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Okesip
Okesip
Okesip
Data Standarisasi
1. Standarisasi Tio 0,025N
TA :
S : 10,03 mL
D : 10,02 mL
W KIO 3 1000
N TIO = ×
bst KIO 3 V
0,0890 1000
= ×
35,6 10,025
= 0,2494 N
2. Standarisasi I2
TA :
S : 10,07 mL
D : 10,07 mL
V tio × N tio
N I2 =
VI2
10,07× 0,2494
=
10
= 0,2511 N
3. Standarisasi Larutan Induk H2S
Pengulangan V I2 V TIO
S 14,00 mL 0,10 mL
D 14,00 mL 0,13 mL
16000
Ppm S2- = ( [ V I 2×∋2 ] −[ Vtio× Ntio ] ) ×
V . Lar . Induk H 2 S
16000
= ( [ 14,00 ×0,2511 ] −[ 0,115 ×0,2494 ] ) ×
5
= 1028 ppm
DATA S2-
Deret Standar
ppm Abs
0 0
0,1 0,0804
0,2 0,1689
0,4 0,3405
0,6 0,5002
0,8 0,6365
Sampel
Abs Ppm
S 0,0040 -0,0018
D 0,0039 -0,0017
Sp (0,1) 0,0292 0,0293
Cs (0,4) 0,3496 0,4267
RPD = | −0,00185 |
−0,0018−(−0,0017 )
× 100 %
= 5,4%
0,4267
Cs(0,4) = × 100 %
0,4
= 106,67%
0,0293−(−0,00185)
Sp = ×100 %
0,1
= 31,15%
Deret Standar
ppm Abs
0 0
0,02 0,0940
0,04 0,1878
0,06 0,2350
0,08 0,3765
0,1 0,4655
0,2 0,8635
Sampel
0,0176−0,0002
Sp = ×100 %
0,02
= 87%
0,0367
Cs = × 100 %
0,04
= 91,75%
Standarisasi AgNO3
Vp I : 35,20 mL
II: 35,2 mL
C NaCl× V NaCl
N AgNO3 =
V AgNO 3
0,0141× 50
=
35,20
= 0,0200 N
Standarisasi CN
Vb : 0,12 mL
Vp I : 24,10 mL
II : 24,10 mL
( V AgNO 3−Vb ) × N AgNO 3 × Bst CN −×1000
Ppm CN =
V Lar . Standar
( 24,10−0,12 ) ×0,0200 ×52,04 × 1000
=
25
= 998,33 ppm
Deret Standar
Abs
0 0,7134
0,2 0,6705
0,5 0,5981
1 0,5007
1,5 0,4189
Intercept = 0,7067
R = -0,9974
S = -0,1976
Sampel
Abs Ppm
S 0,6967 0,0506
D 0,6965 0,0516
Sampel sp 0,5850 0,6159
CRM 0,5841 0,6341
ANALISIS TOTAL SUSPENDED SOLID
Data TSS
I II
Botol Cawan Kosong + Kertas Saring 4,5542 g 4,5252 g
Bobot Cawan Kosong 4,4420 g 4,4133 g
Bobot Kertas Saring 0,1122 g 0,1119 g
Perhitungan
Simplo Pemanasan I
4,5529−0,1122
Ppm TSS = × 1000
100
= 44,40 ppm
Simplo Pemanasan I
4,5532−0,1122
Ppm TSS = ×1000
100
= 44,41 ppm
Duplo Pemanasan I
4,5256−0,1119
Ppm TSS = ×1000
100
= 44,14 ppm
Duplo Pemanasan II
4,5259−0,1119
Ppm TSS = ×1000
100
= 44,14 ppm
COD
0 0,2152
10 0,1996
20 0,1759
40 0,1487
60 0,1146
80 0,0663
90 0,0455
R = -0,9968
I = 0,2176
S = -0,00186
Abs Ppm
S 0,2150 1,3478
D 0,2152 1,2903
Sp (20) 0,1827 18,7634
Cs (60) 0,1149 55,3763
RPD = |1,3478−1,2903
1,3191 |×100 %
= 4,36%
18,7634−1,3191
Sp = × 100 %
20
= 87,22%
55,3763
Cs = ×100 %
60
= 92,29%
Deret Standar
ppm abs
0 0
0,1 0,0919
0,2 0,1807
0,4 0,3663
0,6 0,5431
0,8 0,7118
1 0,8806
R = 0,9998
I = 0,0053
S = 0,8828
Sampel
Abs Ppm
S 0,0006 -0,0053
D 0,0004 -0,0055
Sp (0,4) 0,3584 0,3999
Cs (0,6) 0,5356 0,6007
RPD = |
−0,0053−(−0,0055)
−0,0054 |
× 100 %
= 3,70%
0,3999−(−0,0054)
Sp = × 100 %
0,4
= 101,33%
0,6007
Cs = × 100 %
0,6
= 100%
Data TDS
Simplo Duplo
Botol Cawan Kosong 63,6472 g 59,0546 g
Bobot Cawan + Residu Pemanasan I 63,6583 g 59,0661 g
Bobot Cawan + Residu Pemanasan II 63,6586 g 59,0663 g
Perhitungan
Larutan SPADNS
958 mg = 0,958 g SPADNS →
LU 500 mL
+ H2O
Lar. As. Zirkonil
133 mg = 0,133 g