-HPHT 4

Thermal insulators

Electronics

Vacuum layer
Dewar flask
0 cm 2.5 > Flasks for thermal barriers. The most common method of protecting
sensitive electronics from extreme heat is to use a Dewar flask (top). The
> The results of failure. This tool failed when exposed to pressures only flask (bottom) consists of a glass liner inside a metal housing that serves as
slightly above its rating. The failure was initiated at the threaded-ring a vacuum layer; the glass and air are poor heat conductors. Thermal
connection, where the pressure seal was most vulnerable. The result was a insulators at each end isolate the electronics section. Internally generated
catastrophic loss of the tools above and below the failure caused by the heat from the electronic components is trapped inside the tool and can
sudden inrush of drilling mud from the wellbore. cause the tool to overheat.

8 Oilfield Review
Thermal Hot Spots Unbalanced Loading

24 26 28 30 32 34 36 38 40 42 44 46 48
Temperature, °C
> Thermal imaging. Infrared images reveal localized hot spots and overloaded electronic components (left). Identical components on a circuit board (right)
may not have the same loading. Large loading differences may be identified using thermal imaging and may require circuit board redesign. Solutions
include changing the layout to redistribute the load or installing heat sinks to draw heat away from target areas.

For long-duration measurements in HPHT wells, temperatures has become increasingly difficult. contain volatile compounds that are released at
flasks are not a solution for these types The electronics industry is driven by consumer elevated temperatures. These chemicals are
of tools. products that use plastic electronic components highly corrosive.
For solutions to address self-generated heat that are not rated for use in even moderately For high-temperature environments, design
or extended operations in high-temperature high-temperature conditions, for instance above engineers at Schlumberger have learned to elim-
environments, design engineers often focus on 125°C [257°F]. Plastic components are often inate plastic overpacks and use only the silicon
the circuit boards. By maximizing efficiency, ana- composed of silicon chips, or dies, enveloped in a chips. These chips and other components are
lyzing the heat generated by electronic compo- plastic overpack. These components cannot attached directly to heat-tolerant ceramic multi-
nents and, wherever possible, employing withstand the rigors of extreme environments layered circuit boards; the connecting wires
components that have above-average tempera- because the overpack fails first from tempera- have the diameter of a human hair (below). In
ture ratings, engineers can extend the time avail- ture effects, although the underlying electronic some cases, engineers have created proprietary
able for tools to operate and acquire data component may not have failed. In addition,
6. DeBruijn et al, reference 1.
downhole (above). manufacturers treat plastic electronic compo- 7. For more on Xtreme logging tools: DeBruijn et al,
Sourcing components that withstand high nents with flame retardant chemicals, which reference 1.

Oilfield Review
AUTUMN 12
HPHT Fig. 7
ORAUT 12-HPHT 7

× 65

> Designed for extremes. To ensure tools are able to operate under extreme temperatures, engineers use components that rely on the underlying ceramic
and metal (center) without the plastic overwrap commonly used in consumer electronics. Ceramic components may be combined in multichip modules
(MCMs) (left). Component reliability can also be improved with manufacturing techniques such as the use of low-mass connections (right), some of which
are similar in thickness to a human hair.

Autumn 2012 9
Seven Days at 150°C Without Desiccant
Cracked wedge

× 1,000

Seven Days at 150°C with Desiccant

Broken
wedge

× 200

× 50

> Electronic component failure mode. When electronic components fail, the mode can often be traced to mechanical failure from shock and vibration.
Cracks may form at connections (left) that eventually break under repeated loading. In the sealed environments of logging tools, corrosive chemicals may
be released from circuit boards and other components. At elevated temperatures, the corrosivity of these chemicals is accelerated, which causes damage
to sensitive electronics (top right). If the tools are opened for maintenance and repair, moisture in the air may also become a problem. When space is
available, desiccants can be used inside tool housings, protecting electronics from corrosion by absorbing humidity and volatilized chemicals (bottom right).

dies that are programmed and packaged for spe- design effectiveness or identifies weaknesses formation dynamics tester. The electronics sys-
cific applications and built to high-temperature that can then be rectified. tems for the MDT Forte tool were completely
specifications that exceed those readily available reconfigured and mounted on a ruggedized chas-
in the commercial marketplace. Engineered for Extremes sis (next page, top). Engineers then subjected the
Extensive analysis of failed electronic compo- The MDT modular formation dynamics tester has new design to a rigorous qualification process.
nents has resulted in other design innovations. been an industry standard for fluid sampling since The temperature qualification process of the
The failure of electronic components may occur its introduction in 1989. Through the decades, an MDT Forte platform consisted of thermal aging of
at elevated temperatures; however, the actual extensive array of sampling and downhole analy- components, thermal cycling from –40°C to
failure mode is often traced to mechanical break- sis tools has been added to the basic platform. 200°C [–40°F to 392°F] and cold storage at
downs (above). The two most common causes of Along with new features and services, several –55°C [–67°F]. Shock and vibration qualification
mechanical failure are corrosion and vibration. modifications have been implemented to improve included thousands of shocks on individual cir-
Corrosion can be problematic because high the tool’s reliability and performance; however, cuit boards, which were administered on differ-
temperatures accelerate chemical corrosivity, the basic design and layout of the tool electronics ent axes by rotating the boards in the test facility.
especially that resulting from humidity and vola- and hardware have not changed. Vibration testing of the boards included 10- to
tilized gases from products used in the manufac- In the years since
Oilfield the MDT tool was intro-
Review 450-Hz sweeps. Engineers also performed pres-
ture of circuit boards. Where space permits, AUTUMN 12engineers have been
duced, Schlumberger sure cycling, vibration transmissibility and trans-
desiccants are inserted in tool housings to absorb HPHT
designing tools Fig. 8
to withstand high levels of shock verse shock transmissibility testing. After
volatilized chemicals and moisture. ORAUTprimary
and vibration—the 12-HPHTsources
8 of most elec- qualifying the boards, they conducted tempera-
Techniques to extend operability time miti- tronic component failures. Much of the impetus ture and shock qualification on full tool assem-
gate the effects of high temperature, but such for establishing higher standards came from blies. They also performed extended low- and
techniques only extend the time available for requirements for LWD tools, which operate in high-temperature operations, including operation
tools to operate at elevated temperatures. extremely harsh conditions. Design engineers at 210°C [410°F] for 100 h while administering
Similarly, shock and vibration cannot be elimi- have integrated techniques developed for LWD shocks to the tool assembly (next page, bottom).
nated, but better tool designs can improve the tools in wireline tools, and new designs of wire- These tests confirmed the new design could
mechanical integrity of connections and compo- line tools are qualified to LWD standards when- withstand mechanical shock and vibration in
nents. Attaching circuit boards to specially ever possible. addition to thermal shocks, thereby meeting qual-
designed mounting rails and shock absorbers can To pass these new qualification standards, the ification standards that previous-generation tools
improve tool reliability. Once the designs are MDT tool could not simply be upgraded but could not. The temperature and pressure ratings
finalized, thorough and rigorous testing, using required a full redesign. This newly designed tool of the MDT Forte tool are 177°C [350°F] and
both thermal and mechanical loads, validates the was introduced as the MDT Forte rugged modular 172 MPa [25,000 psi].

10 Oilfield Review
Original Design Redesign

> Making tools stronger and better. Older tool designs, like those of early generation MDT tools (left), used discrete components and circuit boards attached
to a central mandrel. These designs have been replaced by boards rigidly mounted to solid rails, such as those used in the MDT Forte tool (right). This
approach isolates sensitive electronics from shock and vibration and also helps dissipate heat. Many of the design changes have been introduced from
lessons learned developing LWD tools; newer generation tools are designed to pass LWD shock and vibration standards whenever possible.

Design engineers next focused on develop- nanotubes in the O-ring seals. The structure of Engineers also upgraded the pressure gauge
ing a tool with the improved reliability of the these sealing elements provides strength to with- used for the MDT tool by adding a new-generation
MDT Forte tool that could also withstand higher stand downhole effects such as temperature deg- quartz gauge qualified to 207 MPa and 200°C for
temperatures and pressures. The result is the radation and rapid gas decompression during 100 h. A high-temperature InSitu Density reser-
MDT Forte-HT rugged high-temperature version, operations. The seals, which provide sample voir fluid density sensor, which monitors fluid
which is rated to 204°C [400°F] and 207 MPa assurance that is not possible with conventional density and helps improve fluid sample quality,
[30,000 psi]. elastomers, retain full high-pressure capability was developed and placed in the flowline. The
To meet the 207-MPa pressure rating of the even at low subsea temperatures routinely expe- fluid density measurement provides the
MDT Forte-HT tools, engineers employed innova- rienced in deepwater environments while run- ability to identify compositional grading and fluid
tive sealing technology that incorporates carbon ning in the well. gradients at HPHT conditions—the first time

50 h 50 h 50 h
400°F
45 h 5h 45 h 5h
75% power load
75% 100% 75% 100%
Oilfield Review power power power power
Ambient AUTUMN 12 load load load load
temperature
HPHT Fig. 9 Shock test Shock test Shock test
ORAUT 12-HPHT 9

> Proof of concept. The MDT Forte tool platform (bottom) was designed to pass shock and vibration standards similar to those for LWD tools. Tool
qualification using the laboratory equipment shown (top left) cycles the tool through temperature variations while subjecting the tool to repeated
mechanical shocks. The test cycle (top right), which is just one of many, elevates the temperature to the tool limit and holds it for 50 h. The tool is allowed to
return to ambient conditions and subjected to fifty 250-gn shocks on four axes. The cycle is then repeated. These tests help identify design weaknesses as
well as validate design concepts.

Autumn 2012 11
Upgraded Inflatable Packer these measurements have been available in these
environments.
For the MDT Forte-HT version, the dual-packer
module was also upgraded to 210°C. This module
uses sealing elements above and below the zone of
interest to isolate formations for sampling (left).
The inflatable packer elements isolate an interval
from 1 to 3.4 m [3.3 to 11.2 ft] in length.
The pumpout module presented one of the
most challenging aspects of upgrading the
MDT tools to the higher temperature and pres-
sure ratings. The pumpout module is important
for ensuring a reliable sample of formation fluid.
It uses a positive displacement pump to transfer
formation fluids that may be contaminated with
drilling mud filtrate into the wellbore until the
sample stream is free of impurities. When the
quality of the stream is acceptable, samples are
taken and recovered for analysis.
Four new pumpout displacement units are
now available to meet a range of specifications,
from a standard version to an extra, extra high-
pressure version (below left). Engineers designed
the new pump to operate more efficiently—to
generate less heat, resist plugging and handle
mud solids more effectively. The increased flow
area of the new pump decreases O-ring erosion
and delivers better sand-handling capabilities.
The pumpout modules are compatible with the
Quicksilver Probe device.8

Meeting the Sampling Challenge


The challenge of taking samples and pressures in
HPHT conditions extends beyond simply being
> MDT Forte-HT tool additions. Engineers designed modules and tools to able to acquire fluids or pressure data. The sam-
complement the new higher temperature rating of the MDT Forte-HT tool- pling time must be minimized to avoid tool dam-
string. This inflatable fullbore packer withstands temperatures up to 210°C. age from both internally generated heat and
external heat exposure; however, the sample
must be as free of contamination as possible to
ensure that the fluids collected by the tool and
analyzed in the laboratory are representative of
the formation fluids. In a recent test, a North Sea
operator successfully ran an MDT Forte-HT tool-
string that included two pumpout tools, a
Pumpout Module Displacement Units
Quicksilver Probe assembly and downhole fluid
analysis modules.
Standard tool High-pressure
Oilfield Review tool Extra high-pressure tool Extra, extra high- The well was drilled with oil-base mud (OBM)
pressure tool
AUTUMN 12 into a reservoir with pressures in excess of
Volume/stroke, 485 [30] HPHT366Fig.[22]11 177 [11] 115 [7]
cm3 [in.3] 17,000 psi [117 MPa]. Along with high downhole
ORAUT 12-HPHT 11
Maximum differential 32 [4,641] 42 [6,092] 58 [8,412] 81 [11,748] pressures, the operator faced bottomhole tem-
pressure, MPa [psi] peratures ranging from 347°F to 370°F [175°C to
Pump flow rate, 8.2 to 32.8 6.3 to 24.6 4.4 to 18.3 0.8 to 16 188°C]. Sample quality was crucial for accurately
cm3/s [in.3/s] [0.5 to 2] [0.4 to 1.5] [0.3 to 1.1] [0.05 to 1]
characterizing the reservoir fluids, but the high
> MDT pumpout module options. temperatures limited the time available for sam-
pling. Samples had to be taken quickly, yet fluids
needed to flow long enough to minimize OBM
filtrate contamination.

12 Oilfield Review
Fluid Composition Pressure GOR Mobility

CO2 C1 C2 C3–5 C6+ psi XX,000 ft3/bbl YY,000 0.2 mD/cP 2,000
Station 1

Station 2
Depth

Station 3

Station 4

Station 5

CO2 C1 C2 C3–5 C6+


Fluid composition, %

100
80
60
40
20
0
2,000 2,500 3,000 3,500 4,000 4,500 5,000 5,500
Elapsed time, s

YY,000
GOR
ft3/bbl

XX,000
2,000 2,500 3,000 3,500 4,000 4,500 5,000 5,500
Elapsed time, s
> Quality sampling at extreme conditions. Using a reverse low-shock sampling technique, a North Sea
operator was able to identify fluid contacts and fluid composition in wellbore conditions approaching
370°F with the MDT Forte-HT tool. Samples were acquired with the Quicksilver Probe assembly, and
the filtrate contamination was less than 2%. The operator was interested in CO2 content (Track 1,
purple, top), which was available in the fluid composition analysis. A water contact can be identified
by the blue color in the composition track at Station 5. During the time interval shown in the sampling
plot (center), flow consisted of hydrocarbons with a trace of CO2. The change in GOR (green, bottom)
at 2,750 s was associated with a shift in direction of the reverse low-shock sampling. Accurate H2S
content was measured in the flowing stream using specially designed coupons. The low levels of
OBM filtrate resulted in samples that were unaltered by filtrate contamination, and reverse low-shock
sampling minimized scavenging of H2S by metal components of the tool.

The presence of OBM filtrate affects labora- For the well in question, the North Sea opera- results than those that draw formation fluid into
tory analysis of reservoir fluids and may distort tor collected several high-quality PVT samples in chambers at atmospheric pressure. Reverse
H2S measurements because the filtrate may scav- a single trip (above). Filtrate contamination for low-shock sampling routes fluid directly into
enge H2S from reservoir fluids. Sample quality all samples was 2% or lower. Downhole fluid anal- sample bottles without passing it through the
and reliability of the fluid property measure- ysis provided fluid composition, CO2 content, pumpout module. This technique reduces the
ments are improved when engineers, using the GOR and fluorescence. opportunity for metal hardware to scavenge
pumpout module, first remove fluids contami- Because H2S was a concern for the operator, H2S, although additional precautions are taken
Oilfield Review
nated with filtrate. The Quicksilver Probe device, the MDT tool was configured
AUTUMN 12 for reverse low- to minimize scavenging, including replacing
which uses a focused sampling technique, greatly shock sampling. This technique
HPHT Fig. 11B helps minimize exposed parts with INCONEL alloys and coating
decreases the time required to remove contami- ORAUT 12-HPHT
the scavenging of H 2S by tool11B
hardware and by
8. For more on the Quicksilver Probe device: Akkurt R,
nated fluids and reach acceptable purity levels, OBM filtrate. The low-shock sampling technique Bowcock M, Davies J, Del Campo C, Hill B, Joshi S,
cutting sampling time by as much as half com- holds the pressure in the piston chambers of the Kundu D, Kumar S, O’Keefe M, Samir M, Tarvin J,
Weinheber P, Williams S and Zeybek M: “Focusing
pared with the time required for sampling with pumpout module near that of the borehole on Downhole Fluid Sampling and Analysis,”
conventional probes. pressure, minimizing the drawdown pressure Oilfield Review 18, no. 4 (Winter 2006/2007): 4–19.

during sampling. The technique produces better

Autumn 2012 13
Sensor Assembly Bellows Assembly Reservoir Pressure Only
Temperature crystal Operators cannot always acquire fluid samples or
perform complex downhole fluid analyses, nor do
they always need to. These tasks are especially
problematic in low-permeability formations in
Pressure
inlet which fluid samples may be difficult to obtain or
long sampling times are required. However, accu-
rate pressure and fluid mobility data are important
Pressure crystal Bellows for understanding these reservoirs.9 These data
0 cm 2.5 are especially crucial for establishing fluid gradi-
Reference crystal
ents and identifying fluid contacts. Engineers at
Schlumberger developed the PressureXpress res-
ervoir pressure while logging service, which typi-
cally measures downhole pressure and mobility in
less than a minute, to address situations in which
pressure data alone may be sufficient.
The speed with which this service delivers
> Quartzdyne pressure transducer. Three quartz crystal resonators—a
multiple measurements greatly improves the like-
temperature sensor, a pressure sensor and a reference—make up the
Quartzdyne transducer. An increase in pressure at the pressure inlet of the lihood of successful operations at elevated tem-
bellows assembly causes an increase in frequency of the signal from the peratures, although the original tool is rated for
pressure crystal. An increase in temperature causes the frequency of the only 150°C [300°F]. The lower temperature rating
temperature crystal signal to decrease. The signal from the temperature and absence of a flask to protect sensitive compo-
sensor is used to compensate for temperature effects. The reference
crystal simplifies frequency counting output from the other two crystals. Its nents severely limited the use of the tool in HPHT
output is mixed with the output of the temperature and pressure sensors, environments. A more robust version was devel-
lowering their frequencies from the MHz to the kHz range. The design oped to meet the challenge of HPHT operations.
results in a low power consumption gauge that is highly stable and shock To upgrade the PressureXpress tool design,
resistant, while providing high-resolution measurements. A pressure
resolution of 0.01 psi [70 Pa] and temperature resolution of 0.001°C [0.002°F] engineers focused on the electronics and the
can be obtained using this gauge. pressure gauge. Pressure measurements with
quartz gauges are highly accurate, but the data
must be corrected for temperature. This tempera-
ture correction applies to the measurement elec-
parts with compounds that inhibit H2S were confirmed by laboratory analysis. Combined tronics rather than the reservoir temperature.
adsorption. Specially designed metal strips— Oilfield Review
with a Quicksilver Probe assembly, the MDT For downhole pressure measurements, the
coupons—that detect H2S concentrations AUTUMN
were 12
Forte-HT tool met the operator’s sampling objec- PressureXpress and PressureXpress-HT high-
HPHT Fig. 12
included in the tool flowlines. tives
ORAUT 12-HPHT 12 of obtaining uncontaminated reservoir temperature reservoir pressure services use a
The fluid properties, measured downhole in fluid, determining CO2 concentration and Quartzdyne gauge, which differs from conven-
extreme pressure and temperature conditions, detecting H2S. tional quartz gauges in that it has three separate
crystals: One measures pressure, another mea-
sures temperature and a third acts as a reference
(above left).10 The measurement is extremely
Pressure Data Comparison accurate when all three crystals are at the same
3,393 temperature, and the gauge is reliable at tem-
3,391.99 psi peratures up to 225°C [437°F]. But the gauge is
3,392
sensitive to abrupt pressure and temperature
Pressure, psi

3,391
changes. When exposed to rapid high-tempera-
3,390.03 psi ture and pressure changes, which can occur when
3,390 running into the well on wireline, the gauge must
be allowed to stabilize before acquiring data.
3,389
The PressureXpress-HT tool is equipped with
3,388 two flasks—one for the pressure gauge and
0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 another for the electronics—to isolate the pres-
Time, s sure gauge sensor from the borehole and to isolate
> Thermal isolation of the PressureXpress tool pressure gauge. The PressureXpress-HT tool isolates the the rest of the tool electronics from the gauge.
pressure gauge and the rest of the electronics in separate flasks, which protects the gauge from This configuration has proved to provide more-
external wellbore temperatures and internally generated heat from the electronics. A comparison of
stable measurements than those taken with tools
measurements from a flasked sensor (red) and an unflasked sensor (blue) demonstrates the higher
accuracy and greater stablility of the flasked gauge. The output of the unflasked sensor stabilizes at the without flasks or when the electronics are housed
input pressure (3,391.99 psi) after almost 150 s. with the gauge in the same flask (left). Electronic

14 Oilfield Review
components for the PressureXpress-HT tool were
also upgraded based on many of the lessons
MYANMAR
learned from the MDT Forte-HT tool design.
LAOS
The modifications to the PressureXpress-HT
tool have extended the temperature specifica-
tions of the tool to 232°C [450°F] for 14 h.
Pressure and mobility measurements may be
obtained with drawdown differential pressures
180°F to
up to 55 MPa [8,000 psi] and pretest mobility as 220°F
low as 0.3 mD/cP may be detected. The tool
THAILAND
retains its slim diameter, even with the addition
of flasks. The probe section can be as small as
10.3 cm [4.05 in.] while the main tool body has a
diameter of only 9.8 cm [3.9 in.].
CAMBODIA
Gulf of Thailand Challenges 220°F to
320°F
Because of high geothermal gradients, the south- ailand
f Th
ern regions of the Gulf of Thailand represent some f o
G ul
of the world’s harshest environments for hydro- VIETNAM
320°F to
carbon production (right). The Arthit field in the 350°F
Gulf of Thailand is about 230 km [143 mi] off-
shore. PTT Exploration and Production Plc 350°F to Arthit
(PTTEP) discovered the field in 1999. The field is 500°F field
characterized by highly compartmentalized, com-
Songkhla
plex reservoirs that have bottomhole tempera- Anda
man
tures between 320°F [160°C] and 500°F [260°C].11 Sea 0 km 200
Production is from Late Eocene to Late 0 mi 200
Oligocene formations that are characterized by
> Gulf of Thailand temperature trend. Reservoir temperatures in the Gulf
low permeability. Low-permeability formations
of Thailand range from relatively benign in the north to extremes of 500°F
may require extended sampling time, even when [260°C] in the south. Field development in the high-temperature reservoirs,
only pressures and mobility data are acquired. such as the Arthit field, presents challenges for equipment used downhole.
Most boreholes are small, usually drilled with (Adapted from Daungkaew et al, reference 11.)
a 61/8-in. bit, which limits the size and selection of
tools that can be run at TD. Because of the small
hole size, PTTEP historically acquired pressure
and sampling data with an SRFT slimhole repeat
formation tester. Although this tool is rated only
to 177°C [350°F], it was one of the few options An additional flasked section that isolated the than a minute compared with two to three minutes
available for the hole size typically drilled in the gauge was added next, which resulted in a con- with the SRFT tool.
field. The measurements needed from the tool figuration similar to the PressureXpress-HT tool. Not only does the PressureXpress-HT tool set
included formation pressure, fluid gradients and The success of the modified PressureXpress and retract more quickly than the previous-
CO2 content. Of these, only CO2 content required tool led design engineers at Schlumberger to generation tool did, but tool performance and
fluid sampling. The pressure data were used to develop a fully upgraded PressureXpress-HT tool, data quality are improved. A direct comparison of
determine fluid contacts, fluid mobility, sand-to- which was field-tested in the Gulf of Thailand. the data from the PressureXpress-HT tool with
sand pressure correlation, reservoir connectivity, The tool, which incorporated upgraded electron-
  9. Fluid mobility is a measurement of the ease with which
compartmentalization and perforation design ics for high-temperature operations and flasks fluids travel through rock. It is the ratio of rock permeability
strategy. The data were also used to identify developed specifically for it, is combinable with divided by the dynamic viscosity of the fluid.
10. For more on Quartzdyne Technologies: http://www.
depleted zones. other evaluation tools and can be included on the quartzdyne.com/quartz.php (accessed August 7, 2012).
In 2009, a flasked PressureXpress tool was first trip into the well. The SRFT tool isOilfield
not com-Review
11. Daungkaew S, Yimyam N, Avant C, Hill J, Sintoovongse K,
introduced in Thailand. The tool was capable of binable and requires an additional tripAUTUMN
when the 12 Nguyen-Thuyet A, Slapal M, Ayan C, Osman K,  
obtaining all of the PTTEP objectives except operator requires samples. HPHT Fig. 14 Wanwises J, Heath G, Salilasiri S, Kongkanoi C,
ORAUT 12-HPHTPrapasanobon
14 N, Vattanapakanchai T, Sirimongkolkitti A,
Ngo H and Kuntawang K: “Extending Formation Tester
one—CO2 content. However, this tool did not PTTEP compared PressureXpress-HT opera-
Performance to a Higher Temperature Limit,” paper  
include a separate flask for the pressure gauge, tional and measurement performance with those IPTC 14263, presented at the International Petroleum
which caused gauge stability problems because of the SRFT tool. Rig time was noticeably reduced. Technology Conference, Bangkok, Thailand,  
February 7–9, 2012.
the internal temperature rose during operations. Time savings were realized from improved effi-
ciencies and through set and retract times of less

Autumn 2012 15
data from the SRFT tool demonstrated the stabil-
Resistivity
SRFT Pressure Data ity and accuracy of the measurements. In a Gulf
SRFT Mobility Data 90-in. Induction
of Thailand well, the new tool provided fluid
X,000 psi Y,000 Crossover 0.2 ohm.m 200
gradient data that clearly identified a gas/water
PressureXpress Pressure Data PressureXpress
Mobility Data
Neutron Porosity 30-in. Induction contact, whereas the data from the SRFT tool
X,000 psi Y,000 45 % –15 0.2 ohm.m 200 were scattered and not definitive (left).
Gamma Ray Depth, Drawdown Mobility Bulk Density 10-in. Induction A comparison of pretest data from the first
ft
0 gAPI 200 0.1 mD/cP 10,000 1.95 g/cm3 2.95 0.2 ohm.m 200 application of the tool demonstrated the higher
X,100 efficiency and improved performance of the
PressureXpress-HT tool (below left). Performance
continued to improve after a few jobs; on an off-
set well, 76% of the attempted pressure tests
0.319 psi/ft (gas)
were successful with no unstable tests and no
Gas/water contact lost seals.
The tool is combinable with other logging
tools. Because it sets and retracts quickly, and
because the quartz gauge requires little stabiliza-
tion time, PTTEP has experienced average time
0.401 psi/ft (water)
savings between 157 and 167 min per job. This
translates into direct rig cost savings. Fast set-
retract cycling has also allowed PTTEP to per-
form more tests before the tool heats up and
X,150
must be removed from the well.
The success of the PressureXpress-HT tool
demonstrates that the new design meets the
challenge of extreme conditions by protecting
sensitive electronics with thermal barriers and
> Stable pressure measurements. Engineers identify fluid contacts from fluid pressure gradients. This minimizing heat generation. Because the
information enhances conventional log evaluation. For instance, the rise in resistivity (Track 4) around PressureXpress tool does not have the capability
X,115 ft might be interpreted as a gas/water contact (GWC). The density-neutron porosity data
to sample or measure CO2, PTTEP continues to
(Track 3) provide little help in determining the fluid contact. However, with pressure data at around
X,120 ft from the PressureXpress-HT tool (Track 1, blue circles), a GWC can be identified from the use the SRFT tool for taking fluid samples. In
change in slope of a line drawn through pressure measurements. No such trend can be established development wells, where fluid properties are
with the SRFT data (black circles). Engineers also identified permeable zones using fluid mobility known, fluid sampling is often unnecessary
measurements from the PressureXpress-HT data (Track 2). (Adapted from Daungkaew et al,
reference 11.) and pressure data, from the PressureXpress-HT
tool, for example, can be used for reservoir man-
agement and modeling. Pressure information
helps engineers understand dynamic properties
at the wellbore and across a reservoir.

Field Results Time and Temperature


Well A-1 To understand the reservoir limits and define
Number of attempts Valid Dry Tight Unstable Lost seal Supercharged field potential, engineers often conduct long-
PressureXpress-HT
data 37 18 (49%) 2 (5%) 10 (27%) 2 (5%) 4 (11%) 1 (3%)
duration pressure transient tests. Shut-in and
Number of attempts Valid Dry Tight Unstable Lost seal Supercharged
buildup tests help accurately define reservoir
SRFT data potential. These tests provide data on reservoir
10 Oilfield Review
2 (20%) 2 (20%) 1 (10%) 1 (10%) 4 (40%) 0
AUTUMN 12A-2 volume, permeability thickness and boundaries,
Well
HPHTValid
Number of attempts
Fig. 15 Dry Tight Unstable Lost seal Supercharged
along with skin effect in the well being tested.
PressureXpress-HT ORAUT 12-HPHT 15
data Critical decisions that affect long-term pro-
29 22 (76%) 6 (21%) 1 (3%) 0 0 0
duction plans require data from long-duration
> Comparison of PressureXpress-HT field results with SRFT data. In the first well test (Well A-1), the tests. Although some measurements that reflect
PressureXpress-HT tool was able to make more attempts and had a higher success rate than the SRFT well production can be acquired at the surface,
tool. In Well A-2, only the PressureXpress-HT tool was run. This test had a 76% success rate for
pressure attempts, which engineers considered excellent for the downhole conditions and formation for best results, measurements are acquired with
properties. (Adapted from Daungkaew et al, reference 11.) gauges positioned downhole, as close to the
producing zone as feasible.

16 Oilfield Review
Quartz gauges are the industry standard for
measurement accuracy and precision downhole.
These gauges use quartz as the active sensing ele-
ment because of its well-defined elasticity. When
exposed to a stress, the quartz distorts, or strains,
with a precise, repeatable response in reaction to
the applied load. The measurement must be cali-
brated to compensate for the effects of tempera-
ture on the sensing element and associated
electronics. In HPHT environments, however,
operators have had to forgo extended well tests
because downhole conditions preclude the use of
gauges needed to make the measurements.
Engineers at Schlumberger developed the
Signature quartz gauge in recognition of the
industry’s need for a robust downhole device that
provided the accuracy and precision required but
could withstand harsh HPHT conditions (right).
Not only does the instrument survive HPHT envi-
ronments—no simple task—but the data
acquired meet needed accuracy and stability cri-
teria. In developing the Signature gauge, engi-
neers focused on two main areas of concern:
electronics and batteries.
> Signature gauge. The outside diameter of the Signature gauge is only
For high-temperature applications, engineers
25 mm [1 in.] and the tool weighs 1.7 kg [3.8 lbm]. Rated to 207 MPa and
chose ceramic electronic components; plastic 210°C, the gauge is accurate to within 0.015% at full scale and has a
components would never survive the tempera- resolution of 7 Pa [0.001 psi].
ture extremes for long-duration tests. The major-
ity of the electronic functionality for the
Signature gauge is incorporated into a high-tem-
perature application-specific integrated circuit
(ASIC), which minimizes component size and
power consumption. Limiting power consump-
tion is a challenge because consumption
increases dramatically at high temperatures,
often surpassing the ability of the battery to
deliver sufficient current to operate the tool.
Condensing the electronics into an ASIC
reduces the number of components, connections
and potential failure mechanisms. Since the pre-
dominant failure mode of electronics is mechani-
cal, this design was developed with reliability and Oilfield Review
AUTUMN 12
ruggedness in mind. HPHT Fig. 16
The electronic circuitry is integrated into a ORAUT 12-HPHT 16
multichip module (MCM). There are many types
of MCMs but the Signature gauge uses rigor-
ously tested high-temperature electronic com-
ponents on a single cofired ceramic substrate
(right).12 This technology provides mechanical
rigidity and hermeticity.
12. Cofiring is a fabrication technique used for creating
multilayer ceramic chips. 0 cm 1

> Designed for extreme conditions. The electronic components (gold) used in the Signature gauge are
applied directly to a ceramic substrate (brown). Conventional tools may use plastic components mounted
on circuit boards. The Signature gauge is designed for low power consumption to maximize battery life,
which is a chief limiting factor for high-temperature operations that rely on downhole batteries.

Autumn 2012 17
Pranhita-
Godavari Basin
I N D I A

Krishna-
Cuddapah Godavari Basin
Basin

Palar-
Pennar GSPC lease
Chennai Basin

Cauvery
Basin
Deep exploration 0 km 20
engal
y of B targets
Ba 0 mi 20

SRI 0 km 200
LANKA
0 mi 200

> Bay of Bengal basins. In 2005, Gujarat State Petroleum Corporation made a huge natural gas discovery offshore
India in the Godavari basin. Well depths here are approximately 5,500 m [18,050 ft], with bottomhole temperatures
greater than 200°C. (Adapted from Khan et al, reference 14.)

Electronics that survive long-term exposure gauges differ in electronics, memory size and bat- amounts of natural gas in the Krishna-Godavari
at high temperatures still need power to operate. teries. The maximum pressure rating of the HP basin, which extends into the Bay of Bengal off-
Because the melting point of lithium is 181°C version is 207 MPa and the temperature rating is shore India. Initial reports by GSPC in 2005 indi-
[358°F], conventional lithium batteries—the 177°C. The HPHT model has the same pressure cated a resource potential for 566 billion m3
industry standard—cannot be used in high-tem- rating but the maximum temperature is 210°C. [20 Tcf] of gas, the largest discovery in India at
perature wells for long periods. Battery special- Because of the limitations imposed by high-tem- that time (above).15
ists at Schlumberger developed lithium batteries perature environments, the HPHT memory The discovery well encountered 800 m
that incorporate magnesium to strengthen the capacity is 12 days of 1-s recordings at maximum [2,600 ft] of gas-bearing sandstone at around
cell structure of the battery, which allows battery temperature in contrast to 50 days for the other 5,500 m [18,050 ft]. Reservoir temperatures
operation up to 210°C. Although battery life two models.13 exceed 204°C. The highly faulted horst and gra-
remains the primary limiting factor in high- For the Signature gauge, the accuracy and ben structures are lower Cretaceous-age sand-
temperature operations, batteries with this resolution for both pressure and temperature stones that have experienced extensive rifting
design can power the tool for 12 days at 210°C measurements are some of the best in the indus- and tectonic faulting. Although seismic data indi-
and 37 days at 205°C [400°F]. try. The HP and HPHT models have pressure accu- cated potential targets for exploration, the depth
To maximize test duration and extend battery racy of 0.015% at full
Oilfield scale—207 MPa—with a
Review and complexity of the reservoir led reservoir
life, the electronics are designed to consume min- AUTUMN 1270 Pa [0.01 psi]. Field
resolution better than engineers to design a drillstem test (DST) to bet-
imal power during operations. Even if the batter- results have HPHT Fig. 18 resolution better than
demonstrated ter understand the reservoir potential.
ies are fully discharged, data are recorded in ORAUT
7 Pa [.001 psi]. 12-HPHT 18
Temperature accuracy is 0.2°C
13. Storage capacity for the standard and HP Signature
nonvolatile memory and stored for the duration of [0.4°F] with a resolution of 0.001°C [0.002°F]. gauges is 16 MB. It is 4 MB for the HPHT model.
extended tests with no loss of information. 14. Khan ZA, Behera BK, Kumar V and Sims P: “Solving
the Challenges of Time, Temperature and Pressure,”
The Signature quartz gauges are available in The Challenge of the Bay of Bengal World Oil 233, no. 5 (May 2012): 75–78.
three models: standard quartz, high-pressure The HPHT version of the Signature quartz gauge 15. “India’s Gujarat Petroleum Strikes Record Gas Find,”
(HP) quartz and HPHT quartz. The physical was recently put to the test in a well operated Spirit of Chennai, http://www.spiritofchennai.com/news/
national-news/a0272.htm (accessed June 6, 2012).
dimensions for all three gauges are the same at by the Gujarat State Petroleum Corporation 16. Khan et al, reference 14.
25 mm [1 in.] outside diameter; however, the (GSPC).14 GSPC, India’s only state-owned oil and
gas company, made discoveries of significant

18 Oilfield Review
Temperature
20,000 Pressure 425

18,000 405

16,000 385

Temperature, °F
All electronic gauges, except
Pressure, psi
Disturbance the Signature quartz gauge,
14,000 during buildup failed to record after this time. 365
Clean buildup
Drawdown Drawdown
12,000 345

10,000 325
Buildup 1 Buildup 2 Buildup 3
8,000 305
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Time, d
> Extended pressure test. GSPC performed an extended well test that included three buildup and drawdown
sequences performed over 15 days. Five gauges were run downhole for redundancy and data security. The first
two sequences experienced operational problems, and the tests were compromised by disturbances in the
pressure data (blue). The third sequence was performed properly. After the gauges were retrieved, all but one
were discovered to have failed prior to the commencement of the third (and only valid) test. The only usable data
retrieved were from the HPHT Signature gauge. (Adapted from Khan et al, reference 14.)

To establish stable flow within the reservoir, other gauges because they had all failed prior to to lower temperatures and pressures. Pressure
engineers designed the DST to include three suc- the commencement of the final test. The data and sampling tools were once in that class. Now
cessive drawdowns and buildups conducted over from the Signature gauge were of sufficient that it has been proved that these services can
15 days. The estimated downhole pressure was quality—pressure fluctuations of as little as 7 Pa be performed in extreme conditions, geologists,
more than 95 MPa [13,800 psi] and the tempera- were detected—that a second confirmation test engineers and geophysicists often consider the
ture was greater than 210°C at TD. Extensive was considered unnecessary. GSPC engineers measurements essential to fully characterize
backup systems included five different electronic estimated that US$ 1 million was saved because and understand reservoirs.
recording devices. The Signature quartz gauge remedial services to resolve reservoir complexity Extreme wells call for extreme solutions.
was the only device that engineers deemed suit- were not needed.16 Although HPHT fields may contain a relatively
able for deployment at the 210°C level, which was small number of wells, they also may contain sig-
close to TD. The Limit nificant sources of hydrocarbons. Thanks to an
For the most accurate data, gauges should be At one time, oil and gas service companies enormous research and engineering effort, more
positioned as close to the producing zone as pos- expressed grave concern about their ability to and more options are available for operators to
sible because the compressibility of natural gas develop tools capable of withstanding extreme drill wells, evaluate formations and properly
may distort the measurement. Although not opti- conditions. Electronics manufacturers shifted characterize reservoirs. —TS
Oilfield Review
mal, but because of temperature and pressure their focus from rugged 12
AUTUMN components to those that
limitations, three of the five devices were located consume littleHPHT Fig. 19 operate at ambient
power and
more than 1,000 m [3,280 ft] above the depth at ORAUTservice
conditions, leaving 12-HPHT 19
companies to fend for
which the Signature gauge was positioned. themselves. Design engineers, however, are now
The operator ran three pressure transient meeting the challenge of extreme operating envi-
tests in sequence for the full 15 days. During the ronments with innovative pressure and sampling
first two tests, the operator experienced prob- tools and downhole gauges for evaluating
lems that invalidated the tests but were unre- HPHT reservoirs.
lated to the gauges. The third test sequence, Service companies have demonstrated an
however, was performed as planned. ability to meet the challenge of hostile drilling
The test assembly was retrieved and only one environments. Although the portfolio of offer-
of the gauges was found to be operational, the ings has expanded in recent years, it is still
Signature quartz gauge (above). No usable down- limited to primary evaluation services. Some
hole electronic data were recorded from the measurements that operators would like to have
to characterize producing wells remain limited

Autumn 2012 19
When Rocks Get Hot: Thermal Properties of
Reservoir Rocks

For many years, thermal stimulation has been the leading method for enhanced oil
recovery. Operators are using new techniques on heavy oil, tar sands, bitumen and oil
shale to liberate a vast store of liquid energy that could provide transportation fuels
for worldwide use for a century or more. Design of stimulation programs to produce
these resources efficiently over long periods of time requires better understanding
and measurement of thermal properties of rocks.

Evgeny Chekhonin When reservoir fluid gets hot, its viscosity remarkable successes. At the Kern River oil field
Anton Parshin decreases, and a greater amount of fluid usually in California, USA, for example, a massive pro-
Dimitri Pissarenko can be produced from the reservoir rock. gram of cyclic steam injection, starting in the
Yury Popov Stimulation of conventional petroleum reservoirs 1960s, revived this supergiant field by increasing
Raisa Romushkevich with heat from injected steam or hot water has its production rate more than tenfold after it
Sergey Safonov
been practiced for more than 50 years with some had stagnated for decades (below). Today, about
Mikhail Spasennykh
Moscow, Russia

Mikhail V. Chertenkov
Vladimir P. Stenin
Lukoil
Ca

Moscow, Russia
lif

UNITED STATES
orn

Oilfield Review Autumn 2012: 24, no. 3.


ia

Copyright © 2012 Schlumberger.


For help in preparation of this article, thanks to Yevgeniya Kern River field
Gelman, Houston; and Sidney Green and Roberto Suarez- Bakersfield
Rivera, Salt Lake City, Utah, USA.
Micarta® is a trademark of Norplex-Micarta.
Plexiglas® is a registered trademark of ATOFINA.
TerraTek is a mark of Schlumberger.

Kern River Field Production History


160,000

140,000

120,000
Oil production, bbl/d

100,000

80,000

60,000

40,000

20,000
Steam stimulation
0
1900 1910 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010
Year
> Kern River field, operated by Chevron near Bakersfield, California, USA.
Production of heavy oil at Kern River field peaked within its first 10 years of
operation and went into a 50-year decline. A program of thermal EOR by
cyclic steam injection, accompanied by intensive infill drilling, rejuvenated
the field in the 1960s, with high production levels continuing today.

20 Oilfield Review
Autumn 2012 21
sandstones, shales and carbonates from many
petroleum reservoirs. The measurements have
revealed important new results about the hetero-
geneity and anisotropy of thermal rock proper-
Ukhta
ties. Investigators are also finding intriguing
Yarega field correlations between thermal and other petro-
physical properties.
0 km 200 Research on cores from Russian oil fields
0 mi 200 revealed surprising variability in reservoir ther-
mal properties over spatial scales ranging from
centimeters to tens of meters. Reservoir simula-
tions show why it is important for engineers to
understand this variability when they attempt to
Komi predict the outcome of thermal EOR. In the cases
Republic Timan-Pechora simulated, incorrect values caused estimates of
basin A
I
S key metrics for thermal stimulation to vary by up
S
U
R to 40% after just 10 years of production.

Yarega Oil Field


The Yarega heavy oil field in the Komi Republic,
Russia, illustrates the enormous potential of
thermal EOR. Discovered in 1932, and now oper-
ated by Lukoil, Yarega lies in a prolific oil prov-
ince west of the Ural Mountains called the
1,000 4,000 Timan-Pechora basin (left). The reservoir holds
large quantities of bitumen, a highly viscous,
semisolid hydrocarbon formed during the pro-
Steam injection, Mg × 10 3

750 3,000
Oil production, Mg × 10 3

Oil production cess of petroleum generation. Natural bitumen


occurs at depths shallower than 370 m [1,200 ft]
500 2,000 in many Russian oil fields, where it constitutes a
Thermal
mining
resource estimated at more than 16 billion m3
250 1,000
[100 billion bbl] of oil. The pay zone in Yarega is
Steam at depths between 180 and 200 m [590 and 660 ft]
injection
and is composed of fine-grained quartz sandstone
0 0 of Middle Devonian age, with a porosity of 20% to
1940 1950 1960 1970 1980 1990 2000
Year 25% and nearly 100% oil saturation.2
Production from the shallow reservoirs at
> Yarega oil field, operated by Lukoil near Ukhta in the Komi Republic, Russia. Primary production of oil
from bitumen in the shallow Yarega field started in the 1930s and peaked in the early 1950s. Production the Yarega field resembles a mining operation.
was declining rapidly around 1970, when new programs of thermal mining by steam injection were Operators have used several configurations to
introduced. heat the reservoir with steam and extract the lib-
erated fluids. In the most common scheme, devel-
oped in the 1970s and called the two-level, or
60% of world oil production attributed to methods often only loosely constrained, even though these two-horizon, system, steeply inclined steam
of enhanced oil recovery (EOR) comes from properties help determine project economics. injection wells, drilled from overlying chambers
thermal stimulation. For the future, heavy oil After a brief look at an unusual thermal recov- reached by conventional mine shafts, penetrate
deposits, tar sands, bitumen and oil shale— ery operation taking place in the Yarega heavy oil and heat the reservoir. Additional mine shafts
unconventional resources that represent Earth’s field in Russia, this article reviews the basic ther- lead to a second set of galleries near the bottom
largest store of liquid fuels—are now being mal properties of rocks and their measurement of the reservoir, from which gently sloping pro-
coaxed into releasing the oil they contain by by often time-consuming conventional tech- duction wells are drilled upward into the oil-
Oilfield Reviewniques. It also introduces a new measurement
highly evolved forms of thermal recovery. bearing layers.
1

This article examines an important, but often12 technique that employs optical sensors to rapidly
SUMMER The effect of thermal stimulation on produc-
overlooked, facet of thermal EOR—the Thermal
thermalProperties Fig.thermal
quantify 2 properties of rock. Since the tion from the Yarega field has been dramatic.
ORSUMflu-
behavior of reservoir rocks. Heating reservoir 12-THMPTS 2
1980s, scientists have scanned thousands of rock Before thermal mining began in the late 1960s,
ids means also heating large volumes of rock. samples with this optical method, including igne- production in conventional wells drilled from
And, while engineers designing a stimulation pro- ous and metamorphic rocks from deep scientific the surface recovered barely 4% of the original
gram usually know the thermal properties of the boreholes around the world and, more recently, oil in place. Thermal mining has raised the
fluids, thermal properties of formation rocks are

22 Oilfield Review
average recovery to 33% and in some zones, to After a steady state is reached, the sample’s bar method defines the standard for accuracy in
nearly 70%. Lukoil recently introduced new thermal conductivity is estimated by comparing measuring thermal conductivity, but is time-
forms of steam-assisted gravity drainage the temperature drop across its faces with the consuming. The measurement of a typical cylin-
(SAGD) at Yarega, which are expected to drop across those of reference materials of known drical sample, 3 to 5 cm [1.2 to 2.0 in.] in
increase annual production to 3.5 million met- conductivity flanking the sample. The divided diameter and 1 to 3 cm [0.4 to 1.2 in.] long, takes
ric tons (3,500,000 Mg) [25 million bbl] of oil in (continued on page 27)
the near future.3

Thermal Rock Properties Steel head plate


Engineers often use reservoir simulations to
Micarta
design thermal EOR programs and predict the
amount of additional oil attributed to thermal
stimulation and its production rate over time at Brass warm bath
various wells in the field. To accomplish this, sim-
ulators employ sophisticated algorithms to com-
Copper Micarta
pute the evolution of temperature and heat flow
within a reservoir after stimulation. These two Copper
Temperature
quantities—temperature and heat—are linked transducer Rock or cell Fused silica
by the thermal properties of rocks and their pore wells
Copper
fluids (see “Physics of Temperature and Heat,”
page 24). The most important of these properties Copper Micarta
are volumetric heat capacity, thermal conductiv-
Increasing temperature
ity and thermal diffusivity. Volumetric heat capac- Brass cold bath
ity specifies the amount of heat required to raise
the temperature of a unit volume of rock (and any
pore fluids within) by one degree. Thermal con- Rubber
ductivity determines where and how much heat Micarta
flows in response to temperature differences in
Steel
the reservoir. Thermal diffusivity determines
the speed at which a temperature front moves Steel Hydraulic ram
through the reservoir.4
50 mm
A fourth property, the coefficient of thermal
> Measuring rock thermal conductivity. The divided bar method is the
expansion, links the thermal and mechanical
standard laboratory technique for determining rock thermal conductivity. The
responses of reservoir rocks by determining the
method sandwiches a disk-shaped rock sample between brass plates—two
amount by which a volume of rock expands as its ends of a divided bar—held at different temperatures. The sample is flanked
temperature increases. Knowledge of this prop- by disks of a reference material of known thermal conductivity; fused silica,
erty is needed, for example, to assess changes in with a thermal conductivity of 1.38 W/m°K, is a commonly used reference.
After a steady state is reached, as indicated by steady temperatures in the
mechanical wellbore stability and in caprock transducer wells, the sample’s thermal conductivity is determined by
integrity caused by changing temperature condi- comparing the temperature drop across its length with the drop across the
tions in the reservoir. reference material. The hydraulic ram compresses samples for
In the enormous volume of petrophysical data measurements under high pressure. (Adapted from Popov et al,
reference 12.)
from geologic formations around the world, there
are relatively few measurements of thermal prop-
1. For more on Kern River and modern methods of thermal of the Former Soviet Union: Reserves and Prospects,
erties of reservoir rocks made in the laboratory or EOR: Curtis C, Kopper R, Decoster E, Guzmán-Garcia A, Extraction, Transportation. Amsterdam: Gordon and
in situ. As a result, engineers often calculate Huggins C, Knauer L, Minner M, Kupsch N, Marina Breach Publishers (1998): 69–184.
Linares L, Rough H and Waite M: “Heavy-Oil Reservoirs,” For a recent comprehensive review of enhanced recovery:
these thermal properties by using crude predic- Oilfield Review 14, no. 3 (Autumn 2002): 30–51. Alvarado V and Manrique E: “Enhanced Oil Recovery:
tive models, without reference to actual mea- Alboudwarej H, Felix J, Taylor S, Badry R, Bremner C, An Update Review,” Energies 3, no. 9 (2010): 1529–1575.
surements on core samples. This lack of thermal Brough B, Skeates C, Baker A, Palmer D, Pattison K, 2. Mamedov YG and Bokserman AA: “Development of
Beshry M, Krawchuk P, Brown G, Calvo R, Cañas Triana JA, Heavy Oils and Natural Bitumens in the Former Soviet
measurements represents a big gap in current Hathcock R, Koerner K, Hughes T, Kundu D, Oilfield
López de Review Union and Eastern and Central Europe: State-of-the-Art
Cárdenas J and West C: “Highlighting Heavy Oil,”
knowledge of reservoir rock properties. SUMMER 12 and Outlook,” Proceedings of the Sixth UNITAR
Oilfield Review 18, no. 2 (Summer 2006): 34–53. International Conference on Heavy Crude and Tar Sands,
One reason for the lack of data is that it is Thermal Properties
Allix P, Burnham A, Fowler T, Herron M, Kleinberg R
Fig. 4
Houston, February 12–17, 1995: 11–18.
difficult to measure thermal rock properties. and Symington B: “Coaxing Oil from Shale,”ORSUM 12-THMPTS 4
Chertenkov MV, Mulyak VV and Konoplev YP: “The
Oilfield Review 22, no. 4 (Winter 2010/2011): 4–15. Yarega Heavy Oil Field—History, Experience, and
The long-time standard for measuring thermal
Butler RM: Thermal Recovery of Oil and Bitumen. Future,” Journal of Petroleum Technology 64, no. 4
conductivity, the divided bar method, obtains Englewood Cliffs, New Jersey, USA: Prentice Hall, 1991. (April 2012): 153–160.
the property by placing a disk-shaped sample of For a comprehensive report on methods developed in the 3. Chertenkov et al, reference 2.
former Soviet Union: Bokserman AA, Filippov VP, 4. The three thermal properties are not independent;
material between two cylindrical metal bars Filanovskii VYu: “Oil Extraction,” in Krylov NA, thermal diffusivity is the ratio of thermal conductivity to
held at constant temperature (above right). Bokserman AA and Stavrovsky ER (eds): The Oil Industry volumetric heat capacity.

Autumn 2012 23
Physics of Temperature and Heat

Thermal properties connect temperature and Volumetric heat capacity, thermal conduc-
Heat Flow
heat flow, which are fundamental concepts tivity, thermal diffusivity and the coefficient of
in physics and classical thermodynamics. thermal expansion are the main thermal prop- q
Temperature is a measure of the average erties of interest for engineers. Volumetric 1m Heat flow
energy content of macroscopic bodies—solids, heat capacity (VHC) measures the amount of vector
liquids and gases—while heat flow represents heat needed to raise the temperature of a unit
the transfer of thermal energy between bodies volume (1 m3) of a substance by 1°K (below). θ
or regions at different temperatures. The original unit of heat, the Calorie, was
Temperature has its own basic SI unit, defined in 1824, by the French physicist and
1m
degrees kelvin (°K), with absolute zero (0°K) chemist Nicolas Clément, as the amount of
as the lowest possible temperature. In the heat needed to raise 1 kg of water by 1°C. The
commonly used Celsius scale (°C), the later discovery, by the English physicist and
freezing point of water is taken as 0°C, placing brewer James Prescott Joule, of the equivalence
absolute zero at −273.15°C. A difference of of heat and mechanical energy led to > Heat flow. Heat flow is a vector quantity, q,
one degree in either scale represents the replacement of the Calorie as a basic physical whose magnitude, at any point in a material,
same change in temperature. unit by the derived unit for mechanical or gives the amount of thermal energy flowing per
kinetic energy, kg m2/s2—now called the unit time across a surface of unit area oriented
perpendicular to the vector direction. If the
heat flow vector (red arrow) is oriented at an
angle, θ, to the surface, energy flow across the
surface is reduced by the cosine of the angle.

Volumetric Heat Capacity

joule (J). Clément’s Calorie, which is equiva-


26°C lent to about 4.2 kJ, survives today as the com-
mon unit for measuring the energy content of
food. Since 1 m3 of water weighs 1,000 kg,
Bitumen Sandstone Water the volumetric heat capacity of water is about
1m 1m 4.2 MJ/m3°K. The volumetric heat capacity
of rocks is generally lower, in the range
25°C 1 to 4 MJ/m3°K (next page, bottom left).
1m

Temperature differences drive the flow of


thermal energy—the flow of heat (above).
Like the flow of fluid or electrical current,
heat flow has both magnitude and direction
1.7 MJ and is therefore represented as a vector
2.7 MJ
quantity. The magnitude of the heat flow
4.2 MJ Oilfield Review
vector gives the amount
SUMMER 12 of thermal energy per
second crossing a surface
Thermal Propertiesof unit
Fig.area
3B oriented
> Volumetric heat capacity. Volumetric heat capacity is the amount of thermal
energy in the form of heat needed to raise the temperature of a unit volume of ORSUM 12-THMPTS 3B vector.
perpendicular to the direction of the
material—1 m3 in SI units—by 1°K, starting from a given temperature T0. The units of heat flow are thus energy per unit
There can be no change of phase, such as melting, during the temperature time per unit area, or power per unit area and
rise. The volumetric heat capacity of dry sandstone typically falls between are conventionally taken as watt per square
that of bitumen and water.
meter (W/m2).

24 Oilfield Review
Thermal conductivity provides the quanti- proportional to the temperature difference
tative connection between heat flow and divided by the distance between the faces. Thermal Conductivity
temperature differences (right). It can be The constant of proportionality is the ther- T
defined by considering a cube of homoge- mal conductivity, which thus has units of
neous material with a temperature differ- W/m°K. The thermal conductivity of water is ∆z q
ence between two opposite faces. The about 0.6 W/m°K. The thermal conductivity
amount of heat flowing through the cube, of rocks is generally higher, in a range from T + ∆T
from the high- to low-temperature faces, is about 0.5 to 6.5 W/m°K. ∆T
q = –k
∆z

Anisotropic Thermal Conductivity

T +∆T T
∆x
Volumetric Heat Thermal Conductivity, T
Capacity, MJ/m 3 °K W/m°K
5 1,000
∆z qz
qx
Silver
Copper T + ∆T
q z = –k ∆T q x = – k ∆T
Gold
Aluminum ∆z ∆x
Water at 100°C
Water at 25°C > Thermal conductivity. Thermal conductivity
4 100
Limestone Nickel relates temperature gradients and heat flow. A
block of material with a temperature difference
Human
Steel ΔT across two opposing faces separated by a
tissue
Lead distance Δz sustains a heat flow whose
Copper magnitude is proportional to the temperature
difference divided by the distance (top). The
Stainless steel
Ammonia proportionality constant is the block’s thermal
conductivity k. Many materials display
3 10 anisotropic thermal conductivity, in which
Sandstone
temperature differences placed across
Shale, siltstone different pairs of opposing faces of a cube
result in different magnitudes of heat flow
Gold (bottom). Thermal anisotropy is common in
finely layered materials, such as rocks, where
Paraffin the thermal conductivity parallel to layers (k ||)
is up to 50% higher than thermal conductivity
Carbon
2 Ethanol 1.0 Glass perpendicular to layers (k⊥).
Bitumen
Shale, siltstone Water

Limestone
Petroleum
Lead
Methanol
Some materials, including rocks, exhibit
Bitumen Oilfield Review
Motor oil, grade SAE 50 macroscopic thermal12
SUMMER anisotropy; for example,
1 0.1
Sandstone Thermal Properties
different numerical values for Fig. 3C con-
thermal
ORSUM
ductivity result 12-THMPTS
from measurements3C across
different pairs of opposing faces on a cube of
the material. The simplest type of thermal
Air anisotropy, common in rocks, arises when the
Carbon dioxide material has a layered structure at fine scales.
0 Air, dry at sea level 0.01 The thermal conductivity in the direction per-
pendicular to the layering is generally lower
than the conductivity in any direction parallel
> Thermal properties of common materials. to the layering.

Autumn 2012 25
Volumetric heat capacity and thermal
Thermal Diffusivity conductivity combine to determine a third
q out q out thermal property, called thermal diffusivity
(left). Imagine a cube of uniform material
with more heat flowing in through the bot-
tom face than is flowing out through the top
face. The difference in the two flows is the
T T + ∆T
rate at which heat is being added to the
cube, which will cause its temperature to
rise. Since the rate of heat flow is deter-
mined by the material’s thermal conductivity
and the temperature increase by its volumet-
q in q in
ric heat capacity, the rate of temperature
increase is obtained by dividing the thermal
conductivity by the volumetric heat capacity.
Time 0 Time 0 + 1 s
This ratio, called thermal diffusivity, governs
the speed at which temperature changes
propagate through a material.
Temperature is not the only property that
> Thermal diffusivity. Thermal diffusivity controls the rate at which changes when a cube of material is heated:
temperature rises in a uniform block of material when more heat is flowing
Most substances also expand. The rate of
into the block than flowing out. If an initial temperature gradient is established
between the block and its surroundings, the heat fluxes in and out are linear expansion—defined as the fractional
determined by the block’s thermal conductivity, while the temperature rise increase in length of a cube’s sides per unit
caused by the heat imbalance is determined by the block’s volumetric heat temperature rise—is called the coefficient
capacity. Thermal diffusivity is thus the ratio of thermal conductivity to
volumetric heat capacity.
of linear thermal expansion (below left).
The thermal expansion of reservoir rocks
provides an important link between the ther-
mal and mechanical responses of the reser-
voir during thermal EOR.
Thermal conductivity, heat capacity,
Thermal Expansion
thermal diffusivity and the coefficient of
Block of material Block of material thermal expansion are properties that apply
at temperature T0 at temperature T0 + 1°K to macroscopic chunks of matter. The con-
x 1m cepts break down when applied to individual
1m 1m 1m+∆ + ∆y
atoms or molecules of a substance. Like all
macroscopic properties—including petro-
physical properties such as porosity, permea-
1 m + ∆z
1m

bility and electrical conductivity—thermal


properties may vary from point to point in a
rock formation and depend on its tempera-
ture and pressure.

Oilfield Review
SUMMER 12
Thermal Properties Fig. 3D
ORSUM 12-THMPTS
> Thermal expansion. The coefficient 3D
of thermal expansion measures a
fractional change in linear dimension of a uniform cube for a unit temperature
rise. Each side of the cube may expand by a different amount in anisotropic
materials.

26 Oilfield Review
about 10 to 15 minutes. In addition, laboratory
Drainage
technicians must spend an hour or two cutting, channel
trimming and polishing the disk to ensure good
thermal contact with the heating bars. This last
step is difficult to complete with fractured or Plunger system
for pressure control
poorly consolidated reservoir rocks.5
Alternatives to the steady state method are Pressure- Unconsolidated
transient methods in which a scientist applies a resistant rock sample
steel cell
pulse of heat to the sample, usually with a needle-
Needle probe for
shaped probe, and records the temperature thermal property
response at one or more locations on the sample measurements
(right). Thermal conductivity or diffusivity is
then calculated from a theoretical model that
predicts how the material should respond in the
given configuration. One configuration of this
transient line source method, which is useful for Connection wires
measuring loose samples such as unconsolidated
sediments and soils, applies the pulse of heat
Minimum Sample
along a thin wire that carries a temperature sen-

Thermal conductivity
sor at its midpoint. This wire is inserted, like a
Maximum
hypodermic needle, into the material and mea-
sures the temperature as a function of time. In
another configuration, a scientist places the Minimum
needle-shaped probe with its sensor on the flat
top of a cylindrical core and records this surface’s 0 30 60 90 120 150 180
Maximum
temperature response to a pulse of heat.6 Azimuth, degree
Because thermal conductivity relates two
Connection
directional quantities, the temperature gradient wires Maximum

Thermal conductivity
and the heat flow vector, its value may depend on
the direction of measurement, for example, on Sample
the direction of the temperature gradient
imposed on a sample. The line source method Minimum
provides a convenient way of characterizing
directional dependence: Any variation of the
90 120 150 180 210 240 270
temperature response as the needle is rotated Azimuth, degree
Minimum Maximum
through various directions on the surface of the
> Measuring thermal conductivity of unconsolidated or anisotropic materials. The line source method
core indicates that its thermal conductivity is
determines thermal conductivity by placing a thin probe with a heating element and temperature
anisotropic—heat flows preferentially in certain sensor in contact with a sample. A theoretical model predicting the temperature response to a pulse of
directions through the rock. heating is used to calculate the sample’s thermal conductivity. For unconsolidated samples, the probe
The most common form of anisotropy in is inserted, like a hypodermic needle, inside the material (top). For solid rocks, the probe is attached to
the bottom of a Plexiglas block placed on the surface of the sample. For laminated samples cut at an
crustal rocks is the result of features such as thin
angle to the measurement surface, the response of the probe changes as it rotates through various
layers or oriented fractures that determine the directions (bottom). Variations in response with angle may be used to determine the thermal anisotropy
directional characteristics of a rock’s bulk physi- of layered rocks.
cal properties. The simplest example is fine layer-
ing or bedding, which is present in nearly all
clastic reservoir and source rocks—sandstones 5. Beck A: “A Steady State Method for the Rapid Von Herzen R and Maxwell AE: “The Measurement of
and shales—and distinguishes the direction per- Measurement of the Thermal Conductivity of Rocks,” Thermal Conductivity of Deep-Sea Sediments by a
Journal of Scientific Instruments 34, no. 5 (May 1957): Needle-Probe Method,” Journal of Geophysical
pendicular to the layers from the directions par- 186–189. Oilfield Review Research 64, no. 10 (October 1959): 1557–1563.
allel to the layers. This type of anisotropy induced Pribnow DFC and Sass JH: “Determination ofSUMMER Thermal 12 Waite WF, Gilbert LY, Winters WJ and Mason DH:
Conductivity for Deep Boreholes,” Journal of Geophysical “Estimating Thermal Diffusivity and Specific Heat from
by layering—also called transverse isotropy, Thermal Properties
Research 100, no. B6 (June 10, 1995): 9981–9994. Fig.Probe
Needle 5 Thermal Conductivity Data,” Review of
axial anisotropy or cross anisotropy—may be Beck AE: “Methods for Determining ThermalORSUM 12-THMPTS
Conductivity 5 Instruments 77, no. 4 (April 2006): 1–5.
Scientific
present in sedimentary and igneous rocks perme- and Thermal Diffusivity,” in Haenel R, Rybach L and Woodside W and Messmer JH: “Thermal Conductivity of
Stegena L (eds): Handbook on Terrestrial Heat Flow Porous Media. I. Unconsolidated Sands,” Journal of
ated by thin oriented fractures, and in metamor- Density Determination. Dordrecht, the Netherlands: Applied Physics 32, no. 9 (September 1961): 1688–1699.
phic rocks that have been compressed strongly in Kluwer (1988): 87–124. Woodside W and Messmer JH: “Thermal Conductivity of
6. Jaeger JC: “The Measurement of Thermal Conductivity Porous Media. II. Consolidated Rocks,” Journal of
with Cylindrical Probes,” EOS Transactions American Applied Physics 32, no. 9 (September 1961): 1699–1706.
Geophysical Union 39, no. 4 (1958): 708–710.

Autumn 2012 27
one direction and, as a result, have acquired a anisotropy, which is critical to the proper evalua- tectonics revolution of the 1960s and 1970s,
distinctive planar fabric.7 tion of laminated reservoirs.8 when scientists recognized that the Earth’s
In finely layered rocks, the value of thermal internal heat and its flow to the surface were
conductivity in the direction perpendicular to Measuring Thermal Properties by driving forces of global tectonics. Much of the
the layers—and therefore the heat flow for a Optical Scanning latter research was devoted to mapping heat flow
given temperature drop—is usually 5% to 30% Most of the fundamental science of rock thermal through ocean basins, which shows the thermal
lower than its value in directions parallel to the properties was carried out in two waves. The first signature of convection patterns in the Earth’s
layers; in some rocks, the difference is as high as took place in the 1930s, when scientists began to deep interior (below).9 Scientists study thermal
50%. The physics and mathematics of thermal unravel the thermal structure of Earth’s interior; rock properties as a necessary component for
anisotropy are similar to those of electrical the second occurred during the years of the plate heat flow determination and to understand the

Shallow Geothermal Gradients


Temperature, °C
Cross Section of Ocean Ridge
0 50 100 150 200 250
0

Battle Mountain, Nevada


1
Basin and Range province erican
East of Rocky Mountains North Am Eurasian
Plate Plate
2
Depth, km

Sierra Nevada Mountains

5
0 10 20 30 40 50 60 70 80 90 100 110 120
Surface heat flow, mW/m2

Surface Heat Flow

Heat flow, mW/m2


23 to 45 45 to 55 55 to 65 65 to 75 75 to 85 85 to 95 95 to 150 150 to 450

> Earth’s surface heat flow. Flow of heat from the Earth’s deep interior to the surface is a driving force of global tectonics. A map of surface heat flow
highlights ocean ridges, where magma derived from partial melting of the upper mantle rises to the surface to create new oceanic crust (bottom, adapted
from Davies and Davies, reference 9). To produce this map, Davies and Davies compiled nearly 40,000 measurements, from which correlations of heat flow
with geologic regions were derived to extend the discrete measurements using a digital map of global geology. At ocean ridges (top right), heat flow is
dominated by convection—the movement of hot material (white arrows) from depth to the surface. Over the continents, average heat flow is determined by
the geothermal gradient—the variation of temperature with depth—and the thermal conductivity of crustal rocks. The graph shows geothermal gradients in
the shallow crust for several regions of the US (top left). Each geothermal gradient corresponds to a different value of surface heat flow.

Oilfield Review
28 SUMMER 12 Oilfield Review
Thermal Properties Fig. 6
ORSUM 12-THMPTS 6
potential of geothermal energy. Beginning in the n
ctio
g dire
1980s, researchers looked at thermal properties nnin
Sca Infrared
of sedimentary rocks to provide input to model 1 sensor
the thermal history of basins in early quantita- Optical
Infrared heat
tive attempts at petroleum system modeling.10 sensors source
2 3
These lines of research converged in a study of
thermal and other petrophysical measurements
on rocks from deep scientific boreholes, including
the 12,262-m [40,230-ft] Kola Superdeep Borehole
Temperature
n line
profiles Sca
in the Soviet Union, the deepest hole ever drilled.
The work was driven by the recognition that
thermal properties measured along the track of
long scientific boreholes were much more hetero-
geneous than previously imagined. Scientists
realized that new methods were needed to char-
Scan lines
acterize the thermal properties of rocks, includ- p le
ing better methods of measuring these properties Sam
in situ, as well as laboratory methods that worked
more rapidly and at higher resolution on smaller
core samples.11
In the 1990s, scientists from Russia, Germany
and the US participated in a joint study of major
laboratory methods for measuring thermal con-
ductivity, focusing on cores from the superdeep
KTB borehole in Germany.12 One method in this
study used an optical device developed in the
early 1980s in the former Soviet Union. Unlike > Principle of the optical scanning method. Optical scanning provides a fast, contactless method of
prior techniques for measuring thermal proper- measuring thermal properties (top right). This method determines thermal conductivity and thermal
diffusivity by heating a spot on the sample with a moving optical heat source—a laser or focused
ties, the optical method is contactless—no sen-
electric light (top left). Three infrared sensors, moving in tandem with the source, measure temperature
sor touches the material; instead, the device uses at the surface of the sample. Sensor 1 is situated ahead of the heat source along the scan line
remote optical thermal sensors to scan the sam- to register surface temperature before the sample is heated. Two trailing sensors register the
ple surface for the thermal signature of a con- temperature rise induced by the heating: Sensor 2 measures along the scan line, and Sensor 3, along
a parallel line (dashed black). A theoretical model predicting the temperature at these two locations as
stant, focused heat source (right). The source a function of time is used to calculate the thermal conductivity and thermal diffusivity at various
and sensors move together along the sample—a locations under the scan line. By scanning the sample in three different directions, the method can
core, for example—in a fixed arrangement that determine anisotropic thermal properties of laminated rocks (bottom right).

7. Transverse isotropy, axial anisotropy and cross Krige LJ: “Borehole Temperatures in the Transvaal and McKenna TE, Sharp JM Jr and Lynch FL: “Thermal
anisotropy are synonymous terms referring to the Orange Free State,” Proceedings of the Royal Society of Conductivity of Wilcox and Frio Sandstones in South
particular directional character of materials in which London A 173, no. 955 (December 29, 1939): 450–474. Texas (Gulf of Mexico Basin),” AAPG Bulletin 80, no. 8
properties have the same values in all directions parallel Bullard EC: “Heat Flow in South Africa,” Proceedings of (August 1996): 1203–1215.
to planes of isotropy and different values perpendicular the Royal Society of London A 173, no. 955 (December For more on petroleum system modeling: Al-Hajeri MM,
to or crossing the planes of isotropy; this perpendicular 29, 1939): 474–502. Al Saeed M, Derks J, Fuchs T, Hantschel T, Kauerauf A,
direction is the axis of cylindrical symmetry. Neumaier M, Schenk O, Swientek O, Tessen N,
Birch AF and Clark H: “The Thermal Conductivity of
8. Thin oil-bearing layers in laminated reservoirs significantly Rocks and Its Dependence on TemperatureOilfieldand Welte D, Wygrala B, Kornpihl D and Peters K: “Basin
increase the resistance to current flow, but only in the Composition, Part I,” American Journal of Science 238,
Review and Petroleum System Modeling,” Oilfield Review 21,
direction perpendicular to the beds. A resistivity logging no. 8 (August 1940): 529–558. SUMMER 12 no. 2 (Summer 2009): 14–29.
tool that measures resistance in directions parallel to the
Birch AF and Clark H: “The Thermal ConductivityThermalof Properties Fig.
11. Orlov VP 7and Laverov NP (eds): Kola Superdeep Well:
beds generally will not detect the presence of oil. For
Rocks and Its Dependence on TemperatureORSUM and 12-THMPTS 7 Results and Research Experience. Moscow:
Scientific
more on the anisotropy of finely layered formations: Technoneftegaz, 1998 (in Russian).
Composition, Part II,” American Journal of Science 238,
Anderson B, Barber T, Leveridge R, Bastia R, Saxena KR,
no. 9 (September 1940): 613–635. Burkhardt H, Honarmand H and Pribnow D: “Test
Tyagi AK, Clavaud J-B, Coffin B, Das M, Hayden R,
Many researchers contributed to mapping surface heat Measurements with a New Thermal Conductivity
Klimentos T, Minh CC and Williams S: “Triaxial
flow over the globe and unraveling its relation to plate Borehole Tool,” Tectonophysics 244, nos. 1–3 (April 15,
Induction—A New Angle for an Old Measurement,”
tectonics. For more: Sclater JG and Francheteau J: 1995): 161–165.
Oilfield Review 20, no. 2 (Summer 2008): 64–84.
“The Implications of Terrestrial Heat Flow Observations 12. Popov YA, Pribnow DFC, Sass JH, Williams CF and
9. The earliest systematic studies of Earth’s surface heat
on Current Tectonic and Geochemical Models of the Burkhardt H: “Characterization of Rock Thermal
flow were a series of papers in the late 1930s:
Crust and Upper Mantle of the Earth,” Geophysical Conductivity by High-Resolution Optical Scanning,”
Anderson EM: “The Loss of Heat by Conduction from
Journal of the Royal Astronomical Society 20, no. 5 Geothermics 28, no. 2 (April 1999): 253–276.
Earth’s Crust,” Proceedings of the Royal Society of
(September 1970): 509–542. KTB is the Kontinentales Tiefbohrprogramm der
Edinburgh 60, part 2. Edinburgh, Scotland: Robert Gran
and Son, Ltd. (1939–1940): 192–209. The most recently published compilation of surface heat Bundesrepublik Deutschland, or German Continental
flow data: Davies JH and Davies DR: “Earth’s Surface Deep Drilling Program. For more on the KTB borehole:
Benfield AE: “Terrestrial Heat Flow in Great Britain,”
Heat Flux,” Solid Earth 1, no. 1 (February 22, 2010): 5–24. Bram K, Draxler J, Hirschmann G, Zoth G, Hiron S and
Proceedings of the Royal Society of London A 173,
10. Brigaud F, Chapman DS and Le Douaran S: “Estimating Kühr M: “The KTB Borehole—Germany’s Superdeep
no. 955 (December 29, 1939): 428–450.
Thermal Conductivity in Sedimentary Basins Using Telescope into the Earth’s Crust,” Oilfield Review 7, no. 1
Lithologic Data and Geophysical Well Logs,” (January 1995): 4–22.
AAPG Bulletin 74, no. 9 (September 1990): 1459–1477.

Autumn 2012 29
allows the first sensor to register the ambient recorded temperature profiles. According to a sured temperature rise, source-to-sensor distances
surface temperature under laboratory condi- model for the arrangement with two thermal sen- and source power. Alternatively, thermal conduc-
tions. After a spot on the surface has been heated sors flanking the heat source, the maximum tem- tivity can be determined by comparing the tem-
by the source—either a laser or a focused elec- perature rise seen by the trailing sensor is directly perature rise in the sample with that in a standard
tric light—one or two trailing sensors record the proportional to the source power, in watts, and material of known conductivity placed next to it in
rise in temperature along lines parallel to the inversely proportional to the product of the source- the scan line. Another common configuration adds
trace of the heated spot.13 sensor separation and the sample’s thermal con- a second trailing sensor offset from the main scan
Optical scanning uses tailored theoretical ductivity. This model can be inverted for the line and uses two different standards flanking the
models to determine thermal properties from the unknown thermal conductivity, given the mea- sample to determine both thermal diffusivity and
thermal conductivity. Aligning the axis of the scan
along various directions through the rock allows
Hamburg characterization of the thermal conductivity of an
anisotropic sample; full characterization requires
Berlin
scans along three distinct directions lying in two
G E R M A N Y
nonparallel planes.
Nearly all of the core samples from the KTB
borehole were crystalline metamorphic rocks,
KTB wellsite Prague
chiefly amphibolites and gneisses, possessing a dis-
CZECH REPUBLIC tinctive foliation and requiring measurement of
Nuremberg
thermal conductivity parallel and perpendicular to
5
their planar fabric.14 The joint international study of
5
cores from the KTB borehole demonstrated that
Thermal conductivity by divided bar, W/m°K
Thermal conductivity by divided bar, W/m°K

measurements of thermal properties by optical


4 4 scanning compare well in precision, or repeatabil-
ity, and in accuracy with measurements made by the
divided bar and line source methods (left). The
3 3 divided bar measurements were conducted with a
device maintained and continually improved since
the late 1960s by the US Geological Survey; the line
2 2 source measurements were conducted with a unit
specially constructed at the Technische Universität
Collection 2 Collection 1 Berlin to work on cores from deep scientific wells.
1 1 Differences between optical scanning and divided
1 2 3 4 5 1 2 3 4 5
Thermal conductivity by optical scanning, W/m°K Thermal conductivity by line source, W/m°K
bar measurements averaged 2.1%, with a standard
deviation of 6.5%; the closest agreement was for
5 5
measurements in directions parallel to rock folia-
Thermal conductivity by optical scanning, W/m°K
Thermal conductivity by divided bar, W/m°K

tion. Differences between optical scanning and line


4 4
source measurements were generally less than 5%.15
The accuracy and reliability of thermal properties
measured by optical scanning have since been con-
3 3
firmed on thousands of core samples. Many of these
cores come from deep scientific wells drilled into
large impact structures such as the Puchezh-Katunki
2 2
impact structure in Russia, the Ries impact structure
in Germany, the Chesapeake crater in the US and the
Collection 1 Collection 1 Chicxulub crater in Mexico.16 This work established
1 1 that optical scanning measurements can be accurate
1 2 3 4 5 1 2 3 4 5
to within 1.5% for thermal conductivity within the
Thermal conductivity by optical scanning, W/m°K Thermal conductivity by line source, W/m°K
range 0.1 to 50 W/m°K and to within 2% for thermal
> Thermal properties of rock samples from the superdeep KTB borehole. A study of core samples from diffusivity in the range 0.1 × 10–6 to 5 × 10–6 m2/s. The
the KTB borehole in Germany (top) demonstrated that measurements of thermal conductivity by optical remote sensing and nondestructive nature of optical
scanning compare well with measurements made by the divided bar and line source methods. The
crossplot at upper left, for example, shows good agreement between optical scanning measurements scanning allows easy, repeated testing of samples
of thermal conductivity and divided bar measurements on 36 different samples cut from the KTB cores. of a variety of sizes; the laboratory instrument used
Scientists prepared this collection so that the same physical rock sample could be used in both in the scientific studies characterizes samples from
instruments. The remaining crossplots compare one method against another when two different rock 1 to 70 cm [0.4 to 28 in.] long.
samples are cut from the same core. Open diamonds represent measurements in the direction parallel
to the rock foliation; solid diamonds represent measurements perpendicular to the foliation. (Adapted Optical scanning measurements are also rela-
from Popov et al, reference 12.) tively immune to the shape and quality of the sample
Oilfield Review
SUMMER 12
Thermal Properties Fig. 8
30 ORSUM 12-THMPTS 8 Oilfield Review
surface, tolerating up to 1 mm [0.04 in.] of roughness
with little loss of accuracy. The scan speed is routinely
set between 1 and 10 mm [0.04 and 0.4 in.] per sec-
ond, which usually allows a throughput of about one
sample per minute. Slower speeds and a smaller dis-
tance between the heating spot and temperature sen-
sor enlarge the measurement’s depth of investigation,
which can be up to 3 cm in samples with moderate to
high thermal conductivity.
A new instrument developed at Schlumberger
Moscow Research Center and engineered at the
Schlumberger Innovation Center in Salt Lake City,
Utah, USA, has further refined the specifications
for rapid, high-resolution optical measurement of
thermal properties (right). This instrument for
rock profiling, housed at TerraTek Rock Mechanics Parameter Value
and Core Analysis Services laboratory, can detect Thermal conductivity range 0.2 to 6.0 W/m°K
heterogeneity in thermal conductivity and thermal Thermal diffusivity range (0.1 to 2.5) × 10–6 m 2/s
diffusivity—or volumetric heat capacity, as calcu- Accuracy of thermal conductivity 4%
lated from these two quantities—with a resolution Accuracy of thermal diffusivity 5%
better than 0.4 mm [0.016 in.] at a core scanning Spatial resolution in rock profiling Better than 0.4 mm
velocity of 3.0 mm/s [0.12 in./s] (below right).17
Scanning velocity 3.0 mm/s
13. Popov Yu A: “Theoretical Models for Determination of
the Thermal Properties of Rocks on the Basis of Movable
> High-resolution optical scanner at the Schlumberger Innovation Center in
Sources of Thermal Energy, Part I,” Geologiya i Razvedka Salt Lake City, Utah.
(Geology and Prospecting) no. 9 (September 1983): 97–105
(in Russian).
Popov Yu A: “Theoretical Models for Determination
of the Thermal Properties of Rocks on the Basis of
Movable Sources of Thermal Energy, Part II,” Geologiya i
Razvedka (Geology and Prospecting) no. 2 Maximum
(February 1984): 81–88 (in Russian). 7.0
Popov Yu A: “Peculiarities of the Method of Detailed
Investigations of Rock Thermal Properties,” Geologiya i
Razvedka (Geology and Prospecting) no. 4 (April 1984):
76–84 (in Russian). 6.5
14. Foliation is the layered fabric—the orientation,
arrangement and texture of minerals, grains and other Average
Excess temperature, °C

constituents in rock—of metamorphic rocks that have


been strongly compressed in one direction. 6.0
15. Popov et al, reference 12.
16. Popov Yu, Pohl J, Romushkevich R, Tertychnyi V and
Soffel H: “Geothermal Characteristics of the Ries Impact
5.5
Structure,” Geophysical Journal International 154, no. 2
(August 2003): 355–378. Oilfield Review
Popov Yu, Romushkevich R, Korobkov D, Mayr S, SUMMER 12
Bayuk I, Burkhardt H and Wilhelm H: “Thermal Thermal Properties Fig. 9
5.0
Properties of Rocks of the Borehole Yaxcopoil-1 (Impact
Crater Chicxulub, Mexico),” Geophysical Journal ORSUM 12-THMPTS 9
International 184, no. 2 (February 2011): 729–745.
Mayr SI, Burkhardt H, Popov Y, Romushkevich R,
4.5
Miklashevskiy D, Gorobtsov D, Heidinger P and Minimum
Wilhelm H: “Physical Rock Properties of the Eyreville
Core, Chesapeake Bay Impact Structure,” in Gohn GS,
Koeberl C, Miller KG and Reimold WU (eds): The
ICDP-USGS Deep Drilling Project in the Chesapeake Bay
0 50 100 150 200 250 300
Impact Structure: Results from the Eyreville Core Holes.
Boulder, Colorado, USA: The Geological Society of Scan line Displacement, mm
America, Special Paper 458 (2009): 137–163.
The Chicxulub crater is believed to be an imprint
of the catastrophic asteroid impact that ended the
age of dinosaurs. For more: Barton R, Bird K,
Garcia Hernández J, Grajales-Nishimura JM,
Murillo-Muñetón G, Herber B, Weimer P, Koeberl C,
Neumaier M, Schenk O and Stark J: “High-Impact
Reservoirs,” Oilfield Review 21, no. 4 (Winter 2009/2010):
14–29.
>Resolution and repeatability of optical scanning. Two optical scans (red and blue, top) of a gravelly
17. Popov Yu, Parshin A, Chekhonin E, Gorobtsov D,
Miklashevskiy D, Korobkov D, Suarez-Rivera R and sandstone core illustrate the strong heterogeneity of thermal properties in rocks and the repeatability
Green S: “Rock Heterogeneity from Thermal Profiles of optical measurements. Excess surface temperature—the temperature rise measured along a scan
Using an Optical Scanning Technique,” paper ARMA line (yellow, bottom) after heating by the laser—is proportional to thermal conductivity. The difference
12-509, presented at the 46th US Rock Mechanics/ between the maximum and the minimum, divided by the average, gives a measure of property
Geomechanics Symposium, Chicago, June 24–27, 2012.
heterogeneity.

Autumn 2012 31
Thermal Properties of Reservoir Rocks:
A Growing Database
Because scientists are now better able to mea-
sure thermal properties, new avenues of petro-
physics are opening up. Like many rock
properties, thermal conductivity depends in com-
plex ways on the composition and distribution of
minerals in the rock matrix and fluids in its pore
space. Studies going back to the 1950s have pro-
vided data on this dependence, but until recently
Okhotsk such studies were limited by measurement tech-
Timan- Yeniseisk-Anabar
Pechora basin niques that were unable to resolve layers and
basin fractures at scales finer than a few centimeters.
Tungus
Moreover, conventional techniques cannot deter-
Middle Ob’
I A mine thermal conductivity and diffusivity simul-
Northern S
Volga-Urals U S taneously and have difficulty characterizing
Southern R
unconsolidated rocks and core samples and plugs
Volga-Urals
saturated with brine, oil or gas.18
Optical scanning avoids nearly all of the
obstacles hindering accurate, routine determina-
tion of thermal rock properties. This method
enabled a large petrophysical study of more than
8,000 samples, including sedimentary rocks of
various lithologies, ages and geologic settings
from eight geologic regions, to uncover new con-
nections between thermal rock properties and
the usual staples of petrophysical reservoir evalu-
> Core samples from Russian oil provinces. Scientists have compared thermal conductivity measured ation: porosity, permeability, electrical conduc-
by high-resolution optical scanning with other petrophysical properties on more than 8,000 core samples tivity, acoustic velocity and fluid saturation.19
of sedimentary rocks from various petroleum provinces in Russia. The collection was supplemented by
samples from deep scientific boreholes and oil fields in Germany, Mexico and the US. Most of the cores in this study came from
basins in petroleum provinces of the former
Soviet Union (above left). Scientists measured
the thermal conductivity of all samples under
Samples from Northern and Southern Volga-Urals Provinces
50
both dry and fluid-saturated conditions, and the
high-resolution scans revealed several key fea-
40 Dry tures of this diverse collection.
Heterogeneity factor, %

Scientists first discovered a wide variation of


30 thermal properties within individual dry samples.
A simple measure of heterogeneity within a sam-
20 ple is the difference between the maximum and
minimum thermal conductivity measured along a
10 scan line, divided by the average conductivity
Water along the same line. This heterogeneity factor,
saturated
0 expressed as a percentage, characterizes the
0 5 10 15 20 25 30 35 40 45 50
range of conductivity in the sample as seen by
Sample numbers
optical scanning. Measured on dry samples, the
> Heterogeneity of thermal conductivity and porosity. Heterogeneity of rock
factor varied from about 4% to 50% for rocks in
thermal properties is closely related to variations in porosity. In this plot,
Oilfield Review
50 clay-rich limestone samples, studied under dry and water-saturated the collection (left).
conditions, are arranged inSUMMER 12
order of increasing heterogeneity as measured Second, and more interesting, was that the
Thermal
under dry conditions (blue). Properties
Heterogeneity Fig. 11 as the difference
is quantified heterogeneity factor went no higher than about
between the maximum and ORSUM
minimum 12-THMPTS 11
thermal conductivities measured along 15% when measured on samples saturated with
a scan line, divided by the average value along the line. When this
heterogeneity factor of a dry sample is less than about 15%, it changes by water. This result could be explained by higher
only a few percent when the sample is saturated with water and scanned values of porosity in samples whose heterogene-
again (red). When the heterogeneity factor of a dry sample is greater than ity factor, when dry, was above about 15%. Void
15%, it generally changes dramatically after water saturation. Scientists
space, or air, has essentially zero thermal con-
traced this effect to large spatial variations of porosity in samples with dry
heterogeneity factors above 15%. (Adapted from Popov et al, reference 12.) ductivity, in contrast to most solid rock, and is
distributed in a complex way at scales below the

32 Oilfield Review
resolution of the optical scans—about 1 mm. Middle Ob’ Province
When its low thermal conductivity is averaged 1.45 2.0

with that of the rock matrix, void space has large 1.5
1.25
effects on the result because an optical scan
1.0
senses low and high values of conductivity

Logarithm of permeability
depending on whether the heated spot contains 1.05
0.5
more or less pore space. In contrast, when pore
space is saturated with water, whose thermal 0.85 δk 0

δk
Permeability measured
conductivity is relatively close to that of solid parallel to bedding –0.5
rock, its effect on the average thermal conductiv- 0.65

ity is much less significant. –1.0


Scientists have known for some time that 0.45
–1.5
changes in thermal properties are caused by the Increasing thermal anisotropy
opening of microscopic cracks and fissures in 0.25 –2.0
0 10 20 30 40 50 60
rock samples brought from high pressure deep Sample numbers
underground to atmospheric pressure at the sur- δk
face.20 But high-resolution optical scans con- 1.0 1.2 1.4 1.6 1.8 2.0 2.2
X00
firmed the importance, for thermal properties, of
Fine-grained massive polymictic sandstone
even small variations in natural porosity in sedi-
mentary rocks. The threshold of 15% to 20% in the Massive and bedded polymictic sandstone
heterogeneity factor is significant: When varia-
tions along a scan line remain below this level on Bedded polymictic arkosic siltstone

dry samples, saturating the rock with water does X40


Intercalated sandstone and siltstone
not change the measured range of scanned con-
ductivity values. In such rocks, heterogeneity Fine-grained bedded mica-quartz sandstone
along a scan line arises directly from variations in

Depth, m
composition or mineralogy of the rock matrix. Fine-grained massive mica-quartz sandstone
Optical scans have also revealed that anisot- Medium- and coarse-grained bedded
polymictic sandstone X80
ropy may be a key to unlocking new relationships
Fine- and coarse-grained massive and
among thermal and other petrophysical proper- bedded mica-quartz sandstone
ties. One example is the relationship between Fine- and coarse-grained bedded
mica-quartz sandstone
thermal conductivity and permeability (right).
These two properties depend not only on the
Y20
amount of pore space, but also on its distribution Bedded mica-quartz siltstone
through the rock volume—in isolated pores or in
connected pathways. When compared on a col-
lection of rock samples, permeability and ther-
–1.5 –0.5 0.5 1.5 2.5 3.5
mal conductivity often show a wide scatter. But Logarithm of permeability
when the samples are limited to rocks with a > Anisotropic thermal conductivity and permeability. Most sedimentary rocks have anisotropic thermal
heterogeneity factor above 20%—that is, to sam- properties: Thermal conductivity measured in a direction parallel to the layering generally is 5% to
ples in which thermal conductivity is strongly 50% higher than its value measured perpendicular to the layering. Moreover, the value measured in
affected by pore fluids—there appears to be a each direction changes in going from dry to water-saturated conditions. The degree of thermal
direct correlation between permeability and the anisotropy and its change with fluid saturation are both related to permeability (top). Samples with
higher thermal anisotropy generally have lower permeability. Moreover, the percentage change in
percentage change in thermal conductivity in thermal conductivity parallel to layering when going from dry to water-saturated conditions—a
going from dry to water-saturated conditions. The quantity labeled δk || in these plots—closely tracks the logarithm of permeability. Measurements on
relationship is strongest when both thermal con- core samples collected throughout a 140-m [450-ft] depth interval in the Middle Ob’ province of Russia
ductivity and permeability are measured parallel show that this correlation holds across different lithologies (bottom). (Adapted from Popov et al,
reference 19.)

18. Early studies of the thermal properties of fluid-saturated Oilfield Review20. Walsh JB and Decker ER: “Effect of Pressure and
A large, published compilation of thermal rock
porous rocks include the following: SUMMER
properties is maintained by the US Geological Survey: 12 Saturating Fluid on the Thermal Conductivity of Compact
Asaad Y: “A Study of the Thermal Conductivity of Fluid Thermal
Robertson EC: “Thermal Properties of Rocks,” Reston,Properties Fig. Journal
Rock,” 13 of Geophysical Research 71, no. 12
Bearing Porous Rocks,” PhD thesis, University of Virginia, USA: US Geological Survey, OpenORSUM
File 12-THMPTS (June1315, 1966): 3053–3061.
California, Berkeley, USA, 1955. Report 88-441 (1988). Pribnow D, Williams CF, Sass JH and Keating R:
Zierfuss H and van der Vliet G: “Laboratory 19. Popov Y, Tertychnyi V, Romushkevich R, Korobkov D and “Thermal Conductivity of Water-Saturated Rocks from
Measurements of Heat Conductivity of Sedimentary Pohl J: “Interrelations Between Thermal Conductivity the KTB Pilot Hole at Temperatures of 25 to 300°C,”
Rocks,” AAPG Bulletin 40, no. 10 (October 1956): and Other Physical Properties of Rocks: Experimental Geophysical Research Letters 23, no. 4 (February 15,
2475–2488. Data,” Pure and Applied Geophysics 160, no. 5–6 1996): 391–394.
(2003): 1137–1161.
Somerton WH: “Some Thermal Characteristics of
Porous Rocks,” Petroleum Transactions, AIME 213
(1958): 375–378.

Autumn 2012 33
Yarega Field Samples to any layering. A conclusion of the large study
7 of samples from Russian oil fields was that a
6 specific relative change of thermal conductiv-
Thermal conductivity, W/m°K 5
ity—defined as the percentage change in ther-
mal conductivity in the direction parallel to
4
layering when going from dry to water-saturated
3 conditions—may be the single most important
2
thermal property for the petrophysical charac-
terization of reservoir rocks.21
1
Understanding these subtleties enabled sci-
0 entists to discern new correlations relating ther-
0 5 10 15 20 25 30
Porosity, % mal conductivity to porosity, acoustic velocity
and electrical resistivity (left). These functional
Dry samples Oil-saturated samples Brine-saturated samples
mappings hold promise in both directions: Going
from the standard petrophysical properties to
Yarega Field Samples thermal conductivity opens the possibility of
4.5 detecting changes in thermal properties far from
the wellbore by remote geophysical sensing with
4.0
Thermal conductivity, W/m°K

electrical or seismic methods; going in the


3.5 reverse direction enables high-resolution optical
scans to explore the petrophysical heterogeneity
3.0
of rocks at both macroscopic and microscopic
2.5 scales. Thermal rock properties may also help to
quantify this multiscale heterogeneity in the
2.0
evaluation of unconventional reservoirs such as
1.5 gas shale.22
1,500 2,000 2,500 3,000 3,500 4,000 4,500
Acoustic velocity, m/s
Thermal Properties at Reservoir Conditions
Optical scanning provides rapid measurements
West Siberia Samples
3.1 of thermal properties under normal laboratory
2.9 conditions—ambient temperature and atmo-
Thermal conductivity, W/m°K

spheric pressure. To calibrate these measure-


2.7
ments to conditions in the reservoir, a special
2.5
chamber was built at the Schlumberger Moscow
2.3 Research Center to study the influence of ele-
2.1 vated temperature and pressure on thermal
1.9 properties (next page). The new device employs
1.7 a variation of the line source method to deter-
1.5
mine thermal conductivity and diffusivity at
0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 temperatures up to 250°C [480°F] and at pres-
Logarithm of resistivity
sures up to 200 MPa [29,000 psi]. Pore pressure
NaCl concentration: 240 g/cm3 120 g/cm3 60 g/cm3 Tap water in the sample and axial and lateral components
of confining stress can be varied independently
> Correlation of thermal conductivity with porosity, acoustic velocity and
within the chamber.23
electrical resistivity. Thermal conductivities of samples from the Yarega field
show good correlation with porosity (top) and acoustic velocity (center). The Thermal conductivity and diffusivity usually
solid lines in the top two panels are based on best least-squares fits to the have an inverse relationship with temperature.
measurements for curves with an exponential dependence of thermal For example, under an increase of temperature
conductivity on porosity or on acoustic velocity. Measurements on samples from 25°C to 100°C [77°F to 212°F], thermal con-
from western Siberia (bottom) show a correlation between thermal
conductivity and resistivity. The solid lines in the bottom plots are best fits to ductivity in core samples from the Yarega oil field
the measurements for curves with a logarithmic dependence of thermal decreased by 50% while thermal diffusivity
conductivity on the logarithm of resistivity. decreased by 70%. A suite of measurements on
samples selected from different reservoir rocks
determined average trends for changes in thermal
Oilfield Review properties with temperature, which were then
SUMMER 12 applied to all measurements in the database.
Thermal Properties Fig. 14
ORSUM 12-THMPTS 14

34 Oilfield Review
To connect thermal and mechanical proper- Pore pressure
ties, a new instrument was developed at the Input and output wires

Schlumberger Moscow Research Center to mea-


sure the thermal expansion of core samples over a
range of typical reservoir temperatures. The Water thermostat
instrument, which uses a standard test method Upper power gate
called a quartz-rod dilatometer, accommodates Rubber rings
either cube-shaped samples or standard cylindri- Sealing rubber
cal core plugs used in petrophysical studies— Axial stress gauge
3 cm in diameter and length—and can measure Elastic cuff

anisotropic thermal expansion coefficients by ori- Heat screen


Perforated container
enting the same sample in different positions.
This measurement technique gives results that Heat insulating disks Rock sample
are more consistent than conventional approaches
in which thermal expansion along a variety of External heater
directions is measured on three different samples
Side (overburden)
cut from the same rock core. A typical measure- pressure Plunger
ment sequence, which takes up to 12 hours, deter-
Lower power gate
mines the coefficient of thermal expansion at
Pressure for axial
temperatures from 20°C to 300°C [70°F to 572°F] stress
in temperature steps of 20°C.24 Rubber rings
A second instrument at TerraTek provides Lower internal screw
thermal expansion measurements at elevated
pressure. The device accommodates dry or satu-
rated cylindrical plugs 5 cm [2 in.] long and 2.5 to
3.8 cm [1 to 1.5 in.] in diameter. The specimen
can be loaded axially and radially in two direc- 12
tions and subjected to a maximum hydrostatic 11 1

Thermal conductivity, W/m°K


confining stress of 27 MPa [3,900 psi]. The device 2
10
3
measures thermal expansion coefficients at tem- 9
Rock sample
peratures up to 200°C [400°F] in a few tempera- 8
ture steps.25
7
Platinum line source
Platinum 6
Thermal Properties in Russian line source
Platinum 5
Heavy Oil Fields potential
Platinum lead 4
Since its introduction in the 1980s, the optical potential 20 40 60 80 100 120 140
lead Temperature, °C
scanning method has measured thermal proper-
ties of more than 80,000 rock samples. About 10% 0.1 25 50 80 100 130
of the samples come from 15 oil and gas fields in Pressure, MPa
Russia.26 This growing database of reservoir ther- > Measuring thermal properties at high temperature and pressure. Scientists at Schlumberger Moscow
mal properties is beginning to change the way Research Center constructed a chamber (top) to determine rock thermal properties at reservoir
petrophysicists regard the importance of hetero- conditions. The measurement cell (bottom left), which employs a version of the line source method,
was calibrated on quartz crystals, a material with well-known anisotropic thermal properties.
geneity in EOR processes.
Measurements (bottom right) indicate that values for the thermal conductivity along the principal axes
Thermal rock properties measured by scans (1, 2 and 3) of the quartz thermal conductivity tensor measured at different temperatures and pressures
of more than 500 cores from the production zone with the new instrument (solid circles) compare well with published results (open circles). (Adapted
and surrounding formations at Yarega field, for from Popov et al, reference 23.)
example, showed variations up to 150% over dis-
tances of a few meters. The largest variations cor-
related generally with changes in lithology, but 21. Popov et al, reference 19. 24. Popov Yu, Parshin A, Miklashevskiy D and Abashkin V:
the degree of heterogeneity in individual dry 22. Popov et al, reference 17. Oilfield Review “Instrument for Measurements of Linear Thermal
SUMMER
23. Popov YA, Spasennykh MY, Miklashevskiy DE,12
Expansion Coefficient of Rocks,” paper ARMA 12-510,
samples was not expected. Moreover, differences presented at the 46th US Rock Mechanics/
Thermal
Parshin AV, Stenin VP, Chertenkov Properties
MV, Novikov SV and Fig. 15
Geomechanics Symposium, Chicago, June 24–27, 2012.
in thermal conductivity and diffusivity of up to Tarelko NF: “Thermal PropertiesORSUM 12-THMPTS
of Formations from 15 ASTM International: “Standard Test Method for Linear
Core Analysis: Evolution in Measurement Methods,
Equipment, and Experimental Data in Relation to Thermal Thermal Expansion of Solid Materials with a Push-Rod
EOR,” paper CSUG/SPE 137639, presented at the Dilatometer,” West Conshohocken, Pennsylvania, USA,
Canadian Unconventional Resources and International ASTM E228-11, April 2011.
Petroleum Conference, Calgary, October 19–21, 2010. 25. Popov et al, reference 24.
26. Popov et al, reference 23.

Autumn 2012 35
Thermal Conductivity, W/m°K Thermal Diffusivity, 10 –6 m 2/s Volumetric Heat Capacity, MJ/m 3°K 120% were observed among nearly identical rock
X85
0 1 2 3 4 5 6 0.5 1.0 1.5 2.0 2.5 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 samples saturated with air, oil or water (left).
Overall, the ranges of thermal properties seen
X90
in the Yarega study ran from 0.8 to 5.2 W/m°K for
X95 thermal conductivity and from 1.1 to 3.4 MJ/m3°K
for volumetric heat capacity. Coefficients of lin-
Y00
ear thermal expansion, measured on samples
Y05 from Yarega under reservoir conditions, varied by
more than a factor of two, from 8 × 10–6 to 17 ×
Y10
Depth, m

10–6 per °K.


Y15 This variation far exceeds what had been
observed in previous studies. Optical scanning
Y20
and complementary measurements are revealing,
Y25 possibly for the first time, the natural variability
of thermal properties in reservoirs—caused
Y30
either by natural heterogeneity in rock texture,
Y35 mineral and organic composition, or by changes
in fluid saturation, temperature and pressure. All
Y40
Dry sample Oil-saturated sample Water-saturated sample these factors affect the flow of heat into the res-
Quartz sandstone and leucoxene sandstone Siltstone with layers of sandstone and silty sandstone Basalt ervoir and therefore the production forecasts for
Quartz sandstone Siltstone a thermal recovery project.
> Variation of rock thermal properties. Thermal properties at the Yarega oil field show large
variations—up to 150%—over a 50-m [166-ft] interval covering the depths of thermal mining. Each Precise Design and Control of Thermal EOR
data point represents a separate core sample measured under various conditions. Colored lines Estimating the economics of thermal EOR requires
represent moving averages of the data. (Adapted from Popov et al, reference 23.)
that operators accurately predict the amount of
additional hydrocarbon that will be produced from
a field and the production rates of wells following
stimulation by a given amount of heat. The thermal
properties used in these reservoir simulations are
often derived from theoretical models, called mix-
ing laws, that estimate the combined thermal
properties of a volume of rock and pore fluid from
Range of measurements the volume fractions of its constituents.27
6
made by optical scanning
Arithmetic 27. The bulk physical properties of a composite material
Thermal conductivity, W/m°K

generally cannot be precisely calculated without


knowledge of the microscopic distribution of its
constituents. Mixing laws are mathematical
4 combinations of the constituent properties to estimate
bulk properties. Examples are the weighted arithmetic
Landau mean, weighted harmonic mean, weighted geometric
Weiner
mean and Hashin-Shtrikman model.
For more on mixing laws see: Berryman JG: “Mixture
2 Theories for Rock Properties,” in Ahrens TJ (ed): Rock
Physics & Phase Relations: A Handbook of Physical
Hashin-Shtrikman
Constants. Washington, DC: American Geophysical
Harmonic Union (1995): 205–228.
Zimmerman RW: “Thermal Conductivity of Fluid-
0 Saturated Rocks,” Journal of Petroleum Science and
0 10 20 30 40 Engineering 3, no. 3 (1989): 219–227.
Porosity, % 28. Popov Y, Parshin A, Ursegov S, Taraskin E, Chekhonin E,
Oilfield Review Andrianov N, Bayuk I and Pimenov V: “Thermal
> Models of rock thermalSUMMER
properties.12Reservoir engineers use predictive Reservoir Simulation: Thermal Property Data
models called mixing laws Thermal Properties
to calculate Fig.bulk
a rock’s 16 thermal conductivity Uncertainties and Their Influence on Simulation
as a function of porosityORSUM
from the 12-THMPTS
conductivities16of the solid matrix and Results,” paper WHOC12-291, presented at the World
Heavy Oil Congress, Aberdeen, September 10–13, 2012.
saturating fluid. Each model employs different assumptions about the
29. For more on cementing: Boisnault JM, Guillot D,
distribution of pore space. Predictions of standard mixing laws for Bourahla A, Tirlia T, Dahl T, Holmes C, Raiturkar AM,
oil-saturated quartz sandstones, with matrix thermal conductivity of Maroy P, Moffett C, Pérez Mejía G, Ramírez Martínez I,
6.6 W/m°K and varying porosity, overlap the range of thermal conductivities Revil P and Roemer R: “Concrete Developments in
measured by optical scanning of oil-saturated sandstones from the Yarega Cementing Technology,” Oilfield Review 11, no. 1
oil field (blue shading), but can differ from actual values for specific samples (Spring 1999): 16–29.
by more than 100%. 30. For more on asphaltenes: Akbarzadeh K, Hammami A,
Kharrat A, Zhang D, Allenson S, Creek J, Kabir S,
Jamaluddin A, Marshall AG, Rodgers RP, Mullins OC and
Solbakken T: “Asphaltenes—Problematic but Rich in
Potential,” Oilfield Review 19, no. 2 (Summer 2007): 22–43.

36 Oilfield Review
Temperature, °C The economic implications for the various
50 110 170 230 290 scenarios differ dramatically from one another
and, given the typical life of an EOR project, have
Reservoir long-term consequences. Production predictions
based on empirically derived thermal rock prop-
erties may provide field operators with realistic
expectations for returns on capital investments.

Heater well Other Applications


Many oilfield processes other than thermal stim-
Producer well ulation may benefit from operators having accu-
rate knowledge of thermal properties surrounding
4.0 50 7 60 the wellbore. A cementing operation, for exam-
HC
3.5 2, V ple, has to maintain pressure in the annulus
Cumulative oil production, × 10 5 m 3

TC× 6
C×2 50
40
2, VH between the casing and the formation in the nar-
Cumulative steam/oil ratio
3.0
×2 5 TC ×
row range between formation pore pressure and
Relative variation, %

Relative variation, %
C
VH 40
2.5 TC, 30 H C formation fracture pressure. This requirement
4 TC, V
2.0 30 holds over the full length of the wellbore from the
20 3 start of the job until the cement fully cures. Since
1.5
Relative 20
variation 2 the curing process can raise the temperature of
1.0
10 the slurry by more than 100°C [180°F], pressure
1 10
0.5 and temperature in the annulus may be strongly
0 0 0 0 affected by the thermal response of the surround-
0 5 10 15 0 5 10 15
Number of years Number of years
ing rock and its pore fluids. Knowing the actual
values of thermal properties in a formation helps
> Sensitivity of a SAGD operation to reservoir thermal properties. In SAGD operations (top), steam is
operators determine the best choice of cement
injected into a heater well and oil is produced from a producer well. Predictions of the performance
over time of a SAGD operation—in terms of cumulative oil production (bottom left) and cumulative mixtures and additives.29
steam/oil ratio (bottom right)—vary with the modeled thermal properties of the reservoir zone. The Another important process governed in part
base scenario (dashed black line) is modeled with an assumed, or measured, average volumetric heat by the temperature regime near the wellbore,
capacity (VHC) and thermal conductivity (TC) for the reservoir zone. Variation in cumulative oil and therefore by the surrounding distribution
production from the base scenario is determined, on the low side, by doubling volumetric heat capacity
(left, dashed red line), thereby reducing the temperature rise for a given amount of injected heat. of thermal properties, is the precipitation of
Variation in oil production on the high side is determined by doubling thermal conductivity (left, red asphaltenes, which can choke off production
line), thereby increasing the speed at which the temperature rise at the heater well propagates into the by clogging flow pathways. Knowing where
reservoir. Increasing thermal conductivity or volumetric heat capacity drives the cumulative steam/oil
asphaltenes are likely to precipitate helps engi-
ratio higher (right, red line) than its value in the base scenario (dashed black line). Relative changes
(green) in oil production and steam/oil ratio in these different scenarios are as high as 40% in the early neers design better well completions.30
years of production and persist at levels above 20% for 10 years or more. (Adapted from Popov et al, Petroleum production is essentially a ther-
reference 28.) momechanical process. Modern reservoir simu-
lators calculate the pressure, volume and
temperature changes accompanying mass and
heat transfer during production or testing, but
Values of thermal conductivity obtained from model has two horizontal wells crossing a they often use average values of thermal proper-
standard mixing laws may be compared
Oilfield Review with 150-m by 500-m by 25-m [490-ft by 1,640-ft by 80-ft] ties, usually based on point measurements on
experimental results obtainedSUMMER
by optical
12 scan- pay zone of uniform thermal and production prop- cores, to characterize the entire reservoir. The
ning (previous page, bottom).Thermal
AlthoughProperties
the mix- Fig. 18 typical of tar sand reservoirs. The key met-
erties, growing database of measurements made possi-
ORSUM
ing laws provide helpful bounds, the 12-THMPTS
predicted 18rics for a SAGD operation are the cumulative oil ble by optical scanning shows that thermal rock
values may differ from measured values by more production (COP) and the cumulative steam/oil properties vary significantly at both macroscopic
than a factor of two. Similar large discrepancies ratio (CSOR), which is the volume ratio of steam and microscopic scales. Understanding the
are found between the default settings for ther- input to oil produced. This ratio largely determines effects of heterogeneity in scaling up from high-
mal conductivity and volumetric heat capacity efficiency of a steam injection process. Simulations resolution thermal scans of cores to full reser-
programmed in most reservoir simulators and the in which the thermal conductivity and volumetric voir simulations is a fundamental challenge for
average values calculated from the database of heat capacity were varied by factors of up to two— engineers constructing the next generation of
measured thermal properties maintained at the to reflect a range of uncertainties in reservoir reservoir models. —MO
Schlumberger Moscow Research Center.28 properties—show production scenarios with rela-
A simplified model of a SAGD process illus- tive deviations in COP and CSOR of 20% to 50%
trates the importance of using accurate rock prop- persisting over the duration of the simulated
erties in simulations of thermal EOR (above). This SAGD operation.

Autumn 2012 37
Basin to Basin:
Plate Tectonics in Exploration

Ian Bryant The principles of plate tectonics help explorers understand and evaluate hydrocarbon
Nora Herbst
Houston, Texas, USA plays. Since the start of the 21st century, these ideas have been successfully applied
to presalt basins and turbidite fans along the coasts of South America and western
Paul Dailly
Kosmos Energy Africa. Guided by global plate tectonics, exploration companies are applying winning
Dallas, Texas
play strategies from one coast of the South Atlantic to discover and prove similar
John R. Dribus plays on the opposite coast.
New Orleans, Louisiana, USA

Roberto Fainstein
Al-Khobar, Saudi Arabia

Nick Harvey New discoveries often emerge from previous suc- Basic Concepts
Neftex cesses. Once a play concept has proved commer- Basins, petroleum systems and hydrocarbon plays
Abingdon, England cially viable, oil companies are able to apply are vital concepts in petroleum exploration. Basins
characteristics from their play to a regional or collect the sediments that become the building
Angus McCoss global framework in search of other accumula- blocks for petroleum systems. A petroleum system
Tullow Oil plc
tions. Through integration of exploration infor- comprises an active source rock and the oil and
London, England
mation, drilling data and geologic models from a gas derived from it that migrate to a reservoir and
Bernard Montaron successful play and through application of plate become confined there by a trap and seal.1 A play
Beijing, People’s Republic of China tectonic models, geoscientists are finding analog is a model used to explore for hydrocarbon depos-
plays across ocean basins. its having similar characteristics. Petroleum sys-
David Quirk From the North Sea to the Gulf of Mexico and tems may contain one or more plays, depending on
Maersk Oil from offshore South America to offshore Africa, the reservoir and style of trapping mechanism.2
Copenhagen, Denmark explorationists have discovered major oil and gas Exploration experts systematically apply these
fields in continental margin systems. The Santos, concepts to locate prospects for drilling. Software
Paul Tapponnier Campos and Espirito Santo basins off the coast of platforms for databases, data integration and
Nanyang Technological University Brazil contain prolific oil discoveries, and the modeling are helping experts optimize their explo-
Singapore
application of plate tectonic concepts has enabled ration workflows.
Oilfield Review Autumn 2012: 24, no. 3.
explorers to extend that play across the Atlantic A basin is a depression in the Earth’s surface
Copyright © 2012 Schlumberger. to offshore western Africa. Within the last few that accumulates sediments. Basins form when
For help in preparation of this article, thanks to Steve years, exploration companies have applied prin- the Earth’s lithosphere is stretched, fractured,
Brown, Copenhagen, Denmark; George Cazenove and
Jonathan Leather, Tullow Oil plc, London; James W. ciples of plate tectonics to extend and relate loaded down or compressed in response to
Farnsworth, Cobalt International Energy, Inc., Houston; upper Cretaceous turbidite fan plays westward— global tectonic processes. These processes also
Winston Hey, Houston; Susan Lundgren, Gatwick, England;
and Richard Martin and Mike Simmons, Neftex, Abingdon, from West Africa across the Equatorial Atlantic to govern the size and depth—the accommodation
England. French Guiana and Brazil. This article describes space—of a basin, while climatic conditions
Petrel is a mark of Schlumberger.
some of the fundamental concepts that today’s determine water and sediment input for the
geoscientists use to extrapolate plays across basin fill material.
ocean basins. Case studies demonstrate how
explorers have used plate tectonics and regional
geology to expand exploration efforts in both
directions across the Atlantic Ocean.

38 Oilfield Review
Basins may be deformed by tectonic motion: 1. Al-Hajeri MM, Al Saeed M, Derks J, Fuch T, Hantschel T, 2. Doust H: “Placing Petroleum Systems and Plays in
extension, compression, strike-slip motion or Kauerauf A, Neumaier M, Schenk O, Swientek O, Their Basin History Context: A Means to Assist in the
Tessen N, Welte D, Wygrala B, Kornpihl D and Identification [of] New Opportunities,” First Break 21,
any combination thereof. Extension may cause Peters K: “Basin and Petroleum System Modeling,” no. 9 (September 2003): 73–83.
normal faulting and may be accompanied by Oilfield Review 21, no. 2 (Summer 2009): 14–29. Doust H: “The Exploration Play: What Do We Mean By
stretching, thinning and sagging of the crust. Stewart L: “The Search for Oil and Gas,” Oilfield Review 23, It?,” AAPG Bulletin 94, no. 11 (November 2010): 1657–1672.
no. 2 (Summer 2011): 59–60.
Compression results in thrust faulting, folding,
shortening and thickening. Strike-slip motion
gives rise to translation and lateral faulting.
A combination of these phenomena produces

Autumn 2012 39
O Overburden
C Caprock
R Reservoirs
Source rocks
O

Tertiary
Clayey-sandy
R sediments
C

Marls
C

Oceanic R

Cretaceous
crust Continental crust Limestone

C Salt

C
Lithosphere Synrift
R lacustrine
sediments

> Petroleum systems. Explorationists define the petroleum system as the geologic elements and processes that are
essential for the existence of a petroleum accumulation. This cross section summarizes petroleum systems along a South
Atlantic continental margin. The geologic elements must be present in the following order: The source rock contains
organic matter, reservoir rock receives the hydrocarbons and has sufficient porosity and permeability for storage and
recovery of hydrocarbons, sealing caprock is impermeable to keep the fluids in the reservoir and overburden rock buries
the source rock to depths having the optimal temperature and pressure for source rock maturation and hydrocarbon
generation. Rifting of the South Atlantic Ocean started with extension and faulting (black solid going to dashed lines) of
continental crust (brown). The continental crust thinned and eventually split apart. As the two parts of the continental crust
separated (only the right side is shown here), oceanic crust (gray) formed at a midocean ridge (not shown) during seafloor
spreading. The continental margin is located where the thinned continental crust meets oceanic crust. Synrift lacustrine
basins were preserved and filled with source (blue) and reservoir (white) rock that were eventually trapped and sealed
underneath salt (purple). Hydrocarbons from synrift source rock migrated to limestone reservoirs (green bricks) that were
buried and trapped beneath postsalt marls (green). The marls also provided source rock (dark green). During the Tertiary,
clayey-sandy sediments (yellow and tan) buried the margin, providing source rock, reservoirs, caprock and overburden.
[Illustration adapted from Huc AY: “Petroleum in the South Altantic,” Oil & Gas Science and Technology—Revue de l’Institut
Français du Pétrole 59, no. 3 (May–June 2004): 243–253.]

pull-apart basins, push-up blocks and transten- Exploration teams composed of geologists, geo- have potential to trap hydrocarbons, it becomes
sion or transpression oblique slip. Thus, local chemists, paleontologists, geophysicists and petro- a prospect.4
or large-scale movements provide the impetus physicists unravel the history of a basin and Once identified, the prospects are ranked
for creation of stratigraphic or structural sequence of tectonic events and cycles of sedimen- according to uncertainty, risk, potential reward
traps. Stratigraphic traps result from facies tation filling a basin. They identify source rocks and market value of hydrocarbons.
changes or juxtaposition of impermeable and within the basin and correlate them with known Integrated software systems that incorporate
permeable strata. Structural traps form as a trapped hydrocarbons.The
Fig1_6 teams examine the geo- mapping and petroleum systems and play analy-
result of strata deformation. The tectonic and logic elements and processes that created known sis tools, such as the Petrel E&P platform, help
stratigraphic history of a basin gives it a global source rocks and traps to develop leads to other geoscientists evaluate basins (next page).5
and regional setting for its formation, filling similarly generated accumulations (above). After Geoscientists use them to construct and share
and deformation.3 further investigation, if the lead still appears to geologic models in 3D and provide an environ-
ment for storing data and models.

40 Oilfield Review
Project and portfolio economics Model-based interpretation from basin to prospect Trap

Play and prospect evaluation Reservoir

Geomechanics and seal analysis Charge and timing petroleum system modeling Structural restoration
> Exploration software platform. Exploration experts combine seismic information, well logs, geochemical and heat flow data and other geologic data to
work from basin to prospect scale (clockwise top center to middle right). Regional to prospect scale models of traps (top right) and reservoirs (middle right)
built in the Petrel platform benefit from integration with structural restoration tools (bottom right) and petroleum system modeling (bottom center). Both
petroleum system modeling and structural restoration tools may be used to gain an understanding of the geomechanics of the basin to guide evaluation of
seals (bottom left) and plan exploration wells. Risk assessment tools allow exploration teams to assign uncertainty and risk to acreage and drillable
prospects (middle left). Petroleum economic evaluation enables planning exploration portfolios (top left).

By creating models at various scales, geo- 3. A facies is a rock unit defined by characteristics that 4. This chain of events from hydrocarbon source to its
scientists are able to develop geocellular mod- distinguish it from neighboring units. resting place in a distant reservoir applies to
For more on stratigraphic and structural traps: conventional petroleum systems. For unconventional
els from global to regional and local scales. systems, the source rock may also be the reservoir rock.
Caldwell J, Chowdhury A, van Bemmel P, Engelmark F,
This integration allows geoscientists to deter- Sonneland L and Neidell NS: “Exploring for Stratigraphic Such unconventional systems include oil and gas from
Traps,” Oilfield Review 9, no. 4 (Winter 1997): 48–61. shale or coalbed methane.
mine, for example, whether a particular local
For sequence stratigraphy: Neal J, Risch D and Vail P: McCarthy K, Rojas K, Niemann M, Palmowski D, Peters K
channel-levee interpretation is consistent with “Sequence Stratigraphy—A Global Theory for Local and Stankiewicz A: “Basic Petroleum Geochemistry for
the regional interpretation or whether a wide- Success,” Oilfield Review 5, no. 1 (January 1993): 51–62. Source Rock Evaluation,” Oilfield Review 23, no. 2
(Summer 2011): 32–43.
spread organic-rich facies mapped at the tec- 5. Al-Hajeri et al, reference 1.
tonic plate scale corresponds to source rock
facies in the prospect model of the targeted Fig2_1
petroleum system.

Autumn 2012 41
Present day

Jubilee discovery,
Tano basin
Cretaceous
Zaedyus discovery,
Guyana-Suriname basin
Precambrian

Play projection
Present day Cretaceous Precambrian

Extrusive volcanics
Nondeposition
Organic-rich clastics
Tupi discovery, Azul and Cameia discoveries,
Lacustrine facies Kwanza basin
Santos-Campos basin
Deep marine sand-dominated clastics
Paralic facies
Deep marine carbonates
Shallow marine carbonates
Deep marine clastics
Shallow marine clastics
Terrestrial sediments
> South Atlantic conjugate margins through geologic time. Two regional geologic models, built on opposing coasts of the South Atlantic, are constrained by
a global sequence stratigraphic model. By assimilating interpretations into a 3D environment using the Petrel platform, geoscientists have derived a
workflow to populate a tectonic plate–scale geocellular model for the sedimentary evolution of the margins through geologic time as illustrated in the
exploded view of the South Atlantic continental margins from Precambrian time at the deepest surface to the present at the upper surface. Data assembled
in this way on a common software platform allow explorationists to project petroleum system facies to a data-poor region by using sequence stratigraphy
and elements of petroleum system modeling from a data-rich region to correlate and extrapolate associated facies. A recent example of this approach may
be found along the transform margin where successful exploration concepts developed in Turonian-age lowstand turbidite fans offshore Ghana have been
applied offshore French Guiana, leading to the recent Zaedyus discovery within similar deposits. Visualized in geologic time, these lowstand systems may
be explored with their associated petroleum elements. Compelling evidence from wireline log responses, hinterland cooling events and biostratigraphically
constrained unconformities were integrated; the results suggest that Campanian-age lowstand deposits may also provide attractive reservoir targets in the
Guyana-Suriname basin offshore northern South America. The Campanian stratigraphic interval, while not as well tested as the Turonian interval, has also
been attracting interest on the African margin offshore Ghana, Liberia and Côte d’Ivoire. (Illustration used with permission from Neftex.)

Because these various input data are con- graphic interval to analogous strata in conjugate Plate Boundaries and Rifted and
strained by a stratigraphic model, the geocellular basins or in frontier areas. Geologists are also Transform Margins
models are displayed not only in true vertical able to use qualitiesFig3_2
from a data-rich region to Plate tectonic science has established that the
depth (TVD) or two-way traveltime, but also in develop a sequence stratigraphic context for pre- Earth’s outermost layer, the lithosphere, com-
geologic time (above). In addition, geologists are dicting facies in data-poor regions. prises a number of major and many minor plates
able to project characteristics of a given strati- that move relative to one another (next page).6

42 Oilfield Review
This motion is driven by the convection and flow denser and thinner than continental crust. Its Pangea, formed during the Paleozoic era, then was
of hot ductile material in the mantle underlying density averages about 2.9 g/cm3, and its thick- rifted apart beginning about 225 to 200 million
the lithosphere. The lithosphere consists of two ness ranges from 5 to 10 km [3 to 6 mi]. The years ago [Ma]. The breakup started with Pangea
layers: the crust and the lithospheric mantle.7 higher density of the oceanic crust causes it to separating into the Laurasia and Gondwana super-
The crust is further divided into two categories. rest lower in the mantle than continental crust. continents in the north and south, respectively.
Continental crust is mostly of granitic composi- Over geologic time, tectonic plate motions The subsequent breakup of Laurasia and
tion; its density averages about 2.7 g/cm3, and its have amalgamated small continents to form super- Gondwana resulted in the opening of the Atlantic
thickness is about 35 km [22 mi] in most places continents and separated them again into a collec- and Indian oceans and evolved to the present day
but ranges from 20 to 70 km [12 to 43 mi]. tion of smaller continents distributed across the configuration of continents and oceans.
Oceanic crust has a basaltic composition and is planet. The most recent giant supercontinent,

Eurasia plate
Eurasia plate

North America plate


Juan de Fuca
plate Anatolia plate

Pacific plate
Caribbean plate
Philippine Arabia
Africa plate plate
plate
India
Cocos plate
plate

South America plate


Australia
plate
Nazca plate
Australia plate

Pacific plate

Scotia plate
Antarctica plate
Antarctica plate

Antarctica plate

Convergent boundary barbs point Possible boundary Major transform boundary Divergent boundary Plate movement
to direction of convergence
> Plates. The Earth’s lithosphere is divided into numerous plates. Relative motion of the plates (arrows) determines whether the plate boundaries are
convergent, transform or divergent. [Map adapted from “Interpretative Map of Plate Tectonics,” an inset to Simkin T, Tilling RI, Vogt PR, Kirby SH,
Kimberly P and Stewart DB: “This Dynamic Planet—World Map of Volcanoes, Earthquakes, Impact Craters, and Plate Tectonics,” US Geological Survey,
Geologic Investigations Series Map I–2800 (2006).]

6. The lithosphere is the 50 to 200 km [30 to 120 mi] thick, For more on plate boundaries: Bird P: “An Updated 7. Earth’s mantle is the 2,900 km [1,800 mi] thick layer that
rigid outer layer of Earth; its thickness is determined by Digital Model of Plate Boundaries,” Geochemistry lies between Earth’s crust and outer core. The mantle is
the depth of the brittle-to-ductile transition temperature, Geophysics Geosystems 4, no. 3 (March 2003), divided into the upper mantle, transition zone and lower
which is roughly 1,000°C [1,800°F]. The upper part of the http://dx.doi.org/10.1029/2001GC000252 (accessed mantle. The upper mantle is about 370 km [230 mi] thick
lithosphere is the crust and the lower part is the August 21, 2012). and divided into the lithospheric mantle and the
lithospheric mantle. asthenosphere.

Autumn 2012
Fig4_3 43
The plates move relative to one another and
Convergent Transform Divergent Convergent Continental rift zone
plate boundary plate boundary plate boundary plate boundary (young plate boundary) interact with each other at their boundaries
(left). The three types of plate boundaries are the
following: convergent, or compressional; trans-
Shield form, or strike slip; and divergent, or extensional.
Island arc Trench Oceanic spreading Trench
volcano ridge At convergent plate boundaries, plates move
stratovolcano
Lithosphere Continental crust toward one another. Plates respond in a number
tle Oceanic crust Uppe
n Asthenosphere r ma of ways when they collide, depending on whether
r ma ntle
pe
Up Subducting the convergence is continent to continent, ocean
Hot spot plate
to ocean or ocean to continent. Continent-to-
Lower mantle
continent convergence—collision—results in
shortening and thickening of the crust. The colli-
sion between the Indian and Asian continents is
one example. This convergence created the
Plate
Himalaya Mountains and Tibetan Plateau and
Asthenosphere resulted in the southeastward lateral escape of
Convergent boundary Transform boundary Divergent boundary
Sundaland and southeast China in the direction
away from the collision between India and Asia.8
> Plate boundaries. Earth’s lithospheric plates move relative to one another. This movement is Ocean-to-ocean or ocean-to-continent conver-
accommodated along plate boundaries. Convergent boundaries occur where plates move toward one gence results in subduction: one oceanic plate
another. One plate may subduct—dive—under another; trenches mark the line of the bending,
subducting plate. Chains of island arc stratovolcanoes may form along subduction zones above the dives under the other plate. An example of ocean-
downgoing plate. Transform boundaries occur where plates slide past one another; oceanic transform to-ocean convergence occurs at the Marianas
fault zones transfer seafloor spreading from one midocean ridge segment to another. Divergent plate Trench, where the Pacific plate plunges west-
boundaries occur where plates split apart at seafloor spreading ridges and continental rift zones. Hot ward under the small Philippine plate in the
spots occur where plumes of hot mantle material impinge on lithospheric plates; they may induce
shield volcanoes and cause flood basalts to pour out over plates (not shown). [Image adapted from western Pacific Ocean. Ocean-to-continent con-
“Schematic Cross Section of Plate Tectonics,” an inset to Simkin T, Tilling RI, Vogt PR, Kirby SH, vergence occurs along the western Andes
Kimberly P and Stewart DB: “This Dynamic Planet—World Map of Volcanoes, Earthquakes, Impact Mountains, where the Pacific plate dives east-
Craters, and Plate Tectonics,” US Geological Survey, Geologic Investigations Series Map I–2800 (2006).] ward under the South America plate.
At transform boundaries, plates slide past
each other, which occurs along the San Andreas
Fault in California, USA. This fault accommo-
dates movement of the Pacific plate northward
Plate boundary
Midocean past the North America plate. The North and
ridge East Anatolian faults in Turkey are also trans-
form boundaries. These faults accommodate the
westward movement of the Anatolia plate
toward the Mediterranean Sea as it escapes the
Ocean crust
compression between the converging Eurasia
and Arabia plates.
At divergent plate boundaries, a plate splits,
forming two smaller plates that move apart from
Fracture Transform fault Fracture each other. Divergent plate boundaries may start
zone (active part of zone out as continental rift systems; in millions of
(inactive) fracture zone) (inactive)
years, these land-based rifts become oceanic rifts.
Fig5_1
Examples of modern-day continental rifts are the
East African rift; the Lake Baikal rift, Russia; and
Oceanic crust
the Basin and Range Province, western USA.
Lithosphere
In continental rifts, the crust undergoes
Asthenosphere
Plate boundary
extension, faulting and thinning until it splits. At
the split, a volcanic ridge forms as hot mantle
> Midocean ridge and transform fault plate boundary. Midocean spreading (white and red arrows) material wells up to fill the void left by the sepa-
rarely occurs along a single clean rift zone. Here, the divergent plate boundary (dashed yellow line) rating plates. The mantle material of basaltic
consists of two segments of a midocean ridge connected by a transform fault. In the transform fault, composition accretes to the plate edges, cools
or the active part of the fracture zone between the ridge segments, the plates slide past each other and forms new oceanic crust. As the plates move
in opposite directions (black opposing arrows). In the inactive part of the fracture zone, outside of the
ridge segments, the plate sections are locked together and move in the same direction (black parallel apart, the oceanic crust grows, building an ocean
arrows). (Adapted from Garrison TS: Oceanography: An Invitation to Marine Science, 4th ed. Pacific that widens between the slowly separating plates.
Grove, California, USA: Brooks/Cole Publishing Company, 2002.) The process is called seafloor spreading. The Red

44 Oilfield Review
Sea and Gulf of Aden rift that separates the fitting apparent polar wander curves.10 For netic field and from fracture zones on the ocean
Africa and Arabia plates is a young divergent oceans, scientists determine plate movement floor (below).11 However, there are no useful mag-
plate boundary. The Mid-Atlantic Ridge, which from magnetic anomaly patterns caused by netic anomalies to constrain the Gondwana
encompasses the midocean rift and ridge that north-to-south polarity reversals of Earth’s mag- breakup history during the Cretaceous period
separates the Americas from Europe and Africa,
is a mature divergent plate boundary.
As continents move apart, they rarely do so
along a single separation zone or rift. Rather,
Magnetic chrons
the rift is a series of segments offset by trans-
MC1 MC1
form faults and fracture zones. Transform faults MC3 MC2 MC2 MC3
MC6 MC5 MC4 MC4 MC5 MC6
are strike-slip faults that connect rift segments.
Is M Is
They transfer the spreading motion or accom- oc id oc
hr oc hr
on ea on
modate spreading rate differences between rift s n s
rid
segments; they are active only between rift seg- ge Normal polarity
ments.9 Transform faults leave scars on the Reverse polarity
ocean floor called fracture zones. Transform
faults and fracture zones are oriented perpen- Oceanic
crust
dicular to the midocean ridge and parallel to
the spreading direction; they mark the path of
plate movement as the rifted continental mar-
Seafloor spreading Lithosphere
gins move farther apart.
The ages and thermal histories of oceanic Cold Hot and
rocks differ on opposite sides of transform faults. and old young
Along the fault, younger, hotter and lower density
rocks are juxtaposed against older, colder and Plate temperature and age
higher density rocks. Because they are hotter, the
> Magnetic anomalies and seafloor spreading. Scientists obtained evidence
younger rocks are thermally uplifted to a higher
of seafloor spreading by determining the polarity of magnetic anomalies on
elevation than their older, cooler and denser both sides of midocean ridges. Earth’s magnetic field changes its polarity
cross-fault neighbors, causing a difference in from time to time. The ocean floor is youngest and hottest at the oceanic
ocean floor elevation on either side of the fault. ridge spreading center and becomes progressively older and cooler toward
the continent-ocean boundary. As the ocean floor rocks and their
These elevation differences may remain as the ferromagnetic minerals cool below the Curie temperature, the ferromagnetic
rocks cool, leaving scars—fracture zones. minerals become magnetized in the direction consistent with the existing
Because the fracture zones are nearly parallel to polarity of Earth’s magnetic field. Rocks displaying dominantly normal
the midocean ridge spreading direction—the polarity, equivalent to present-day magnetism, are shown by black stripes on
the plate cross section. Rocks with dominantly reverse polarity magnetism
direction of relative plate motion—they leave are shown as white stripes. The symmetry of the magnetic anomaly striping
tracks of the opening of the ocean (previous on either side of the ridge demonstrates the movement of the seafloor
page, bottom). away from the spreading center. Dating each polarity shift—normal to
As seafloor spreading continues, previously reverse and reverse to normal—turns the magnetic anomaly map into an
magnetochronology map for seafloor spreading; the age of each reversal is
connected continental margins move farther an isochron (white lines)—a contour of time—and the time interval between
apart. A continental margin, where continental magnetic reversals is a magnetic chron (MC), during which Earth’s magnetic
crust meets or transitions to oceanic crust, is a field is dominantly, or constantly, one polarity.
relic of faulting during continental breakup.
Thus, continental margins that face a midocean
rift commonly have overlaps and may also have
  8. Sundaland refers to the Sunda shelf region of Southeast Besse J and Courtillot V: “Correction to ‘Apparent and
transform and rifted margin segments. Transform Asia, which includes Malaysia, Sumatra, Java and True Polar Wander and the Geometry of Geomagnetic
margins occur where continents break up and Borneo. For more about the lateral escape of Southeast Field Over the Last 200 Myr,‘” Journal of Geophysical
Asia and Sundaland: Tapponnier P, Lacassin R, Leloup Research 108, no. B10 (October 2003): EMP 3-1 to 3-2.
separate by shear movement along transform PH, Schärer U, Zhong D, Wu H, Liu X, Ji S, Zhang L and 11. For more on plate motions, magnetic anomalies and
strike-slip faults. Rifted margins form where con- Zhong J: “The Ailao Shan/Red River Metamorphic Belt: seafloor spreading: Hellinger SJ: “The Uncertainties of
tinents break up and separate by extensional Tertiary Left-Lateral Shear Between Indochina and South Fig7_1 Finite Rotations in Plate Tectonics,” Journal of
China,” Nature 343, no. 6257 (February 1, 1990): 431–437. Geophysical Research 86, no. B10 (October 1981):
movement perpendicular to coastlines and along   9. Strike-slip displacement or motion refers to the horizontal 9312–9318.
dip-slip faults. movement of the other side of the fault relative to the Karner GD and Gambôa LAP: “Timing and Origin of the
reference side—the side on which one is standing, South Atlantic Pre-Salt Sag Basins and Their Capping
facing the fault. The motion is right lateral when the Evaporates,” in Schreiber BC, Lugli S and Babel M (eds):
Gondwana Breakup other side of the fault moves to the right and left lateral Evaporites Through Space and Time. London:
when the other side moves to the left. The Geological Society, Special Publication 285
The relative movement of adjacent tectonic 10. For more on plate motions and polar wander: Besse J (January 2007): 15–35.
plates throughout geologic time has been quanti- and Courtillot V: “Apparent and True Polar Wander and
the Geometry of Geomagnetic Field Over the Last 200
fied by remote-sensing technologies. For conti- Myr,” Journal of Geophysical Research 107, no. B11
nents, scientists determine plate movement by (November 2002): EMP 6-1 to 6-31.

Autumn 2012 45
Cratons
Marathon FZ Cretaceous
AFRICA volcanism
Midocean
Demerara Guinean ridge
Plateau Plateau
Aptian salt
Equatorial Segment Romanche FZ Gulf of
Chain FZ Guinea Gabon
Potiguar basin basin

Ascension FZ
Congo
Sergipe- basin
Alagoas
basin Kwanza
basin
SOUTH Espírito Central Segment
AMERICA Santo Namibe
basin basin
Campos
basin
Rio Grande FZ
Walvis
Santos Ridge
basin Rio Grande Namibia
Paraná Rise basin
Province

Pelotas Tristan da Cunha


basin hot spot
Southern Segment

Rawson
basin
Agulhas-Falkland FZ
Falkland Segment

> Tectonic map of the South Atlantic Ocean at the end of magnetic polarity chron 34 (MC34, 84 Ma). The red line
represents the midocean ridge at the end of MC34. From north to south, the South Atlantic Ocean is divided into the
Equatorial, Central, Southern and Falkland segments, bounded by the Marathon, Ascension, Rio Grande and
Agulhas-Falkland fracture zones (FZs). The black dots show the approximate locations of the discoveries of Tupi
offshore Brazil, Azul and Cameia offshore Angola, Jubilee offshore Ghana and Zaedyus offshore French Guiana.
(Adapted from Moulin et al, reference 12.)

from roughly 120 to 84 Ma because Earth’s mag- segment opened later because the continental Ridge formed as the South America plate drifted
netic field was stable and did not experience plate was hotter and softer there. Consequently, to the NW and the African plate drifted NE rela-
magnetic polarity reversals during that interval.12 it stretched further and reached a higher eleva- tive to the Tristan da Cunha hot spot. The result-
Nonetheless, through dating of the flood basalts tion because of thermal uplift before breakup. ing ridges formed a broad volcanic high that
that poured over the Gondwana continent, geo- The South Atlantic Ocean extends from the isolated the central segment of the South Atlantic
scientists generally agree that the breakup of the Marathon Fracture Zone (FZ) in the north to the Ocean from encroachment by marine water from
Gondwana supercontinent, which resulted in the Antarctic Plate in the south and may be divided the southern segment.
opening of the South Atlantic Ocean and the into four segments separated by major FZs that The basin filling histories of the central and
separation of the South America and Africa cross the Atlantic Ocean (above). southern segments of the South Atlantic differ
plates, started about 130 Ma during the Early Adjacent to the Rio Grande FZ, the Rio from one another.15 In particular, the central seg-
Cretaceous epoch. The breakup started in the Grande Rise and the Fig8_1
Walvis Ridge originated from ment is dominated by thick salt basins that formed
south, moved progressively north and was com- the Tristan da Cunha hot spot that is responsible during the Aptian age (125 to 112 Ma), whereas
pleted about 20 to 30 million years later during for the Paraná and Etendeka flood basalts in the continental margins of the southern segment
the Aptian to Albian geologic ages.13 The central Brazil and Namibia, respectively.14 When the subsided at the margins of an open ocean.
ocean opened, the Rio Grande Rise and Walvis

46 Oilfield Review
The equatorial South Atlantic segment began the Santos basin by Petróleo Brasileiro SA, or carbonates form the reservoirs of Brazil’s Santos
to open later in the Early Cretaceous epoch— Petrobras.19 The discovery was made beneath and Campos presalt basins.
around 112 Ma.16 In its northern latitudes, this Aptian salt on the Brazilian rifted margin of the With increased aridity during the Late Aptian
segment encompasses the Demerara plateau of central South Atlantic and established the pre- (117 to 113 Ma), the basins became conducive to
Suriname and French Guiana and the Guinea pla- salt play.20 deposition of thick, 800- to 2,500-m [2,600- to
teau in West Africa. In its southern latitudes, it The presalt fields offshore Brazil are charged 8,200-ft] layered evaporite sequences. Evaporites
includes coasts of northern Brazil, Côte d’Ivoire with hydrocarbons migrating from organic-rich in the Santos basin show a history of rapid pre-
and Ghana.17 The opening of the equatorial seg- source rocks deposited within anoxic lakes that cipitation of mostly halite from marine waters,
ment, unlike the other segments, was not perpen- developed around the time the South Atlantic was followed by slow precipitation of complex salts.
dicular to the continental margins because some forming. At the start of the Aptian age, continental These later salts precipitated from highly con-
of the plate motion was taken up by oblique rifting ended and seafloor spreading began; how- centrated brines augmented by hydrothermal
movement or sideways tearing along faults.18 ever, lake, rather than marine, conditions pre- processes involving a fluid-rock chemical
Geologists’ understanding of the geologic vailed as the region was uplifted above the mantle exchange with basaltic rock. The first 600 m
events that controlled geography, climate and plume of the Tristan da Cunha hot spot. In these [2,000 ft] of these evaporites are formed by two
basin history are based on the principles of plate lakes above the rifted continental margins, massive halite layers separated by a thin anhy-
tectonics. These principles form the foundation unusual carbonates were deposited during the drite layer. The top of the evaporite sequence
for developing exploration plays. Discoveries in Early Aptian (123 to 117 Ma). Similar to the pro- shows a number of deposition cycles with potas-
the presalt and transform margin basins along cess in present-day Lake Tanganyika in East sium- and magnesium-rich layered evaporites.22
the South American and western African coasts Africa, shallow lacustrine carbonates were depos- This entire evaporite sequence precipitated in a
since 2006 illustrate these points. ited during slow deepening of the lakes. Within the deep rift lake behind the barrier created by the
Early Aptian carbonates, the fossil record shows Walvis Ridge and Rio Grande Rise. This barrier
Matching Salt Basins: From Brazil to Angola coquina strata overlain by microbialite strata as was penetrated by deep fissures along which
The Lula oil field—renamed from Tupi in 2010 to conditions changed from fresh to hypersaline marine waters traveled, interacting chemically
honor former Brazilian president Luiz Inacio water when the climate became more arid.21 These with the basaltic wall rock and leaking into the
Lula da Silva—was discovered in 2006 within evaporating lake.
12. Torsvik TH, Rousse S, Labails C and Smethurst MA: Quirk DG, Hertle M, Jeppesen JW, Raven M, Mohriak W, 20. Presalt refers to before the formation or deposition of
“A New Scheme for the Opening of the South Atlantic Kann DJ, Nørgaard M, Mendes MP, Hsu D, Howe MJ salt deposits. Presalt reservoirs are beneath salt
Ocean and the Dissection of an Aptian Salt Basin,” and Coffey B: “Rifting, Subsidence and Continental deposits that have not flowed away from their place of
Geophysical Journal International 177, no. 3 (June 2009): Break-Up Above a Mantle Plume in the Central South deposition—beneath the autochthonous, or in place,
1315–1333. Atlantic,” in Mohriak WU, Danforth A, Post PJ, salt. This definition differentiates presalt strata from
Moulin M, Aslanian D and Unternehr P: “A New Starting Brown DE, Tari GC, Nemc̆ok M and Sinha ST (eds): subsalt or postsalt strata. For more: Beasley et al,
Point for the South and Equatorial Atlantic Ocean,” Conjugate Divergent Margins. London: The Geological reference 19.
Earth-Science Reviews 98, no. 1–2 (January 2010): 1–37. Society, Special Publication 369 (in press). 21. Coquina is a limestone formed principally from shell
Blaich OA, Faleide JI and Tsikalas F: “Crustal Breakup 15. Séranne M and Anka Z: “South Atlantic Continental fragments and indicates a nearshore environment with
and Continent Ocean Transition at South Atlantic Margins of Africa: A Comparison of the Tectonic vs. vigorous wave action. Microbialites, which are
Conjugate Margins,” Journal of Geophysical Climate Interplay on the Evolution of Equatorial West carbonate structures thought to be formed by microbes,
Research 116, B01402 (January 2011): 1–38. Africa and SW Africa Margins,” Journal of African Earth have a range of shapes and sizes. They form in
Sciences 43, no. 1–3 (October 2005): 283–300. environments that are not conducive to the growth
Cartwright J, Swart R and Corner B: “Conjugate Margins
16. Moulin et al, reference 12. of corals.
of the South Atlantic: Namibia–Pelotas,” in Roberts DG
and Bally AW (eds): Regional Geology and Tectonics: 17. The Guyanas, or Guianas, is the region of northern South 22. Hardie LA: “On the Significance of Evaporites,” Annual
Phanerozoic Passive Margins, Cratonic Basins and America that includes the nations of Suriname, Guyana Review of Earth and Planetary Sciences 19 (May 1991):
Global Tectonic Maps, Vol. 1c. Amsterdam, The and French Guiana. West Africa, or western Africa, is 131–168.
Netherlands: Elsevier BV (2012): 202–221. the westernmost region of the African continent and its Jackson MPA, Cramez C and Fonck J-M: “Role of
Mohriak WU and Fainstein R: “Phanerozoic Regional southern edge extends along the northern coastline of Subaerial Volcanic Rocks and Mantle Plumes in
Geology of the Eastern Brazilian Margin,” in Roberts DG the Gulf of Guinea and includes, from east to west, Creation of South Atlantic Margins: Implications for Salt
and Bally AW (eds): Regional Geology and Tectonics: Nigeria, Togo, Benin, Ghana, Côte d’Ivoire, Liberia, Tectonics and Source Rocks,” Marine and Petroleum
Phanerozoic Passive Margins, Cratonic Basins and Sierra Leone and Guinea. Geology 17, no. 4 (April 2000): 477–498.
Global Tectonic Maps, Vol. 1c. Amsterdam, The 18. Darros de Matos RM: “Tectonic Evolution of the Nunn JA and Harris NB: “Subsurface Seepage of
Netherlands: Elsevier BV (2012): 222–283. Equatorial South Atlantic,” in Mohriak W and Talwani M Seawater Across a Barrier: A Source of Water and
13. Szatmari P: “Habitat of Petroleum Along the South (eds): Atlantic Rifts and Continental Margins. Salt to Peripheral Salt Basins,” Geological Society of
Atlantic Margins,” in Mello MR and Katz BJ (eds): Washington, DC: American Geophysical Union, America Bulletin 119, no. 9–10 (September–October 2007):
Petroleum Systems of South Atlantic Margins. Tulsa: Geophysical Monograph 115 (2000): 331–354. 1201–1217.
The American Association of Petroleum Geologists, Mascle J, Lohman P, Clift P and ODP 159 Scientific Party: Nunn JA and Harris NB: “Erratum for ‘Subsurface
AAPG Memoir 73 (2000): 69–75. “Development of a Passive Transform Margin: Côte Seepage of Seawater Across a Barrier: A Source of
14. Hot spots are surface manifestations of mantle plumes, d’Ivoire–Ghana Transform Margin—ODP Leg 159 Water and Salt to Peripheral Salt Basins,’” Geological
which are stationary thermal anomalies that produce Preliminary Results,” Geo-Marine Letters 17, no. 1 Society of America Bulletin 120, no. 1–2 (January–
thin upwelling conduits of magma within the mantle. Hot (February 1997): 4–11. February 2008): 256.
spot volcanism yields flood basalts and long linear Darros de Matos RM: “Petroleum Systems Related to
chains of volcanoes within tectonic plate interiors; along the Equatorial Transform Margin: Brazilian and West
each chain, the volcanoes become progressively older African Conjugate Basins,” in Post P, Rosen N, Olson D,
in the direction of plate movement. Palmes SL, Lyons KT and Newton GB (eds): Petroleum
Wilson M: “Magmatism and Continental Rifting Systems of Divergent Continental Margin Basins. Tulsa:
During the Opening of the South Atlantic Ocean: Gulf Coast Section, Society for Sedimentary Geology
A Consequence of Lower Cretaceous Super-Plume (2005): 807–831.
Activity?,” in Storey BC, Alabaster T and Pankhurst RJ 19. Beasley CJ, Fiduk JC, Bize E, Boyd A, Frydman M,
(eds): Magmatism and the Causes of Continental Zerilli A, Dribus JR, Moreira JLP and Pinto ACC:
Break-Up. London: The Geological Society, Special “Brazil’s Presalt Play,” Oilfield Review 22, no. 3
Publication 68 (1992): 241–255. (Autumn 2010): 28–37.

Autumn 2012 47
W E

Postsalt sediments

Salt

Presalt

Basement
2 km

20 km

>Seismic lines across conjugate presalt rifted margins. These paired seismic lines are dip lines from the Santos basin
offshore Brazil (above) and the Kwanza basin offshore Angola (next page, top). The Santos basin seismic section is from a
generic 2D seismic line crossing close to the Lula field, a presalt discovery. The seismic section shows a nearly 2-km [1.2-mi]
thickness of presalt sediments underneath the salt. The Kwanza basin section, offshore Angola, is from a 3D seismic survey
and shows a well-developed presalt section separated from postsalt sediments by complex salt geometries. (The Santos
basin section is used with permission from WesternGeco and TGS. The Kwanza basin section is used with permission from
WesternGeco and Sonangol.)

The necessary factors promoting such thick The end of the Aptian age saw the final rifted margins tilted seaward, causing halokine-
salt accumulations were a rapidly sinking margin breaching of the Walvis Ridge–Rio Grande Rise sis, in which the salt flows and deforms, giving
with balance-filled basins or lakes behind an barrier accompanied by flooding of marine rise to the salt structures that affected postsalt
elevated outer volcanic high. This volcanic high waters from the southern segment of the South sediments where large volumes of oil were found
was a leaky barrier that restricted inflow of sea- Atlantic Ocean. These open marine conditions in the Campos basin (above).25
water in an environment characterized by a allowed ocean waters to fill the basins of the cen- The Tupi discovery in 2006 opened up a new
warm, arid, desert climate (next page, bottom).23 tral segment, halting any further evaporite depo- petroleum play in the central South Atlantic, the
Conditions were somewhat similar to present-day sition. Marine sediments formed on top of the presalt play. Lula field lies in 2,126 m [6,975 ft] of
conditions in the Dead Sea basin and in the salt, starting with marine carbonates in the water in the Santos basin Block BM-S-11 about
Danakil Depression on the Afar Peninsula, north- Albian age (113 to 110 Ma). The postsalt sedi- 250 km [155 mi] southeast of Rio de Janeiro. The
east Africa.24 These layered salts form the seal for mentation was controlled by continual opening 1-RJS-628A discovery well was drilled to 4,895 m
the presalt reservoirs (See “Salt Deposition in and deepening of the South Atlantic by global [16,060 ft] TVD subsea.26 The well flowed 780 m3/d
Actively Spreading Basins,” page 50). changes of sea level. As the ocean opened, the [4,900 bbl/d] of oil and 187,000 m3/d [6.6 MMcf/d]
(continued on page 52)

23. Davison I: “Geology and Tectonics of the South Atlantic Exhibition, Rio de Janeiro, November 15–18, 2009. shortening. Salt deformation may cause deformation in
Brazilian Salt Basins,” in Ries AC, Butler RWH and Bosworth W, Huchon P and McClay K: “The Red Sea the strata deposited above it.
Graham RH (eds): Deformation of the Continental Crust: and Gulf of Aden Basins,” Journal of African Earth Hudec MR and Jackson MPA: “Terra Infirma:
The Legacy of Mike Coward. London: The Geological Sciences 43, no. 1–3 (October 2005): 334–378. Understanding Salt Tectonics,” Earth-Science
Society, Special Publication 272 (January 2007): 345–359. Reviews 82, no. 1–2 (May 2007): 1–28.
Mohriak WU and Leroy S: “Architecture of Rifted
Lakes or basins are balance filled when the rate of Continental Margins and Break-Up Evolution: Insights Quirk DG, Schødt N, Lassen B, Ings SJ, Hsu D, Hirsch KK
water and sediment input is similar to the rate that the from the South Atlantic, North Atlantic and Red Sea– and Von Nicolai C: “Salt Tectonics on Passive Margins:
accommodation space—area and depth—forms. For Gulf of Aden Conjugate Margins,” in Mohriak WU, Examples from Santos, Campos and Kwanza Basins,”
more: Carroll AR and Bohacs KM: “Stratigraphic Danforth A, Post PJ, Brown DE, Tari GC, Nemc̆ok M and in Alsop GI, Archer SG, Hartley AJ, Grant NT and
Classification of Ancient Lakes: Balancing Tectonic and Sinha ST (eds): Conjugate Divergent Margins. London: Hodgkinson R (eds): Salt Tectonics, Sediments and
Climatic Controls,” Geology 27, no. 2 (February 1999): The Geological Society, Special Publication 369, http:// Prospectivity. London: The Geological Society, Special
99–102. dx.doi.org/10.1144/SP369.17 (accessed September 17, Publication 363 (January 2012): 207–244.
24. Montaron B and Tapponnier P: “A Quantitative Model for 2012). Beasley et al, reference 19.
Salt Deposition in Actively Spreading Basins,” Search 25. Halokinesis is the deformation of salt. Halokinetic 26. Parshall J: “Presalt Propels Brazil into Oil’s Front
and Discovery Article 30117, adapted from an oral processes include downslope movement under gravity Ranks,” Journal of Petroleum Technology 62, no. 4
presentation at the AAPG International Conference and flow, expulsion and diapirism caused by overburden (April 2010): 40–44.
Fig10_1_left pageresulting from tectonic stretching or
loading and faulting

48 Oilfield Review
E
W

Postsalt sediments

Salt

Presalt

Basement
2 km

20 km

450 km
Salt basins

Tropic of
Capric
orn
Arid belt

Walvis
Ridge

Present-day Atacama Desert Present-day Kalahari Desert

> Conditions conducive for thick salt accumulations. By the Aptian, about 120 Ma, the South Atlantic Ocean (map, center) had scissored open from the
south. The central segment of the South Atlantic was isolated from the open marine conditions of the southern segment by the Walvis Ridge (purple).
The region was in an arid belt (between dashed white lines) where climate conditions were similar to those in the present-day Atacama desert, northern
Chile (bottom left), and Kalahari desert, southern Africa (bottom right ). The central segment contained balance-filled basins and lakes. Under these climatic
and isolated basin conditions, the basins and lakes became centers for precipitation of thick, layered salt sequences from basinal and hydrothermal brines,
which were fed by marine water flowing through fracturesFig10_1_right
in the leakypage
basaltic dam formed by the Walvis Ridge. (Map courtesy of CR Scotese, used
with permission.)

Autumn 2012 49
Salt Deposition in Actively Spreading Basins

Rifting, Spreading and Tectonics along the newborn plate boundary. Basaltic vol- Walvis Ridge. Rapid evaporation of seawater
The salt basins that face one another between canism and anoxic deepwater lakes—some created thick, layered evaporite deposits.
the Rio Grande Rise and the Gulf of Guinea deeper than 1,000 m [3,300 ft], similar to Lake Continuous open marine conditions were rees-
are among the largest found along Tanganyika today—punctuated the geology of tablished in the Early Albian (112 to 110 Ma).
Phanerozoic passive ocean margins (below). such rifts in the Late Hauterivian to Early
They formed during the Aptian (125 to Barremian (133 to 128 Ma).2 Evaporites in the Santos Basin
110 Ma), during the opening stages of the cen- Continental separation was completed Three conditions are required to create a
tral South Atlantic. The geometric, kinematic 128 to 125 Ma. As full seafloor spreading thick, layered salt deposit: a basin about
and temporal environment of this lower began, the rate of plate separation increased 1,500 m [4,900 ft] deep, a continuous supply of
Cretaceous salt deposition appears strikingly to a few centimeters per year. The marine mineral-laden seawater and a warm and arid
similar to that of the Mid-Late Miocene Red basin, now 1,700 km [1,060 mi] long, 300 to climate. As evaporation takes place, the basin
Sea (15 to 5 Ma).1 500 km [190 to 310 mi] wide and 2 km water level drops quickly and stabilizes to a
After the Tristan da Cunha hot spot induced [1.2 mi] deep, remained isolated between two critical level: The evaporation rate equals the
giant volcanic eruptions that covered huge large “dams” formed by the nascent equatorial water intake rate. The water salinity increases
areas of the African–South American litho- Atlantic transform margin to the north and gradually until the saturation concentration is
sphere with thick flood basalts about 143 Ma, the Walvis Ridge and Rio Grande Rise to the reached for the least soluble salt mineral con-
the plates started to separate slowly at several south. These dams restricted seawater flow tained in the water.
millimeters per year. Narrow rifts, 50 to 80 km into the basin—flow that took place mostly Layers of calcite, dolomite and gypsum pre-
[31 to 50 mi] wide, which overlapped, formed along tectonic fissures through the southern cipitate—in that order—followed by halite
(rock salt). Halite precipitates in quantities
just sufficient to maintain the water salinity at
the halite saturation level; this process can last
several thousand years to accumulate hundreds
of meters of halite. If the climate becomes wet-
ter, increased freshwater intake from rivers and
Tra
nsfo rain may reduce the salinity enough to stop
rm
ma
rgin halite precipitation. For example, salinity may
AFRICA drop back to the gypsum precipitation point
and eventually increase back to the halite pre-
cipitation point. This is the layered sequence
SOUTH AMERICA
observed in the bottom 600 m [2,000 ft] of
Aptian salt basin
Santos basin evaporites.
Water salinity levels may increase further,
until they reach the saturation point at which
Hot spot complex salts begin to precipitate. These salts
are potassium-, calcium- and magnesium-rich
evaporites such as sylvite, carnallite and
tachyhydrite. Precipitation of complex salts
requires an extremely arid climate and pre-
cipitation may take a long time because these
highly saline brines evaporate very slowly.
During this process, the lake surface level
> South Atlantic restoration. The Aptian, about 120 Ma, salt basin (purple) was 1,700 km [1,060 mi] will not change despite salt accumulating
long and restricted from open ocean conditions by the Tristan da Cunha hot spot (red circle) to its on the lake bottom. The final result is a salt
south and the embryonic equatorial Atlantic transform margin (opposing red arrows) to its north. flat (next page).
The black arrows indicate the direction of plate movement. (Map courtesy of CR Scotese, used
with permission.)

50 Oilfield Review
During the Aptian, South Atlantic salt
1 5 Basin level drops
Freshwater lakes form.
as water evaporates.
basins were located at latitudes correspond-
ing to the arid belt that contains most of the
southern hemisphere’s modern deserts. The
initial evaporation rate was probably 2 m
2 6 [7 ft] per year greater than the rainfall input,
Freshwater lakes deepen.
Ocean level falls. Salt deposition starts.
a rate currently observed in the Red Sea.4 At
an average halite deposition rate of 2 to 3 cm
[0.8 to 1.2 in.] per year, it may have taken
3 Ocean level rises, spills over barrier 7 20,000 to 30,000 years to deposit the lower-
and floods into freshwater lakes. Salt deposition ending.
most 600 m of Santos basin evaporites.5 Above
Terminal brine marks final salt deposition.
that level, there are at least nine cycles con-
taining complex salts, and these could have
Ocean level falls.
taken 10 times longer to precipitate.
4 8 Basin returns to
Fractured ridge allows hydraulic full marine conditions. Replacing water by salt doubles the weight
communication between ocean and lake.
applied to the basin floor and accelerates sub-
sidence. Approximately 30% of accommoda-
tion space is gained in about 50,000 years by
> Salt deposition sequence. During early rifting (1), freshwater lakes form on the stretching adding 500 m [1,600 ft] to the initial 1,500-m
continental margin. (The developing ocean is on the left side of each panel.) The ocean level [4,900-ft] basin depth.
drops and the lakes deepen (2) as the stretching continental margins thin and subside. The barrier
that separates the ocean from the lakes increases in relief with respect to the lake bottom. Sea Observations from modern analogs such as
level rises (3), and seawater spills over the barrier and mixes with the lake water. About 123 Ma in Lake Assal in the Afar region, Ethiopia, sug-
the Early Aptian (4), sea level falls by 50 m [80 ft] and isolates the basins from open ocean waters. gest seawater entered the salt basin through
The evaporation rate from the basins (5) is greater than the rate of water influx from rivers and fissures across the basaltic Walvis Ridge. This
rainfall and from seawater springs emanating from the leaky barrier; such leaks are the result of
fractures and fissures. The basin water level drops and water salinity gradually increases until fissural process is also based on other
the brine salinity level reaches the saturation concentration of the least soluble chemical considerations:
component in the brine, which begins to deposit as a salt mineral (white, 6). During salt • The volumetric flow rate through cracks
deposition, salt layers (not shown) form as the brine chemistry changes. Salinity and salt
must be small, as required by the salt pre-
saturation concentrations depend on the climatic water balance within the basins and the
seawater input to them through the leaky barrier. Salt mineral precipitation begins with the least cipitation model.
soluble chemical component in the brine. This component precipitates until it depletes. More • Because fissures in basalts can be up to a
soluble components precipitate later. In this way, salt layers gradually build up and fill the basins hundred meters deep, seawater flowing
to form thick layered salt sequences. The final episode of salt deposition is marked by a terminal
brine (purple, 7) of high salinity, supersaturated with the least soluble component at the time.
through fissures is less sensitive to varia-
Finally, sea level rises sufficiently to inundate the continental margins (8); open marine conditions tions in ocean water level compared to that
are reestablished above the salt basins and such marine conditions shut down salt deposition. required by flow over a dam.
• When the evaporation rate increases and
the basin level drops below the ocean level,
the hydraulic-head difference will tend to
promote flow through the fissures to main-
tain the basin’s water level.
1. Mohriak WU and Leroy S: “Architecture of Rifted Montaron B and Tapponnier P: “A Quantitative Model
Continental Margins and Break-Up Evolution: Insights for Salt Deposition in Actively Spreading Basins,” • The fractures provide a large contact sur-
from the South Atlantic, North Atlantic and RedSide
Sea– Bar, Fig3_4
Search and Discovery Article 30117, adapted from an face between seawater and basalts, which
Gulf of Aden Conjugate Margins,” in Mohriak WU, oral presentation at the AAPG International
Danforth A, Post PJ, Brown DE, Tari GC, Nemc̆ok M Conference and Exhibition, Rio de Janeiro, favors the rock-to-fluid chemical exchange
and Sinha ST (eds): Conjugate Divergent Margins. November 15–18, 2009. required for a chemical composition that is
London: The Geological Society, Special Publication 3. Montaron and Tapponnier, reference 2.
369, http://dx.doi.org/10.1144/SP369.17 (accessed compatible with complex salt deposition.6
4. Hardie LA: “The Roles of Rifting and Hydrothermal
September 17, 2012).
CaCl2 Brines in the Origin of Potash Evaporites: An Field observations and model results dem-
Bosworth W, Huchon P and McClay K: “The Red Sea Hypothesis,” American Journal of Science 290, no. 1 onstrate that the deposition of thick, layered
and Gulf of Aden Basins,” Journal of African Earth (January 1990): 43–106.
Sciences 43, no. 1–3 (October 2005): 334–378. evaporitic sequences requires a deep basin in
Hardie LA: “On the Significance of Evaporites,”
2. Karner GD and Gambôa LAP: “Timing and Origin of the Annual Review of Earth and Planetary Sciences 19 a hot and arid climate with a continuous sup-
South Atlantic Pre-Salt Sag Basins and Their Capping (May 1991): 131–168.
Evaporates,” in Schreiber BC, Lugli S and Ba˛bel M ply of mineral-laden saltwater. These condi-
Warren JK: Evaporites: Sediments, Resources and
(eds): Evaporites Through Space and Time. London:
Hydrocarbons. Berlin: Springer-Verlag, 2006. tions must remain stable long enough for
The Geological Society, Special Publication 285
(January 2007): 15–35. 5. Montaron and Tapponnier, reference 2. thick deposits to accumulate.
6. Montaron and Tapponnier, reference 2.

Autumn 2012 51
of gas on a 5/8-in. choke, producing light oil with a In 2012, the Azul-1 well by Maersk Oil and was in 1,682 m [5,518 ft] of water in Kwanza
density of about 880 kg/m3 [30° API gravity] and then the Cameia-1 well by Cobalt International basin Block 21; the well was drilled to 4,886 m
a low sulfur content of about 0.5%.27 Development Energy, Inc., extended the proven presalt play [16,030 ft] and flowed 5,010 bbl/d [800 m3/d] of
drilling in the field confirmed the operator’s esti- across the South Atlantic to the Kwanza basin, oil and 14.3 MMcf/d [405,000 m3/d] of gas.
mates of up to 1,000 million m3 [6.5 billion bbl] of offshore Angola.29 The Azul-1 well was in 953 m In the process leading up to the Cameia-1
recoverable oil, thus drawing worldwide atten- [3,130 ft] of water in Kwanza basin Block 23; the discovery, exploration experts at Cobalt
tion to Brazil’s presalt play.28 Many subsequent well was drilled to 5,334 m [17,500 ft] and dem- International Energy recognized that during the
presalt discoveries have been made in the Santos onstrated potential flow capacity of greater than Aptian age, the present-day Kwanza and Campos
and Campos basins of Brazil. 3,000 bbl/d [480 m3/d] of oil. The Cameia-1 well presalt basins were in the same depositional
basin, separated by only 80 to 160 km [50 to
100 mi]; explorationists concluded the basins
must have shared the same presalt history and
have similar characteristics.30 The presalt play
A FR I CA
that led to the Tupi discovery in the Brazilian
Santos basin was extended north along the
Angola
20 Brazilian coastline to the Campos basin. Cobalt
drilled the Cameia-1 well to hunt for a Campos
21
basin presalt play analog across the Atlantic
Ocean in the Kwanza basin offshore Angola. The
Lontra Idared Mavinga Cameia-1 Cameia-2 Bicuar
Cameia-1 oil discovery well drilled into a reser-
voir that contained high-quality, highly perme-
able and fractured carbonates in postrift and
presalt strata atop a basement high and was
sealed by salt. The well encountered an oil col-
umn that was about 370 m [1,200 ft] thick and
Postsalt Postsalt
Salt contained more than 270 m [900 ft] of net pay.31
Salt
To appraise the discovery, Cobalt drilled the
Postrift Postrift
Synrift Synrift Cameia-2 well and confirmed the vertical and lat-
Synrift Basement
eral extent, geometry and quality of the reservoir
(left). The appraisal well validated the Cobalt
Block 20 Block 21 model of additional reservoirs within the postrift
North South
and synrift strata beneath the original discovery
Oil confirmed by production Cameia-1 Cameia-2 and indicated the reservoirs were separated by
Oil confirmed by log or oil sample
seals. Cobalt is conducting ongoing testing to
determine reservoir potential—the number of
Untested possible oil zone
reservoirs and seals, how the fluids vary between
Seal Postsalt the reservoirs, the reservoir properties and the
depths to the oil/water contacts.32
Salt Superpay reservoir
Salt Matching Turbidite Sequences:
Middle reservoir
From Ghana to French Guiana
Postrift The West Cape Three Points partnership discov-
Postrift Lower reservoir
ered the Jubilee oil field offshore Ghana in June
Postrift Postrift 2007. The partnership comprises Kosmos Energy
Basement Ltd., Tullow Oil plc, Anadarko Petroleum
Synrift
Synrift Corporation, Sabre Oil & Gas, Inc., Ghana
National Petroleum Company and EO Group Ltd.
> Kwanza basin presalt prospects and discoveries. The Cobalt Cameia-1 and Cameia-2 wells The Mahogany-1 discovery well encountered 90 m
discovered and appraised, respectively, oil reservoirs in the synrift (light brown) and postrift (yellow) [300 ft] of high-quality pay in an upper Cretaceous
sedimentary basins under the autochthonous salt (purple)—the presalt sediments—in Block 21 turbidite reservoir confined by a combination
(center right), Kwanza basin offshore Angola. Cobalt plans to drill the Lontra, Idared, Mavinga and structural-stratigraphic trap.33 In August 2007, the
Bicuar wells (dashed lines) to test other prospects in Blocks 20 and 21. The Cameia-1 well discovered Hyedua-1 well, located 5.3 km [3.3 mi] southwest
a superpay reservoir (bright green) atop a basement high (bottom). Cobalt drilled the Cameia-2 well,
a step-out well, to confirm the size of the discovery and to explore prospective reservoir zones below of the Mahogany-1 discovery, encountered 41 m
the superpay reservoir. The appraisal well confirmed the discovery and underlying reservoir intervals [130 ft] of high-quality reservoir in equivalent tur-
(light green), which are separated by sealing intervals (red). (Illustrations used with permission from bidite sandstones. These wells opened up a deep-
Cobalt International Energy, Inc., reference 32.)

52 Oilfield Review
15˚W 10˚W 5˚W 0˚ 5˚E 15˚W 10˚W 5˚W 0˚ 5˚E
Senegal basin AFRICA Senegal basin A FR I C A
Benue Benue
Ocean Ocean Volta
10˚N Bové basin trough Bové basin trough
Volta Benin and 10˚N basin Benin and
basin Keta basins Keta basins
Ivory Coast
Ivory Coast
basin
basin
5˚N 5˚N

~
Para-Maranhao
~
Para-Maranhao basin
basin
0 500 km 0 500 km
0 310 mi SOUTH AM E RICA Early Cretaceous, 125 Ma 0 310 mi S O U TH A M ER IC A Late Albian, 100 Ma

15˚W 10˚W 5˚W 0˚ 5˚E 15˚W 10˚W 5˚W 0˚ 5˚E


Senegal basin AFRICA Senegal basin A FR I C A
Benue Benue
Ocean Ocean Bové basin Volta trough
10˚N Bové basin Volta trough 10˚N Benin and
Benin and basin
basin Keta basins Keta basins
Ivory Coast Ivory Coast
basin basin
5˚N 5˚N

~
Para-Maranhao ~
Para-Maranhao Ocean
SOUTH AMERICA
basin basin SOUTH AMERICA

0 500 km 0 500 km
0 310 mi Late Aptian to Early Albian, 110 Ma 0 310 mi Late Santonian to Early Campanian, 85 Ma

Thick continental crust Transform fault zones Zaedyus discovery,


West African shield
and extension Guyane Maritime, French Guiana
Brazilian shield Present-day 2,000-m [6,560-ft] isobath
Onshore Mesozoic to Cenozoic Divergent basins, thinned Direction of crustal extension Jubilee discovery,
coastal basins continental crust and thick clastics Tano basin, Ghana
> Opening of the equatorial Atlantic Ocean. Rifting between northern South America and southern West Africa started during the Early Cretaceous about
125 Ma (top left). Small basins opened when continental crust stretched, thinned and faulted. These basins filled with sediment from the eroding continental
uplands and were deformed along the transform fault zones. During the Late Aptian to Early Albian, about 110 Ma (bottom left), oceanic spreading and
accretion began. Ocean floors grew as the plates were separating during the Late Albian, about 100 Ma (top right). By Late Santonian to Early Campanian,
about 85 Ma (bottom right), the continental separation was complete. The seafloor spreading and passive margin phase began and the steep transform
margins subsided thermally and were cut, loaded and blanketed by river and delta sediments from the continents while South America and Africa continued
to separate. (Adapted from Brownfield ME and Charpentier RR: “Geology and Total Petroleum Systems of the Gulf of Guinea Province of West Africa,“
Reston, Virginia, USA: US Geological Survey Bulletin 2207-C, 2006.)

water play targeting reservoirs in Late Cretaceous 27. “BG, Petrobras Announce Discovery of Oil Field in 31. Cobalt International Energy, Inc.: “Investor
turbidites along the equatorial African transform Santos Basin Offshore Brazil,” Drilling Contractor 62, Presentation—March 2012,” (March 13, 2012),
no. 6 (November–December 2006): 8. http://phx.corporate-ir.net/phoenix.zhtml?c=231838&p=
margin, which stretches from northern Sierra irol-presentations (accessed June 8, 2012).
28. “Country Analysis Briefs: Brazil,” US Energy Information
Leone east to southern Gabon in the equatorial Administration (February 28, 2012), http://www.eia.gov/ 32. “Multiple Catalysts To Grow Shareholder Value,” Cobalt
segment of the South Atlantic Ocean. countries/cab.cfm?fips=BR (accessed August 29, 2012). International Energy, Inc. (September 19, 2012), http://
29. “Maersk Oil Strikes Oil with Its First Pre-Salt Well in phx.corporate-ir.net/External.File?item=UGFyZW50SUQ9
Deepwater turbidite fields discovered off- Angola,” Maersk Oil (January 4, 2012), http://www. NDgwMTA3fENoaWxkSUQ9NTEzNzk4fFR5cGU9MQ==
shore Ghana are charged with hydrocarbons maerskoil.com/Media/NewsAndPress &t=1 (accessed September 20, 2012).
Releases/Pages/MaerskOilstrikesoilwithitsfirst 33. A turbidite is a rock deposited from a turbidity flow,
sourced from organic-rich sediments that rap- pre-saltwellinAngola.aspx (accessed March 29, 2012). which is an underwater current of sediment-laden water
idly filled deep, active pull-apart basins during Fig12_1
“Cobalt International Energy, Inc. Announces Successful that moves rapidly down a slope. The gravity, or density,
Pre-Salt Flow Test Offshore Angola,” Cobalt current moves downslope because its density is higher
the Early Cretaceous epoch (above). These than that of the surrounding water.
International Energy, Inc. (February 9, 2012),
basins formed on rifted continental crust http://ir.cobaltintl.com/phoenix.zhtml?c=231838&p= Dailly P, Henderson T, Hudgens E, Kanschat K and
between transform faults. During the Albian age, irol-newsArticle&ID=1659328&highlight (accessed April Lowry P: “Exploration for Cretaceous Stratigraphic Traps
4, 2012). in the Gulf of Guinea, West Africa and the Discovery of
the continents split and seafloor spreading 30. Cobalt International Energy, Inc.: “Update on West Africa the Jubilee Field: A Play Opening Discovery in the Tano
began. Oblique motion between the two margins and Gulf of Mexico Drilling Programs,” (February 8, Basin, Offshore Ghana,” in Mohriak WU, Danforth A,
2012), http://phx.corporate-ir.net/External.File?item= Post PJ, Brown DE, Tari GC, Nemc̆ok M and Sinha ST
is recorded by transform faults and fracture UGFyZW50SUQ9MTI1NzQyfENoaWxkSUQ9LTF8VHlwZT0 (eds): Conjugate Divergent Margins. London: The
z&t=1 (accessed August 2, 2012). Geological Society, Special Publication 369, http://dx.doi.
org/10.1144/SP369.12 (accessed August 7, 2012).
Dribus JR: “Integrating New Seismic Technology and
Regional Basin Geology Now a Must,” Journal of
Petroleum Technology 64, no. 10 (October 2012): 84–87.

Autumn 2012 53
SW Offset, km NE
0 330 340 350 360 370 380 390 400

Demerara Plateau

Marginal
ridge

Continental
slope Suriname–French Guiana
abyssal plain

> Conjugate transform margins. These seismic lines cross the Suriname–French Guiana (above) and Côte d’Ivoire–Ghana (next
page, top) transform margins; the red dots on the globes are the locations of these seismic sections. The red lines mark the
approximate position of the Demerara Fracture Zone (FZ) and the Romanche FZ, on the left and right, respectively. Transform
margins are characterized by shallow dipping, often narrow, continental margins, bordered by marginal ridges that backstop
steep continental slopes across abrupt continent-ocean boundaries leading to oceanic abyssal plains. Explorers are targeting
reservoirs located in abyssal plain sediments in upper Cretaceous turbidites that lie on top of lower Cretaceous organic-rich
source rocks. The green dots mark the approximate stratigraphic position of these upper Cretaceous reservoirs. These
Cretaceous source and reservoir rocks are sealed and buried under marine shales. On the Côte d’Ivoire–Ghana seismic line,
the labels A through F represent stratigraphic units identified from seismic data. [Adapted from Greenroyd CJ, Peirce C, Rodger M,
Watts AB and Hobbs RW: “Demerara Plateau—The Structure and Evolution of a Transform Passive Margin,” Geophysical Journal
International 172, no. 2 (February 2008): 549–564.]

zones, and subsidence and sediment deposition buried beneath thousands of meters of younger dite play concept and subsequent drilling
occurred during rifting and subsequent sag of sediment. During the Late Cretaceous epoch, the revealed that Jubilee is part of a collection of
the margins (above). movement of the tectonic plates changed direc- fields offshore Ghana that includes Tweneboa,
The opening and deepening of the equatorial tion, causing deformation of the rifted margin Enyenra and Ntomme.
South Atlantic and the global rise and fall of sea and the formation of structures that helped form Similar Late Cretaceous turbidite reservoirs
level controlled sedimentation after continental traps, and oil started migrating updip toward the occur along the entire equatorial African coast,
breakup. Erosion of the continent led to deposi- coast (next page, bottom right).34 which have led to additional oil discoveries such
tion of sediments in deltas on the continental The partnership drilled the Mahogany-1 well as the Akasa and Teak fields offshore Ghana, the
margins. When sea level fell—a lowstand—the to reservoir rock in a Turonian-stage stack of low- Paon field offshore Côte d’Ivoire and the Venus,
rivers cut through their deltas and carried sedi- stand turbidite sands on the SW flank of the Mercury and Jupiter fields offshore Sierra Leone.
ments, often in sediment avalanches known as South Tano ridge.35 The reservoir was Tullow Oil sought to project the Jubilee play
turbidity currents, onto the steep continental 3,530 to 3,760 m [11,600 to 12,300 ft] below the to the transform margin of South America and
slopes and toward the deep abyssal plain. Sands seafloor. A drillstem test demonstrated that the duplicate the company’s deepwater success.36
that were deposited as these turbidity currents well was capable of flowing oil at 20,000 bbl/d Exploration experts at Tullow Oil used the prin-
slowed may have formed reservoirs for deepwater [3,200 m3/d]. The oil was sourced from Early ciples of plate tectonics, followed the major frac-
oil fields such as those of the upper Cretaceous Cretaceous rift-related organic-rich shales. The ture zones across the equatorial Atlantic and
series in the Jubilee field. Subsequent deposition Jubilee well proved the Late Cretaceous turbi- identified basins offshore South America that
of muds sealed these reservoirs as they were displayed similar elements of the Jubilee play.

Fig13_1_left page
54 Oilfield Review
S Offset, km N
90 80 70 60 50 40 30 20

Marginal Deep Ivorian basin


ridge

F
E
D
Continental
slope
C
A B

Gulf of Guinea
abyssal plain

Shelf and
delta
Midfan
Canyon fed by active Inner fan channelized
nearshore littoral drift channels lobes
or relict shelf sands Barrier bar

Sandy coastal Longshore


plain drift Slump
scar
Inner fan
They found evidence for an upper Cretaceous Midfan channelized and
unchannelized sands
series of lowstand turbidite channels and fans 500 to 2,000 m
deposited during seafloor spreading and buried [1,640 to 6,562 ft]
Coastal Slump
scar Outer fan
under a thick sequence of marine shales. They plain
Continental
inferred the presence of Cretaceous source rocks shelf
and stratigraphic traps, buried and sealed by the Slump
Slope
apron Basin plain
marine shales. This led the exploration teams to
focus on the continental slope off the Guyana Slumps
10 to 50 km
34. Antobreh AA, Faleide JI, Tsikalas F and Planke S: 6.2 to 31 mi
“Rift–Shear Architecture and Tectonic Development of
the Ghana Margin Deduced from Multichannel Seismic Basin plain
Reflection and Potential Field Data,” Marine and
Petroleum Geology 26, no. 3 (March 2009): 345–368.
35. Dailly et al, reference 33.
36. Patel T: “Did the Continental Drift Create an Oil
Bonanza?: Tullow Oil Bets Huge Fields Are ‘Mirrored’
Across the Atlantic,” Bloomberg Businessweek > Reservoirs in Late Cretaceous turbidites. Explorationists looked for canyons feeding reservoir rocks in
(February 24, 2011), http://www.businessweek.com/
magazine/content/11_10/b4218020773519.htm channel-levee and turbidite fan deposits on the basin floor that originated from the Guyana Continental
(accessed August 20, 2012). Shelf and slope. These reservoir rocks are sourced and charged by Early Cretaceous organic-rich
shales that were deposited during continental rifting. Since their deposition, these reservoir rocks have
been buried and sealed by marine shales (not shown). Expected well log responses are plotted for the
five types of deposits (boxed red areas between black curves); the left curve is spontaneous potential
or gamma ray, and the right curve is resistivity. (Illustration used with permission from Tullow Oil plc.)

egap thgir_1_31giF
Autumn 2012 55
Shelf and east of the Demerara Plateau offshore Tullow Oil started operations in March 2011, Learning from Success
French Guiana (below).37 drilling near the toe of the continental slope in The recent history of oil discovery along the
Tullow Oil and partners acquired 2,500 km2 2,048 m [6,719 ft] of water. By September 2011, South Atlantic margins has been one of learning
[970 mi2] of high-quality 3D marine seismic the company announced the discovery of 72 m from success. Pioneering explorationists studied
data over the steep continental slope offshore [240 ft] of net oil pay within two turbidite fans.40 the large discoveries of the Lula reservoir in the
French Guiana.38 Explorers at Tullow Oil used Wireline logs and samples of reservoir fluids Santos basin, offshore Brazil, and the Jubilee
these data to look for submarine canyons and showed good quality reservoir sands at a reser- reservoir, offshore Ghana, and stepped along the
turbidite deposits on the basin floor that origi- voir depth of 5,711 m [18,740 ft]. The Zaedyus same margin to look across the ocean where con-
nated from the Guyana Continental Shelf and exploration well proved that the Jubilee play— jugate margins hosted similar large discoveries.
slope. These seismic data showed features simi- developed for the transform margin offshore Explorationists used the principles of plate
lar to those observed in 3D seismic data over the Ghana and applied successfully elsewhere along tectonics to leverage their accomplishments.
Jubilee field offshore Ghana. The exploration the equatorial African margin—was also appli- When a continent splits and a new spreading
team identified and mapped a number of pros- cable to the transform margin offshore French center opens up, plate tectonic concepts pro-
pects (next page). After follow-up regional Guiana and probably elsewhere along the trans- vide the basis for hypothesizing which series of
investigations, the Tullow Oil team decided to form margin of northern South America. tectonic and stratigraphic events will occur.
test the play by drilling a well at the GM-ES-1 Armed with the principles of plate tectonics and
location within the Zaedyus prospect, in the astute observations from exploration plays that
Guyane Maritime license, which is about 150 km have led to successful discoveries, exploration-
[93 mi] offshore.39 ists have extrapolated plays into new leads,

Oil discovery
Gas condensate and oil discovery
Prospect
Dry hole
Oil shows

Deepwater West Cape


Tano block Three Points block

WEST AFRICA

Sierra
Oceanic transform fract ure zone Leone

Côte d’Ivoire
Jubilee discovery
Lib

Guyana Ghana
er

0 25 km
margin
ia

Suriname French Equato rial Atlantic transform 0 16 mi


Guiana

n e
Oceanic transform fracture zo

SOUTH AMERICA

Guyane Discovery
Maritime Prospect
0 600 km Mid-Atlantic Ridge
license Lead
0 370 mi

Atlantic Ocean

Zaedyus discovery > Extending West African success across to South America. Tullow Oil plc used plate tectonic
concepts to develop an exploration program to extend the Jubilee play (black star) proved along
the West Africa transform margin to the northern South America transform margin. The transform
margins (gray shading) on the west and east sides of the Equatorial Atlantic have similar geology.
0 100 km
Explorationists had recognized Late Cretaceous stratigraphic traps within the Guyana-Suriname basin
0 62 mi that were analogous to those proved by the Jubilee and similar discoveries in West Africa. Tullow
explorationists made the Zaedyus discovery in the Guyane Maritime license, offshore French Guiana
(red star). (Illustration adapted with permission from Tullow Oil plc.)

56 Oilfield Review
Seismic horizon relationship
View angle
Structural high Turbidite feeder canyon
Late Cretaceous
horizon

Early Cretaceous
horizon

Fan systems Channel

Major turbidite fan Channels Discovery


Guyane
Maritime Prospect
license Lead

Atlantic Ocean

Zaedyus discovery

0 100 km
0 62 mi

> Jubilee analogs offshore French Guiana. Tullow Oil plc acquired 2,500 km2 [970 mi2] of 3D seismic data in 2009 (red box in map inset). The depth-based
seismic interpretation image (top), viewed from above and the northeast, shows an Early Cretaceous horizon (color-coded in red to blue from shallow to
deep) overlain by a Late Cretaceous horizon (brown to yellow) intersecting at the steep continental slope formed by the transform margin. The data
revealed features similar to those observed in the Tano–West Cape Three Points area, offshore Ghana. These features include a turbidite feeder canyon
and structural high that focus sediments into channels and fan systems that are prospects for reservoirs. The close-up view of the area (bottom) shows
channels and turbidite fans imaged by the 3D seismic data. (Images used with permission from Tullow Oil plc.)

37. Plunkett J: “French Guiana—A New Oil Province,” prospects and drilling targets both regionally rift basin of Kenya, the Levant basin offshore
presented at the Kayenn Mining Symposium, Cayenne, and globally. Israel and Cyprus and the Mozambique basin off-
French Guiana, December 1–3, 2011.
38. The partnership was a joint venture between Tullow Oil Understanding plate tectonics also allows shore Tanzania have been similarly impressive.
plc—the operator—Royal Dutch Shell, Total and explorationists to take what they learn from one Plate tectonic concepts and models, and their
Northpet, a company owned 50% by Northern Petroleum
plc and 50% by Wessex Exploration plc. Royal Dutch play and ask, “What if?” If hydrocarbons are found ability to engender reasoned hypotheses for new
Shell formally took over as operator of the Guyane in an immature rift margin setting, could one find plays, are powerful exploration tools for hitherto
Maritime license on February 1, 2012.
the same in a mature rift margin or a transform undeveloped basins. They are also cause for
39. Plunkett, reference 37.
40. “Zaedyus Exploration Well Makes Oil Discovery margin setting? In recent years, exploration com- reexamining basins that have been explored
Offshore French Guiana,” Tullow Oil plc (September 9, panies have answered these questions affirma- but deemed either hydrocarbon poor or too risky
2011), http://www.tullowoil.com/index.asp?pageid=
137&newsid=710 (accessed August 10, 2012).
Fig16_2
tively through discovery wells. Recent discoveries to develop. —RCNH
in the Albert rift basin of Uganda, the East Africa

Autumn 2012 57
Contributors

Chris Avant is the Schlumberger Oilfield Services technical team leader for Equatorial Guinea and later Roberto Fainstein is a Geophysics Advisor to
Account Manager for Chevron in Bangkok, Thailand. as regional exploration manager in the deepwater Gulf Schlumberger in the Dhahran Carbonate Research
He manages all contracts and business development of Mexico. Paul holds a BSc degree in geology from Center, Al-Khobar, Saudi Arabia. Beginning in 1995
with Chevron Thailand, a position he has held since Edinburgh University, Scotland, and a DPhil degree in when he joined Schlumberger, he designed the multi-
2011. He began his career with Dowell Schlumberger geology from the University of Oxford, England. client seismic libraries offshore Southeast Asia and
in 1999 and has held a number of positions with the Supamittra Danpanich is Vice President, Petroleum offshore Brazil; recently, he was the UniQ* land seis-
company in Canada, Indonesia, Mexico and the US, Development, Arthit Asset, PTT Exploration and mic system project coordinator and is currently
acquiring expertise in cementing, coiled tubing and Production Public Company Limited (PTTEP). She involved in the interpretation of complex salt tectonics
wireline operations. Chris received a BS degree in began her career in 1987 as a geologist in airborne in the Red Sea. He has worked for Petrobras as chief
petroleum engineering from the University of Alberta, projects for the Thailand Department of Mineral geophysicist for the first comprehensive survey off-
Edmonton, Canada. Resources and then worked for Unocal Thailand, Ltd, shore South America, was on the oceanography and
Bijaya K. Behera is a Professor at the School of until 1995. She next worked as senior geologist for ocean engineering faculty at the Florida Institute of
Petroleum Technology in Pandit Deendayal Thai Shell Exploration and Production Company Ltd. Technology, Melbourne, USA, and was a senior staff
Petroleum University, Gandhinagar, Gujarat, India. During that time, she published articles on enhanced geophysicist and manager of exploration teams for
Previously, he was the deputy general manager (geo- oil recovery and reservoir karstification. In 2004, she Atlantic Richfield Company. Roberto holds a PhD
sciences) with Gujarat State Petroleum Corporation joined PTTEP as chief geologist and then worked in degree in geology from Rice University, Houston.
(GSPC) Ltd where he was responsible for exploration Vietnam as deputy subsurface manager until 2011 Nick Harvey is the 3D Modeling Team Leader at
and development projects in the Krishna-Godavari when she assumed her current position; she is Neftex, Abingdon, England. After joining Neftex in
offshore HPHT field. He has 18 years of experience in based in Bangkok, Thailand. Supamittra received 2008, he built a sequence stratigraphic framework of
the oil and gas industry and prior to GSPC, he worked a BSc degree in geology from Chulalongkorn the South and Central American regions. His subse-
for Schlumberger, Fugro Group of Companies, University, Bangkok. quent projects have focused on the origin of the
Geosoft Infotech LLC, Tata Petrodyne and Jubilant Saifon Daungkaew is a Schlumberger Principal Caribbean Plate, the sedimentary evolution of the Gulf
Oil and Gas Pvt Ltd. Bijaya earned a doctorate degree Reservoir Engineer and Reservoir Domain Champion of Mexico and integrated approaches to regional geo-
in geology from the Indian Institute of Technology, for Thailand and Myanmar; she is based in Bangkok, logical studies. Nick studied geology and oceanography
Mumbai, India. Thailand. Prior to taking this position in 2009, she was at the University of Southampton, England, and
Ian Bryant is a Senior Geoscience Advisor and also a senior reservoir engineer and reservoir domain received a master’s degree in micropaleontology from
Worldwide Métier Manager for Technical Consulting champion for Malaysia, Brunei and the Philippines. University College London.
for Schlumberger Information Solutions in Houston. Saifon has a BS degree in chemical engineering from Greg Heath is a Petrophysicist and Operations
Before moving to this position, he managed the the Prince of Songkla University, Thailand, and MS and Geologist for Chevron Thailand Exploration and
Schlumberger Integrated Services for Exploration doctorate degrees in petroleum engineering from the Production Ltd in Bangkok, Thailand, and has worked
group and held a variety of research, marketing and Imperial College London. as a consulting petrophysicist in Thailand since 1997.
business development positions. He began his career Ilaria De Santo, based in Aberdeen, is a Principal He began his career in 1978 with Exlog North Sea Ltd
in 1984 with Shell, first as a reservoir geologist at the Reservoir Engineer and a Reservoir Domain Champion in the UK and Norwegian North Sea before moving to
Exploration and Production Laboratory, in Rijswijk, for Schlumberger Wireline in the North Sea. She Baker Hughes in 1980, with positions in Canada, the
the Netherlands, and then as a geologist working in joined Schlumberger in 1998 and has worked in soft- US, Senegal and Ghana. Greg was an independent
exploration, appraisal and development in New ware support, marketing and reservoir engineering in wellsite geologist for Décollement Consulting Inc. from
Zealand. Ian has a BS degree in physical geography Italy, France, Algeria, Nigeria and the UK. She special- 1985 to 1997 and has a BSc degree (Hons) in geology
with geology and a PhD degree in sedimentology from izes in advanced application of downhole fluid analysis from the University of Portsmouth, England.
the University of Reading, England. and its integration with pressure surveys, vertical Nora Herbst, based in Houston, is a Geology
Evgeny Chekhonin is a Schlumberger Senior Research interference tests and interval pressure transient Interpretation and Inversion Team Leader for
Scientist in Moscow. He works in the thermal measure- tests. Ilaria obtained an MS degree in geology from the Schlumberger. Nora, who has 20 years of exploration
ments and interpretation program with a focus on opti- University of Pavia, Italy, and an MS degree in petro- experience in the oil industry, joined WesternGeco in
cal scanning technology and theoretical support of leum engineering from Heriot-Watt University, 2007. Prior to that, she worked for Repsol YPF in
thermal property measurement. Evgeny received a mas- Edinburgh, Scotland. Argentina and Spain and as a consultant for various
ter’s degree in applied mathematics and a doctorate John R. Dribus, a Global Geology Advisor for operating companies in Argentina. She focuses on the
degree in mathematics and computer science from Schlumberger, is responsible for deepwater basins geology of passive margin basins, mainly in deep- and
Gubkin Russian State University of Oil and Gas, Moscow. along the Atlantic Margin; the Gulf of Mexico; the ultradeepwater offshore western Africa, East Africa
Mikhail V. Chertenkov is the Head of the Field Black, Red and Mediterranean seas; and eastern and in Libya and works on seismic interpretation and
Development Technologies Department for Lukoil in Africa. Based in New Orleans, he is a reservoir geolo- depth imaging in salt tectonic basins. She has been a
Moscow. His areas of interest are the enhancement of gist with more than 30 years of experience in the Gulf company portfolio manager and developed play con-
heavy-oil fields and new field development technologies. of Mexico. His assignments have spanned all aspects of cepts and risk analysis. Nora earned a degree in geol-
Mikhail obtained a degree in reservoir geology and exploration, exploitation and production geology for ogy from the Universidad Nacional de Tucumán, San
exploration from Tomsk Polytechnic University, Russia. Schlumberger and for a major oil and gas company, Miguel de Tucumán, Argentina.
Paul Dailly is Senior Vice President for Exploration including more than 15 years working in the deepwa- Zuber A. Khan began his career with Geoservices as a
and a founding partner of Kosmos Energy Ltd in ter Gulf of Mexico and five years as a uranium field mudlogging geologist, monitoring more than 200 wells
Dallas. He led the technical team that discovered the geologist. His areas of expertise are petroleum systems for various multinational E&P operators. Currently a
Jubilee play offshore Ghana, currently coordinates the analysis, deepwater exploration and analogs, geologic Senior Geology Manager with Gujarat State Petroleum
Kosmos exploration portfolio and manages the transi- risk analysis and geoscience training and develop- Corporation Ltd in Gandhinagar, Gujarat, India, he
tion of the company’s Ghanaian discoveries from ment. John serves on the advisory committee of the joined the company in 2000 as an operations geologist
appraisal to development. Before joining Kosmos in Delta Chapter of the API and is a member of the focused on the Krishna-Godavari offshore HPHT field.
2004, he spent 15 years as an exploration geologist, AAPG Imperial Barrel Award Committee. He received Zuber earned a BS degree (Hons), an MS degree in geo-
including positions with BP and Triton Energy. After BS and MS degrees in geology from Kent State sciences and a PG diploma in hydrogeology, all from
the sale of Triton to Hess Corporation, he served as the University, Ohio, USA. Aligarh Muslim University, Aligarh, Uttar Pradesh, India.

58 Oilfield Review
Waranon Laprabang has been Senior Vice President, ging in low-rate horizontal wells and formation satura- Paul Sims is the South and East Africa Operations
Arthit Asset, PTT Exploration and Production Public tion monitoring in freshwater environments. Anton Manager of Testing Services for Schlumberger in Dar
Company Limited (PTTEP) since 2011. He began his has BS and MS degrees in physics and a doctorate es Salaam, Tanzania. Prior to his current position, he
career in 1980 as geologist for the Thailand degree in petroleum engineering, all from Bashkir was the product champion for Testing Services in
Department of Mineral Resources and Italian-Thai State University, Ufa, Russia. Clamart, France, where he was responsible for new
Development plc, Thailand. After working for Dimitri Pissarenko, based in Moscow, has been the product development and the introduction of surface
Geoservices Eastern, Inc. in South and Southeast Asia, Schlumberger Moscow Research Director since 2007. testing and memory gauge technology. He joined
he joined PTTEP as senior geologist and worked in He focuses on the development of partnerships with Schlumberger in 2004 as a field engineer in Australia
several exploration and new ventures. In Oman, as an Russian academia and research institutions. Dimitri and then became a field service manager there; he
asset manager, he was responsible for oil, gas and con- earned a higher national diploma in electronic engi- next worked as a location manager for East Malaysia,
densate field discoveries and for setting up production neering from the Moscow Power Engineering Institute, Brunei and the Philippines. Paul obtained bachelor’s
processing facilities and pipelines; he was also Russia, and a doctorate degree in geophysics from the degrees in petroleum engineering and finance, both
involved in forming the first gas sale agreement Institut de Physique du Globe de Paris, France. from the University of Western Australia in Perth.
between PTTEP and the Omani government. In 2005, Miroslav Slapal, who is based in Moscow, is the Sales
he returned to Thailand as PTTEP vice president of Yury Popov is a Scientific Advisor at the Schlumberger
Moscow Research Center. He manages the development and Marketing Manager for Schlumberger Wireline
domestic and Malaysia-Thailand Joint Development Russia and Central Asia. He joined Schlumberger in
Area, Joint Venture Assets. Waranon has a bachelor’s of advanced experimental methods in thermal petro-
physics and their implementation in the oil and gas 1994 as a field engineer and had assignments in the
of science degree in geology from Chiang Mai North Sea, West Africa and Russia. During his most
University, Thailand. industry. He is the author of more than 200 publications
and holder of more than 40 patents. Prior to joining recent assignment in Houston as reservoir sampling
Angus McCoss is Exploration Director for Tullow Oil Schlumberger, he was the head of the department of and pressure product champion, he was involved in
plc in London. Before joining Tullow in 2006 as general technical physics and rock physics and was the scien- the development and definition of future
manager of exploration, he had 21 years of exploration tific leader of the research laboratory of geothermic Schlumberger HPHT technologies for reservoir pres-
experience, primarily with Shell in Africa, Europe, problems at Russian State Geological Prospecting sure and sampling. Miroslav has an MS degree in
China, South America and the Middle East. He held a University, Moscow. Yury obtained a PhD degree from petroleum engineering from the Technical University
number of Shell senior positions including Americas the Russian Technological Institute and a doctorate of Ostrava, Czech Republic.
regional vice president of exploration and general degree in physics and mathematics from the Institute of Mikhail Spasennykh is a Business Development
manager of exploration in Nigeria. He was appointed Physics of the Earth, Russian Academy of Sciences. Manager with Schlumberger. He is based in Moscow.
to the board of directors of Tullow in 2006. He is a
Nonexecutive Director of Ikon Science Limited and a David Quirk is Lead Geoscientist in global play analy- Vladimir P. Stenin is the Head of the Geological
member of the advisory board of the Energy & sis at Maersk Oil in Copenhagen, Denmark. He was Prospecting and Exploration Section for Lukoil in
Geoscience Institute of the University of Utah, Salt previously technical team leader for Maersk Brazil Moscow. His 30-year career includes positions with
Lake City, USA. Angus received a BSc degree (Hons) in exploration activities. Before joining Maersk, he Schlumberger, PetroAlliance and Orenburg Geophysical
geology from the University of Dundee, Scotland, and a worked for Shell, Oxford Brookes University in Research Expedition. Vladimir received a PhD degree in
PhD degree in structural geology from the University England, Burlington Resources and Hess Corporation. engineering and geophysics from Gubkin Russian State
of St Andrews, Scotland. His recent publications have focused on plate recon- University of Oil and Gas, Moscow.
structions in the South Atlantic, salt tectonics and Paul Tapponnier is Professor and Group Leader of the
Bernard Montaron is Director of the Schlumberger analysis of risk and uncertainty in petroleum explora-
China Petroleum Institute in Beijing. He joined Tectonics and Earthquakes Group at the Earth
tion. David holds a PhD degree in geology from the Observatory of Singapore at the Nanyang Technological
Schlumberger in 1985 and has worked in R&D and University of Leicester, England.
marketing in Europe, the US and the Middle East. His University in Singapore, where he has worked since
assignments included theme director for carbonates Raisa Romushkevich is a Geologist for the 2009. Previously, he worked at the Tectonique,
and naturally fractured reservoirs, director of engi- Schlumberger Moscow Research Center, where she Mécanique de la Lithosphère group at the Institut de
neering and general manager of R&D and manufac- focuses on geologic interpretation of experimental Physique du Globe de Paris. His contributions to geol-
turing at Schlumberger Riboud Product Center in results on the thermal properties of rocks. Before join- ogy, tectonics and geophysics span more than 40 years
Clamart, France; Oilfield Services marketing vice ing Schlumberger, she was a geologist and head of the and his research interests include continental dynam-
president for Europe, CIS and Africa; and vice presi- laboratory of rock physics at Russian State Geological ics and tectonics, particularly in Asia and the
dent of marketing for Schlumberger Middle East. Prospecting University, Moscow. The coauthor of more Mediterranean region; active faulting and seismotec-
Bernard obtained an MSc degree in physics from than 50 publications, Raisa received an MSc degree tonics; earthquake hazard assessment; quantitative
École Supérieure de Physique et de Chimie from Irkutsk State University, Russia. geomorphology; rates of active deformation processes;
Industrielles (ESPCI ParisTech) in Paris and a PhD Jay Russell is the Oilfield Services and Technical and rock mechanics and rock deformation physics. He
degree in mathematics from Université Pierre et Challenges Marketing Communications Manager for is a member of both the French and US National
Marie Curie, Paris. He is a member of the board of Schlumberger in Houston. He began his career in 1991 Academy of Sciences and a Fellow of the American
directors of ESPCI ParisTech and a member of AAPG, as a wireline field engineer for Schlumberger in Geophysical Union, Geological Society of America and
SPE, SPWLA and the European Association of Bakersfield, California, USA, and held various field Geological Society of London. Paul holds an ingénieur
Geoscientists and Engineers. operations positions worldwide. He has also worked at des mines degree from Ecole Nationale Supérieure des
engineering centers and held wireline management Mines de Paris and a doctorat d’etat degree from
Kamal Osman is a Senior Staff Petrophysicist at Université Montpellier 2 Sciences et Techniques,
Chevron Thailand Exploration and Production Ltd and positions for Schlumberger. Jay has a BS degree in
mechanical engineering from Worcester Polytechnic France.
is the Geologic Operations Team Leader in Bangkok,
Thailand. He began his career in 1980 as a develop- Institute, Massachusetts, USA, and an MS degree in Chris Tevis, based in Sugar Land, Texas, USA, is a
ment geologist in the Sudan and has worked in operations management from Rensselaer Polytechnic Product Champion with Schlumberger at the Houston
Chevron overseas operations in West Africa, Papua Institute in Troy, New York, USA. Pressure and Sampling Product Center. Prior to his cur-
New Guinea, the Middle East and Kazakhstan. Kamal, Sergey Safonov is a Reservoir Physics Discipline rent position, he was a field engineer, an engineer in
who has coauthored several petrophysical papers and Manager at the Schlumberger Moscow Research charge, a field service manager and quality operations
is a member of SPE and the SPWLA, received a BS Center. He concentrates on a wide range of topics support manager and worked in China, Southeast Asia
degree (Hons) in geology from the University of related to measurement and interpretation of complex and the US. Chris has a BS degree in mechanical engi-
Khartoum, Sudan. fluid flows in reservoirs. Sergey earned a BS degree in neering from Columbia University, New York City, and is
natural science and an MS degree in physics from the pursuing an MSc degree in oil and gas industry manage-
Anton Parshin is the Thermal Measurements and ment from Heriot-Watt University, Edinburgh, Scotland.
Interpretation Program Manager with Schlumberger Moscow Institute of Physics and Technology and a
in Moscow. His responsibilities include production log- postgraduate diploma in physics from the University of An asterisk (*) is used to denote a mark of Schlumberger.
Exeter, England.

Autumn 2012 59
Coming in Oilfield Review NEW BOOKS

Well Placement and Completion


Evolution. The advent of new LWD
tools and measurements has led to
changes in the way some operators
approach drilling horizontal wells.
New tools are able to detect boundar-
ies in the formation away from the
borehole and in front of the drill bit,
resulting in an improvement in well
placement techniques. In addition,
tools have been developed that accu-
rately image borehole details and
identify naturally occurring fracture Waking the Giant: How a Free Radicals: The Secret The Idea Factory: Bell Labs
networks. Engineers use these data Changing Climate Triggers Anarchy of Science and the Great Age of American
to create effective completion Earthquakes, Tsunamis, Michael Brooks Innovation
designs. This article presents some of and Volcanoes Overlook Press Jon Gertner
the technologies and processes that Bill McGuire 141 Wooster Street The Penguin Press, a division of
Oxford University Press New York, New York 10012 USA Penguin Group (USA) Inc.
are making these changes possible.
198 Madison Avenue 2012. 320 pages. US$ 27.95 375 Hudson Street
New York, New York 10016 USA ISBN: 978-1-59020-854-0 New York, New York 10014 USA
Debris Removal. Small debris can 2012. 432 pages. US$ 29.95
2012. 320 pages. US$ 29.95
foul completions, increase operation ISBN: 978-0-19-959226-5 This book looks behind the formal doors ISBN: 978-1-594-20328-2
costs and ultimately diminish well of scientific discovery to reveal the
productivity. Engineers are designing The author describes how the Earth’s extreme behavior some celebrated Author Jon Gertner describes the
specialized wellbore cleaning sys- climate has affected and caused major scientists have engaged in to bring the history of the AT&T Bell Laboratories
tems capable of performing critical geologic events through the millennia. world’s attention to their findings. and its role in one of the most produc-
debris recovery operations. Case By looking at such trends, McGuire Sparing no one—from Newton and tive periods in US innovation—the
contends that as our climate change Einstein to Watson and Crick—author 1920s to the 1980s. In addition to
studies from Alaska, USA, the Gulf
crisis emerges, the world may Brooks finds fraud, deception, manipu- describing the birth of pioneering
of Mexico and the North Sea demon- lation and unethical experiments are
experience a resulting increase in technologies such as radar, lasers, radio
strate how operators are using these just some of the behaviors that break astronomy and mobile phones, all of
natural disasters.
new systems to reduce risks and the illusion of the logical and level- which were developed at Bell
improve operational efficiency. Contents: headed “Scientist” front that is pre- Laboratories, Gertner explains how Bell
sented to the world. Laboratories created a culture of
• The Storm After the Calm
Fishing. Any object that is lost in creativity. The book also explores the
the hole or that impedes normal • Once and Future Climate Contents: concept of the business of innovation.
downhole operations must be • Nice Day for an Eruption • How It Begins: Dreams, Drugs and
retrieved. The concept of fishing— Visions from God Contents:
• Bouncing Back
the process of recovering lost items • The Delinquents: Rules Are There • Introduction: Wicked Problems
• Earth in Motion
such as tubulars, tools or completion to Be Broken • Oil Drops
• Water, Water, Everywhere
components from the wellbore— • Masters of Illusion: Evidence Isn’t • West to East
requires imagination and innovation. • Reawakening the Giant
Everything • System
This article describes tools and strat- • Selected Sources, Further
• Playing with Fire: No Pain, No Gain • War
egies developed for dealing with lost Reading, Index
• Sacrilege: Breaking Taboos Is Part • Solid State
equipment in the wellbore. of the Game
McGuire . . . has written a dry but
• House of Magic
enthralling overview of how climate • Fight Club: There’s No Prize for the
Evaluation While Drilling. affects the geophysical world, and • The Informationist
Runner-Up
Motivated by environmental, health vice versa. . . . He provides a solid
• Defending the Throne: Machiavelli • Man and Machine
and security reasons, scientists have critical foundation for current climate
spent years developing alternatives Would Be Proud • Formula
projections, noting the difference
to radioisotope-based logging tools. between the scientific and popular • In the Line of Fire: Life on the • Silicon
Through the use of pulsed-neutron narratives of climate change. . . . Barricades • Empire
generators that have replaced chem- Despite its heavy-handed scene- • Epilogue, Notes and Sources, Index • An Instigator
ical sources in other logging tools, setting, the book will satisfy dooms-
day eschatologists and curious ‘Science is not for the meek and • On Crawford Hill
engineers have developed a radio-
Earth lovers interested in what the mild,’ Michael Brooks writes in this • Futures, Real and Imagined
isotope-free gamma-gamma density future holds. entertaining new book. . . . ‘Free
measurement. This innovation • Mistakes
“Book Review,” Publishers Weekly (February 13, Radicals’ is an exuberant tour through
allows operators to deploy a full the world of scientists behaving badly. • Competition
2012), http://www.publishersweekly.com/978-0-
suite of LWD tools that have no • Apart
19-959226-5 (accessed September 6, 2012). Bouton K: “Rebels Whose Bold Moves Set
chemical sources.
Science Aglow,” The New York Times (May 21, • Afterlives
McGuire lays out a strong case for 2012), http://www.nytimes.com/2012/05/22/ • Inheritance
the interconnectedness of Earth science/free-radicals-book-review-rebels-
systems. . . . Yet when it comes to the who-set-science-aglow.html?_r=1 (accessed • Echoes
most crucial question, of how future May 29, 2012). • Endnotes and Amplifications,
climate change will affect the planet, Sources, Selected Bibli-
even he cannot say. ography, Index
Witze A: “Book Review,” Science News 181,
no. 10 (May 19, 2012): 30.

60 Oilfield Review
Jon Gertner, an editor at Fast In a series of essays, the author • Icarus and Fukushima Daiichi: Contents:
Company magazine, has produced a explores epigenetics: the concept of Human Factors in a Meltdown • 1953
well-researched history of Bell Labs, how our genes respond to our environ- (Sv=1J/kg.w)
ments. Biology meets pop culture in • Olden Farm
filled with colorful characters and • References, Index
inspiring lessons. But more important, these pages, and the author furthers the • Veblen’s Circle
“The Idea Factory” explores one of nature versus nurture debate. Each essay provides its fair share • Neumann János
the most critical issues of our time: of wit and satire, poignantly illustrat- • MANIAC
What causes innovation? Why does it Contents: ing faults or curiosities in current
happen, and how might we nurture it? • Walter Benjamin and Biz Stone: scientific thought or public discourse • Fuld 219
The Scientific Paper in the Age of the scientific realm. • 6J6
Isaacson W: “Inventing the Future,” The New York
of Twitter • V-40
Times (April 6, 2012), http://www.nytimes. Ingram MAC: “#FramingTheArtofScience,”
com/2012/04/08/books/review/the-idea-factory-by- • Epigenetics in the Adirondacks Science 337, no. 6096 (August 17, 2012): 801. • Cyclogenesis
jon-gertner.html?_r=1 (accessed April 12, 2012). • A Nobel Is out of Order: “J. Lo” • Monte Carlo
vs. Hypatia of Alexandria A crackle of erudite energy leaps
‘The Idea Factory’ is an expansive from this lively commingling of art, • Ulam’s Demons
• Epigenetics and Alma Mahler
treatment of the labs’ history. . . . The culture and science. In 28 essays, • Barricelli’s Universe
tensions among the three nominal • Inflammation Is Complicated: From biologist Gerald Weissmann explores
Metchnikoff to Meryl Streep • Turing’s Cathedral
inventors, Walter Brattain, John the complex territory of modern
Bardeen and William Shockley, have • An Arrowsmith for the NASDAQ biology and epigenetics in this era of • Engineer’s Dreams
been chronicled often. But Gertner’s Era: Extraordinary Measures social media. In each, Weissmann • Theory of Self-Reproducing
version is especially well told. finds links between research and Automata
• Sarah Palin and Marie-Antoinette:
elements of history and pop culture,
Post-Traumatic Tress Disorder • Mach 9
Yet Gertner’s focus may be too which play off each other to illuminat-
narrow. . . . ‘The Idea Factory’ might • Coca-Cola and H.G. Wells: Dietary ing effect. • The Tale of the Big Computer
have benefited from a fuller discus- Supplements as Subprime Drugs • The Thirty-Ninth Step
“Books in Brief,” Nature 483, no. 155 (March 8,
sion of the fate of corporate research • Voodoo Economics and Voodoo 2012), http://www.nature.com/nature/journal/ • Key to Archival Sources, Notes,
in today’s world. Healing: Witchcraft Persists in v483/n7388/full/483155a.html (accessed Index
Hiltzik M: “‘The Idea Factory’ by Jon Gertner,” Massachusetts September 24, 2012).
Los Angeles Times (March 25, 2012), • Myrna Loy: Co-Principal (Dyson’s book is worth reading
http://articles.latimes.com/2012/mar/25/ Investigator for its treatment of the institute’s early
entertainment/la-ca-jon-gertner-20120325
• Dr. Ehrlich and Dr. Atomic: Beauty history alone.) . . . While Dyson
(accessed April 11, 2012).
vs. Horror in Science doesn’t shy away from discussing
obscure technical and theoretical
. . . Mr. Gertner’s book offers • Free Radicals Can Kill You: aspects of Von Neumann’s computer,
fascinating evidence for those seeking Lavoisier and the Oxygen he also provides ample social and
to understand how a society should Revolution cultural context. . . . Dyson, who grew
best invest its research resources. • Experimental Errors: Paul Bert and up at the institute, where his father
Metcalfe B: “Where the Future Came From,”
the Alabama Tenure Killings Freeman Dyson was a fellow, also
The Wall Street Journal (March 16, 2012), • Monumental Revolutions: brings a charming personal touch to
http://online.wsj.com/article/SB1000142405 Scientific, Sanitary and ’Omic the narrative. . . . Turing’s Cathedral
2970204781804577271442604380350.html
is an engrossing and well-researched
• Quorum Sensing on the Airbus book that recounts an important
(accessed April 11, 2012). Wing chapter in the convoluted history of
• SiCKO Statistics: Michael Moore 20th-century computing.
and L’École de Paris Turing’s Cathedral: The
Origins of the Digital Universe Morozov E: “Turing’s Cathedral by George
• Ask Your Doctor: Justice Holmes Dyson—Review,” The Guardian (March 24,
George Dyson
and the Marketplace of Ideas 2012), http://www.guardian.co.uk/books/2012/
Pantheon Books,
• Filter the Dogs: Microbial Mishaps mar/25/turings-cathedral-george-dyson-review
a division of Random House, Inc.
in Massachusetts (accessed April 10, 2012).
1745 Broadway
• Pattern Recognition and Gestalt New York, New York 10019 USA
2012. 432 pages. US$ 29.95 Mr. Dyson’s . . . determination to
Psychology: The Day Nüsslein-
ISNB: 978-0-375-42277-5 keep the book accessible to the
Volhard Shouted “Toll!”
layman means that there is not
• Not by the Sword, but Disease: enough for the more expert reader to
Through interviews, exploration of
Doctor Howe and General Shinseki get a step-by-step sense of what the
archives and a unique personal vantage
• Science as Oath and Testimony: point, George Dyson tells the story of computer did.
Joshua Lederberg the people who came together at the
Institute for Advanced Study at Modern digital computing is too
Epigenetics in the Age of • X-Ray Politics: The Nazi War on
Princeton University, New Jersey, USA, complicated a thing to be traced to a
Twitter: Pop Culture and Röntgen and Einstein
to create the “Turing Machine.” Though single moment of divine conception.
Modern Science • Wild Horses and The Doctor’s
mathematician Alan Turing lends his But Mr. Dyson’s chronicle, if too
Gerald Weissmann Dilemma limited in scope to be a definitive
name to the title, this is the story of
Bellevue Literary Press • Glass Ceilings at the Nobel Prizes mathematician John von Neumann and history of the computer, is a well-told
New York University his team, which created the chapter of that larger story.
School of Medicine • Medea and the Microtubule
Mathematical Analyzer, Numerical Kakaes K: “The Nucleus of the Digital Age,”
350 First Avenue OBV 612 • Wiki-Science and Molière’s Beast
Integrator, and Computer, or MANIAC. The Wall Street Journal (March 3, 2012),
New York, New York 10016 USA • Arts and Science: Lewis Thomas Dyson argues that this early computer is http://online.wsj.com/article/SB1000142405
2012. 300 pages. US$ 18.95 and F. Scott Fitzgerald the nucleus of today’s digital universe. 2970204909104577237823212651912.html
ISBN: 978-1- 934-13739-0
(accessed March 21, 2012).

Autumn 2012 61
Philosopher and ‘lapsed econo- In Reinventing Discovery, Contents:
mist’ John Broome vaults in where [Nielsen’s] easy-to-read and enthusi- • Fire and Brimstone: How
policy-makers fear to tread, exploring astic narrative integrates a set of Volcanoes Work
the moral aspects of climate choices. ideas that could, indeed, revolutionize • Eruption Styles, Hazards and
In the latest installment in the knowledge creation. . . . Nielsen’s Ecosystem Impacts
Amnesty International Global Ethics timely volume weaves together themes
Series, Broome argues that countries of big data, open access, gamification, • Volcanoes and Global
and individuals are ethically obliged and citizen science to make bold Climate Change
to curb emissions. With penetrating claims about what discovery may look • Forensic Volcanology
clarity, he uses science and economics like in the 21st century. • Relics, Myths and Chronicles
as a springboard to cover big issues,
from the need for action despite While he should be applauded for • Killer Plumes
uncertainty to the value of human life. integrating these developments, one • Human Origins
Climate Matters: Ethics in a “Books in Brief,” Nature 487, no. 299 (July 19,
wishes for a deeper analysis of • The Ash Giant/Sulphur Dwarf
Warming World foundational issues. . . .
John Broome
2012), http://www.nature.com/nature/journal/ • European Volcanism in Prehistory
v487/n7407/full/487299a.html (accessed
W.W. Norton & Company, Inc. The social, organizational, and • The Rise of Teotihuacán
September 24, 2012).
500 Fifth Avenue computational sciences have a long • Dark Ages: Dark Nature?
New York, New York 10110 USA and rich history in understanding and
2012. 224 pages. US$ 23.95 improving collaboration. . . . Nielsen • The Haze Famine
ISBN: 978-0-393-06336-3 provides an important foundation for • The Last Great Subsistence Crisis
moving forward. in the Western World
In this book from the Amnesty Fiore SM: Science 336, no. 6077 (April 6, 2012): • Volcanic Catastrophe Risk
International Global Ethics Series,
philosopher John Broome posits that
36–37. • Appendices, References, Index
the principles that underlie everyday . . . Nielsen makes a compelling
decision making also provide simple Oppenheimer, a reader at the
case in this self-described manifesto. University of Cambridge, argues that
and effective ideas for confronting With friendly, engaging writing, he
climate change. The author explores volcanoes and life have been inter-
describes specific approaches and twined throughout time. . . . [and]
the moral dimensions of climate change characteristics that can make
and discusses universal standards of uses all sorts of evidence to unravel
collaborations truly bloom. the stories behind some of the greatest
goodness and justice that both citizens
and governments must adhere to when Ehrenberg R: “Book Reviews,” Science News 181, and most significant volcanic
trying to solve this global dilemma. cataclysms.
Reinventing Discovery: The no. 6 (March 24, 2012): 34.

New Era of Networked Science I recommend Eruptions That


Contents: Michael Nielsen Shook the World as motivational
• Introduction Princeton University Press reading for physics students looking
• Science 41 William Street for a thesis topic in Earth or environ-
Princeton, New Jersey 08540 USA mental sciences. The book may
• Economics 2012. 280 pages. US$ 24.95 encourage physicists to take up the
• Justice and Fairness ISBN: 978-0-691-14890-8 fascinating but challenging mission of
• Private Morality understanding the workings of deep
In this book, Michael Nielsen, a pioneer Earth and the claims that are made
• Goodness of quantum computing, describes how for it.
• Uncertainty the internet is not only transforming
our collective intelligence, but also Anderson DL: “Book Review,” Physics Today 65,
• The Future Versus the Present no. 5 (May 2012): 55.
revolutionizing scientific discovery.
• Lives Nielsen shows how online collaboration
• Population tools, networked science and open
• Summary data policies are bringing scientists Eruptions That Shook
together, expanding our problem- the World
• Notes, Index solving ability and increasing our
Clive Oppenheimer
combined brainpower.
By providing readers with an Cambridge University Press
overview of the science and economic 32 Avenue of the Americas
Contents:
questions behind global warming, New York, New York 10013 USA
Broome lays a solid foundation for • Reinventing Discovery 2011. 408 pages. US$ 30.00
the . . . arguments in the book. . . . • Part 1: Amplifying Collective ISBN: 978-0-521-64112-8
Broome’s overall message appeals to Intelligence: Online Tools Make Us
the moral goodness of humanity. . . . Smarter; Restructuring Expert Volcanologist Oppenheimer takes a
A moral and just viewpoint on an Attention; Patterns of Online forensic approach to describe some of
ever-expanding global issue. Collaboration; The Limits and the the largest cataclysmic volcanic events
Potential of Collective Intelligence of the past quarter of a billion years by
“Book Review,” Kirkus Reviews (May 15, 2012), examining geologic, historic, archaeo-
https://www.kirkusreviews.com/book-reviews/ • Part 2: Networked Science: All the
logical and paleoenvironmental records
john-broome/climate-matters/#review (accessed World’s Knowledge; Democratizing
such as ice cores and tree rings. The
September 4, 2012). Science; The Challenge of Doing
author argues that catastrophic risk
Science in the Open; The Open
management will be an easier task if
Science Imperative
scientists have a better understanding
• Appendix, Selected Sources and of these events and how they affected
Suggestions for Further Reading, all aspects of life on Earth.
Notes, References, Index

62 Oilfield Review
DEFINING POROSITY

How Porosity Is Measured


Tony Smithson
Editor

When it comes to evaluating conven- The most common reservoir rocks are sandstone ( ρmatrix = 2.65 g/cm3 ),
tional reservoirs, petrophysicists are Porosity Rock grain limestone ( ρmatrix = 2.71 g/cm3 ) and dolomite ( ρmatrix = 2.87 g/cm3 ). These
often concerned with three key matrix density values are used to compute density porosity. The other input,
parameters: permeability, porosity ρfluid, is usually that of water (1 g/cm3).
and the presence of hydrocarbons. Appropriate choice
Permeability is the measure of a rock’s of ρmatrix values, which
Formation
ability to allow fluids to pass through are often derived from
it. Porosity is the volumetric void other measurements,
space in the rock—the space not is crucial to the density Long-spaced
occupied by solid material (right). porosity computation. detector
Without the presence of hydrocar- An incorrect ρmatrix Short-spaced
bons, porosity—which is directly input or a mixture of detector
> Porosity. The void space in rocks
related to production potential—and rock types will yield
not occupied by solid material
permeability may be of little interest may be filled with water, oil or gas. an incorrect density
to log analysts. porosity measurement.
Although porosity is a crucial parameter for evaluating reservoirs, the The same is true for Source
first logs measured formation resistivity. Introduced in the 1920s, resistivity the ρfluid input.
tools helped identify potential hydrocarbon-bearing rocks. High resistivity is Neutron porosity > Density porosity tool. A radioactive source emits
gamma rays into the formation, where they
a characteristic of the presence of hydrocarbons and low resistivity is indic- tools emit high-energy
interact with minerals and fluids; some gamma
ative of water. However, log analysts could not differentiate between rocks fast neutrons (on the rays return to detectors where they are counted
containing hydrocarbons and those with no porosity because both exhibit order of 106 eV) from and their energy levels measured.
high resistivity. Even when hydrocarbon-bearing zones were identified using chemical or electronic
resistivity tools, the volume of hydrocarbon could not be determined with- sources (below). Neutrons, which are neutrally charged subatomic particles,
out a porosity measurement. lose energy when they collide with nuclei of formation materials. The energy
The first porosity measurements, which became available in the early loss is related to the relative mass of the particles with which the neutron
1950s, came from sonic, or acoustic, logging tools. Sonic porosity is com- collides. Hydrogen, which consists of a nucleus with a single proton, is the
puted by comparing the speed of sound through the formation to that of most effective element for slowing fast neutrons. In reservoir rocks, hydrogen
rocks with no porosity. Sound travels more slowly though fluid-filled rocks is associated with the liquids—oil or water—that fill the pore space. Gas has
than through rocks with no porosity. a much lower hydrogen density than oil and water.
Scientists have developed an assortment of porosity logging tools based
on various physical principles. Today, although sonic porosity logs are still
Borehole Electronic source
used, the two predominant porosity measurements are density porosity and Formation Chemical source
neutron porosity. Long- 10 6
spaced
Neutron energy, eV

detector
Porosity Measurements 10 4
Oilfield Review Short-
Density tools emit medium-energy gamma rays into a borehole
AUTUMN 12 wall (above spaced
detector
right). The gamma rays collide with electronsDefining
in the formation,
Porosity lose
Fig. 1energy 10 2
ORAUT
and scatter after successive collisions. The number 12-DEFPOR
of collisions 1
is related to Average thermal
Thermal
the number of electrons per unit volume—the electron density. The elec- neutron 10 0 energy 0.025 eV
Neutron
tron density for most minerals and fluids encountered in oil and gas wells is region Capture
source
directly proportional to their bulk density, ρbulk. 10 –2
10 100
The bulk density measured by the tool, ρlog , results from the combined Time, ms
effects of the fluid (porosity) and the rock (matrix) and is used to compute
density porosity (fdensity ): > Life of a fast neutron. The neutron porosity tool (left) sends out high-
Oilfield Review
energy neutrons that collide with molecules in the formation rocks and
ρmatrix – ρlog AUTUMN
φdensity = fluids, lose energy (right) and eventually reach12thermal energy level
ρmatrix – ρfluid . (0.025 eV) in a region some distanceDefining
from thePorosity Fig. 2of the thermal
source. Some
ORAUT
neutrons return to the tool where they 12-DEFPOR
are counted by the2 detectors. These
counts are converted into a hydrogen index (HI) measurement, which is
used to compute neutron porosity. Thermal neutrons are eventually captured
Oilfield Review Autumn 2012: 24, no. 3. by elements in the formation.
Copyright © 2012 Schlumberger.

Autumn 2012 63
DEFINING POROSITY

Matrix: Sandstone Matrix: Limestone Matrix: Dolomite


Assumed Matrix Density: 2.65 g/cm3 Assumed Matrix Density: 2.71 g/cm3 Assumed Matrix Density: 2.87 g/cm3

Shale Shale effect Shale effect Shale effect

Gas Crossover Crossover Crossover


Sandstone
Formation Oil

Water
60 Porosity, % 0 60 Porosity, % 0 60 Porosity, % 0
Curves overlie 4% difference 12% difference
each other

> Lithology and fluid effects. Density porosity (red) and neutron porosity (dashed blue) are computed from
lithology-dependent relationships. Log analysts use the tools’ characteristic responses to help determine fluid
type and lithology. For example, in a sandstone formation, with porosity computed using correct parameters
(left), the curves overlie one another at the correct porosity of 30% in water, cross over somewhat in oil, cross
over a great deal in gas and separate in shales. If an incorrect matrix is used, such as limestone (middle) or
dolomite (right), the computed porosities are incorrect by 4% and 12%, respectively.

After multiple collisions, the neutrons achieve a low energy state measurements and correcting for environmental and lithologic conditions.
(0.025 eV) and are referred to as thermal neutrons. The number of thermal This total porosity includes fluids associated with shale. Because the fluids
neutrons resulting from collisions with hydrogen is proportional to the hydro- in shales cannot usually be produced, their contributions to the measure-
gen index (HI) of the formation. ment can be subtracted from the total porosity. By quantifying the shale
A conventional neutron porosity tool has two detectors located fixed dis- contribution and removing it from the total porosity measurement, log
tances from the source. The detectors count neutrons that have passed analysts are able to compute the effective porosity, which more accurately
through the formation and attained thermal energy levels. The HI is derived portrays a reservoir’s potential.
from the ratio of counts from these two detectors, and analysts apply a The gas effect results from two physical measurement principles. Gas-
lithology-dependent transform to convert HI to neutron porosity. As with the filled porosity is seen by the neutron porosity tool as low porosity. In contrast,
density porosity, obtaining accurate neutron porosity depends on using the the density porosity measurement may be higher than the true porosity. The
correct matrix. result is that the density and neutron porosity curves are neither overlying
For clean, shale-free formations, in which the porosity is filled with each other—which would indicate water- or oil-filled porosity and the correct
water or oil, the neutron log measures the fluid-filled porosity. Because gas matrix—nor separated from each other, the shale effect. Because the neutron
has a much lower hydrogen density than oil or water, gas-filled porosity porosity is lower than the density porosity, the curves cross over each other,
appears as low porosity. giving rise to the term crossover.
Several environmental factors affect neutron porosity measurements and The shale effect counteracts the crossover effect; however, petrophysicists
corrections have been developed to compensate for them. These include bore- use other measurements to correct for the shale volume and determine the
hole size, mud weight and salinity, mudcake thickness, hydrostatic pressure, effective porosity. The gas effect can also be masked by the presence of deep
formation salinity and temperature. invasion when drilling fluid filtrate displaces the original gas in place. Logging-
while-drilling (LWD) tools, which acquire data before invasion takes place,
Complementary Measurements Oilfield Review identify the presence of gas zones that are missed by wireline tools, which
may
AUTUMNof12 are run some time after drilling.
Porosity tools respond in well-defined ways to the physical attributes
fluids and rocks. As part of the log interpretation process, log Defining Porosity Other
analysts Fig. 4 measurement techniques can be used to determine porosity.
account for these different responses. Two of the most easily ORAUT 12-DEFPOR
recognized These4include nuclear magnetic resonance (NMR) tools and core samples.
examples of tool responses are the shale effect and the neutron-density An NMR tool directly measures liquid-filled porosity. Core data provide an
gas effect (above). empirical porosity value, although damage during the core recovery process
In clean rocks filled with water, the density and neutron porosity logs may affect the measured value.
should overlie each other if the correct lithology input is applied. When shale
is present, the neutron porosity measurement is higher than the density Crucial Parameter
porosity. This results from the neutron responding to the large volume of fluid Porosity is one of the most critical parameters for quantifying hydrocarbon
adsorbed by the shale. The net effect is that, in shales, there is a separation reserves. Petrophysicists have developed numerous ways to determine
between the density and neutron porosity curves—the shale effect. porosity to make sure they have the most accurate data possible. The ulti-
The effects of shale also give rise to another term—effective porosity. mate goal is to use these data to understand a reservoir’s production poten-
Petrophysicists derive total porosity values by combining different tial and ensure that its hydrocarbons are effectively recovered.

64 Oilfield Review

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