Desired capacity of Nitro-Phosphate fertilizer (tons/day)

Raw materials
Rock phosphate (Kg) 1612640.31826918

Nitric acid(50%) (Kg) 3945822.05533948

Theoratical Ratio between rock phosphate to nitric acid(50% wt.) = 0.47.

We are feeding 15% excess nitric acid to ensure complete digestion of rock phosphate.

Composition of Raw materials

Rock Phosphate Nitric Acid

Compounds %wt. Compounds
Moisture 2% Nitric Acid

Ca3(PO4)2 64.59% H2O

MgO 1.30%

CaF2 8.07%

CaCO3 13.40%
SiO2 7.86%

Inerts 2.78%

Reactor

Input Stream 1 Input Stream 2

Component Mass Flowrate Component
H2O 1972911.02766974 H2O

HNO3 1972911.02766974 Ca3(PO4)2

3945822.05533948 MgO

CaF2

CaCO3

SiO2

Inerts

Total input (Kg) 5558462.37360866

Total output (Kg) 5558462.37360866

Difference 0

Reactions

CaCO3 + 2HNO3 Ca(NO3)2 + H2O + CO2

CaF2 + 2HNO3 Ca(NO3)2 + 2HF

Ca3(PO4)2 + 6HNO3 3Ca(NO3)2 + 2H3PO4

MgO + 2HNO3 Mg(NO3)2 + H2O

Ca(NO3)2 + SiO2 + 6HF CaSiF6 + 2HNO3 + 2H2O

For reaction 1
 CaCO3 + 2HNO3 Ca(NO3)2 + H2O + CO2

Conversion of CaCO3 = 100%

Inlet flow of CaCO3 216093.80264807
Outlet flow of CaCO3 0

Extent of reaction 2160.9380264807

Specie Molecular weight Coefficent

HNO3 63 2
Ca(NO3)2 164 -1
CO2 44 -1
H 2O 18 -1

For reaction 2

CaF2 + 2HNO3 Ca(NO3)2 + 2HF

Conversion of CaF2 100%

Inlet flow of CaF2 130123.94728114
Outlet flow of CaF2 0

Extent of reaction 1668.25573437359

Specie Molecular weight Coefficent

HNO3 63 2

Ca(NO3)2 164 -1

HF 20 -2
 For reaction 3

Ca3(PO4) + 6HNO3 3Ca(NO3)2 + 2H3PO4

Conversion of Ca3(PO4)2 100%

Inlet flow of Ca3(PO4)2 1041604.38157006
Outlet flow of Ca3(PO4)2 0

Extent of reaction 3360.01413409698

Specie Molecular weight Coefficent

HNO3 63 6

Ca(NO3)2 164 -3

H3PO4 98 -2

For reaction 4

MgO + 2HNO3 Mg(NO3)2 + H2O

Conversion of MgO 100%

Inlet flow of MgO 20964.3241374993

Outlet flow of MgO 0

Extent of reaction 524.108103437483

Specie Molecular weight Coefficent

HNO3 63 2

Mg(NO3)2 148 -1
H2O 18 -1

For reaction 5

Ca(NO3)2 + SiO2 + 6HF CaSiF6 + 2HNO3 + 2

Conversion of SiO2 20%

Inlet flow of SiO2 126801.908225506
Outlet flow of SiO2 101441.526580404

Extent of reaction 422.673027418352

Specie Molecular weight Coefficent

Ca(NO3)2 164 1

HF 20 6

CaSiF6 182 -1

HNO3 63 -2

H2O 18 -2
 Inert Seperator

Since 100% removal of inerts is not possib

During the operation minute proporti
proprtion to be 2% of total coming from the reactor

Specie Input stream (Kg) Output Stream (Kg)

Ca(NO3)2 2211796.35425921 2167560.42717402

H 2O 2068710.89336071 2027336.6754935

HF 16009.4660847414 15689.2767630466
H3PO4 658562.770283008 645391.514877348

Mg(NO3)2 77567.9993087475 76016.6393225726

HNO3 207566.451535032 203415.122504332

SiO2 101441.526580404 99412.6960487964

CaSiF6 76926.4909901401 75387.9611703373

Inerts 44799.1480415178 17919.6592166071

Heat exchanger #1

In heat exchanger, temperature of digesting solution coming from the inert removal section is decr
using the ammonical solution(25%) coming from the crystillizer to maximize the heat conservation

Main Stream
Specie Input (Kg) Output (Kg)
Ca(NO3)2 2167560.42717402 2167560.42717402

H 2O 2027336.6754935 2027336.6754935

HF 15689.2767630466 15689.2767630466

H3PO4 645391.514877348 645391.514877348

Mg(NO3)2 76016.6393225726 76016.6393225726

HNO3 203415.122504332 203415.122504332

SiO2 99412.6960487964 99412.6960487964

CaSiF6 75387.9611703373 75387.9611703373

Inerts 17919.6592166071 17919.6592166071

 Crystallizer

In Crystallizer, when cooled below 10°C, one mole of calcium nitrate combin

to give needle like CNTH crystals.

Moles of Ca(NO3)2 entering the crystalizer

Moles of H20 entering the crystalizer

Moles of H2O required for crystalization

Moles of H2O left

1 mole of Ca(NO3)2 combines with four moles of H2O to give 1 mole of Ca(NO3)2.4H

Moles of Ca(NO3)2.4H2O produced

Main stream
Specie Input (Kg) Output (Kg)
Ca(NO3)2 2167560.42717402 0

Ca(NO3)2.4H2O 0 3119172.32203091

H2O 2027336.6754935 1075724.78063661

HF 15689.2767630466 15689.2767630466

H3PO4 645391.514877348 645391.514877348

Mg(NO3)2 76016.6393225726 76016.6393225726

HNO3 203415.122504332 203415.122504332

SiO2 99412.6960487964 99412.6960487964

CaSiF6 75387.9611703373 75387.9611703373

Inerts 17919.6592166071 17919.6592166071

CNTH Separator

Crystals of Calcium nitrate tetra-hydrate(CNTH) do not have same size. Therefore 100% separation
Assuming 92% CNTH crystals can be separated from the main stream. Similarly, some portion(1.5%
stream also retained in the CNTH crystals separated from the main stream.

Specie Input (Kg) CNTH filtrate (Kg)

CNTH 3119172.32203091 2869638.53626844

H 2O 1075724.78063661 16135.8717095492

HF 15689.2767630466 235.339151445699

H3PO4 645391.514877348 9680.87272316021

Mg(NO3)2 76016.6393225726 1140.24958983859

HNO3 203415.122504332 3051.22683756497

SiO2 99412.6960487964 1491.19044073195

CaSiF6 75387.9611703373 1130.81941755506

Inerts 17919.6592166071 268.794888249107

Heat exchanger #2

In heat exchanger mother liqour is heated from 278K to 318K by means of condensate steam leavin

Main Stream
Specie Input (Kg) Output (Kg)

CNTH 249533.785762473 249533.785762473

H 2O 1059588.90892706 1059588.90892706

HF 15453.9376116009 15453.9376116009

H3PO4 635710.642154187 635710.642154187

Mg(NO3)2 74876.389732734 74876.389732734

HNO3 200363.895666767 200363.895666767

SiO2 97921.5056080644 97921.5056080644

CaSiF6 74257.1417527822 74257.1417527822

Inerts 17650.864328358 17650.864328358

 Neutralizer

Reactions

CaSiF6 + 2Ca(NO3)2 + 2H2O + 4NH3 3CaF2 + SiO2 +

Ca(NO3)2 + H3PO4 + 2NH3 CaHPO4 + 2NH4N

H3PO4 + NH3 NH4H2PO4

HNO3 + NH3 NH4NO3

Input Stream 1 Input Stream 2

Specie Mass Flowrate (Kg) Specie

Ammonia 221576.779730185 CNTH

H 2O

HF
H3PO4

Mg(NO3)2

HNO3

SiO2

CaSiF6

inerts
 Reaction 1

CaSiF6 + 2Ca(NO3)2 + 2H2O + 4NH3 3CaF2 + SiO2 + NH4NO3

Conversion of CaSiF6 100%

Inlet flow of CaSiF6 74257.1417527822
Outlet flow of CaSiF6 0

Extent of reaction 408.006273366935

Specie Molecular weight Coefficient

Ca(NO3)2 164 2

H2O 18 2

NH3 17 4

CaF2 78 -3

SiO2 60 -1

NH4NO3 80 -4

Reaction 2

Ca(NO3)2 + H3PO4 + 2NH3 CaHPO4 +2 NH4N

Conversion of Ca(NO3)2 100%

Inlet flow of Ca(NO3)2 39599.923440564
Outlet flow of Ca(NO3)2 0

Extent of reaction 241.462947808317

 Specie Molecular weight Coefficient
H3PO4 98 1

NH3 17 2

CaHPO4 136 -1

NH4NO3 80 -2

Reaction 3

H3PO4 + NH3 NH4H2PO4

Conversion of H3PO4 100%

Inlet flow of H3PO4 612047.273268972
Outlet flow of H3PO4 0

Extent of reaction 6245.38033947931

Specie Molecular weight Coefficient

NH3 17 1

NH4H2PO4 115 -1

Reaction 4

HNO3 + NH3 NH4NO3

Conversion of HNO3 99%

Inlet flow of HNO3 200363.895666767
Outlet flow of HNO3 2003.63895666768

Extent of reaction 3148.5755033349

 Specie Molecular weight Coefficient
NH3 17 1

NH4NO3 80 -1
 Evaporator

Input Stream Output Stream 1

Specie Mass flowrate (Kg) Specie

Ammonia 25925.3635879093 NH4NO3

NH4NO3 421082.119393542 NH4H2PO4

NH4H2PO4 718218.739040121 CaHPO4

CaHPO4 32838.9609019311 SiO2

SiO2 122401.882010081 CaF2

CaF2 95473.4679678628 H2O

H2O 500000.052762728 Mg(NO3)2

Mg(NO3)2 74876.389732734 HF

HF 15453.9376116009 HNO3

HNO3 2003.63895666768 inerts

inerts 17650.864328358
 Prilling Tower
Humidity of entering air at 32 degree C (kg H2O/kg Air)
Saturation Humidity of air at 32 degree C (kg H2O/kg Air)

Minimum air required for drying (kg)

Actual air required is 15% excess of the minimum required air (kg)
Actual humidity of leaving air (kg H2O/kg Air)

Input Stream 1 Input Stream 2

NH4NO3 421082.119393542 Air

NH4H2PO4 718218.739040121 H2O

CaHPO4 32838.9609019311

SiO2 122401.882010081

CaF2 95473.4679678628

H2O 2500.00026381364

Mg(NO3)2 74876.389732734

HF 15453.9376116009

HNO3 2003.63895666768

Inerts 17650.864328358

Total 1502500.00020671
 Overall material balance

Input Stream Output Stream

Specie Mass flowrate (Kg) Specie

Rock phosphate (Kg) 1612640.31826918 CO2

Nitric acid(50%) (Kg) 3945822.05533948 Ca(NO3)2

Ammonia 221576.779730185 H2O

Air 2438403.03074342 HF

H2O 18166.1025790385 H3PO4

Mg(NO3)2

HNO3

SiO2

CaSiF6

Inerts

Air

Ammonia

Nitro-Phosphate fertilizer

Total input to the plant(Kg) 8236608.28666131

Total output from the plant(Kg) 8236608.28671841

Difference 0
 1500

k phosphate.

Nitric Acid
%wt.
50%

50%

Input Stream 2 Output Stream 1

 Mass Flowrate Component Mass

32252.8063653836 Ca(NO3)2 2211796.35425921

1041604.38157006 H2O 2068710.89336071

20964.3241374993 HF 16009.4660847414

130123.94728114 H3PO4 658562.770283008

216093.80264807 Mg(NO3)2 77567.9993087475

126801.908225506 HNO3 207566.451535032

44799.1480415178 SiO2 101441.526580404

1612640.31826918 CaSiF6 76926.4909901401

Inerts 44799.1480415178

+ CO2

H3PO4

2
O

O3 + 2H2O
+ CO2

Input Extent Output

1972911.02766974 2160.9380264807 1700632.83633317

0 2160.9380264807 354393.836342835

0 2160.9380264807 95081.2731651508

2005163.83403512 2160.9380264807 2044060.71851178

Input Extent Output

1700632.83633317 1668.25573437359 1490432.6138021

354393.836342835 1668.25573437359 627987.776780104

0 1668.25573437359 66730.2293749437
H3PO4

Input Extent Output

1490432.6138021 3360.01413409698 220347.271113443

627987.776780104 3360.01413409698 2281114.73075582

0 3360.01413409698 658562.770283008

Input Extent Output

220347.271113443 524.108103437483 154309.65008032

0 524.108103437483 77567.9993087475
 2044060.71851178 524.108103437483 2053494.66437365

CaSiF6 + 2HNO3 + 2H2O

Input Extent Output

2281114.73075582 422.673027418352 2211796.35425921

66730.2293749437 422.673027418352 16009.4660847414

0 422.673027418352 76926.4909901401

154309.65008032 422.673027418352 207566.451535032

2053494.66437365 422.673027418352 2068710.89336071

val of inerts is not possible as well as feasible therefore considering 60% removal of inerts and SiO2 from diss
peration minute proportion of the dissolved slurry components also seperated with inerts. Therefore taking t
eactor

Inert Stream (Kg)

44235.9270851842

41374.2178672143

320.189321694828
 13171.2554056602

1551.35998617495

4151.32903070064

2028.83053160809 Total input (Kg) 5463381.10044351

1538.5298198028 Total output (Kg) 5463381.10044351

26879.4888249107 Difference 0

t removal section is decreased from 352K to 318K

e the heat conservation

Utility stream
Specie Input (Kg) Output (Kg)

Ammonical sol. 6188461.68791732 6188461.68791732

Total input (Kg) 11516591.6604879

Total output (Kg) 11516591.6604879

Difference 0
le of calcium nitrate combines with four molecules of water

13216.8318730123

112629.815305194

52867.3274920494

59762.487813145

to give 1 mole of Ca(NO3)2.4H2O

13216.8318730123

Utility stream
Specie Input (Kg) Output (Kg)

Ammonical sol. 6188461.68791732 6188461.68791732

 Total input (Kg) 11516591.6604879

Total output (Kg) 11516591.6604879

Difference 0

refore 100% separation of CNTH crystals is not possible.

arly, some portion(1.5%) of other components of the main

Mother Liquour (Kg)

249533.785762473

1059588.90892706

15453.9376116009

635710.642154187

74876.389732734
 200363.895666767

97921.5056080644 Total input (Kg) 5328129.97257056

74257.1417527822 Total output (Kg) 5328129.97257056

17650.864328358 Difference 0

condensate steam leaving the evaporator.

Utility stream
Specie Input (Kg) Output (Kg)

Steam 475253.786927674 475253.786927674

Total input (Kg) 2900610.8584717

Total output (Kg) 2900610.8584717

Difference 0
 3CaF2 + SiO2 + 4NH4NO3

CaHPO4 + 2NH4NO3

Input Stream 2 Output Stream 1

Mass Flowrate (Kg) Specie Mass Flowrate (Kg)

249533.785762473 NH4NO3 421082.119393542

1059588.90892706 NH4H2PO4 718218.739040121

15453.9376116009 CaHPO4 32838.9609019311

635710.642154187 SiO2 122401.882010081

74876.389732734 CaF2 95473.4679678628

200363.895666767 H2O 500000.052762728

97921.5056080644 Mg(NO3)2 74876.389732734

74257.1417527822 HF 15453.9376116009

17650.864328358 HNO3 2003.63895666768

inerts 17650.864328358
 Input (Kg) Extent Output (Kg)

173425.981104919 408.006273366935 39599.923440564

1135696.71358462 408.006273366935 1121008.48774341

221576.779730185 408.006273366935 193832.353141234

0 408.006273366935 95473.4679678628

97921.5056080644 408.006273366935 122401.882010081

0 408.006273366935 130562.007477419

CaHPO4 +2 NH4NO3
Input (Kg) Extent Output (Kg)

635710.642154187 241.462947808317 612047.273268972

193832.353141234 241.462947808317 185622.612915751

0 241.462947808317 32838.9609019311

130562.007477419 241.462947808317 169196.07912675

Input (Kg) Extent Output (Kg)

185622.612915751 6245.38033947931 79451.1471446027

0 6245.38033947931 718218.739040121
Input (Kg) Extent Output (Kg)

79451.1471446027 3148.5755033349 25925.3635879093

169196.07912675 3148.5755033349 421082.119393542

Output Stream 1 Output Stream 2
Mass flowrate (Kg) Specie Mass flowrate (Kg)

421082.119393542 H2O 497500.052498914

718218.739040121

32838.9609019311

122401.882010081

95473.4679678628

2500.00026381364

74876.389732734

15453.9376116009 Total input (Kg) 2025925.41629354

2003.63895666768 Total output (Kg) 2000000.05270563

17650.864328358 Difference 25925.3635879094

O/kg Air) 0.00745
O/kg Air) 0.01776
242483.051776299
quired air (kg) 2438403.03074342
Air) 0.00847526130106

Input Stream 2 Output Stream 1

2438403.03074342 NH4NO3 421082.119393542

18166.1025790385 NH4H2PO4 718218.739040121

2456569.13332246 CaHPO4 32838.9609019311

SiO2 122401.882010081

CaF2 95473.4679678628

Mg(NO3)2 74876.389732734

HF 15453.9376116009

HNO3 2003.63895666768

Inerts 17650.864328358

Total 1499999.9999429
Output Stream
Mass flowrate (Kg)

95081.2731651508

2038634.70979175

2071924.43346108

555.528473140527

22852.1281288204

2691.60957601354

7202.55586826562

3520.02097234004

2669.34923735786

27148.2837131598

2438403.03074342

25925.3635879093

1500000
 Properties of compound used

Tref =298K

Specie Cp (J/mol.K)
H 2O 71.749051294135

Ca3(PO4)2 59.8951969712465

MgO 41.1743563885
CaF2 71.775320294275

CaCO3 113.063013009029

SiO2 51.4593859655

Ca(NO3)2 146.84253466175

HF 53.2396455429776

H3PO4 145.7123

Mg(NO3)2 142.537143994853

HNO3 110.1297035

CaSiF6 64.5058206031463

CO2 41.073061181773

Ca(NO3)2.4H2O 123.93695
NH3 38.503830507094

NH4NO3 133

NH4H2PO4 141.82

CaHPO4 91.6

Output Stream 2
Component Mass
CO2 95081.2731651508
oval of inerts and SiO2 from dissolved solution
ed with inerts. Therefore taking this minute
 Output Stream 2
Specie Mass Flowrate (Kg)

Ammonia 25925.3635879093

H 2O 621008.434980678

Total input (Kg) 2646933.85127421

Total output (Kg) 2646933.85127421

Difference 0
 Output Stream 2
Air 2438403.03074342

H2O 20666.1028428521

Total input (Kg) 3959069.13352917

Total output (Kg) 3959069.13352917

Difference 0
mpound used

Tref =298K Tref =268K

ΔHof,298K (J/mol) Molecular weight Cp (J/mol.K)

-285800 18 76.1

-4120800 310

-601600 40

-1228000 78

-1207000 100

-910700 60

-938200 164

-321090 20

-1284400 98

-790700 148

-174100 63

-2211765 182

-393509 44

-509370 236

-46110 17 37.4

-230600 80

-1180300 115

-578705 136

Reactor
 Component m (moles)
H2O 109606.168203875

HNO3 31316.0480582499

Tinlet of both input streams (K)

TR (K)

From energy balance:-

(Energy)in - (Energy)out + (Energy pro

So, arranging for outlet temperature

Toutlet (K)

Reaction 1
CaCO3 + 2HNO3 Ca(NO3)2 + H2
Heat of formation of each reaction is calcu

Products
Specie m (moles)
Ca(NO3)2 2160.9380264807
CO2 2160.9380264807
H 2O 2160.9380264807

Heat of Reaction ΔHr298 (J)

 Product
Specie m (moles)
Ca(NO3)2 2160.9380264807
CO2 2160.9380264807
H 2O 2160.9380264807

Reaction 2

CaF2 + 2HNO3 Ca(NO3)2 + 2HF

Products
Specie m (moles)
Ca(NO3)2 1668.25573437359

HF 3336.51146874718

Heat of Reaction ΔHr298 (J)

Product
Specie m (moles)
Ca(NO3)2 1668.25573437359

HF 3336.51146874718
 Reaction 3

Ca3(PO4) + 6HNO3 3Ca(NO3)2 +

Products
Specie m (moles)
Ca(NO3)2 10080.0424022909

H3PO4 6720.02826819396

Heat of Reaction ΔHr,298 (J)

Product
Specie m (moles)
Ca(NO3)2 10080.0424022909

H3PO4 6720.02826819396

Reaction 4
 MgO + 2HNO3 Mg(NO3)2 + H2

Products
Specie m (moles)
Mg(NO3)2 524.108103437483

H2O 524.108103437479

Heat of Reaction ΔHr,298 (J)

Product
Specie m (moles)
Mg(NO3)2 524.108103437483

H2O 524.108103437479

Reaction 5

Ca(NO3)2 + SiO2 + 6HF

Products
Specie m (moles)
CaSiF6 422.673027418352

HNO3 845.346054836704
H2O 845.346054836707

Heat of Reaction ΔHr,298 (J)

Product
Specie m (moles)
CaSiF6 422.673027418352

HNO3 845.346054836704

H2O 845.346054836707

Inert Seperator

Inerts separator is just a separation equipment and no appreciable chan

Therefore, Tinlet = Toutlet (K)
TR (K)

Specie m (moles)
Ca(NO3)2 13486.5631357269

H 2O 114928.382964484
HF 800.47330423707

H3PO4 6720.02826819396

Mg(NO3)2 524.108103437483

HNO3 3294.70557992115

SiO2 1690.69210967341

CaSiF6 422.673027418352

Inerts 44799.1480415178

Heat exchanger

To reduce the consumption of more fresh coolant(ammonical sol.) for c

to 278K, ammonical solution leaving crystilizer at 286K is brought to pre

Law of heat exchange states that

Heat lost by one stream = -Heat gained by o

Inlet Temperature of main stream (K)

Outlet Temperature of main stream (K)

Main stre
Specie m(moles)
Ca(NO3)2 13216.8318730123

H 2O 112629.815305194

HF 522.975892101553

H3PO4 21513.0504959116
Mg(NO3)2 2533.88797741909

HNO3 6780.50408347772

SiO2 1656.87826747994

CaSiF6 414.219566869985

Inerts 298.660986943452

Crystallizer

Law of heat exchange states that

Heat lost by one
In this situation heat is lost by main stream while heat is gained by utilit

Cp of ammonical solution
Cp of ammonical sol. (J/mol.K)

Inlet Temperature of ammonical sol. (K)

Rule of thumb states that minimum and maximum change in temperatu

Therefore, we take a change of 20 between the inlet and outlet temper
Outlet temperature of ammonical sol.

Since mass is conserved and only heat exchange takes place between tw

Main stre
Specie m (moles)
Ca(NO3)2 13216.8318730123

Ca(NO3)2.4H2O 0
 H 2O 112629.815305194

HF 784.463838152329

H3PO4 6585.62770283008

Mg(NO3)2 513.625941368734

HNO3 3228.81146832272

SiO2 1656.87826747994

CaSiF6 414.219566869985

Inerts 298.660986943452

Moles of ammonical solution required

Mass of ammonical solution required (Kg)

CNTH Separator

This section is just a separation equipment

Therefore,
Tinlet = Toutlet (K)

Specie m (moles)

CNTH 13216.8318730123

H 2O 59762.487813145

HF 784.463838152329

H3PO4 6585.62770283008

Mg(NO3)2 513.625941368734
HNO3 3228.81146832272

SiO2 1656.87826747994

CaSiF6 414.219566869985

Inerts 17919.6592166071

Heat exchanger #2

Tinlet of mother liqour (K)

Toutlet of mother liqour (K)

Main stre
Specie m (moles)

CNTH 1057.34654984099

H 2O 58866.0504959478

HF 772.696880580044

H3PO4 6486.84328728763

Mg(NO3)2 505.921552248203

HNO3 3180.37929629788

SiO2 1632.02509346774

CaSiF6 408.006273366935

Inerts 294.1810721393
 Neutralizer

In neutralizer, mother liqour mainly containing phosphoric acid with oth

As a result of which temperature inside the neutralizer is increased to 1

Temperature of mother liqour entering in n

Temperature of NP solution leaving the ne

TR 318

Specie m (moles)

Ammonia 13033.9282194227

Heat of reaction calculations

 Reaction 1

CaSiF6 + 2Ca(NO3)2 + 2H2O + 4NH3 3CaF2 +

Products
Specie ΔHf,298K (J/mol)

CaF2 -1228000

SiO2 -910700

NH4NO3 -230600

Product
Specie m (moles)
CaF2 1224.01882010081

SiO2 2033.23126227856

NH4NO3 1632.02509346774
 Reaction 2
Ca(NO3)2 + H3PO4 + 2NH3

Products
Specie ΔHf,298K (J/mol)

CaHPO4 -578705

NH4NO3 -230600

Product
Specie m (moles)
CaHPO4 241.462947808317

NH4NO3 482.925895616634

Reaction 3

H3PO4 + NH3 NH4H2PO4

Products
Specie ΔHf,298K (J/mol)

NH4H2PO4 -1180300
 Produc
Specie m (moles)
NH4H2PO4 6245.38033947931

Reaction 4

HNO3 + NH3 NH4NO3

Products
Specie ΔHf,298K (J/mol)

NH4NO3 -230600

Produc
 Specie m (moles)
NH4NO3 3148.5755033349

Sum of heat of

Evaporator

Saturated steam at 474K is used for concentrating NP solution from 75%

Input Strea
Specie

Steam

moles of steam required 26402.9881626486

mass of steam required (Kg) 475253.786927674

 Prilling Tower

Tinlet of Nitro-Phosphate sol. (K)

Tinlet of Nitro-Phosphate sol. (K)

Latent heat of vaporization of water (J/mol)

Total Latent heat of vaporization of water (J)

Specie m (mole)
NH4NO3 5263.52649241928

NH4H2PO4 6245.38033947931

CaHPO4 241.462947808317

SiO2 2040.03136683468

CaF2 1224.01882010081

H2O 138.888903545202

Mg(NO3)2 505.921552248203

HF 15453.9376116009

HNO3 31.8037929629791
Inerts 294.1810721393

Total 31439.1528991389

Moles of air required 84082.8631290835

Mass of air required (Kg) 2438403.03074342

 Calculation of Cp data

Tref =474K Specie

Cp (J/mol.K) H 2O

81.2 Ca3(PO4)2

MgO
CaF2

CaCO3

SiO2

Ca(NO3)2

HF
H3PO4

Mg(NO3)2

HNO3

CaSiF6

CO2

Ca(NO3)2.4H2O

NH3

NH4NO3

NH4H2PO4

CaHPO4

Input Stream 1
 Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

71.749051294135 305 0

110.1297035 305 0

s (K) 305

305

(Energy)out + (Energy produced by reaction) - (Energy consumed by reaction) = 0

352.209466745747 79.2094667457474

Ca(NO3)2 + H2O + CO2

of each reaction is calculated at 298K, therefore ΔT= T R-T (K)

Products Rea
ΔHf,298K (J/mol) m*ΔHf298 (J) Specie

-938200 -2027392056.44419 CaCO3

-393509 -850348561.862394 HNO3

-285800 -617596087.968184

Sum -3495336706.27477

-134645887.491985
 Products
Cp (J/mol.K) ΔT (K) ΔH (J)

146.84253466175 7 2221223.31938771

41.073061181773 7 621294.378401632

71.749051294135 7 1085316.77313787

Sum 3927834.47092721

Heat of reaction at required Temp. (J) -135760076.668391

Ca(NO3)2 + 2HF

Products Rea
ΔHf,298K (J/mol) m*ΔHf298 (J) Specie

-938200 -1565157529.9893 CaF2

-321090 -1071320467.50003 HNO3

Sum -2636477997.48934

-6973308.96968126

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

146.84253466175 7 1714796.30349592

53.2396455429776 7 1243442.81562326

Sum 2958239.11911918
 Heat of reaction at required Temp. (J) -7425390.1096764

3Ca(NO3)2 + 2H3PO4

Products Rea
ΔHf,298K (J/mol) m*ΔHf298 (J) Specie

-938200 -9457095781.82936 Ca3(PO4)2

-1284400 -8631204307.66832 HNO3

Sum -18088300089.4977

-732483081.233143

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

146.84253466175 7 10361252.8309522

145.7123 7 6854335.42516491

Sum 17215588.2561172

Heat of reaction at required Temp. (J) -732217803.070185

3
Mg(NO3)2 + H2O

Products Rea
ΔHf,298K (J/mol) m*ΔHf298 (J) Specie

-790700 -414412277.388018 MgO

-285800 -149790095.962431 HNO3

Sum -564202373.350449

-66404496.7055278

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

142.537143994853 7 522934.105459765

71.749051294135 7 263229.814380452

Sum 786163.919840217

Heat of reaction at required Temp. (J) -66577469.6630161

+ SiO2 + 6HF CaSiF6 + 2HNO3 + 2H2O

Products Rea
ΔHf,298K (J/mol) m*ΔHf298 (J) Specie

-2211765 -934853408.487951 Ca(NO3)2

-174100 -147174748.14707 SiO2

 -285800 -241599902.472331 HF

Sum -1323628059.10735

272148595.528991

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

64.5058206031463 7 190854.093363059

110.1297035 7 651683.972618427

71.749051294135 7 424569.442148415

Sum 1267107.5081299

Heat of reaction at required Temp. (J) 271883860.514446

Sum of heat of all reactions occuring in reactor (J)

and no appreciable change in temperature occurs between inlet and outlet streams
352.209466745747

305 ΔT (K)

Input Stream
Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

146.84253466175 352.209466745747 47.2094667457474

71.749051294135 352.209466745747 47.2094667457474

 53.2396455429776 352.209466745747 47.2094667457474

145.7123 352.209466745747 47.2094667457474

142.537143994853 352.209466745747 47.2094667457474

110.1297035 352.209466745747 47.2094667457474

51.4593859655 352.209466745747 47.2094667457474

64.5058206031463 352.209466745747 47.2094667457474

51.4593859655 352.209466745747 47.2094667457474

nt(ammonical sol.) for cooling digesting solution obtained from inert removal section from 352K
t 286K is brought to pre-cool digesting solution from 352K to 318K in a heat exchanger.

eam = -Heat gained by other stream

352.209466745747 Inlet Temperature of utility stream (K)

318 Outlet temperature of utility stream (K)

Main stream
Cp (J/mol.K) Tout - Tin (K) m*Cp*(Tout -Tin) (J)

146.84253466175 -34.2094667457474 -66393496.7559062

71.749051294135 -34.2094667457474 -276449519.481284

53.2396455429776 -34.2094667457474 -952495.931492726

145.7123 -34.2094667457474 -107236965.077923

 142.537143994853 -34.2094667457474 -12355541.0526779

110.1297035 -34.2094667457474 -25545402.8763324

51.4593859655 -34.2094667457474 -2916765.44172367

64.5058206031463 -34.2094667457474 -914062.346427065

51.4593859655 -34.2094667457474 -525762.249771491

Σ(m*Cp*(Tout-Tin)) -493290011.213539

Heat lost by one stream = -Heat gained by other stream

e heat is gained by utility stream which is 25% ammonical solution

on 0.25(Cp,NH3) + 0.75(Cp,H2O)
ol.K) 66.425

cal sol. (K) 266

um change in temperature of stream should not less than 10 and greater than 50 respectively.
inlet and outlet temperature of ammonical sol.
286

takes place between two streams, therefore we can take inlet and outlet flow of each stream to be equal.

Main stream
Cp (J/mol.K) Tout - Tin (K) m*Cp*(Tout -Tin) (J)

146.84253466175 -40 -77631723.6972536

123.93695 -40 0
 71.749051294135 -40 -323243295.823254

53.2396455429776 -40 -1670583.06738055

145.7123 -40 -38384278.3809235

142.537143994853 -40 -2928430.99057468

110.1297035 -40 -14223521.9865512

51.4593859655 -40 -3410477.53056397

64.5058206031463 -40 -1068782.92283313

51.4593859655 -40 -614756.43999841

Σ(m*Cp*(Tout-Tin)) -463175850.839333

348645.72889675 Molecular weight of ammonical sol.

6188461.68791732

a separation equipment therefore no change in temperatureof either stream is observed

TR (K)

278 ΔT=Tin-TR (K)

Input Stream
Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

123.93695 278 5

71.749051294135 278 5

53.2396455429776 278 5

145.7123 278 5

142.537143994853 278 5
 110.1297035 278 5

51.4593859655 278 5

64.5058206031463 278 5

51.4593859655 278 5

278 Tinlet of condense steam (K)

318 Toutlet of condense steam (K)

Main stream
Cp (J/mol.K) Tout - Tin (K) m*Cp*(Tout -Tin) (J)

123.93695 40 5241772.2592126

71.749051294135 40 168943331.060676

53.2396455429776 40 1645524.32136984

145.7123 40 37808514.2052096

142.537143994853 40 2884504.52571606

110.1297035 40 14010169.156753

51.4593859655 40 3359320.36760551

64.5058206031463 40 1052751.17899063

51.4593859655 40 605535.093398434
Σ(m*Cp*(Tout-Tin)) 235551422.168932
phosphoric acid with other compounds is neutralized with ammonia which is an exothermic reaction.
tralizer is increased to 118°C. Due to these conditions almost 55% of total water is evaporated in neutralizer.

her liqour entering in neutralizer 318

solution leaving the neutralizer 391.142054799111

Input Stream 1
Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

38.503830507094 305 -13

4NH3 3CaF2 + SiO2 + 4NH4NO3

Products Rea
m (moles) m*ΔHf298 (J) Specie

1224.01882010081 -1503095111.08379 CaSiF6

2033.23126227856 -1851663710.55709 Ca(NO3)2

1632.02509346774 -376344986.553661 H2O

NH3

Sum -3731103808.19453

Heat of reaction at 298K -1754637778.71906

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

71.775320294275 20 1757086.85717912

51.4593859655 20 2092576.64565426

133 20 4341186.74862419

Sum 8190850.25145757

Heat of reaction at required Temp. -1751797557.94375

2
+ H3PO4 + 2NH3 CaHPO4 +2 NH4NO3

Products Rea
m (moles) m*ΔHf298 (J) Specie

241.462947808317 -139735815.211412 Ca(NO3)2

482.925895616634 -111362711.529196 H3PO4

NH3

Sum -251098526.740608

Heat of reaction at 298K 307844734.10504

Products
Cp (J/mol.K) ΔT (K) ΔH (J)

91.6 20 442360.120384836

133 20 1284582.88234025

Sum 1726943.00272508

Heat of reaction at required Temp. 307786964.115659

NH4H2PO4

Products Rea
m (moles) m*ΔHf298 (J) Specie

6245.38033947931 -7371422414.68743 H3PO4

 NH3

Sum -7371422414.68743

Heat of reaction at 298K 938118580.793188

Product
Cp (J/mol.K) ΔT (K) ΔH (J)

141.82 20 17714396.7948991

Sum 17714396.7948991

Heat of reaction at required Temp. 932822981.594408

NH4NO3

Products Rea
m (moles) m*ΔHf298 (J) Specie

3148.5755033349 -726061511.069029 NH3

HNO3

Sum -726061511.069029

Heat of reaction at 298K -32713699.4796497

Product
 Cp (J/mol.K) ΔT (K) ΔH (J)

141.82 20 8930619.55765912

Sum 8930619.55765912

Heat of reaction at required Temp. -33142758.0049672

Sum of heat of all reactions occuring in neutralizer

ng NP solution from 75% to 99.5%.

Input Stream 1
H (J/mol) T (K) Specie

50240.574 474 Ammonia

NH4NO3

NH4H2PO4

CaHPO4

SiO2

CaF2

H2O

Mg(NO3)2

HF

HNO3
 inerts

448 Tinlet of air (K)

368 Rule of thumb states that minimum and maximu

Therefore, we take a change of 25K between th

40800 Toutlet of air (K)

5666667.26464425

Stream 1
Cp (J/mol.K) Tinlet (K) Toutput (K)

133 448 368

141.82 448 368

91.6 448 368

51.4593859655 448 368

71.775320294275 448 368

71.749051294135 448 368

142.537143994853 448 368

53.2396455429776 448 368

110.1297035 448 368

51.4593859655 448 368

Molecular weight (Kg/Kgmol) 29

Calculation of Cp data

A B C
92.053 -0.039953 -0.00021103

10.461 0.11153 -8.0123E-05

59.264 0.032222 -2.4645E-07

12.572 0.002637
2.478 0.16522 -9.6769E-05

110 0.000333

27.437 0.042315 -1.9555E-05

33.573 -0.012581 8.8906E-05

Input St
 ΔH=m*Cp*ΔT (J) Component m (moles)

0 H2O 1791.82257585464

0 Ca3(PO4)2 3360.01413409698

0 MgO 524.108103437483

CaF2 1668.25573437359

CaCO3 2160.9380264807

SiO2 2113.36513709176

Inerts 44799.1480415178

Reactants
m (moles) ΔHf,298K (J/mol) m*ΔHf298 (J)

2160.9380264807 -1207000 -2608252197.96221

4321.8760529614 -174100 -752438620.82058

Sum -3360690818.78279
 Reactants
Specie m (moles) Cp (J/mol.K)

CaCO3 2160.9380264807 113.063013009029

HNO3 4321.8760529614 110.1297035

Reactants
m (moles) ΔHf,298K (J/mol) m*ΔHf298 (J)

1668.25573437359 -1228000 -2048618041.81077

3336.51146874718 -174100 -580886646.708885

Sum -2629504688.51965

Reactants
Specie m (moles) Cp (J/mol.K)

CaF2 1668.25573437359 71.775320294275

HNO3 3336.51146874718 110.1297035

 Reactants
m (moles) ΔHf,298K (J/mol) m*ΔHf298 (J)

3360.01413409698 -4120800 -13845946243.7868

20160.0848045819 -174100 -3509870764.4777

Sum -17355817008.2645

Reactants
Specie m (moles) Cp (J/mol.K)

Ca3(PO4)2 3360.01413409698 59.8951969712465

HNO3 20160.0848045819 110.1297035

 Reactants
m (moles) ΔHf,298K (J/mol) m*ΔHf298 (J)

524.108103437483 -601600 -315303435.02799

1048.21620687497 -174100 -182494441.616932

Sum -497797876.644922

Reactants
Specie m (moles) Cp (J/mol.K)

MgO 524.108103437483 41.1743563885

HNO3 1048.21620687497 110.1297035

Reactants
m (moles) ΔHf,298K (J/mol) m*ΔHf298 (J)

422.673027418352 -938200 -396551834.323898

422.673027418352 -910700 -384928326.069893

 2536.03816451011 -321090 -814296494.242552

Sum -1595776654.63634

Reactants
Specie m (moles) Cp (J/mol.K)

Ca(NO3)2 422.673027418352 146.84253466175

SiO2 422.673027418352 51.4593859655

HF 2536.03816451011 53.2396455429776

-670096878.996822

47.2094667457474

Output
ΔH=m*Cp*ΔT (J) Specie m (moles)

93493680.5688914 Ca(NO3)2 13216.8318730123

389289378.187594 H2O 112629.815305194

 2011921.83075282 HF 784.463838152329

46227074.3312173 H3PO4 6585.62770283008

3526777.18027427 Mg(NO3)2 513.625941368734

17129716.5365178 HNO3 3228.81146832272

4107316.97873159 SiO2 1656.87826747994

1287159.9962733 CaSiF6 414.219566869985

108833713.915646 Inerts 17919.6592166071

555785865.6140 555785865.613979

difference 0

ction from 352K

mperature of utility stream (K) 286

mperature of utility stream (K) 307.300333785522

Utility Stream
Specie m(moles) Cp (J/mol.K)

Ammonical sol. 348645.7289 66.425

 Tinlet of main stream 318
Toutlet of main stream 278

0 respectively.

of each stream to be equal.

Utility Stream
Specie Cp (J/mol.K) Tout - Tin (K)

Ammonical sol. 66.425 20

ar weight of ammonical sol. 17.75

observed
273

CNTH F
ΔH=m*Cp*ΔT (J) Specie m (moles)

8190269.15501968 CNTH 12159.4853231714

21439509.0178523 H2O 896.437317197175

208822.883422569 HF 11.7669575722849

4798034.79761544 H3PO4 98.7844155424511

366053.873821835 Mg(NO3)2 7.704389120531

 1777940.24831891 HNO3 48.4321720248408

426309.691320496 SiO2 24.8531740121991

133597.865354141 CaSiF6 6.21329350304977

4610673.29998808 Inerts 268.794888249107

41951210.8327

Difference

of condense steam (K) 747

of condense steam (K) 740.896146305084

Utility Stream
Specie m (moles) Cp (J/mol.K)

Steam 475253.786927674 81.2

exothermic reaction.
is evaporated in neutralizer.

Input St
ΔH=m*Cp*ΔT (J) Specie m (moles)

-6524130.11902963 CNTH 1057.34654984099

H2O 58866.0504959478

HF 772.696880580044

H3PO4 6486.84328728763

Mg(NO3)2 505.921552248203

HNO3 3180.37929629788

SiO2 1632.02509346774

CaSiF6 408.006273366935

inerts 17650.864328358
 Reactants
ΔHf,298K (J/mol) m (moles) m*ΔHf298 (J)

-2211765 408.006273366935 -902413995.213419

-938200 816.01254673387 -765582971.345717

-285800 816.012546733875 -233216385.856542

-46110 1632.02509346774 -75252677.0597976

Sum -1976466029.47548

Reactants
Specie m (moles) Cp (J/mol.K)

CaSiF6 408.006273366935 64.5058206031463

Ca(NO3)2 816.01254673387 146.84253466175
H2O 816.012546733875 71.749051294135
NH3 1632.02509346774 38.503830507094
 Reactants
ΔHf,298K (J/mol) m (moles) m*ΔHf298 (J)

-938200 241.462947808317 -226540537.633763

-1284400 241.462947808317 -310135010.165002

-46110 482.925895616633 -22267713.0468829

Sum -558943260.845648

Reactants
Specie m (moles) Cp (J/mol.K)

Ca(NO3)2 241.462947808317 146.84253466175

H3PO4 241.462947808317 145.7123

NH3 482.925895616633 38.503830507094

Reactants
ΔHf,298K (J/mol) m (moles) m*ΔHf298 (J)

-1284400 6245.38033947931 -8021566508.02723

 -46110 6245.38033947931 -287974487.453391

Sum -8309540995.48062

Reactants
Specie m (moles) Cp (J/mol.K)

H3PO4 6245.38033947931 145.7123

NH3 6245.38033947931 38.503830507094

Reactants
ΔHf,298K (J/mol) m (moles) m*ΔHf298 (J)

-46110 3148.5755033349 -145180816.458772

-174100 3148.5755033349 -548166995.130607

Sum -693347811.589379

Reactants
 Specie m (moles) Cp (J/mol.K)

NH3 3148.5755033349 38.503830507094

HNO3 3148.5755033349 110.1297035

-544330370.23865

Input Stream
m (mole) Cp( J/mol.K) Tin (K)

1525.02138752408 36 391.142054799111

5263.52649241928 133 391.142054799111

6245.38033947931 141.82 391.142054799111

241.462947808317 91.6 391.142054799111

2040.03136683468 44.4 391.142054799111

1224.01882010081 67 391.142054799111

27777.7807090404 75.3 391.142054799111

505.921552248203 141.9 391.142054799111

772.696880580044 53.2 391.142054799111

31.8037929629791 109.9 391.142054799111

 294.1810721393 44.4 391.142054799111

305

es that minimum and maximum change in temperature of stream should not less than 10 and greater than 5
a change of 25K between the inlet and outlet temperature of air.

330

ΔT=Tinlet-Toutput (K) Q = m*Cp*ΔT (J) Specie

80 56003921.8793411 Air

80 70857587.1795965 H2O

80 1769440.48153935

80 8398300.91901377

80 7028347.42871647

80 797211.765172071

80 5769009.05143212

80 65820972.8547937

80 280203.383135062
 80 1211070.18679687

Σ(m*Cp*ΔT) 217936065.129537
D E Tmin
5.3469E-07 305

305

305

305

305
-3.12E-05
305

305

305

305

305

305

305

3.9968E-09 -2.9872E-13 305

305

-7.1783E-08 1.8569E-11 305

305

305

305

Input Stream 2
Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

71.749051294135 305 0

59.8951969712465 305 0

41.1743563885 305 0

71.775320294275 305 0

113.063013009029 305 0

51.4593859655 305 0

51.4593859655 305 0
actants
ΔT (K) ΔH (J)

7 1710255.14939784

7 3331768.49793473

Sum 5042023.64733257

actants
ΔT (K) ΔH (J)

7 838177.127671978

7 2572143.13144234

Sum 3410320.25911432
actants
ΔT (K) ΔH (J)

7 1408740.95871538

7 15541569.1344442

Sum 16950310.0931596
actants
ΔT (K) ΔH (J)

7 151058.69685925

7 808078.180469243

Sum 959136.877328494
actants
ΔT (K) ΔH (J)

7 434464.650754864

7 152253.461185891

7 945124.410733874

Sum 1531842.52267463

Output Stream
Cp (J/mol.K) Tout (K) ΔT=Tin-TR (K)

146.84253466175 352.209466745747 47.2094667457474

71.749051294135 352.209466745747 47.2094667457474

 53.2396455429776 352.209466745747 47.2094667457474

145.7123 352.209466745747 47.2094667457474

142.537143994853 352.209466745747 47.2094667457474

110.1297035 352.209466745747 47.2094667457474

51.4593859655 352.209466745747 47.2094667457474

64.5058206031463 352.209466745747 47.2094667457474

51.4593859655 352.209466745747 47.2094667457474

m*Cp (J/K)

23158792.5419666
Cp*(Tout -Tin) (J/mol)

1328.5
 CNTH Filtrate
Cp (J/mol.K) Tout (K) ΔT=Tin-TR (K)

123.93695 278 5

71.749051294135 278 5

53.2396455429776 278 5

145.7123 278 5

142.537143994853 278 5
 110.1297035 278 5

51.4593859655 278 5

64.5058206031463 278 5

51.4593859655 278 5

m*Cp (J/K)

38590607.4985
 Input Stream 2
Cp (J/mol.K) Tin (K) ΔT=Tin-TR (K)

123.93695 318 0

71.749051294135 318 0

53.2396455429776 318 0

145.7123 318 0

142.537143994853 318 0

110.1297035 318 0

51.4593859655 318 0

64.5058206031463 318 0

51.4593859655 318 0
actants
ΔT (K) ΔH (J)

20 526375.589495316

20 2396507.01356383

20 1170962.52144533

20 1256784.35164412

Sum 5350629.4761486
actants
ΔT (K) ΔH (J)

20 709140.625661424

20 703682.429798595

20 371889.936646188

Sum 1784712.99210621
actants
ΔT (K) ΔH (J)

20 18200574.6728062

20 4809421.32087297

Sum 23009995.9936792

actants
 ΔT (K) ΔH (J)

20 2424644.3503839

20 6935033.73259272

Sum 9359678.08297663

ΔT=Tin-TR (K) ΔH=m*Cp*ΔT (J) Specie

93.1420547991108 5113570.52327701 NH4NO3

93.1420547991108 65204004.5081339 NH4H2PO4

93.1420547991108 82497765.8501843 CaHPO4

93.1420547991108 2060116.52869128 SiO2

93.1420547991108 8436564.47325595 CaF2

93.1420547991108 7638511.07713714 H2O

93.1420547991108 194822151.846834 Mg(NO3)2

93.1420547991108 6686693.10069021 HF

93.1420547991108 3828834.60032551 HNO3

93.1420547991108 325553.541904813 inerts

 93.1420547991108 1216587.95166746

Total 377830354.002102

ld not less than 10 and greater than 50 respectively.

Stream 2
Cp (J/mol.K) Tinlet (K) Toutput (K)

29.232 305 330

71.749051294135 305 330

Tmax Cp relation with temperature
474
Cp = A+B(T)+C(T^2)+D(T^3)
474
Cp = 48.24 + 0.03968(T) - 500000(T -2)
474
Cp =A+B*T+C*T^2
474
Cp =A+B*T+C*T^2
474
Cp/R = A + BT + DT-2
474
Cp =A+B*T+C*T^2
474 Cp = 129 + 0.0368T - 413000T -2

474
Cp = 52.83 + 0.00072(T) + 17000(T-2)
474

474
Cp=139.7639+0.00712T+179T^-3
474
Cp = a + b(T) + c(T)2 + d(T)3
474
Cp = 64.15 + 11.74e^-3(T) + 4.08e^5(T^-2)
474
Cp= A + B*T + C*T^2 + D*T^3 + E*T^4
474

474
Cp = A + B*T + C*T^2 + D*T^3 + E*T^4
474

474

474

Output Stream
ΔH=m*Cp*ΔT (J) Component m (moles) Cp (J/mol.K)

0 Ca(NO3)2 13486.5631357269 146.84253466175

0 H2O 114928.382964484 71.749051294135

0 HF 800.47330423707 53.2396455429776

0 H3PO4 6720.02826819396 145.7123

0 Mg(NO3)2 524.108103437483 142.537143994853

0 HNO3 3294.70557992115 110.1297035

0 SiO2 1690.69210967341 51.4593859655

0 CaSiF6 422.673027418352 64.5058206031463

CO2 2160.9380264807 41.073061181773

Inerts 44799.1480415178 51.4593859655

 Inert Stream
ΔH=m*Cp*ΔT (J) Specie m (moles) Cp (J/mol.K)

91623806.9575136 Ca(NO3)2 269.731262714537 146.84253466175

381503590.623842 H2O 2298.56765928968 71.749051294135

1971683.39413777 HF 16.0094660847413 53.2396455429776

45302532.8445929 H3PO4 134.400565363879 145.7123

3456241.63666879 Mg(NO3)2 10.4821620687497 142.537143994853

16787122.2057874 HNO3 65.8941115984226 110.1297035

4025170.63915696 SiO2 33.8138421934682 51.4593859655

1261416.79634783 CaSiF6 8.45346054836705 64.5058206031463

43533485.5662585 Inerts 26879.4888249107 51.4593859655

544670148.301699 555785865.613979
 Mother Liquour
ΔH=m*Cp*ΔT (J) Specie m (moles) Cp (J/mol.K)

7535047.62261811 CNTH 1057.34654984099 123.93695

321592.635267784 H2O 58866.0504959478 71.749051294135

3132.34325133853 HF 772.696880580044 53.2396455429776

71970.5219642315 H3PO4 6486.84328728763 145.7123

5490.80810732753 Mg(NO3)2 505.921552248203 142.537143994853

26669.1037247836 HNO3 3180.37929629788 110.1297035

6394.64536980744 SiO2 1632.02509346774 51.4593859655

2003.96798031212 CaSiF6 408.006273366935 64.5058206031463

69160.0994998212 Inerts 17650.864328358 51.4593859655

8041461.7478
 Output Stream 1
ΔH=m*Cp*ΔT (J) Specie m (moles) Cp(J/mol.K)

0 NH4NO3 5263.52649241928 133

0 NH4H2PO4 6245.38033947931 141.82

0 CaHPO4 241.462947808317 91.6

0 SiO2 2040.03136683468 51.4593859655

0 CaF2 1224.01882010081 71.775320294275

0 H2O 27777.7807090404 71.749051294135

0 Mg(NO3)2 505.921552248203 142.537143994853

0 HF 772.696880580044 53.2396455429776

0 HNO3 31.8037929629791 110.1297035

inerts 17650.864328358 51.4593859655

Σ(m*Cp)
 Output Stream 1
m (mole) Cp( J/mol.K) TOut (K) ΔT=Tin-TR (K)

5263.52649241928 133 448 150

6245.38033947931 141.82 448 150

241.462947808317 91.6 448 150

2040.03136683468 44.4 448 150

1224.01882010081 67 448 150

138.888903545202 75.3 448 150

505.921552248203 141.9 448 150

772.696880580044 53.2 448 150

31.8037929629791 109.9 448 150

294.1810721393 44.4 448 150

ΔT = Tinlet-Toutput (K) Cp*ΔT (J)
-25 -730.8

-25 -1793.72628235337

Σ(m*Cp) -2524.52628235337
Cp (J/mol.K), min Cp (J/mol.K), max Cp (J/mol.K),avg

75.10865507875 68.38944750952 71.749051294135

54.9675007793604 64.8228931631327 59.8951969712465

37.024207925 45.324504852 41.1743563885

69.06878398875 74.4818565998 71.775320294275

111.210433487212 114.915592530845 113.063013009029

43.868163775 59.050608156 51.4593859655

145.033666756248 148.651402567252 146.84253466175

53.2323465735017 53.2469445124535 53.2396455429776

145.7123

141.935506308898 143.138781680808 142.537143994853

110.101565 110.157842 110.1297035

64.6243987764042 64.3872424298884 64.5058206031463

38.6347858140853 43.5113365494608 41.073061181773

123.7039 124.17 123.93695

36.1302931480806 40.8773678661073 38.503830507094

133

141.82

91.6

Output Stream
 Toutlet (K) ΔT=Tin-TR (K) ΔH=m*Cp*ΔT (J) m*Cp (J/K)

352.209466745747 47.2094667457474 93493680.5688914 1980401.11472586

352.209466745747 47.2094667457474 389289378.187594 8246002.44447076

352.209466745747 47.2094667457474 2011921.83075282 42616.9149841977

352.209466745747 47.2094667457474 46227074.3312173 979190.775023558

352.209466745747 47.2094667457474 3526777.18027427 74704.8722085378

352.209466745747 47.2094667457474 17129716.5365178 362844.948636511

352.209466745747 47.2094667457474 4107316.97873159 87001.9778205094

352.209466745747 47.2094667457474 1287159.9962733 27264.8704804369

352.209466745747 47.2094667457474 4190139.47092452 88756.3397716617

352.209466745747 47.2094667457474 108833713.915646 2305336.64999404

Σ(m*Cp) 14194120.9081161
Inert Stream
Tout (K) ΔT=Tin-TR (K) ΔH=m*Cp*ΔT (J)

352.209466745747 47.2094667457474 1869873.61137782

352.209466745747 47.2094667457474 7785787.56375186

352.209466745747 47.2094667457474 40238.4366150563

352.209466745747 47.2094667457474 924541.486624343

352.209466745747 47.2094667457474 70535.5436054859

352.209466745747 47.2094667457474 342594.330730354

352.209466745747 47.2094667457474 82146.3395746318

352.209466745747 47.2094667457474 25743.199925466

352.209466745747 47.2094667457474 65300228.3493877

11115717.3122796
Mother Liquour
Tout (K) ΔT=Tin-TR (K) ΔH=m*Cp*ΔT (J)

278 5 655221.532401575

278 5 21117916.3825845

278 5 205690.54017123

278 5 4726064.2756512

278 5 360563.065714508
278 5 1751271.14459412

278 5 419915.045950688

278 5 131593.897373829

278 5 4541513.20048826

33909749.0849
 Output Stream 2
m*Cp (J/K) Specie m (moles) Cp(J/mol.K)

700049.023491764 Ammonia 1525.02138752408 38.503830507094

885719.839744956 H2O 34500.4686100377 71.749051294135

22118.0060192418

104978.761487672

87854.3428589559

1993029.41293018

72112.6131429015

41138.108034246

3502.54228918827

908302.640097651

7352900.34709496
 Output Stream 2
ΔH=m*Cp*ΔT (J) Specie m (mole) Cp( J/mol.K)

105007353.523765 Vapours 27638.8918054952 80.9244

132857975.961743 Ammonia 1525.02138752408 36

3317700.90288627

13586608.9031189

12301389.1420131

1568750.16554306

10768540.239603

6166121.10702875

524285.52699471

1959245.94044774
288057971.413143
 m*Cp (J/K)

58719.1650249204

2475375.89197329
Output Stream 2 Output Stream 3
TOut (K) ΔT=Tin-TR (K) ΔH=m*Cp*ΔT (J) Specie

448 150 1002024009.73903 Condensate

448 150 8235115.49263002

1010259125.23166
Output Stream 3
H (J/mol) T (K)

15377.598 474
 17

80

115

136

60

78

18

148

20

63

60