Ejercicio 1.

Método Integral

Método Integral
Método inte
t CA 1/CA ln [CA]
1.6
0 1.5 0.6667 0.4055
1.4
2.5 1.24 0.8065 0.2151 f(x) = − 0.061257142857143
5 1.05 0.9524 0.0488 1.2 R² = 0.964339419978518

CA [kmol/m3]
7.5 0.93 1.0753 -0.0726 1

10 0.81 1.2346 -0.2107 0.8

12.5 0.71 1.4085 -0.3425 0.6

0.4
0.2
0
0 2 4
n k
0 0.0613
1 0.0587
2 0.0585
 Método integral - Orden 0 Método Integral - Orde
1.6 0.5000
1.4 0.4000
f(x) = − 0.061257142857143 x + 1.42285714285714
1.2 R² = 0.964339419978518 f(x) =0.3000
− 0.058727259143735 x + 0.
R² = 0.993453506670105
0.2000
CA [kmol/m3]

ln[CA]
0.8 0.1000
0.0000
0.6 0 2 4 6 8
-0.1000
0.4
-0.2000
0.2
-0.3000
0
0 2 4 6 8 10 12 14 -0.4000
t [min] t [min]

Método Integral - Orden 2

1.6000
1.4000
f(x)1.2000
= 0.058470364772695 x + 0.658524662606502
R² =1.0000
0.997375614113903
1/CA

0.8000
0.6000
0.4000
0.2000
0.0000
0 2 4 6 8 10 12 14
t [min]
 Método Integral - Orden 1

058727259143735 x + 0.37430947278122
3453506670105

2 4 6 8 10 12 14

t [min]

en 2

58524662606502

10 12 14
 Ejercicio 1. Método Diferencial

t CA log CA dCA/dt log[-dCA/dt]

0 1.5 0.17609 -0.0998 -1.00086946
2.5 1.24 0.09342 -0.0843 -1.07417243
5 1.05 0.02119 -0.0688 -1.16241156
7.5 0.93 -0.03152 -0.0533 -1.27327279
10 0.81 -0.09151 -0.0378 -1.4225082
12.5 0.71 -0.14874 -0.0223 -1.65169514

log CA log[-dCA/dt]
0.1760912591 -1.000869459
0.0934216852 -1.074172425
0.0211892991 -1.162411562
-0.0315170514 -1.273272791
-0.0915149811 -1.4225082
-0.1487416513 -1.651695137

k
2.81

Error
97.92
 t vs CA
1.6
1.4
f(x) = 0.00308571 x² − 0.0998286 x + 1.4871429
1.2
R² = 0.996965628356606
1
0.8
CA

0.6
0.4
0.2
0
0 2 4 6 8 10 12 14
t [min]

log[-dCA/dt]
0
-0.2 -0.15 -0.1 -0.05 0 0.05 0.1 0.15 0.2
-0.2

-0.4

-0.6

-0.8

-1
f(x) = 1.93652720649587 x − 1.27026420737914
R² = 0.922587949414035
-1.2

-1.4

-1.6

-1.8
 Ejercicio 2 Metodo Integral

Método Integral k
t CA 1/CA ln [CA] 0.0275
0 10 0.1 2.30258509 0.0076
20 8 0.125 2.07944154 0.003
40 6 0.166666667 1.79175947
60 5 0.2 1.60943791
120 3 0.333333333 1.09861229
180 2 0.5 0.69314718
300 1 1 0

Orden 0 - t vs CA
12 2.5

10
f(x)
2 = − 0.007
8
R² = 0.97903
f(x)6 = − 0.027508361204013 x + 7.82943143812709 1.5
CA

R² = 0.808058110367893

ln [CA]
4 1

2
0.5
0
0 50 100 150 200 250 300 350
0
t [min] 0 50
 n
0
1
2

Orden 1 - t vs ln [CA] Orden 2

2.5
1.2

1
f(x)
2 = − 0.007585723137914 x + 2.14810059212316

R² = 0.979034427384873 f(x)0.8= 0.00295185340022

1.5
R² =0.60.96920155753243
ln [CA]

1/CA
1 0.4

0.5 0.2

0
0 0 50 100 1
0 50 100 150 200 250 300 350
t [min]
 Orden 2 - t vs 1/CA
1.2

f(x)0.8= 0.002951853400223 x + 0.042809364548495

R² =0.60.969201557532439
1/CA

0.4

0.2

0
0 50 100 150 200 250 300 350
t [min]
 Ejercicio 2 Metodo Diferencial

Metodo Diferencial
t CA log CA dCA/dt log[-dCA/dt]
0 10 1 0.00909 -2.04143612
20 8 0.90308999 0.0069928 -2.15534889
40 6 0.77815125 0.0049172 -2.30828213
60 5 0.69897 0.0038875 -2.4103296
120 3 0.47712125 0.0018443 -2.73416843
180 2 0.30103 0.0008308 -3.08050351
300 1 0 -0.0001773

Orden 0 - t vs CA
12

10
f(x) = − 8.90125E-07 x³ + 0.000540068 x²
8
− 0.111754 x + 9.93943
6 R² = 0.997515816596276
CA

0
0 50 100 150 200 250 300 350
t [min]

Metodo Diferencial
0
0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 1.1
-0.5

-1

-1.5

-2
f(x) = 1.46891436181074 x − 3.47305784445019
-2.5
R² = 0.990513867031192
-3

-3.5
 f(x) = 1.46891436181074 x − 3.47305784445019
-2.5
R² = 0.990513867031192
-3

-3.5
log CA log[-dCA/dt]
1 -2.041436116778
0.90308999 -2.155348892772
0.77815125 -2.308282127051
0.69897 -2.410329597965
0.47712125 -2.734168433745
0.30103 -3.080503512137

k
0.310

Error
97.55