JPDV Fall 2019

CHEM-1110 CUMULATIVE EXAM REVIEW SHEET

Exam 1 Material

Calculations: density, conversions (including temperature), atomic particle (protons,

neutrons, electrons) numbers
Concepts: dimensional analysis, unit conversions, metric system, significant figures,
states of matter, compounds, elements and mixtures, atomic theory, ions,
isotopes, periodic table

Exam 2 Material

Calculations: c = vλ, Planck's Equation (E = h)

Concepts: Bohr's model of the atom, shapes of orbitals, quantum numbers, ground and
excited states, electron transitions, valence electrons, electron
configurations, periodic trends (atom size, ionization energy, electron
affinity, etc.), isoelectronic

Exam 3 Material

Calculations:
Concepts: naming compounds, bonding in ionic compounds, covalent bonding, octet
rule, Lewis dot structures, formal charges, electronegativity, bond polarity,
VSEPR model, electron domain and molecular geometry, molecular polarity,
dipole, hybridization, sigma and Pi bonds

Exam 4 Material

Calculations: moles, % composition, formula mass, empirical and molecular formula,

limiting reactant, stoichiometry, %yield, molarity, dilution, solution
stoichiometry
Concepts: mole, balancing chemical equations, electrolytes, solubility, acids and bases,
solutions, net ionic equations

Exam 5 Material

Calculations: gas laws, enthalpy of reaction & formation, specific heat, calorimetry
Concepts: Laws of Thermodynamics, heat capacity & specific heat,
exothermic/endothermic, enthalpy (formation, Hess's Law)
JPDV Fall 2019

Cumulative Exam Review Questions

1. The number of unpaired electrons in a gaseous selenium atom is?

2. What is the empirical formula for the substance with this analysis?
Elemental Analysis by Mass: Na – 54.0%
B– 8.50%
O– 37.5%

3. Which molecule has exactly two unshared (lone) pairs of electrons on the central atom?
(A) BF3 (B) OF2
(C) NF3 (D) XeF2
What is the molecular shape? Is it a polar molecule?

4. A typical silicon chip has a mass of 2.3 × 10-4 g. Assuming it is pure silicon, how many
silicon atoms does the chip contain?
(A) 4.9 × 1018 (B) 1.4 × 1020 (C) 3.9 × 1021 (D) 2.6 × 1027

5. What is the molar mass of an ideal gas if a 0.622 g sample of this gas occupies a volume of
300.0 mL at 35oC and 789 mm Hg?
JPDV Fall 2019

6. The combustion reaction of C3H8O with O2 is represented by this balanced chemical equation.
2C3H8O + 9O2  6CO2 + 8H2O

Formula Molar Mass

C3H8O 60.1 gmol-1
O2 32.0 gmol-1

When 3.00 g C3H8O and 7.38 g O2 are combined, how many moles of carbon dioxide form?

7. Given:
Equation 1: SO2(g)  S (s) + O2(g) H= +300kJ
Equation 2: 2SO2 (g) + O2(g)  2SO3(g) H= -200kJ

Use this information to calculate the heat of formation of SO3(g).

8. An atom has a valence shell electron configuration of ns1. To which group (e.g., lanthanides)
of elements in the periodic table does it belong?

9. What do these have in common?

20 19 - 24
Ne F Mg2+
(A) same # protons (B) same # neutrons (C) same # electrons (D) same size

10. What volume of a 12 M HCl solution is required to prepare exactly 500. mL of a 0.60 M HCl
solution?
(A) 10. mL (B) 14 mL (C) 25 mL (D) 40. mL
JPDV Fall 2019

Additional Final Review Problems

1. Consider the Lewis structure for CH3Cl. What is the best description of the molecular shape?
Is this molecule polar? What is the hybridization of the carbon atom? Types of bonds?
(a) Bent
(b) square
(c) square pyramidal
(d) tetrahedral

2. A 0.473 g sample of phosphorus is reacted with excess chlorine. 2.12 g of phosphorus

pentachloride is collected. What is the percentage yield of PCl5?

P4(s) + 10 Cl2(g) → 4PCl5(s)

(a) 3.18%
(b) 33.3%
(c) 66.7%
(d) 37.5%

3. A compound consisting of an element having a low ionization energy and a second element
having a high electron affinity is likely to have
(a) covalent bonds
(b) metallic bonds
(c) coordinate covalent bonds
(d) ionic bonds

4. What mass of NaOH is necessary to make up 400 mL of a 2.5 M solution?