MSE 3002-S-20 Useful Relations February 19/March 25, 2020

Thermal Diffusivity Dimensionless Parameters Series Composite Wall

k T  Tf x
 t hL X 
C P 
Ti  T f
Fo  2
L
Bi 
k L T j  Ti 
Q ij 
 Rth
Cartesian
 1 Q  T T T 
q   kT   k x  ky  kz
A dt  x y z  Rconv  1
hA

 T   T    T    T 
C P 

 R   T      k  T   kx  ky   kz  R plate  L
 t  x  x  y  y  z  z  kA
T   2T  2T  2T 
  2T    2  2  2 
t  x y z 

Cylindrical R 
Ln 2 
 1 Q  T 1 T T  R
q  kT   k r  k  kz Rcylinder   1
A dt  r r  z  2kL

T  1   T  1  2T  2T 
  2 T    r  2  2
t  r r  r  r  z 
2

Spherical

 1 Q  T 1 T 1 T  1  1 
q   kT   k r  k  k  R R2 
A dt  r r  r sin    Rsphere  1
4k
T  1   2 T  1   T  1  2T 
  2 T    2 r  2  sin   2 
t  r r  r  r sin      r sin 2   2 

Newtonian Condition
T  Tf   hA  V V R V R
 ;
 hAT  T f 
dT  exp  t plate :  L; cylinder : sphere : 
 VC P A A 2 A 3
dt Ti  T f  C PV 
Some Useful Boundary Conditions
Fixed Temperature Symmetry, Adiabatic Convection Intimate Contact
Interface  
T
  TSurface  T f 
h  T   T 
TBoundary  TFixed
T k    k 
0 x k  x  boundary  x  boundary
x

Constant Power Input Heat Transfer Coefficient Gas Constant Error Function
2
   kA T q erf  N  
N
Rgas  8.314 J 
2

Q h e u du
x T mol  K  0
MSE 3002-S-20 Useful Relations February 19/March 25, 2020

Mixed Control – Infinite Plate Semi-infinite Wall

T  Tf sin  n L 
  T  TS

 x 
 2 exp  2nt cos n x   erf  
Ti  T f n 1 n L  sin  n L  cos n L  TO  TS  2 t 

  5.669 x108 SI
     1 eb  T 4 Ai Fij  A j F ji F j
ij 1

 T14  T24 
hrad 
 T1  T2  
Q 12  A1F 12 T14  T24 

Sievert’s Law (for H) Equilibrium Constant Activity of Component k Activity Coefficient

  G R   Gk 
K  exp  a k  exp  ak   k X k
C H  S PH 2
 RT   RT 

~ 1 C

j
1 n
 D
C C  2C
D 2
C  CS  x 
 erf 
D
C 
CB
xdC
A t x Ci  C S  2t
t x  2 Dt  x

 Q 
  ln ai   C   C 
D   X i D*j  X j Di*    C*  C* 
~ D  DO exp  dx *
  RT   D      D   
  ln X i  dt  x  x*  x  x*

 C 
     DC 
 t 

 C    C    C    C 
    Dx    Dy    Dz 
 t  x  x  y  y  z  z 