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Journal of Manufacturing Processes 22 (2016) 211–228

Contents lists available at ScienceDirect

Journal of Manufacturing Processes


journal homepage: www.elsevier.com/locate/manpro

Review

Activating flux tungsten inert gas welding for enhanced weld


penetration
R.S. Vidyarthy ∗ , D.K. Dwivedi
Department of Mechanical and Industrial Engineering, Indian Institute of Technology, Roorkee, Uttrakhand 247667, India

a r t i c l e i n f o a b s t r a c t

Article history: The flux assisted GTAW or A-TIG process developed at the Paton Welding Institute in 1960. Despite
Received 5 January 2016 capable of offering a penetration up to 5–6 mm in a single pass weld, it could not find enough space in
Received in revised form 4 March 2016 industrial applications, primarily due to few inherent unfavorable features: (a) two-step nature of the
Accepted 21 March 2016
process, (b) poor weld-bead and (c) poor electrode life. High penetration capability of A-TIG process has
fascinated researchers and renewed the research interest in last one decade. In the present work, attempts
Keywords:
have been made to analyze and review the literature published with respect to (a) advancement of various
A-TIG
hypotheses to explain the reasons for high penetration achieved using A-TIG, (b) effect of input process
Flux
Weld bead geometry
parameters related to GTAW and A-TIG, (c) effect of chemical composition and various alloying elements
Review paper in steel on penetration achieved by A-TIG, (d) feasibility studies of A-TIG on ferrous and non-ferrous
metals and (e) technological problems associated with A-TIG. In light of the above, the present review
will help in (a) highlighting the future scope of research in A-TIG to enhance its industrial application
and (b) to develop systematic understanding of various technological factors determining the capability
of this process.
© 2016 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.

Contents

1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212
2. Mechanism of A-TIG . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 212
2.1. Reversal of the Marangoni convection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 213
2.2. Arc constriction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 214
3. Methods opted for flux deposition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
4. Factors affecting the A-TIG performance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
4.1. Forces acting in A-TIG welding . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 215
4.2. Welding related process parameters . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
4.2.1. Welding current . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
4.2.2. Welding speed . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
4.2.3. Arc length . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 216
4.2.4. Electrode geometry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218
4.2.5. Shielding gas composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 219
4.3. Properties of the metal to be welded . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220
4.3.1. Thickness of the plate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220
4.3.2. Composition of metal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
4.4. Flux . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
5. Recent development in TIG process to enhance the depth of penetration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224
6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 225
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 226

∗ Corresponding author. Tel.: +91 9548204386.


E-mail address: vidyashanker01@gmail.com (R.S. Vidyarthy).

http://dx.doi.org/10.1016/j.jmapro.2016.03.012
1526-6125/© 2016 The Society of Manufacturing Engineers. Published by Elsevier Ltd. All rights reserved.
212 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

1. Introduction published [1–8,10–88]. The detail of the depth of penetration as


reported by various researchers in different materials with A-TIG
Gas tungsten arc (GTA) or tungsten inert gas (TIG) welding pro- welding process is summarized in Fig. 2.
cess is one of the most common fabrication processes employed The present work provides an assessment, based on the publi-
for welding of stainless steels, titanium alloys, aluminum alloys cations, merits and limitations in welding different materials with
and other non-ferrous metals because of its good quality welds activating flux. The present work has been organized under the
and low cost equipment. It is popular to weld thin sections and following headings for better understanding.
can be used for various welding positions such as horizontal, verti-
cal and overhead. The process is also popular to produce a smooth
1. Introduction
and clean weld. Although the process attributes several advantages,
2. Mechanism behind A-TIG
low weld penetration renders it less appropriate for industrial use.
2.1 Reversal of Marangoni convection
To overcome the limitation of low penetration in a single pass,
2.2 Arc constriction
groove design and Multipass is required to weld thick sections
3. Methods opted for flux deposition
which decrease productivity of the process. Additional costs are
4. Factors affecting the process capability of A-TIG performance
incurred on edge preparation and filler metals required to fill the
4.1 Forces in weld pool and arc zone
groove joints.
4.2 Welding related process parameters
Several attempts have been made to improve the productiv-
4.2.1 Welding current
ity of GTA welding process. Activated flux with GTA welding has
4.2.2 Welding speed
been successfully used to improve productivity of the process. The
4.2.3 Arc length
process is also known as flux assisted GTAW (F-GTAW) and A-TIG
4.2.4 Electrode geometry
welding process. Use of fluxes in GTA welding was first proposed by
4.2.5 Shielding gas composition
Paton Electric Welding Institute of National Academy of Sciences,
4.3 Properties of the metal to be welded
Ukraine in the mid-1960s [1–13]. In this process a thin layer of
4.3.1. Thickness of the metal
flux is deposited on the surface that is to be welded, followed by
4.3.2. Composition of metal
the TIG welding process. Fluxes used in this process are generally
4.3.2.1. Ferrous
oxides, chlorides and fluorides. Fluxes are deposited on the sur-
4.3.2.2. Non ferrous
face after mixing it with suitable solvent like acetone or ethanol in
4.4 Flux
proper proportion with the help of a brush or by spraying as shown
5. Recent advancement in the A-TIG
in Fig. 1. The width of the layer is generally kept in the range of
6. Conclusion
10–15 mm [2,3,14].
The first paper on the use of activated flux for welding with tung-
sten inert gas welding in argon shielding (TIG) process appeared in 2. Mechanism of A-TIG
the literature in the 1950s and 1960s. At that time, these fluxes were
intended for welding of the titanium and its alloys. Initial studies on TIG welding with activated flux has resulted in a dramatic
use of activating fluxes with tungsten electrodes on titanium were enhancement in the depth of penetration as compared to the con-
made for reducing the porosity in the welds by utilizing the fluxes ventional TIG process with the same input parameters. Various
[7]. Soon after that, it was successfully applied for high strength forces in arc zone like gravity force, drag force due to arc, electro-
steels by Paton Electric welding institute, Kiev. Paton electric weld- magnetic force due to current flow, etc. should be similar for same
ing institute demonstrated that activating fluxes also affects the process parameters in both the cases. The mechanism of increased
weld fusion zone geometry and penetration depth along with the penetration depth with flux in the weld pool is discussed in the
enhanced mechanical properties. Towards the end of the 1960s, following section.
the process got popularity in armaments and aircraft industries The use of flux in TIG welding to improve the properties of tita-
[7,14]. Later, activating flux in TIG welding process was successfully nium alloys in argon-arc welding was first reported by Gurevic
applied on ferrous and non-ferrous materials for deeper penetra- et al. [89,90]. An improvement in the weld penetration of titanium
tion and with equivalent or better mechanical properties. Further, alloys using an oxygen free activated flux was also reported in same
for many years, the A-TIG welding process had limited applica- work. After this, a number of researchers have been published on
tion in industry for a variety of unknown reasons. The process was the understanding of the mechanism of higher penetration with
rediscovered in 1990 when experts from E O Paton electric weld- constricted weld width during the welding of titanium and steels
ing institute presented on A-TIG at TWI (British welding institute) with different fluxes [3–7,27,30,91]. However, Tanaka et al. [30] did
in Abington, Cambridge. This incident triggered another round of not observe any constriction in arc using flux during A-TIG welding
investigations into the use of A-TIG welding process for the welding of water cooled copper. It was also seen that the non-arc processes
of stainless steel, titanium and nickel alloys [15]. Since then many such as electron beam welding and laser welding produced variable
articles on the various aspects of A-TIG welding process have been penetration [25]. Subsequently researchers started to explore the

Fig. 1. Schematic of processing of A-TIG.


R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 213

Fig. 3. Variation of surface tension with sulfur content.

Fig. 2. Depth of penetration on various materials.

that surface tension gradient (d/dT) across the weld pool could
other responsible mechanism for increased depth of penetration. affect the convective flow in the weld pool. The presence of surface
Then after reversal of Marangoni flow come into consideration in A- active elements like sulfur and oxygen in the steel causes the alter-
TIG welding. After a thorough exercise on the probable forces that ations in surface tension () in the weld pool illustrated in Fig. 3.
can affect the penetration, it was concluded that the higher penetra- It reverses the surface tension gradient (d/dT) in the weld pool
tion could be due to changes in fluid flow direction [11–14,25,92]. which makes the surface tension higher at the center of weld pool
Thereafter, reversal of Marangoni convection and arc constriction that decreases gradually towards outer section [25].
evolved as the most accepted phenomena for higher penetration Roper et al. [95] correlated the effect of a small amount of sur-
depth during flux assisted TIG welding. face active elements on the surface properties of the weld pool with
interfacial energy. Heiple et al. [96] studied the effect of the surface
2.1. Reversal of the Marangoni convection active elements with the fluid flow motion in the weld pool. And
developed a theory that the direction and the magnitude of thermo
Marangoni convection, also known as surface-tension driven capillary forces decide the fluid flow direction in the weld pool
convection or thermo capillary convection, can have a dramatic consequently affect the depth of penetration. The thermo-capillary
effect on the penetration depth of the weld. This phenomenon was forces can be controlled by the concentration of the surface active
first proposed by James Thomson in 1855 [93]. The phenomenon elements such as sulfur and oxygen in the metal. It was observed
got its name on the name of Carlo Marangoni who further investi- that as the concentration of the surface active elements exceed a
gated it in 1865 [7]. According to this theory, the direction of fluid particular amount (about 50 ppm), the temperature coefficient of
flow depends on the surface tension gradient in the fluid. Fluids surface tension (d/dT) changes from negative to positive value.
flow from low surface tension region towards the high surface ten- Since the flow of fluid in weld pool occurs from lower surface ten-
sion region. The strength of thermo-capillary flow is determined sion () region to higher surface tension () region, triggers the
by the Marangoni number (Ma), which is non-dimensional and circulation flow in the molten weld pool as shown in Fig. 4. In case
expressed by Eq. (1) where dT/dx is the temperature gradient,  is of pure metals, including steels and other iron alloys, with low sul-
the viscosity, a is the thermal diffusivity and L is the characteristics fur and oxygen contents the surface tension decreases with increase
length [25]. in temperature that is a negative surface tension gradient (d/dT).
It promotes the molten metal surface flow in a radially outward
d dT L2
Ma = (1) direction which in turn makes the weld bead shallow and wider as
dT dx a
shown in Fig. 4A.
The effect of Marangoni forces was first proposed in welding to Keene et al. [97] studied the relation between surface tension
understand the problems encountered in the case of “cast to cast” and molten metal flow direction in weld pool and indicated that
variations or variable penetration. The problem “variation in pene- all systems exhibit a maximum positive surface tension gradi-
tration” observed during autogenous tungsten inert gas welding of ent (d/dT) at some temperature. Further increase of temperature
stainless and ferritic steel was first identified in 1960. This problem results gradual decrease in the surface tension, combination of
was severe in case of robotic welding due to requirement of higher these produces a complex flow similar to that shown in Fig. 5. Simi-
weld penetration and repetitive work. It was reported that welds on lar type of study done by other researchers, and reported increased
some batches of steel exhibit lower penetration than normal while penetration depth using A-TIG, the same was attributed to reversal
other batches exhibit higher, despite all batches were meeting the of Marangoni convection in the weld pool [6,30,35].
material specification requirements [25]. The above discussion suggests that the trace presence of the
A number of attempts had been made to co-relate the “cast to minor alloying elements in the weld pool can reverse the surface
cast” variation and systematic variations in the concentrations of tension gradient in the weld pool; this effect is described by the
specific minor or impurity elements in the metal. It was suggested name of reversal of Marangoni convection in published literature.
that a small amount of impurities or elements in composition of Reversal in Marangoni convection promotes molten metal’s fluid
steel can result in large changes in arc characteristics and the sur- flow from the fusion boundary to the center of the weld pool. A
face properties of the weld pool [14,23,91]. Ishizaki [94] proposed combination of fluid flow from the fusion boundary towards the
214 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

Fig. 4. Proposed fluid flow on and below the weld pool surface: (A) negative surface tension temperature coefficient; (B) positive surface tension temperature coefficient.

Fig. 5. Schematic illustrating the Keene theory for mixed flow.

center and the pressure of the arc turn it in the direction of the
arc as shown in Fig. 4B. These forces combine and work together
to increase penetration by transferring heat from top to bottom
effectively. Further, it was observed that this reversal of Marangoni
convection is effective only up to a limit of temperature after which
complex behavior of fluid is expected in the weld pool.
Fig. 6. Schematic illustration of arc constriction.

2.2. Arc constriction


region of an arc column, and shaped better constricted arc column
During TIG welding when the TIG torch moved toward the flux [63].
coated surface from bare surface the diameter of the plasma arc In general, the electronegativity of the halides and other sur-
column get reduced. This phenomenon was described as an arc con- face active elements was believed to promote the arc constriction;
striction in A-TIG welding process. A reduced arc or anode root area however, this concept has also some contradiction. Skvortsov [26]
increased the current density and hence the heat density increased, studied the mechanism of arc constriction and its effect on the weld
which produces narrower and deeper weld than conventional TIG penetration depth in TIG welding and explained it with reference of
welding. electronegativity of the flux used. It was reported that the addition
Tanaka et al. [12] reported the presence of blue luminous plasma of halides affect the partial pressure of the electron gas in the arc
in both with and without flux in TIG welding. This blue luminous column shown in Fig. 7. This demonstrated that the halide vapor
plasma was of metal vapor from the weld pool around the arc. The absorb the electrons from the arc column. But he raised the other
peripheral area of the blue luminous plasma in A-TIG was con- part also that with the same halide for example fluorine in differ-
stricted as compared to the conventional TIG [12,30]. Dong et al. ent form (KF, NaF and CaF2 ) effect the partial pressure differently
[51] recorded the video during the welding and reported that as and also the arc constriction was not same. On the basis of finding,
TIG arc approaches the flux coated region a kind of blue vapor rose Skvortsov concluded that it is impossible to shape any quantita-
from the surface of the weld pool to the electrode. These vaporized tive relationship between the ionization of the arc column and its
gases encompass the arc plasma and constrict it from the periph- contraction.
ery (Fig. 6). Tseng et al. [30] compared the arc constriction caused Marya et al. [13] examined the effect of chloride as flux using
by SiO2 and TiO2 during the TIG welding of 316L. More arc con- bead on plate A-TIG welding of wrought AZ21 magnesium alloy
striction was observed with SiO2 than in case of TiO2 and the same and depicted that the metal vapor from the anode region spread
was explained on the basis of electronegativity of the fluxes. Sili- sidewise in the presence of chlorides.
cone (Pauling scale: 1.90) being of more electronegativity than the From published literature, it can be summarized that absorp-
Titanium (Pauling scale: 1.54) absorbs more electrons in the outer tion of electrons from the arc column by vapors coming from the
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 215

Fig. 9. Marangoni convection in (a) Conventional TIG and (b) A-TIG welding process.

Fig. 7. Variation in partial pressure of electron gas and negative ions of Halides (1
and 5 with “KCl” flux, 2 with “Ti”, 3 and 4 with “KF” flux). Fig. 10. Direction of (a) Electromagnetic or Lorentz force and (b) Buoyancy force in
molten weld pool.

activated fluxes during welding offers two effects (due to the more
electron affinitive character): other Alcoholic Liquors” [93]. Subsequently Carlo Marangoni did his
doctoral work on this force and explained that ‘fluid always flows
(a) Reduction in number of charged particles in arc. from low surface tension region to high surface tension region’ [82].
(b) Pushing of the arc column radially inward by more electroneg- Due to Marangoni force in weld pool, fluid flow in the centrally out-
ative charged vapor. ward direction and thus transfer a maximum of its heat to the wall
of the weld pool rather than bottom as shown in Fig. 9. This action
Both these factors in turn lead to arc constriction. leads it to the high width and low depth of penetration during TIG
welding [14,23,25,91,93,99–101].
3. Methods opted for flux deposition Electromagnetic or Lorentz force: Electromagnetic force is caused
by the interaction of the induced magnetic field and that of the
The activating fluxes of micro size are mixed with either acetone current passes through a conductor. The welding current induces a
or ethanol to form a paste, which is applied on the surface of the magnetic field around the conductor. Resulting Lorentz force acts
material to be welded. The paste can be applied with a brush or with toward the weld pool center in the direction of current flow shown
an aerosol applicator like a spray shown in Fig. 8(b) [27,92]. Patent in Fig. 10(a).
filed by Matthew et al. [98] used a polymeric binder and suggested Buoyancy force: Buoyancy force is caused by the density differ-
that it can be applied to the weld zone as a hot melt, paint, tape, ence of the molten metal in the weld pool. Molten metal density
adhesive, rod, wire or a stick. decreases with the temperature rise. Due to buoyancy force, the
fluid tends to flow from high density to low density (Fig. 10(b)).
4. Factors affecting the A-TIG performance During A-TIG welding, it always acts toward the surface of the weld
pool. However, buoyancy forces are generally less effective as com-
4.1. Forces acting in A-TIG welding pared to other forces during TIG welding of plate up to a thickness
of 10 mm.
Four types of forces have been so reported to affect the pen- Aerodynamic drag: Aerodynamic drag forces produced by the
etration during A-TIG welding, namely, (a) Marangoni forces; (b) action of the arc plasma flowing over the surface of weld pool which
Electromagnetic or Lorentz forces; (c) Buoyancy forces; and (d) induce an outward flow along the surface of the weld pool shown
Aerodynamic drag forces [23,25,91,93]. in Fig. 11.
Marangoni forces: James Thomson (1855) proposed this force in However, the fluid flow in the weld pool is extremely com-
his article “On certain curious Motions at the Surfaces of Wine and plicated because, Marangoni, electromagnetic, buoyancy and

Fig. 8. Techniques for applying the activating flux in the A-TIG process (a) a brush and (b) a spray.
216 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

view of published literature, it can be summarized that increase


in current will result in an increase in penetration, but it is limited
after a maximum value, further increase in current will only lead to
increase in weld width in conventional TIG welding while in A-TIG
it increases penetration as well for a large range of temperature.

4.2.2. Welding speed


Welding speed is the average linear travel speed of the welding
torch over the base plate/pipe to be welded during welding. Weld-
ing speed influence the total heat input per unit length of the weld
Fig. 11. Effect of aerodynamic force on the surface of weld pool. and hence has an effective impact on weld fusion zone geometry
also. Net heat at any point during welding can be related to welding
speed with Eq. (3). where, ‘Hnet ’ represents total heat available for
aerodynamic forces can all affect the flow. The condition is addi- fusion, ‘VI’ represents heat transfer rate to the workpiece and ‘s’ is
tionally tangled by (1) the front to back fluid flow due to relative the welding speed.
motion of the workpiece and electrode, particularly at high welding
speed and (2) the spin evolved by molten metal under condition VI
Hnet = (3)
of radially inward flow, which tends to decrease the intensity of s
radially inward fluid flow [100].
Increasing the welding speed reduces heat per unit length for
The mathematical modeling of the relative strengths of the four
the fusion of the substrate, and hence an obvious decrease in the
forces affecting the fluid flow became a subject of great interest
weld pool cross-sectional area should take place, which finely affect
during 1980s. About twenty models have been reported [14], all
the weld pool geometry. Different investigators reported the effect
these models concluded that the Marangoni force is predominant
of welding speed on the weld pool geometry differently. Burgardt
under normal welding conditions and have a major effect on the
et al. [18] proposed that with the decrease in welding speed peak
weld bead geometry [102,103].
temperature and temperature gradient both would increase, and
also that the D/W ratio for high sulfur steel will increase while
4.2. Welding related process parameters for low sulfur D/W ratio will decrease shown in Fig. 14(a). Ishizaki
et al., Glickstein et al. and Lu et al. reported that an increase in
4.2.1. Welding current welding speed caused a reduction in depth (shown in Fig. 14(b)),
For arc welding process, the amount of heat developed is the width and depth to width ratio of weld pool for both high sulfur
main factor affecting the welding outcome, in terms of weld cross and low sulfur steels [18,65,105]. Lu et al. explained that with low
sectional area, penetration, cooling rate, weld structure and proper- welding speed the arc has enough time to dissolve oxygen in the
ties, defect formation tendency, etc. Heat developed during welding weld pool and hence promote the inward flow in weld pool by
is directly related to the welding current and heat flux density can reducing Marangoni convection [65]. Dong et al. state that with
be given as an increase in welding speed, the heat and the current density in
VI the weld zone gradually decreased. Which in turn will responsible
Q = (2) for comparatively weaker outward Marangoni convection and the
2 2 
inward conviction induced by the electromagnetic force, produces
where, ‘’ is the arc efficiency and ‘␴’ the width parameter a narrow weld width and shallow weld depth respectively [35].
(anode root). Heat flux is directly proportional to the close circuit Welding speed affects weld bead geometry by affecting the heat
current. Thus increasing the current would result in an increase in input rate, peak temperature, Marangoni forces and the electro-
the heat input, the temperature gradient and the strength of the magnetic forces in the weld pool. Narrow and shallow weld bead
thermo-capillary convection. Therefore, an increase in current is formation takes place at high welding speed, while deep and wide
expected to produce better penetration for high sulfur steels and weld bead appear with low welding speed.
lower penetration for low sulfur steels. However, Burgard (1986),
Hiraok (1986) and Ishizak (1988) proposed that the situation is
4.2.3. Arc length
more complex as a larger current would also increase both the
Arc length is the distance between the workpiece and the tip of
electromagnetic as well as aerodynamic force [18,104–106]. Elec-
the tungsten electrode. Arc length in the TIG welding process affects
tromagnetic force improves the weld penetration, although the
the amount of heat generated and supplied to the work piece for
aerodynamic force produces an outward flow and cause widening
fusion. An arc in TIG welding is created between the electrode and
of the weld pool. It can be seen from Fig. 12(a) that the surface inten-
workpiece by the ionization of the gases present. An increase in the
sity of the molten metal increases with temperature in case of high
arc length will result in
sulfur steel but decreases in case of low sulfur steel. Consequently,
it is also shown in Fig. 12(b) that with an increase in current depth
to width ratio of the weld bead of selenium and sulfur added steel (a) increase in the voltage if current maintained at a constant value;
increased initially than start declining. But in base metal depth to (b) increase in the anode root (heat distribution) area;
width ratio showing a continual drop with welding current from (c) increases in aerodynamic drag force;
the start. Muthukumaran et al. [47] reported in Fig. 13(a) that the (d) reduce the arc efficiency for runs carried out at constant current.
depth of penetration of 304LN increases with current more effec-
tively in case of flux assisted TIG welding compared to without flux. With an increase in arc length the resistance to flow of charged
Additionally weld width (Fig. 13(b)) in case of the flux assisted TIG particle to maintain the arc increases, which in turn result in higher
welding has lesser increment compare to conventional TIG welding voltage and subsequently strengthen the heat flux density. Because
with welding current [3,14,18,104,106]. of the bell shape of the arc plasma in TIG welding, more the gap
High welding current can influence the nature of molten metal between the electrode tip and work piece, wider will be the anode
VI
flow, consequently the geometry of the weld bead by altering the root area (). This led to a reduction of heat flux density (Q = 2 )
2 
intensity of the responsible forces operating in the weld pool. In at the anode surface. With an increase in arc length heat loss from
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 217

Fig. 12. (a) Surface tension variation with temperature. (b) Weld depth to width ratio of weld as function of welding current for 304 type stainless steel and 304 doped with
sulfur or selenium.

Fig. 13. Variation in weld fusion zone geometry “(a) depth of penetration, (b) weld width” with current, of 304LN austenitic stainless steel welds.

Fig. 14. Effect of weld travel speed on weld geometry with (a) different surface active elements and (b) weld current.

the arc plasma also increases (due to more convection and radi- away from the cathode tip on the arc central axis, the electron
ation) hence the overall efficiency () will decrease. Tanaka et al. temperature was constant value (22,000 K) irrespective of the arc
[40] founded that arc voltage were also increased during TIG weld- length. However, the electron temperature recorded at the anode
ing with increases in arc length shown in Fig. 15. In the same work, spots was decreased with higher arc length. Matsunawa et al. [107]
Tanaka et al. also reported that at a fix position (assumed 1 mm) proposed that out of all these four forces aerodynamic drag forces
218 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

Fig. 15. (a) Schematic of a self-stabilized arc and its root area with anode and (b) Photographs of TIG Arc at 100 A with different arc length.

Fig. 16. Relation between weld ratio d/w and arc length for (a) 304 type stainless steel and 304 doped with sulfur or selenium [28] and (b) various steel casts; each symbol
represents a different steel.

will play dominating role in case of larger arc length (for exam- 5.5 mm of arc length and a current value of 100 A. And stated
ple 8 mm). Later Okada et al. [104] experimentally established this through his finding (Figs. 17 and 18) that although the heat distribu-
and stated that at higher arc length beneficial effect of sulfur on tion area increased with increase in electron tip angle, but that was
penetration became less effective. The effect of arc length on pene- a slight increment (14%) in the heat distribution area over a wide
tration has been further studied by Burgardt et al. [18] and Ishizaki change of electrode tip angle (30◦ –120◦ ). With this Tsai et al. con-
et al. [103] the results being shown in Fig. 16(a) and (b), respec- cluded that theoretically the electrode tip angle should not affect
tively, which corroborate that the d/w ratio decreased with larger the heat distribution area significantly. However, Tanaka et al. [40]
arc length. examined the axial temperature in the arc plasma, anode spot area
With increase in arc length welding voltage, anode root area and and the heat density on the anode surface variation with the elec-
heat loss from the arc column increases. Increase in welding voltage trode tip angle; and reported that the electron temperature and the
strengthens the heat flux density; however, the increase in anode weld cross sectional area attained a maximum value for electrode
root area weakens it. Initially effect of increase in welding voltage tip angle of 45◦ , but a fall in electron temperature was recorded
dominates over the effect of anode root area and the heat loss from for either increase or decrease in electrode tip angle (30◦ and 60◦ ),
the arc column, but after an optimum arc length further increase while the current density changes were little for all three (30◦ , 45◦
in arc length shows that the combine effect of anode root area and and 60◦ ) electrode tip angles taken.
the heat loss from arc column dominate over the welding voltage.

4.2.4.2. Frustum and wedge shaped electrode. Okada et al. [104]


4.2.4. Electrode geometry
reported that a more uniform current distribution obtained in case
The shape of the arc is greatly affected by the geometry of
of frustum and wedge shaped electrode compare to conical tip
the electrode, like the diameter of the electrode, tip type (coni-
electrode of angle 45◦ (Fig. 19), which in turn resulted in lower elec-
cal tipped, Frustum and wedge shaped electrode) and electrode tip
tromagnetic and thermo-capillary forces. Mills et al. [14] observed
angle. For a set of given parameters like current, voltage and arc
that the frustum and wedge shaped electrode produced much
length, electrode geometry may lead to variation of electron den-
lower arc pressure (compared to the conical tip electrode) and
sity which can affect the arc pressure and subsequently Marangoni
inversely proportional to the cross sectional area of the flat surface,
flow in the weld pool. Electrode geometry influences the weld zone
hence produced lesser diameter of the weld pool surface (Fig. 20).
geometry by influencing (a) the arc root area and (b) the arc pres-
The arc pressure varies with electrode tip angle and reported max-
sure (i.e., the aerodynamic drag force).
imum at  = 45◦ [14,103,104,108,109].
Conical type electrode tip is more effective for the higher pene-
4.2.4.1. Conical shaped electrode tip. Tsai et al. [107] studied the tration compare to the frustum and wedge shaped electrode angles.
electrode tip angle effects on the heat distribution area, taking Heat density varies with the electrode tip angle and generally
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 219

Fig. 17. Electron temperature and the cross sectional area with the electrode tip angle.

Fig. 19. Current density obtained with conical tipped and frustum shaped elec-
trodes.

Fig. 18. Heat and the mass distribution with the electrode tip angle.

depends on the arc length. However, the arc pressure was found
maximum at 45◦ in almost all case.

4.2.5. Shielding gas composition


In A-TIG welding process, shielding gases protect the weld zone
and electrode from oxidation and also help to control the temper-
ature of the electrode by cooling effect. Pure argon is commonly
used shielding gas in A-TIG welding process. Different gases have
different ionization potential (IP) and as per their IP, heat flux also
affected during A-TIG welding process. Consequently, it also affects
the fusion zone area
Lambert [14] studied the effect of the different shielding gas
compositions on the weld pool geometry taken Inconel 800 as
base material. Lambert observed during welding that short circuit
voltage were not constant with different shielding gas composi-
tions, which in turn result in different Wb/Wf (Wb = weld width
at the back side of the plate and Wf = front side weld width) ratio
shown in Fig. 21. A number of other shielding gas compositions
were also used by several researchers [2,3,16,18,110,111]. Burgardt
et al. [18] mixed helium (He) with pure argon to TIG weld the AISI Fig. 20. Relation between weld pool diameter and cut (flat) diameter of frustum
304 stainless steel in three conditions (pure, sulfur doped and sele- electrode in stationary arcs.

nium doped). Burgardt et al. reported that the D/W ratio of the pure
AISI 304 without doping reduced with higher percentage of helium, the pure argon and reported that, at the same parameters; depth of
whereas the D/W ratio of the doped AISI 304 (with sulfur and sele- penetration and weld area for both cases (conventional as well as
nium) stainless steels increased with increased helium as shown activating GTAW process) increased with the addition of hydrogen
in Fig. 22. Huang [2,3] added the hydrogen as well as nitrogen in as well as nitrogen shown in Figs. 23 and 24.
220 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

Fig. 21. Wb/Wf as function of arc voltage obtained with various shielding gases for Inconel 800.

Fig. 22. Weld ratio d/w as function of helium content of torch gas for 304 type
stainless steel and 304 doped with 76 ppm Sulfur or 47 ppm Selenium.

Fig. 23. Effect of nitrogen addition on the penetration and cross-sectional area of
weld.

The results obtained in the former cases are consistent with the 4.3. Properties of the metal to be welded
proposal that the enhanced heat input caused increased tempera-
ture gradients and thermo-capillary flows [M(+) and M(−)], which 4.3.1. Thickness of the plate
resulted in further divergence of the d/w ratios for high and low It has been seen that the thickness of the plates to be welded also
sulfur steels. affect the depth and width of the weld. Pollard [19] investigated the

Fig. 24. Penetration and weld area vs hydrogen content in argon shielding gas.
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 221

Fig. 25. Effect of strip thickness on the penetration ratio, D/W.

plate thickness effect on the weld geometry, and reported that it


affects the weld penetration adversely. Depth to width ratio of TIG
welded SUS 304 austenitic stainless steel weld decreased with a
Fig. 26. Dependence of soluble oxygen (%O) on concentration of alloying element
higher plate thickness (Fig. 25). (M) in Fe–M–O systems at 1873 K; concentration of O in Fe where d/dT = 0.
The variation in weld bead geometry can be ascertained with the
heat dissipation rate and the area available for the heat dissipation
which increases with the thickness of the plate.

4.3.2. Composition of metal


Literature survey subjects that base metal affects the penetra-
tion depth and width of the weld during A-TIG welding. Materials
can be broadly classified into two categories (a) ferrous and (b)
non-ferrous.

4.3.2.1. Ferrous alloys. Very small amount of surface active ele-


ments such as oxygen in ferrous alloys have a dramatic effect on the
weld penetration. The Heiple-Roper [96] theory suggests that vari-
able weld penetration is a result of the fluid motion in the weld pool
and that this, in turn, is largely controlled by the concentrations
and properties of certain surface active elements, e.g., S (sulfur)
and O (oxygen), present in the metal. However, some metals such
as aluminum, calcium and cerium react strongly with Group VI ele-
ments, and effectively reduce their solubility in the steel. In order
to obtain an understanding of the effect of certain elements on the
fluid flow in the weld pool and the weld penetration, it is necessary
to appreciate their effect on the surface tension of the melt. For this
purpose, elements are classified into following groups, namely, (a)
Fig. 27. Dependence of soluble sulfur (%S) on concentration of alloying element (M)
Surface active elements and (b) Reactive elements. Only soluble ele- in Fe–M–S systems at 1873 K; concentration of S in Fe d/dT = 0.
ments (sulfur or oxygen) were effective to alter the surface tension
of the molten metal. It means compounds of the sulfur and oxygen
present in the metals during welding do not have any effects on the
the surface properties of the weld pool would be similar to those
surface tension of the weld pool. On the basis of the results obtained
of a pure metal (i.e., d/dT is negative).
from the study of various researchers a general relationship can be
proposed between the elements present and the penetration depth
as follows [14,19,24,25,96,108,112]. (a) Surface active elements
The alloy was assumed to be either a Fe–M–O or a Fe–M–S Sulfur: Effect of sulfur addition in 304 and 316 stain-
ternary, where M is the reactive metal, e.g., Al, Ca, etc (the results less steels had been studied several times in various forms
are given in Figs. 26 and 27 respectively, and indicate the maxi- [6,17,25,111,113–117] like elemental form, compound like FeS
mum levels of soluble oxygen (O) or soluble sulfur (S) which can be or FeS2 as flux and SO2 as shielding gas. In all cases it was
obtained with different alloying additions). The horizontal broken observed that addition of sulfur increased the d/w ratio of the
lines in these diagrams represent the critical O or S concentrations weld.
in pure iron at which d/dT = 0. For concentrations above the bro- Oxygen: Like sulfur oxygen has been reported to increase the
ken lines d/dT would be positive, which is good weld penetration. weld penetration during TIG welding with 304 and 316 stain-
For values of O and S below the lines a negative coefficient and poor less steels. Oxygen was added generally either with shielding
penetration would be anticipated. Low levels of Ca or Al are needed gas or in the form of compound (which release “O” after decom-
to reduce the O content to the critical value (Fig. 27), below which position) as a flux [12,34,36,43,45,51,82,112,117,118].
222 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

Fig. 28. Effect of sulfur content on aspect ratio of weld pool d/w for 304 and 316
type stainless steels.

Fig. 30. Effect of SO2 concentration in shield gas on aspect ratio of weld pool d/w
for 21Cr–6Ni–9Mn stainless steel.

Fig. 31. Effect of various dopant concentrations on aspect ratio of weld pool d/w for
Fig. 29. Effect of oxygen concentrations in shield gas on aspect ratio of weld pool 21Cr–6Ni–9Mn stainless steel.
d/w for 21Cr–6Ni–9Mn stainless steel.

Aluminum: For the Fe–Al–O systems, increase in Aluminum


decreases the percentage of soluble oxygen present, hence con-
Here, one thing is to be pointed out that both Sulfur and Oxy-
sequently increases the amplitude of Marangoni force in the
gen have a positive effect towards penetration, but only up to
weld pool, which in turn result in shallow and wider weld
a limit. Further additions either have no positive influence or
bead. Bennett and Mills [120] pointed out that the addition of
decrease the penetration. The effect can be better understood
Aluminum reduces the penetration shown in Fig. 32 [120].
by the Figs. 28–31.
Silicon and Manganese: Silicon and manganese addition in
Selenium and tellurium: These elements are highly surface
iron up to 1% would not reduce soluble oxygen content to the
active in iron. There are strong indications that positive tem-
critical level where d/dt becomes negative. Oyler [121] pro-
perature coefficients of surface tension are produced by these
posed that the Si (1%) and Mn (2%) levels in 304 steel should be
effects [18,19,24,119]. Heiple et al. [18] have shown (Fig. 23)
reduced to 0.5 ± 0.2% and 1.7 ± 0.3%, respectively. Sundell [24]
that these elements were very effective in improving the weld
and Pollard [19] proposed that small amount of these elements
penetration in 21Cr–6Ni–9Mn stainless steels when using TIG,
(Silicon and manganese) can increase the penetration shown
defocused laser and electron beam welding.
in Fig. 33 and reaches to a peak value of the D/W ratio than fall
(b) Reactive elements
gradually.
During steel making several elements are added to reduce
the Oxygen and Sulfur contents of steels, Silicon and Aluminum
are used for deoxidation and Calcium used for desulfurization. 4.3.2.2. Non-ferrous metals. Variable weld penetration is not
Since the amount of active elements is largely controlled by limited to only ferrous metals; it has also been seen in a case of
these reactive elements so usually these affect the penetration. other metals like zirconium alloys and nickel base alloys.
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 223

Fig. 32. Variation of aspect ratio of weld pool d/w with aluminum content in
21Cr–6Ni–9Mn stainless steel.

Fig. 34. Variation of aspect ratio of weld pool d/w with oxygen content in shield gas
for low and high S samples of Inconel IN 718.

increment in penetration. These fluxes are generally oxides and


halides. The two most renowned and accepted effects of these
fluxes are arc constriction and reversal of Marangoni convection;
because of which about 100–200% increase in penetration achieved
during TIG welding. These fluxes later also known as activating or
activated flux. These fluxes break down into their constituents and
evaporate during welding and make a cover of fumes (electron
negative in nature) around the arc. These fumes extract electrons
from the outer part of the arc column which in turn left narrow
path to flow the charged ions between the electrode and the
workpiece. Hence increase the energy density per unit area of TIG
welding process. The other effects of these fluxes are related to the
Fig. 33. Aspect ratio of weld pool d/w as function of manganese and silicon concen- surface tension force of the weld pool. Surface tension gradient
trations in stainless steels.
(d/dt) becomes positive by using activated flux and hence fluid
flows radially inward into the weld pool. These changes in arc
Differences in depth to width ratios of up to a factor of 10 dur- and weld pool result increase penetration during A-TIG. Initial
ing welding of Zirconium alloys with GTA welding process were studies on this topic showed that surface active elements like
reported [14,96,122]. Samples of the alloys were produced by dif- sulfur and oxygen affect the penetration positively. These works
ferent refining processes, and it was found that the highest weld motivated use of flux after the 1990s. So many researchers worked
penetration was obtained with material which had been produced for enhancement of penetration by using different types of fluxes,
by melting under inert gas. Without exception, the chlorine and including combination of different flux compositions. In this
hydrogen levels in this material were at least twice as high as those section the author has tried to consolidate the outputs of the
found in vacuum melted material. work’s done with different types of fluxes.
Lu et al. [36] mentioned in his published that savage used six dif- A number of fluxes are being used for A-TIG by different
ferent minor elements during the GTA welding of the Inconel 600. researchers and it was proposed that the effect of these are very
Silicon and Sulfur were the most effective amongst them to increase different from each other while keeping other parameters same for
the penetration depth. It is also suggested that even Titanium all [6,13,29,38,42,54,55,61,68,125,126]. Paulo et al. [6] studied six
increased the weld penetration whereas Aluminum had a reverse types of fluxes namely Al2 O3 , AlF3 , CaF2 , Cr2 O3 , Fe2 O3 , SiO2 and TiO2
effect on penetration of Inconel 600. At low oxygen levels, the d/w at the same time on SUS 304. It was observed that the high penetra-
ratio was more for high sulfur Inconel l718 [14,18,20]. The ratio tion occurred just after the transition from TIG to A-TIG welding.
for this alloy progressively decreased with a reduction in oxygen Some fluxes (Cr2 O3 , SiO2 and TiO2 ) give exceptionally good pen-
content shown in Fig. 34. Huang et al. [123,124] proposed a unique etration. Author, however, did not gave the reason for variation
way to use the different flux layer simultaneously for increased responsible of these fluxes while keeping all other parameters same
penetration depth along with quality weld bead appearance. for all fluxes.
Researchers [6,13,35,67] noted in their review of earlier studies
4.4. Flux that when fluorine, chlorine and bromine were either present as
trace elements in steels and titanium alloys, or applied in the form
In A-TIG welding process, concept of use of flux was first of fluxes to the surface of the metal, systematically better pene-
introduced by Paton welding institute way back in the 1960s. A tration was observed. At the same time arc constriction was also
simple process of applying a thin layer of flux over the surface of reported. From the available papers it is clear that chlorine is the
the component to be welded before welding showed a spectacular most frequently used halide as an activating flux in various forms
224 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

Fig. 35. Effect of different chlorides and current on penetration.

Fig. 37. Effect of coating density on penetration depth of TIG weld.

and NiF2 developed by NPUST, Taiwan) on the penetration and


d/w ratio of 316L steel by varying its coating density on the metal
surface to be welded. For a given current level, weld penetration
and d/w ratio increases with increase of coating density shown in
Fig. 37. At the current 125 A, penetration increases with coating
density from 0 to 0.92 mg/cm2 , thereafter in case of coating density
up to 4 mg/cm2 did not affect penetration appreciably. Further,
increase in coating density adversely affected the penetration.
Moreover, at 225 A current, penetration increased with increase in
coating density up to 1.86 mg/cm2 . The reduction in penetration
depth at high coating density attributed to the higher heat energy
consumption required to melt the thick flux barrier. Some other
researchers presented the similar trend of the depth of penetration
with the coating density. Many of them stated that penetration
depth first increases than remain unchanged for a wide range
thereafter fall down [67,76,83,130].
Fig. 36. Characteristics of weld geometry produced with and without flux. Although a large number of study has been done on the flux
assisted welding, but there is not a common proposal that why
to see the effect of the halides on the penetration (Fig. 35). Glick- these fluxes behave differently to the surface tension and the
stein, Ludwig, Savage and Lundin discussed their findings on the arc constriction. However, up to some extent these behaviors are
basis of the surface tension effect while Marya suggested that the correlated with different properties of flux like boiling point, den-
first ionization potential of the element ‘M’ in the chloride ‘MCly ’ is sity, thermodynamic stability, and electronegativity, but a linear
more important [24,91,112,127]. relationship between these properties and weld performance is
Dong et al. [35] has taken eight types of composition out of those lacking.
five were single component (TiO2 , Cr2 O3 , SiO2 , ZrO2 and AlF3 ), three
were different multi component fluxes on SUS 304. Arc constric- 5. Recent development in TIG process to enhance the depth
tion and reversal of Marangoni conviction were reported with these of penetration
fluxes in this work. Effect of AlF3 and ZrO2 as an activated flux for
A-TIG was negative as the d/w ratio of weld is obtained using AlF3 Even though the flux assisted gas tungsten arc welding has been
and ZrO2 was below than conventional (without flux) TIG weld and quite successful to increase the depth of penetration up-to four fold,
the same was attributed to the fact that the reversal of Marangoni the effectiveness of the process is sensitive to the flux coating den-
convection was not found to occur. Tseng et al. [56,128] showed sity, particle size and coating pattern uniformity on the base plate
(Fig. 36) the characteristics of AISI 316 SS TIG welded plate with dif- [127]. The slag after A-TIG is generally retained on the weld sur-
ferent fluxes. And stated that all oxides fluxes were not changed the face, which is not desirable for the weld efficiency and weld quality
Marangoni convection mode in molten weld pool. Similar experi- [65]. To overcome these limitations, some researchers have been
ments have been done by other researchers also, to develop new also looking for alternate processes such as mixed gas TIG welding,
flux and flux compositions for higher penetration and d/w ratio double shielded TIG process and double electrode TIG welding.
during A-TIG welding on a variety of materials [10,36,57,79,129]. In mixed gas TIG welding, the surface active gases were
Tseng et al. [57] used different approaches to see the effect mixed with regular shielding gases to implement on the weld
of flux on the penetration; in his work he studied the effect of a pool. The process has been explored with SO2 by Hieple et al.
commercial flux (comprising of SiO2 , TiO2 , Cr2 O3 , MoO3 , MoS2 [18], with hydrogen by Hsieh et al. [131], with CO2 by Lu
R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228 225

Fig. 38. Schematic of double shielded TIG welding torch nozzle.

et al. [42] and also with other gases by different researchers Fig. 39. Double electrode TIG welding torch.

[2,3,12,36,46,86,111,117,132,133]. All these work have been


reported increased depth of penetration as compared to TIG weld- explored effectively, very less information is available about the
ing process with partial elimination of the A-TIG welding process behavior of the process and its effect on the weldment properties.
limitation. The drawbacks of the mixed gas TIG welding were also
reported and some of them are mentioned here. Addition of O2 in 6. Conclusions
He–Ar shielding gas gave higher penetration but was sensitive to
cast to cast materials [2]. The effect of the mixed gas TIG welding (a) Arc constriction and the reversal of the Marangoni convection
was base metal property dependent [27]. The SO2 is toxic active are the two most accepted mechanisms for the tremendous
gas while O2 and CO2 reduce the life of tungsten electrode through increase of the penetration depth during the A-TIG welding.
oxidation. The vapor of the flux evaporated during the welding is elec-
A double shielded TIG welding torch nozzle was designed in such tronegative in nature and hence it constricts the arc plasma ion’s
a way that two different gases or gas mixture could flow simulta- path toward the center of the arc. Flux applied on the surface
neously without mixing. A schematic of the nozzle is shown in the decreases the surface tension of the weld pool and, it reverses
Fig. 38. From the schematic it is clear that the nozzle was designed the surface tension gradient from negative to positive, which in
to such as extent that the active gas could reach to the weld pool turn responsible for fluid flow from the fusion zone boundary
without affecting the tungsten electrode, which was shielded by toward the weld pool center.
the lesser active or passive gas. Fujii et al. [43] used O2 and CO2 as (b) Oxides and halides are frequently used fluxes to enhance the
active and He as a passive gas during double shielded TIG welding penetration, while the information obtained from the published
of SUS 304 austenitic stainless steel. They reported 9.4 mm pen- papers are also showing that all these fluxes are not useful to
etration depth with almost non-degraded tungsten electrode at enhance the penetration depth; i.e., the effectiveness of the flux
welding current 160 A, welding speed 0.75 mm/min and 1 mm of is chemical and physical property dependent of the material.
electrode gap. Li et al. [4,118,134] used He and He + O2 as active Any kind of relationship to select flux for different material is
and pure argon as passive gas during the welding of 0Cr13Ni5Mo not being proposed till now.
martensitic stainless steel. Lu et al. [133] demonstrated the effect (c) The depth of penetration of A-TIG weld increases with the
of the Ar + CO2 on the penetration depth while welding of the SUS increase of flux coating density, and achieved maximum for an
304 austenitic stainless steel. The active gas used in the process optimum value of flux coating density than being constant for
was successful in reversing the Marangoni flow direction without a wide range, subsequently further increase in coating density
affecting the electrode life, and thus increased depth of penetration will result in a reduction in penetration depth. The optimum
was achieved as compared to TIG welding [4,43,65,118,133,134]. value of flux coating density increases with the welding current.
A double electrode TIG welding is a recently developed variant However there is need of dynamic study to define the limits.
of TIG welding process in which the arc is initiated through the (d) Sulfur and oxygen (soluble) also have positive effects to increase
coupling of two arcs generated from two insulated electrodes in the penetration depth by altering the surface tension gradient.
the same welding torch shown in Fig. 39 [135]. However, some These surface active elements can be provided in the weld pool
researchers used the 2nd electrode to by-pass the current in either through shielding gases or by injecting in the materials at
different torch [136]. Use of two electrodes simultaneously in TIG the time of casting. Aluminum has adverse effect on the depth of
welding was first reported by Kobayashi et al. [40,135,137] and penetration; though with silicone and magnesium it increases
successfully demonstrated in different welding positions. Leng first then starts falling.
et al. [138] and Ding et al. [139] performed the two-dimensional (e) Arc length and the welding speed have a negative effect on the
measurement of coupling arc pressure during double electrode TIG penetration depth, while the welding current promotes it. Elec-
welding and reported that arc pressure distribution was different trode tip geometry has little effect on the weld pool geometry.
from the axial symmetrical distribution of the traditional single arc Depth of penetration increases first with electrode tip vertex
TIG welding. A three dimensional mathematical model for double angle and usually a maximum at about 45 degree then decreases.
electrodes TIG welding was extended to include the anode melting The weld penetration depth also decreases with increased thick-
and the weld pool formation [140]. This model demonstrated that ness of the plate to be welded.
the unequal welding current through the different electrodes had (f) Surface degradation of the A-TIG weldment may be a conceiv-
a significant effect on the arc behavior and weld pool dynamics, able problem. However, because of its easiness and superior
whereas it has a little effect on the weld shape and size. As the result, it has great potential to increase the productivity of the
double electrode TIG welding process is very novel and has not been fabrication industries.
226 R.S. Vidyarthy, D.K. Dwivedi / Journal of Manufacturing Processes 22 (2016) 211–228

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