1st year Test Chemistry Chapter # 9-11

Short questions
i. Aqueous of CH 3 COONa is basic in nature. Justify it.
ii. What are hydrates? How they are formed?
iii. Solubility of glucose increase in water by heating. Give reason.
iv. Why freezing point is depressed due to presence of solute?
v. Why is the vapor pressure of a solution is less than pure solvent?
vi. The sum of the coefficients of a balanced chemical equation is not necessarily important to give order of
reaction. Justify.
vii. Differentiate between enthalpy of reaction and energy of activation of reaction.
viii. The radioactive decay is always a first order reaction. Explain.
ix. A particular catalyst is suitable for a particular chemical reaction. Justify it.
x. What is specific rate constant or velocity constant?
xi. Give the chemistry of electrolysis of aqueous solution of sodium chloride.
xii. How impure copper can be purified by electrolysis?
xiii. SHE acts as anode when connected with Cu electrode but as cathode when connected with Zn electrode.
Justify.
xiv. Zn can displace hydrogen from dilute acid solution but copper cannot. Justify the statement.
xv. Differentiate between electrolytic and voltaic cell.
Long questions
1. Write a note on charging and discharging of lead acid battery.
2. Write down the working and reactions of fuel cell.
3. Describe galvanic cell explaining the functions of electrodes and the salt bridge.
−¿ + MNO ¿
2
−¿ →CN O
4. Balance the following ionic equations by ion-electron method: C N −¿+ Mn O
¿
4
¿

2nd year Test Chemistry Chapter # 7-10

Short questions
1. How would you distinguish 1-Butyne and 2-Butyne?
2. How vicinal dihalides are converted into corresponding alkynes?
3. How do you convert alkynes into cis and trans alkenes?
4. How does sodamide react with alkynes? What are the applications of this reaction?
5. Justify that the order of reactivity of alcohols for dehydration purposes as follows: Ter. Alc.> Sec. alc. >
Pri. Alc.
6. The nitration of higher hydrocarbons breaks the C-C bond. How HN O3 reacts with C H 4 ?
7. How many alkyl groups can be generated by an alkane with molecular formula C 4 H 10?
8. Why the saturated hydrocarbons act as good fuels?
9. What is sigma complex?
10. What is the role of FeC l 3 and AlC l 3 in electrophilic substitution reactions?
11. Give the mechanism of sulphonation and nitration of benzene.
12. Give the general pattern of the reaction of S N 2 mechanism. What is its rate expression? Give example.
13. What is the role of steric hinderance to decide about S N 1 and S N 2 mechanism?
14. What is the role of stability of carbonium ion for determining S N 1 or S N 2 mechanism?
15. How the nature of alkyl group changes when alkyl halide is converted to Grignard’s reagent?
Long questions
1. What is orbital hybridization? Explain sp3mode of hybridization of carbon.
2. Discuss acidic nature of alkynes with at least two examples.
3. What is meant by orientation? Why certain substituents are ortho and para directive and others are meta
directive giving one example.
4. Define elimination reactions and discuss the mechanism of E2 reactions.
Sr. # Questions A B C D
1 Normal human body temperature is: 37 ℃ 986 ℃ 37 ℉ 273 K
127 ℃ and 1 0 ℃ and 2 273 ℃ and 2
9 The molar volume of CO 2 is maximum at: STP
atm atm atm
The order of rate of diffusion of gases
10 NH 3> CO2 > SONH 3>2 SO 2 >CO 2Cl 2 > SO 2 >CO2 >
2 >Cl NHNH3>3 CO2 >Cl 2 ¿ SO 2
NH 3 , SO2∧CO2 is:
William
11 In 1879, plasma was identified by scientist: John Dalton Chadwick Soddy
Crooks
If both “a” “a” is small “a” is large
A real gas obeying Vander Waal’s equation Both “a” and
12 and “b” are and “b” is and “b” is
will resemble ideal gas if: “b” are small
large large small
The deviation of gas from ideal behavior is −10 ℃ and −10 ℃ and 100 ℃ and 0 ℃ and 2.0
13
maximum at: 5.0 atm 2.0 atm 2.0 atm atm
Escape out of gas molecules one by one
20 Diffusion Effusion Osmosis All of these
through tiny hole is:
21 Which gas will diffuse more rapidly: HCl CO 2 NH 3 SO 2
The pair of gases which do not obey NH 3 and
22 Dalton’s law of partial pressure under H 2 and O2 H 2 and He He and Ne
normal condition is: HCl
Number of molecules in one dm 3 of water is 6.02 23 12.04 23 18
23 10 10 10 23 55.6 ×6.02 ×1023
closed to: 22.4 22.4 22.4
280 cm3 of
CO 2 and 11.2dm3 of 44 g of CO 2
Which of the following will have the same 28 g of N 2 and
24 O2 and 32 g and 11.2dm 3
number of molecules at STP: 280 cm3 of 5.6 dm3 of O2
of O 2 of CO
N2 O
Lone pair of Pyramidal Enhanced
NH 3 shows a maximum boiling point among Very small
electrons structure of electronegative
25 size of
the hydrides of 5th group elements due to: present on NH 3 character of
nitrogen
nitrogen nitrogen