IN OUT

MSW = 70°C Syn-gas =

Gasifier

Oxygen = 300°C

Ash = 900°C
HEAT IN (BY MSW) :

Mass ( Kg/hr ) = m = 10652.5

Cp ( KJ/kgK) = 2.5 Reference Characterization of Thermal Prop
Reference Temp = 30°C Jozsef Faitli, Tamas Magyar, Attila
Temp = 70°C
∆ T °C = 40 °C
Q = mCp∆T = 1065250 KJ/hr 295.9028 KW

HEAT IN (BY Oxygen) :

Mass ( Kg/hr ) = m = 4874.615

Cp ( KJ/kgK) = 0.9949 Reference Perry Chemical Engineering Hand
Reference Temp ( °C ) = 30
Temp (°C)= 300
∆ T °C = 270
Q = mCp∆T = 1309434 KJ/hr 363.7316 KW

HEAT IN (BY Steam) :

Mass ( Kg/hr ) = m = 2741.97

Latent Heat of Vap. = λ = 2350 KJ/KgK
Cp ( KJ/kgK) = 1.913 Reference Steam Table
 Reference Temp ( °C ) = 30
Temp (°C)= 152
∆ T °C = 122
Q = mCp∆T = 12966601 KJ/hr 3601.834 KW

Heat Generation ( with MSW ):

Mass ( Kg/hr ) = m = 10652.5

Cp ( KJ/kgK) = 2.5
Reference Temp = 30°C
Temp = 70°C
Temp = 1195.89
∆ T °C = 1125.89 °C
Q = mCp∆T = 29983858 KJ/hr 8328.849 KW

The heat requires to ignite MSW will be heat-in to the gasifier and it will not be considered as
Need to know the practical way of igniting the MSW based gasifier.

As;
IN - OUT + Generation
By Law of conservation of Energy
So, Equation becomes

IN - OUT + Generation = C

( 295.9028 + 363.7316 + 3601.83

 900°C Reference

Steam = 150.1 °C

HEAT OUT ( BY SYN-GAS ) :

Component Cp (at 900 ℃)

Characterization of Thermal Properties of MSW landfills
Jozsef Faitli, Tamas Magyar, Attila Erdelyi CO 1.215
CO2 1.275
N2 1.1998
H2S 1.455
H2 15.29
Ash 0.84

Σ(m*Cp) = 35277.61255
Perry Chemical Engineering Handbook Ref. Temp. = 30°C
Temp. = 900°C
∆T ( °C ) = 870
Q = mCp∆T = 30691522.92

HEAT OUT ( BY ASH ) :

Mass ( Kg/hr ) = m =
Cp ( KJ/kgK) =
Steam Table Reference Temp ( °C ) =
 Temp (°C)=
∆ T °C =
Q = mCp∆T =

8.3MW Thermal out put

er and it will not be considered as a heat geneated

IN - OUT + Generation - Consumption = Accumulation

By Law of conservation of Energy, taking Accumaltion = 0
So, Equation becomes

IN - OUT + Generation = Consumption

( 295.9028 + 363.7316 + 3601.834 ) -( 8525.423 + 229.3494 ) + ( 8328.849 −

) = + KW
3835.54490266
4261.468 8754.77243388333 8328.849
mass ( Kg/hr ) m*Cp

7898.77 9597.006
7695.31 9811.52
242.48 290.9275 Reference Perry Chemical Engineering Handbook
20.67 30.07485
1002.24 15324.25
266.47 223.8348
SUM = 35277.61

KJ/hr

°C
KJ/hr 8525.423 KW

1129.8
0.84 Reference
30
 900
870
825657.84 KJ/hr 229.3494 KW
 Water
25°C

Syn-gas
17125.95 Kg/hr
900°C Heat Exchanger

Water
97.85°C

HEAT LOAD ( Syn-gas IN )

Qsyn-gas = mCp∆T
= 17125.95 Kg/hr * 2.5 KJ/Kg.K * ( 900 - 600 )°C
= 12844462.5 KJ/hr
= 3567.90625 KW

HEAT LOAD:

Qwater = mCp∆T
Qin = Qout
12844462.5 = m(4.18)(370.85 - 298 )
= m(304.513)

m= 12844462.5/304.513
m= 42180.3420544 Kg/hr

So,
Qin = Qout
3567.9 = mCp∆T
= 42180.34 * 4.18 * (370.85 - 298 )
3567.906076 3567.90607623
 Syn-gas
17125.9595 Kg/hr
ger
600°C Reference
 MEA IN

Syn-gas
16898.39 Kg/hr
Scrubber
600°C

MEA + CO2 + Ash =

T2 = ?

MEA IN = 30°C
Massrate of CO2= 7695.29 Kg/hr
Massrate of 94% removed = 7233.575
Heat of Rection = 1533 KJ/ Kg of CO2 absorbed

Heat Librated = Heat of reaction * mass of CO 2 absorbed

= 1533 * 7233.575
= 11089070.475 KJ

massrate of MEA = 15390.58Kg/hr Ratio

Cp of MEA = 2.34 KJ/Kg Reference

Q = mCp∆T
Q = 15390.58 * 2.34 * (∆T)
11089070.48 = 15390.58 * 2.34 * ∆T

∆T = 11089070.48/(15390.58*2.34)
∆T = 307.910358709

T2 - T1 = 307.9
T2 = 307.9 - 30
T2 = 338°C
Qin = Qout
11089070.48 = 15390.58 * 2.34 * ( 308 )°C
11089070.48 ≈ 11092298.8176
 10546.77 Kg/Kg

540°C

21739.656

Kg/hr
Kg of CO2 absorbed Reference Perry's Chemical Engineering Handbook

CO 2 absorbed References

Reference OR calcuations Reference

Perry's Chemical Engineering Handbook
( Syn-gas + MEA )

10546.7718 Kg/hr Knockout Drum

813K
539.85°C

343K
70°C
MEA = 923.407 Kg/hr

Heat Capacity of Syn-gas in at 539.85 ≈ 540°C

Component Cp at 540°C

CO 1.072
CO2 1.04
N2 1.062 Reference
H2 14.525
H2S 1.01
MEA 2.34
Average Cp at 540°C = 3.508167 KJ/Kg

Heat IN By Syn-gas:
Q = 10546.779 * 3.5 * ( 539.85 - 30 )
= 18820463.46 KJ/hr
= 5227.906516 KW

Heat OUT By Syn-gas:

Q = mCp∆T

Component Cp at 437°C

CO 1.051
CO2 0.955
N2 1.046
H2 14.49
 H2S 1.01

Average Cp at 437°C = 3.7104 KJ/Kg

Q = 9623.37 * 3.71 * ( 437 - 30 )

Q = 14531000 KJ/hr
Q = 4036.39 KW

Heat OUT by MEA:

Q = 923.4087 * 2.4 * ( 70 - 30 )
Q = 88647.2352 KJ/hr
Q = 24.624 KW

HEAT LOST :

Heat Loss = Heat IN - Heat OUT

= 5229.5 - ( 4036.38 + 24.62 )
= 1168.5 KW
Syn-gas

9623.37 Kg/hr
710K
436.85°C

Perry's Chemical Engineering Handbook