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  • Curvas de Potenciometria

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    Diarlis Yasith Seña Orozco
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    This document contains the results of two experiments where the pH of a solution was measured after adding increasing amounts of sodium hydroxide (NaOH). For each experiment, tables show the volume of NaOH added, the measured pH, and calculated values. Graphs of the first and second derivatives of pH with respect to volume of NaOH added are also presented. The experiments investigate the relationship between pH and amount of base added to reach different points in the titration curve.

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    CURVAS DE POTENCIOMETRIA

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    This document contains the results of two experiments where the pH of a solution was measured after adding increasing amounts of sodium hydroxide (NaOH). For each experiment, tables show the volume of NaOH added, the measured pH, and calculated values. Graphs of the first and second derivatives of pH with respect to volume of NaOH added are also presented. The experiments investigate the relationship between pH and amount of base added to reach different points in the titration curve.

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    © All Rights Reserved
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    Download as pdf or txt
    17 views3 pages

    Curvas de Potenciometria

    Uploaded by

    Diarlis Yasith Seña Orozco
    This document contains the results of two experiments where the pH of a solution was measured after adding increasing amounts of sodium hydroxide (NaOH). For each experiment, tables show the volume of NaOH added, the measured pH, and calculated values. Graphs of the first and second derivatives of pH with respect to volume of NaOH added are also presented. The experiments investigate the relationship between pH and amount of base added to reach different points in the titration curve.

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    © All Rights Reserved
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    of 3

    PRIMER ENSAYO

    ENSAYO 1
    V (ml) pH Exp. V1 pH' V2 pH''
    0 3,2 0,475 0,54736842
    0,95 3,72 1,45 0,33 0,975 -0,22294197
    1,95 4,05 2,475 0,21904762 1,025 -0,10824623
    3 4,28 3,5 0,19 1,025 -0,02833914
    4 4,47 4,5 0,17 1 -0,02
    5 4,64 5,5 0,17 1 0
    6 4,81 6,5 0,19 1 0,02
    7 5 7,525 0,21904762 1,025 0,02833914
    8,05 5,23 8,525 0,30526316 1 0,08621554
    9 5,52 9,525 0,67619048 1 0,37092732
    10,05 6,23 10,1 1,7 0,575 1,7805383
    10,15 6,4 10,2 2,4 0,1 7
    10,25 6,64 10,3 4 0,1 16
    10,35 7,04 10,9 3,75454545 0,6 -0,40909091
    11,45 11,17 11,95 0,36 1,05 -3,23290043
    12,45 11,53 12,975 0,20952381 1,025 -0,14680604
    13,5 11,75 6,75 0,87037037 -6,225 -0,10616009

    PRIMERA DERIVADA
    4.5
    4
    3.5
    3
    ΔpH/ΔV

    2.5
    2
    1.5
    1
    0.5
    0

    VNaOH (mL)
    SEGUNDA DERIVADA
    20

    ΔpH/ΔV 15

    10

    -5
    VNaOH (mL)

    SEGUNDO ENSAYO

    ENSAYO 2
    V (ml) pH Exp. V1 pH' V2 pH''
    0 3,2 0,475 0,6
    0,95 3,77 1,475 0,31428571 1 -0,28571429
    2 4,1 2,5 0,23 1,025 -0,08222997
    3 4,33 3,5 0,19 1 -0,04
    4 4,52 4,475 0,18947368 0,975 -0,00053981
    4,95 4,7 5,5 0,18181818 1,025 -0,00746878
    6,05 4,9 6,525 0,21052632 1,025 0,02800794
    7 5,1 7,5 0,26 0,975 0,05074224
    8 5,36 8,525 0,44761905 1,025 0,18304297
    9,05 5,83 9,1 0,9 0,575 0,78674948
    9,15 5,92 9,2 1 0,1 1
    9,25 6,02 9,3 1,2 0,1 2
    9,35 6,14 9,425 1 0,125 -1,6
    9,5 6,29 9,55 2 0,125 8
    9,6 6,49 9,65 3,5 0,1 15
    9,7 6,84 10,2 4,19 0,55 1,25454545
    10,7 11,03 11,2 0,45 1 -3,74
    11,7 11,48 12,225 0,21904762 1,025 -0,2253194
    12,75 11,71 6,375 0,91843137 -5,85 -0,11955278
    PRIMERA DERIVADA
    4.5
    4
    3.5
    3
    ΔpH/ΔV

    2.5
    2
    1.5
    1
    0.5
    0

    VNaOH (mL)

    SEGUNDA DERIVADA
    20

    15
    ΔpH/ΔV

    10

    -5
    VNaOH (mL)

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