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General Chem II Homework 1 (Mohammed Thafer Almsri)
General Chem II Homework 1 (Mohammed Thafer Almsri)
Homework # 1
Note: For Q1, Q2, Q3, and Q4 answer either (a or b)
Question one:
b. Rank the following in order of increasing surface tension (at room temperature): (a)
CH3OH, (b) HOCH2CH2OH; (c) CH3CH2OCH2CH3
Answer : b , a , c
Question two
b. Butanol and pentane have approximately the same mass, however, the viscosity (at 20 ºC) of
butanol is η = 2.948 cP, and the viscosity of pentane is η = 0.240 cP. Explain this difference.
Answer : because butanol has hydrogen bond with OH , dipole-dipole force and dispersion forces
but pentane just have dispersion forces .
Question three
a. The enthalpy of vaporization of benzene, C6H6 (l), is 33.9 kJ mol‒1 at 298 K. How many liters
of C6H6 (g), measured at 298 K and 95.1 mmHg, are formed when 1.54 kJ of heat is absorbed by
C6H6 (l) at constant temperature of 298 K?
# of moles for C6H6 =
( )( )( )
Question four
a. The normal boiling point of acetone, an important laboratory and industrial solvent, is
56.2 °C and its ΔvapH is 25.5 kJ mol‒1. At what temperature does acetone have a vapor
pressure of 375 mmHg?
Answer : ( )
( )
Question five
How much heat is required to raise the temperature of 215 g CH3OH from 20.0 to 30 ºC and
then vaporize it at 30 ºC? Use ΔvapH for CH3OH (l) = 38.0 kJ mol–1 and specific heat for
CH3OH (l) of 2.53 J g‒1 K‒1.
Answer :
Good luck!