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Thermodynamics I Properties of Pure Substances: Mohsin Mohd Sies
Thermodynamics I Properties of Pure Substances: Mohsin Mohd Sies
Chapter 2
Properties of Pure Substances
mvapor
Degree of Dryness quality = x
evaporation fraction mtotal
0 x 1
(wet) (dry)
100% liquid 100% vapor
QUALITY, x (2 phase condition)
By employing the
additive behavior
of extensive properties
Some Additional Thermodynamic Properties
Enthalpy, H [kJ]
H ≡ U + PV
h = u + Pv
Entropy, S [kJ/K]
Specific Entropy, s [kJ/kg.K]
PROPERTY TABLES
3 types of tables
Compressed liquid table
Saturated table
Superheated table
Saturated tables
Temperature table – T in easy to read numbers
Pressure table – P in easy to read numbers
Compressed Liquid Approximation
P ↔ Tsat
T ↔ Psat
h25C,1b hf@T=25C
Interpolation (Linear Interpolation)
b
Tb
Assume a & b
T connected by a
a straight line
Ta
va v=? vb
h = u + Pv
POLYTROPIC PROCESS
-Processes that obey/follow the path
pvn = c
n = polytropic index
p 1
pvn = c
2
v
n=1 isothermal
n=0 isobaric
n= const. volume
Reduced
temperature
Pseudo-reduced
specific volume
Reduced
pressure
Is water an ideal gas?
Air,
H2O (Water, Steam) Ideal Gas N2 , He,
etc.
Beattie-Bridgeman :
Benedict-Webb-Rubin :