Period Topics

1.        General etiquettes for CET-II -

Overview of course
2.        Objectives of reaction equilibira
DG <0 criteria; directionality of reaction
DG = 0 reversible reaction - composition
Operating window plot - of Xeq vs. Temp and process
Development - Example of quenching in NH3 reactor
3.        Concept of phase equilibira and process design
Entropy - multiple micro-constituent arrangement for given macro property
4.        Derivation of Gibbs Duhem Equation - summability relationship
5.        Discussion on Partial properties - Solution and Mixture
6.        Gibbs Duhem - Chemical Potential - Genesis behind chemical potential - example of
water evaporation from ocean and saturation in atmosphere
7.        Derivation of partial molar properties for binary component system
8.        Problems: Given V = f(x1,x2) find partial molar volumes
9.        Tangent Intercept method
Problem: Determine pure component volume to make given volume of solution (YVC
Rao - Methanol - water system)
10.    Chemical potential in terms of H, U and A
Criteria for chemical equilibrium
11.    Criteria for chemical equilibrium - Equality of chemical potential - Concept of Ideal gas
12.    Problem : Given x1 vs. V data determine partial volumes at x1 = 05, 0.75 (given x1)
Problem : Given H as polynomial function of x1, x2 determine expression for  partial
properties
Concept of ideal gas - zero volume - no point volumes
13.    Partial molar volume in ideal gas, Gibbs theorem, Def. of property on mixing DMmix
14.    Enthalpy and entropy of mixing of ideal gases
15.    Gibbs energy of mixing
16.    Gibbs energy of mixing cont; fugacity and fugacity in solution; Problem: Given mol of
gases determine Gibbs free energy of mixing
17.    Problem: Given pure component Gibbs energy (cis and trans 2 butene) determine
equilibirum composition
18.    Residual Gibbs energy, fugacity coefficient, Fugacity coefficient from Compressibility
factor
19.    Fugacity coefficient from z using virial EoS; G/RT as generating function
20.    True and false equilibrium; Fugacity as escaping tendency; Residual G/RT and its partial
derivatives
21.    Fugacity coefficient in solution, Criteria for equilibrium - different forms - for single
component and multi-component system; Problem: Given virial equation coeff -
determine fugacity and fugacity coeff
22.    Revision 1
23.    Buffer period
24.    Ideal solution as reference and its salient features
25.    Ponyting Correction Factor; ln f as partial molar property of residual Gibbs energy
26.    Partial molar gibbs energy in ideal solution, Activity coefficient; Lewis Randall rule and
Raoults law
27.    Binary component Ideal G-L system - Algorithm for generation of P-x-y at given T
28.    Problem: MeOH - EtOH : P-x-y at given T
29.    Discussion on P-x-y plot - Bubble point and Dew point definition - Genesis of distillation
 General Instructions
General Class Etiquette

1. Class will commence on time following the allotted timetable slots. Late comers are not entertained and have to lose their attendance for
that period. 

2. Students are expected to actively participate and engage in discussion. Mere physical presence in classroom does not amounts to
attendance and will not help as well to pass the course. 

3. Bring your own calculators to the class (daily)  

4. Student found disturbing other fellow classmates or indulging in non-classroom activities such as browsing net / playing on mobile shall
be dealt strictly. 

5. All announcements pertaining to the course will be through course portal. Hence students are directed to see the announcement page
regularly and/or subscribe to announcement page. Any announcement made in the course portal shall be passed on to your fellow
classmates on maturity basis 

Expectations from student 

1. If a student remains absent for a class, it is moral obligation of the student to know what happened in the class and make-up for the loss
of lecture / tutorials.

2. Lectures delivered in class is catered to average intelligence level of a class. Given the variability of students, it is quite natural that some
might not be able to understand the concepts during lectures. Hence, it is expected that students revise / go through standard books to
enhance / re-affirm their understanding of concepts or discuss among their peers. If they need further assistance, they are welcome to
contact the course instructor through e-mail / phone / meet in person in cabin 

3. Assignments / tutorial problems are meant to help students learn the subject better. Hence it is expected that students take genuine efforts
to solve the problems by themselves / consultation with their peers / referring to books. In case of genuine difficulty in solving a problem,
the student is always welcome to consult the course instructor 

Course Plan Guideline